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The Time-Varying Variation Characteristics of Methane during Nitrogen Injection Process: An Experimental Study on Bituminous Coals 注氮过程中甲烷的时变特性:沥青煤的实验研究
IF 1.7 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2023-12-11 DOI: 10.1155/2023/5075888
Aoxiang Zhang, Longyong Shu, Zhonggang Huo, Xin Song
The existing research on CH4 displacement by N2 mainly focuses on the gas injection displacement mechanism and the factors affecting displacement efficiency. And most of them are theoretical analyses at the model level or multifactor analyses at the simulation test level, while there are few targeted physical simulation tests and quantitative analyses. Given the above problems, the experiment system was used to study the gas migration evolution law and time-varying characteristics of CH4 displacement by N2 in coal under different injection pressures. The experimental results show that the whole process of CH4 displacement by N2 can be divided into three stages: stage I (original equilibrium stage); stage II (dynamic balance stage); stage III (new equilibrium stage). The concentration of CH4 and N2 presents an opposite variation trend, and the variation rate of CH4 and N2 increased first and then decreased. The breakthrough time was 50 minutes, 45 minutes, 35 minutes, 25 minutes, and 20 minutes, respectively, under different injection pressures. The displacement efficiency increased with the injection pressures, while the replacement ratio decreased with the injection pressures. The maximum flow rate of CH4 was 0.085 mL/min, 0.110 mL/min, 0.130 mL/min, 0.222 mL/min, and 0.273 mL/min, respectively, under different injection pressures. The accumulated production of CH4 was 3.59 mL, 3.91 mL, 4.39 mL, 5.58 mL, and 5.94 mL, respectively, under different injection pressures. The effective injection pressure range was 1.6~2 MPa. This research can provide a reference for the theoretical research of N2-ECBM-related technology in low permeability reservoirs and the selection of injection pressure in the field technology implementation.
现有的 N2 对 CH4 的置换研究主要集中在气体注入置换机理和影响置换效率的因素上。且多为模型层面的理论分析或模拟试验层面的多因素分析,有针对性的物理模拟试验和定量分析较少。鉴于上述问题,本文利用实验系统研究了不同注入压力下煤中 N2 置换 CH4 的气体迁移演化规律和时变特征。实验结果表明,N2置换CH4的整个过程可分为三个阶段:第一阶段(原始平衡阶段);第二阶段(动态平衡阶段);第三阶段(新平衡阶段)。CH4 和 N2 的浓度呈相反的变化趋势,CH4 和 N2 的变化率先增大后减小。在不同注入压力下,突破时间分别为 50 分钟、45 分钟、35 分钟、25 分钟和 20 分钟。置换效率随注入压力的增加而提高,置换率则随注入压力的增加而降低。在不同注入压力下,CH4 的最大流速分别为 0.085 mL/min、0.110 mL/min、0.130 mL/min、0.222 mL/min 和 0.273 mL/min。在不同的注入压力下,CH4 的累积产量分别为 3.59 mL、3.91 mL、4.39 mL、5.58 mL 和 5.94 mL。有效注入压力范围为 1.6~2 MPa。该研究可为低渗透油藏中 N2-ECBM 相关技术的理论研究和现场技术实施中注入压力的选择提供参考。
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引用次数: 0
Influence of the Three Gorges Reservoir Impoundment on Xiannvshan Fault Activity 三峡水库蓄水对仙女山断层活动的影响
IF 1.7 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2023-12-06 DOI: 10.1155/2023/6611611
Zhang Jiayu, Zhang Lili, Zhang Yaowen, Yao Yunsheng, Li Haoran, Dai Yiming, Wang Renlong, Hu Caixiong
Since the initial impoundment and commissioning of the Three Gorges Reservoir in June 2003, seismic activity surrounding the reservoir region has undergone substantial changes. Leveraging geological and hydrogeological data from the Three Gorges Reservoir area, this study statistically analyzes the historical water level and earthquake catalog within the reservoir. By examining the correlation between reservoir water levels and earthquake frequency, the relationship between seismicity along the Xiannvshan fault and water level is analyzed. Additionally, the ArcGIS software is employed to evaluate the spatial pattern of earthquake epicenters during the filling of the Three Gorges Reservoir, with the goal of elucidating the impact of water impoundment at the Three Gorges on the activity along the Xiannvshan fault. The results demonstrate the following. (1) There is a complex process of “continuous loading, permeation and saturation, rebound and rebalancing” in the crust of the reservoir head area during the impoundment of the Three Gorges Reservoir area, and the activity of the Xiannvshan fault is closely related to the reservoir water level. (2) At the 135 m impoundment stage, Xiannvshan fault activity is mainly affected by reservoir water level and is positively correlated with reservoir water level. At the 156 m impoundment stage, reservoir water load is still the main influencing factor of Xiannvshan fault activity, but the permeability of reservoir water is enhanced in this stage. (3) The earthquake epicenters near the northern section of the Xiannvshan fault are clustered during the 175 m experimental impoundment stage. During the continuous loading stage, the reservoir water load is still the main control factor of the Xiannvshan fault, and the seismic activity is significantly enhanced. From November 2010 to November 2013, during the permeation and saturation stage, the dominant factor of Xiannvshan fault activity changed from reservoir water load to reservoir water infiltration along the Xiannvshan fault. The period from 2013.11 to 2014.5 was a vertical rebound stage, and the infiltration effect of reservoir water had a more significant impact on Xiannvshan fault activities.
三峡水库自2003年6月蓄水投产以来,库区周边地震活动发生了较大变化。利用三峡库区地质水文地质资料,对库区历史水位和库区地震目录进行了统计分析。通过考察水库水位与地震频率的相关性,分析了仙女山断裂带地震活动性与水位的关系。此外,利用ArcGIS软件对三峡水库蓄水过程中地震震中的空间格局进行评价,以阐明三峡蓄水对仙女山断层活动的影响。结果显示如下。(1)三峡库区蓄水过程中,库头区地壳存在“连续加载-渗透-饱和-反弹-再平衡”的复杂过程,仙牛山断裂活动与库区水位密切相关。(2)在135 m蓄水阶段,仙女山断层活动主要受水库水位影响,与水库水位呈正相关。在156 m蓄水阶段,水库水负荷仍是仙女山断层活动的主要影响因素,但该阶段水库水渗透率有所增强。(3)在175 m实验蓄水阶段,仙女山断层北段附近地震震中集中。在连续加载阶段,水库水荷载仍是仙女山断裂的主要控制因素,地震活动性明显增强。2010年11月至2013年11月,在渗透和饱和阶段,仙女山断层活动的主导因素由水库水负荷转变为沿仙女山断层的水库水入渗。2013年11月~ 2014年5月为垂直回弹阶段,水库水的入渗作用对仙女山断层活动的影响更为显著。
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引用次数: 0
Feasibility of Tunnel TEM Advanced Prediction: A 3D Forward Modeling Study 隧道瞬变电磁法超前预测的可行性:三维正演模拟研究
IF 1.7 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2023-11-28 DOI: 10.1155/2023/8486173
Jiannan Fu, Xiaodong Yang, Guanqun Zhou, Xueliang Jin, Fuqin Zhai, Fanbin Meng, Yafei Wang
The transient electromagnetic (TEM) method has long been applied in tunnel advanced prediction. However, it remains questionable to what extent a geologic anomaly body will influence the induced electromagnetic response in front of the heading face. The dilemma is partly because observed TEM data are frequently interpreted by empirical formulas or proportional relationships, and a quantitative measurement has not been established. In this paper, we strive to understand the TEM characteristics from a 3D finite-element time-domain (FETD) modeling aspect. The modeling algorithm is based on unstructured space meshing and unconditional stable time discretization, which ensures its accuracy and stability. The modeling algorithm is verified by a half-space model, in which the misfit of late-time channels that we are concerned with is generally below 1%. The algorithm has also been utilized to carry out the TEM response of tunnel models with different types of TEM devices. Through model studies, we find that both the traditional central-loop device and the recently developed weak-coupling opposing-coil device are feasible in tunnel advanced detection. Nevertheless, the latter type of device better distinguishes low-resistivity anomalies at 30 m ahead of the heading face with a relative difference (between models with and without the anomaly) of more than 1000% at certain time channels, compared with only a 10% difference of the central-loop device. Also, we conclude that the vertical electromagnetic field component should be recorded and interpreted together with the horizontal field to provide more convincing results.
瞬变电磁法在隧道超前预测中应用已久。然而,地质异常体对掘进工作面前方感应电磁响应的影响程度尚不明确。造成这种困境的部分原因是观测到的透射电镜数据经常用经验公式或比例关系来解释,而且还没有建立定量测量方法。在本文中,我们努力从三维有限元时域(FETD)建模的角度来理解瞬变电磁法的特征。该建模算法基于非结构化空间网格化和无条件稳定时间离散化,保证了建模的精度和稳定性。通过半空间模型对建模算法进行了验证,在半空间模型中,我们所关注的晚时信道的失配率一般在1%以下。该算法还应用于不同类型瞬变电磁法装置下隧道模型的瞬变电磁法响应。通过模型研究,我们发现传统的中心环装置和新开发的弱耦合对线圈装置在隧道超前探测中都是可行的。然而,后一种装置更好地识别了迎头前方30 m处的低电阻率异常,在某些时间通道上(有异常和没有异常的模型之间)的相对差异超过1000%,而中心环装置的差异仅为10%。此外,我们认为垂直电磁场分量应与水平场一起记录和解释,以提供更有说服力的结果。
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引用次数: 0
Fine Detection and Analysis of Hidden Karst in Wellsite with Quasi-Three-Dimensional TDEM Based on Lateral Constraint 基于横向约束的准三维TDEM井场隐伏岩溶精细探测与分析
IF 1.7 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2023-11-22 DOI: 10.1155/2023/2766524
Bin Wu, Yunping Liao, Hongkai Chen, Lichuan Chen, Shicong Ren, Shihong Xiao, Yunjian Yang, Yong Yang, Haiyou Peng
Considering that karst caves, underground rivers, and dissolution fractures in shallow carbonate formation in the Sichuan Basin are extremely developed, leakage, failure and plugging difficulties are easy to occur in the drilling process. The TDEM was used to carry out the exploration of hidden karst geological bodies in well QM2, and the quasi-three-dimensional inversion based on lateral constrain was used to invert the TDEM data. Three NW trending anomalous bands were identified in the lower Triassic Jialingjiang Formation within the range of drilling, consisting of seven relatively low-resistivity anomalous zones. Under the guidance of TDEM quasi-three-dimensional inversion resistivity data, the low-resistivity karst development area is avoided, and the specific drilling location of well QM2 is determined. No karst cave and underground river were drilled in the later drilling process of well QM2, as well as no instability phenomenon occurred. It indicates that the TDEM detection results are consistent with the actual drilling, and the quasi-three-dimensional TDEM inversion interpretation data based on lateral constraints is reliable and can accurately detect the buried karst in the wellsite.
四川盆地浅层碳酸盐岩地层溶洞、地下河、溶蚀裂缝极为发育,钻井过程中容易出现渗漏、破坏、堵漏等困难。利用TDEM对QM2井隐蔽岩溶地质体进行勘探,采用基于横向约束的准三维反演方法对TDEM数据进行反演。在钻探范围内,发现下三叠统嘉陵江组有3条北西向异常带,共7个相对低电阻率异常带。在TDEM准三维反演电阻率数据指导下,避开低电阻率岩溶发育区域,确定QM2井的具体钻井位置。QM2井后期钻探过程中未钻出溶洞和地下河,未发生失稳现象。结果表明,TDEM探测结果与实际钻井吻合,基于侧向约束的准三维TDEM反演解释数据可靠,能够准确探测井场埋藏岩溶。
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引用次数: 0
Well-Testing Model for Dual-Porosity Reservoir considering Stress-Sensitivity and Elastic Outer Boundary Condition 考虑应力敏感性和弹性外边界条件的双重孔隙度油藏试井模型
IF 1.7 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2023-11-16 DOI: 10.1155/2023/4658604
Song Chol Kim, Song Guk Han, Yong Il Song, Jin Sim Kim, Myong Gun Hong
Stress sensitivity and the elastic outer boundary (EOB) condition have a great effect on the analysis of the characteristics of the fluid flow in a reservoir. When researchers analyzed the characteristics of the fluid flow, they have considered the stress sensitivity and the EOB condition separately but have not considered them simultaneously. Therefore, errors are inevitable during the analysis of well testing. The main object of this work is to present a well-testing model for stress-sensitivity dual-porosity reservoir (DPR) with EOB to improve the accuracy of the analysis of well-testing data. To this end, in this paper, we established a well-testing model for the DPR, considering the stress sensitivity and the EOB simultaneously, and presented its semianalytical solution. On the basis of the consideration of the EOB condition and stress sensitivity of permeability (SSP), a seepage model for the DPR with the EOB is built using the continuity equation, motion equation, state equation, and interporosity flow equation between matrix and fracture, which considers the stress sensitivity, wellbore storage, and skin. To solve this model, a nonlinear partial differential equation is changed into a linear form of a partial differential equation by introducing an effective well radius and applying Pedrosa’s transformation and perturbation transformation. Applying the Laplace transformation, an analytical solution in the Laplace space is obtained, and curves of pressure and pressure derivative (PPD) are drawn by numerically inverting them. The model is verified by comparing it with the EOB without consideration of SSP and using case data. The sensitivity of parameters on the curves of PPD is analyzed. This work may be significant for evaluating more accurately the parameters of wells and reservoirs using well testing.
应力敏感性和弹性外边界条件对储层流体流动特征的分析有很大影响。研究人员在分析流体流动特性时,分别考虑了应力敏感性和EOB条件,而没有同时考虑。因此,在试井分析中,误差是不可避免的。本文的主要目的是建立具有EOB的应力敏感性双孔储层试井模型,以提高试井数据分析的准确性。为此,建立了同时考虑应力敏感性和EOB的DPR试井模型,并给出了该模型的半解析解。在考虑EOB条件和渗透率应力敏感性的基础上,利用连续方程、运动方程、状态方程和基质与裂缝间渗流方程,综合考虑应力敏感性、井筒储集性和表皮,建立了含EOB的DPR渗流模型。为求解该模型,引入有效井半径,应用Pedrosa变换和微扰变换,将非线性偏微分方程转化为线性形式的偏微分方程。应用拉普拉斯变换,得到了Laplace空间的解析解,并对压强和压强导数(PPD)进行数值反演,绘制出了压强和压强导数(PPD)曲线。将该模型与不考虑SSP的EOB模型进行了比较,并利用实例数据对模型进行了验证。分析了参数对PPD曲线的敏感性。这项工作对于通过试井更准确地评价井和储层参数具有重要意义。
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引用次数: 0
Heat Transfer Analysis of Enhanced Geothermal System Based on Heat-Fluid-Structure Coupling Model 基于热-流-固耦合模型的增强型地热系统传热分析
IF 1.7 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2023-11-16 DOI: 10.1155/2023/8840352
Linchao Wang, Xin Liang, Xuyang Shi, Jianyong Han, Yang Chen, Wan Zhang
Dry hot rock geothermal resources by virtue of its wide distribution, large reserves, clean and low-carbon, stable, high utilization rate, and other characteristics have been widely used. The enhanced geothermal system (EGS) is the most efficient approach for harnessing and exploiting geothermal energy from hot, arid rock formations. To investigate the impact of varying parameters on heat recovery in EGS operations, we employed the COMSOL numerical simulation software to construct a seepage heat transfer model for fractured rock masses. Essential parameters and boundary conditions were established, followed by conducting numerical simulations. Through the numerical simulation results, the temporal and spatial changes of coupling effects among seepage field, stress field, and temperature field in fractured rock mass were analyzed. We investigated the impact of water injection temperature, injection-production pressure difference, injection flow rate, and initial reservoir temperature on the heat transfer process. The findings indicate that raising the water injection temperature and injection-production pressure difference can enhance the reservoir’s heat recovery capability. However, it may also accelerate thermal breakthrough and reduce the system’s operational lifespan. The higher injection flow rate can improve the heat recovery efficiency. However, too large injection flow can cause problems in other aspects of the reservoir; increasing reservoir temperature leads to higher production temperatures, which can potentially result in dynamic catastrophes. Therefore, while ensuring the heat recovery efficiency of the system, the operation life of the system can be extended by adjusting the water injection temperature in stages, setting a reasonable injection and production pressure difference, and selecting an appropriate injection flow rate, so as to achieve the purpose of EGS optimization.
干热岩地热资源凭借其分布广、储量大、清洁低碳、稳定、利用率高等特点得到了广泛的应用。增强型地热系统(EGS)是利用和开发高温干旱岩层地热能的最有效方法。为了研究不同参数对EGS作业热回收的影响,我们利用COMSOL数值模拟软件建立了裂隙岩体的渗流传热模型。建立了基本参数和边界条件,并进行了数值模拟。通过数值模拟结果,分析了裂隙岩体渗流场、应力场和温度场耦合效应的时空变化规律。研究了注水温度、注采压差、注入流速和储层初始温度对换热过程的影响。研究结果表明,提高注水温度和注采压差可以提高储层的热采能力。然而,它也可能加速热突破,缩短系统的使用寿命。较高的注射流量可以提高热回收效率。然而,过大的注入流量可能会导致储层其他方面的问题;储层温度的升高会导致生产温度的升高,这可能会导致动态灾难。因此,在保证系统热回收效率的同时,通过分阶段调整注水温度,设置合理的注采压差,选择合适的注入流量,可以延长系统的运行寿命,从而达到EGS优化的目的。
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引用次数: 0
Fracture Initiation and Propagation in the Hot Dry Rock Subject to the Cyclic Injection Hydraulic Fracturing Treatment 干热岩石循环注入水力压裂裂缝萌生与扩展研究
IF 1.7 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2023-11-16 DOI: 10.1155/2023/8859177
Yilong Yuan, Wei Wang, Jiawei Tang, Qiang Guo, Yulong Liu
Cyclic injection hydraulic fracturing is a promising way for the geothermal energy exploitation by reactivating the fractures in geothermal reservoir. However, fracture initiation and growth induced by cyclic injection schemes have been inadequately studied for hot dry rock (HDR), and the cyclic injection fracturing optimized often by experience. For this reason, the initiation and propagation of hydraulic fractures in the HDR under different cyclic injection methods were determined by experiment research for hydraulic fracturing. The results show that the cyclic frequency and injection rate play different roles in the stimulation of HDR. The cyclic injection with low frequency-low pressure can create more branched fractures, forming a short but complex hydraulic fracture network. However, when high flow-high frequency injection method is subjected, the branch fractures formed are significantly reduced, but each branch fracture can be fully expanded. To fully exploit the advantages of different injection methods, a numerical model that contains a fracture network was established with PFC software, and an alternating cyclic injection scheme with synergistic control of the cyclic frequency and injection rate was proposed. The comparison results indicated that the alternating cyclic injection method can effectively improve the fracturing effect in the HDR. The stimulation area of the alternating cyclic injection method is about 2.3 times and 2.7 times that of the low flow-low frequency and high flow-high frequency injection methods, respectively. The method presented here can be adopted to optimize the fracture growth regime and provide a scientific basis for EGS hydraulic fracturing design.
通过激活地热储层裂缝,循环注入水力压裂是一种很有前途的地热能源开发方法。然而,对于热干岩(HDR),循环注入方案对裂缝的起裂和扩展的研究还不够充分,循环注入压裂的优化往往依靠经验。为此,通过水力压裂实验研究,确定了不同循环注入方式下HDR水力裂缝的起裂和扩展情况。结果表明,循环频率和注入速度对HDR的刺激有不同的作用。低频低压循环注入可形成更多分支裂缝,形成短而复杂的水力裂缝网络。而在高流量-高频注入方式下,形成的分支裂缝明显减少,但每个分支裂缝都能得到充分扩展。为了充分发挥不同注入方式的优势,利用PFC软件建立了含裂缝网络的数值模型,提出了循环频率和注入速度协同控制的交替循环注入方案。对比结果表明,交替循环注入方法可以有效改善HDR的压裂效果。交替循环注入法的增产面积分别约为低流量-低频注入法和高流量-高频注入法的2.3倍和2.7倍。该方法可用于优化裂缝发育状态,为EGS水力压裂设计提供科学依据。
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引用次数: 0
The Impact of Microscopic Pore Network Characteristics on Movable Fluid Properties in Tight Oil Reservoir 致密油储层微观孔隙网络特征对可动流体性质的影响
4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2023-11-14 DOI: 10.1155/2023/7464640
Jie Gao, Hu Wang, Xiaojun Ding, Qingxiao Yuchi, Qiang Ren, Bo Ning, Junxiang Nan
The fluid flow behavior, generally referred to as seepage, could determine the hydrocarbon and brine movement behavior. Movable fluid property, as one of the vital parameters for seepage characteristic evaluation, was generally used for tight oil reservoirs’ fluid flow ability assessment. The nuclear magnetic resonance technique was used to experiment with movable fluid percentage and movable fluid porosity, which can provide a realistic assessment of the amount of fluid that can flow in the porous media. Other techniques were also used to analyze the main factors in regulating the differences in movable fluid parameters. However, the research about fluid flow behavior was generally based on traditional methods, while the seepage characteristics from the pore-scale view are still a myth. To promote this process, in this study, core samples obtained from the Chang 7 reservoir of the Triassic Yanchang Formation in the Longdong region of Ordos Basin, China, were tested. The results show that the average movable fluid percentage and average movable fluid porosity of the total 16 core samples are 36.01% and 2.77%, respectively. The movable fluid exists mainly in the midlarge pores with the corresponding T 2 relaxation time over 10 ms. T 2 distributions mainly present four typical patterns: (1) bimodal distribution with similar amplitudes of the two peaks (occupying 6.25%), (2) bimodal distribution with higher right peak and lower left peak (occupying 18.75%), (3) bimodal distribution with higher left peak and lower right peak (occupying 56.25%), and (4) unimodal distribution (occupying 18.75%). Pore structure heterogeneity is closely related to the movable fluid parameters; the movable fluid parameters exhibit a relatively good correlation with core throat radius as well as permeability. There is an obvious difference between the movable fluid parameters and the microscopic characteristic factors in tight oil reservoirs due to the difference in physical properties, clay mineral content, microcracks, and pore structure characteristics. This research has provided a new perspective for the movable fluid property evaluation, and the relevant results can give some advice for the oil field development.
流体的流动行为,一般称为渗流,可以决定油气和盐水的运移行为。可动流体属性作为渗流特性评价的重要参数之一,通常用于致密油储层流体流动能力评价。利用核磁共振技术对可动流体百分比和可动流体孔隙度进行实验,可以对可在多孔介质中流动的流体量进行真实评估。其他技术也用于分析调节可动流体参数差异的主要因素。然而,对流体流动特性的研究一般是基于传统的方法,而从孔隙尺度的角度来研究渗流特征仍然是一个迷。为了促进这一进程,本研究对鄂尔多斯盆地陇东地区三叠系延长组长7储层的岩心样品进行了测试。结果表明,16个岩心样品的平均可动流体百分比和平均可动流体孔隙度分别为36.01%和2.77%。可动流体主要存在于中大型孔隙中,相应的t2弛豫时间大于10 ms。t2分布主要呈现四种典型模式:(1)两峰振幅相近的双峰分布(占6.25%),(2)右峰高左峰低的双峰分布(占18.75%),(3)左峰高右峰低的双峰分布(占56.25%),(4)单峰分布(占18.75%)。孔隙结构非均质性与可动流体参数密切相关;可动流体参数与岩心喉道半径和渗透率具有较好的相关性。由于物性、粘土矿物含量、微裂缝、孔隙结构特征等方面的差异,致密油储层可动流体参数与微观特征因素存在明显差异。该研究为可动流体物性评价提供了一个新的视角,相关研究结果对油田开发具有一定的指导意义。
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引用次数: 0
Influence of Water Saturation on Adsorption Behavior at Liquid-Liquid Interfaces in Unsaturated Porous Media 水饱和度对非饱和多孔介质液-液界面吸附行为的影响
4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2023-11-09 DOI: 10.1155/2023/8155349
Yan Zhu, Ziteng Cui, Kun Li, Chaoqi Wang, Zhao Li, Xueyi Zhang, Zhi Dou
Adsorption reaction in unsaturated porous media is of great importance for soil and groundwater remediation. In this study, the influence of the Peclet number (Pe) and water saturation on adsorption behavior at liquid-liquid interfaces was quantitatively investigated. The pore-scale reactive transport in unsaturated porous media was directly simulated. The Navier-Stokes equations, the surface transfer and adsorption reaction equations, and the advection-diffusion equation (ADE) were coupled to obtain the flow and concentration fields. The results showed that water saturation had a significant influence on the complexity of the flow field. A nonmonotonic relationship was found between water saturation and the uniformity of the flow field. Peclet number had little influence on the maximum adsorption. On the other hand, the adsorption time showed a nearly linear relationship with the Peclet number and increased with increasing Peclet number. Additionally, a nonlinear relationship was found between water saturation and the maximum adsorption. As water saturation increased, the maximum adsorption tended to increase to a peak and then decrease. The peak of the maximum adsorption occurred at Pe = 5 , S w = 0.458 , and the shortest adsorption time was observed at S w = 0.902 . However, the difference in adsorption times for saturations of 0.458 and 0.698 was not significant and was only about 20 PV difference.
非饱和多孔介质中的吸附反应对土壤和地下水的修复具有重要意义。在本研究中,定量研究了Peclet数(Pe)和水饱和度对液-液界面吸附行为的影响。直接模拟了非饱和多孔介质中孔隙尺度的反应输运过程。将Navier-Stokes方程、表面转移和吸附反应方程、平流扩散方程(ADE)耦合得到了流动场和浓度场。结果表明,含水饱和度对流场的复杂程度有显著影响。发现含水饱和度与流场均匀性之间存在非单调关系。Peclet数对最大吸附量影响不大。另一方面,吸附时间与Peclet数呈近似线性关系,并随着Peclet数的增加而增加。此外,含水饱和度与最大吸附量之间存在非线性关系。随着含水饱和度的增加,最大吸附量呈先增大后减小的趋势。最大吸附峰出现在Pe = 5, S w = 0.458, S w = 0.902时吸附时间最短。而饱和度0.458和0.698的吸附次数差异不显著,仅相差约20 PV。
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引用次数: 0
Investigation of the Impact of Leaching Agent Concentration and pH on the Stability of Agglomeration of Ion-Absorbed Rare Earth Deposits 浸出剂浓度和pH对离子吸附型稀土矿床团聚稳定性影响的研究
4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2023-10-25 DOI: 10.1155/2023/6333122
Zhongquan Gao, Yunzhang Rao, Liang Shi, Xiaoming Zhang, Run Xiang
Ion-absorbed rare earth deposits react with the leaching agent during the in situ leaching process through ion exchange and hydration, which change the stability of ore agglomerates and even result in mining slopes or landslides. Indoor simulated column leaching assays were conducted on ion-absorbed rare earth deposit samples by using magnesium sulfate solution as the leaching solution. Surface zeta potential, double electric layer thickness, particle gradation, and pore structure were analyzed to measure the different concentrations and pHs of leaching solutions’ impact on the stability of ore agglomerates. Results show that the critical magnesium sulfate solution concentration and pH affecting the stability of deposit sample agglomerates are 3.5% and 4, respectively. The chemical replacement reaction between the leaching agent and rare earth ions occurs during column leaching when it reaches its zero-point potential at a pH of 3.5168. This breaks the balance between the van der Waals gravitational force and double-layer repulsion in clay particles and induces the disruption of agglomerates, which causes the difference in the pore radius ratio of the ore samples before and after column leaching. It is of great engineering guidance to solve the problems of slope instability and landslides that may occur in the ore body during the mining process of ionic rare earth ore.
离子吸附型稀土矿床在原地浸出过程中与浸出剂发生离子交换和水化反应,改变矿团的稳定性,甚至造成采矿边坡或滑坡。以硫酸镁溶液为浸出液,对离子吸附型稀土矿床样品进行了室内模拟柱浸出试验。通过分析表面zeta电位、双电层厚度、颗粒级配和孔隙结构,考察浸出溶液不同浓度和ph值对矿石团聚体稳定性的影响。结果表明:影响矿床样品团聚体稳定性的硫酸镁溶液临界浓度为3.5%,pH值为4%;当浸出剂在pH为3.5168时达到零点电位时,浸出剂与稀土离子发生化学取代反应。这打破了粘土颗粒中范德华引力与双层斥力之间的平衡,导致团聚体破碎,导致柱浸前后矿样孔隙半径比的差异。对解决离子型稀土矿开采过程中矿体可能出现的边坡失稳和滑坡问题具有重要的工程指导意义。
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Geofluids
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