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The jadeitites from Syros and Tinos, Cycladic Blueschist Unit, Greece: field observations, mineralogical, geochemical and geochronological characteristics 希腊基克拉迪蓝片单元Syros和Tinos的硬玉岩:野外观察、矿物学、地球化学和年代学特征
3区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2023-10-16 DOI: 10.1017/s0016756823000602
Michael Bröcker
Abstract This study illustrates the field relationships of jadeitite-bearing block-in-matrix sequences on Syros and Tinos, Cycladic Blueschist Unit, and adds additional U–Pb zircon ages for jadeitites to the geochronological database. The results confirm the importance of Cretaceous ( c. 80 Ma) and Eocene ( c. 50 Ma) processes in their geological evolution. Interpretations suggesting that the jadeitites were formed by complete metasomatic replacement of a pre-existing rock are not fully supported by field observations. In at least some cases, the formation of jadeitite is likely due to precipitation from Na-Al-Si-rich aqueous fluids, which also caused variable metasomatic alteration of the host rock. Unambiguous age constraints for formation of the Syros and Tinos jadeitites are not available. A relationship to Eocene blueschist facies metamorphism recorded in the associated metamafic rocks seems plausible. However, since high-pressure overprinting of pre-Eocene jadeitite is also conceivable, there is a much larger time window for jadeitite formation, framed by Cretaceous ( c. 80–76 Ma) protolith ages of various mélange blocks and the waning stages of blueschist facies metamorphism ( c. 40 Ma). Field observations are consistent with the interpretation that the mélange-like occurrences on Syros and Tinos record, to varying extent, multi-stage processes that include detachment of mafic rocks from the subducting plate, local infiltration of Na-Al-Si-rich aqueous fluids, exhumation via a serpentinitic matrix in a subduction channel and reworking of the primary block-in-matrix fabric by sedimentary or tectonic processes during accretionary wedge formation.
摘要本研究阐明了基克拉迪蓝片单元Syros和Tinos上含翡翠岩块状基质层序的场域关系,并将翡翠岩的U-Pb锆石年龄添加到其年代学数据库中。结果证实了白垩纪(约80 Ma)和始新世(约50 Ma)过程在其地质演化中的重要性。有关硬玉岩是由先前存在的岩石完全交代取代而形成的解释,并没有得到实地观察的充分支持。至少在某些情况下,翡翠岩的形成可能是由于富na - al - si水溶液的沉淀,这也导致了寄主岩石的可变交代蚀变。对于Syros和Tinos硬玉的形成,没有明确的年龄限制。与伴生变质岩中记录的始新世蓝片岩相变质作用的关系似乎是可信的。然而,由于前始新世翡翠岩的高压叠印也是可能的,因此,根据白垩纪(约80-76 Ma)各种岩块的原岩年龄和蓝片岩相变质作用的减弱阶段(约40 Ma),翡翠岩形成的时间窗要大得多。野外观测结果与解释一致,即Syros和Tinos上的msamulange样产状在不同程度上记录了多阶段的过程,包括基性岩从俯冲板块分离、富na - al - si含水流体的局部渗透、俯冲通道中的蛇纹岩基质的挖掘以及增生楔形成过程中沉积或构造过程对原始块体基质结构的改造。
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引用次数: 0
The latest encrinurid trilobites from the Lower Devonian of Xinjiang, Northwest China 新疆下泥盆世最新发现的棱叶三叶虫
3区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2023-10-09 DOI: 10.1017/s0016756823000596
Juan Ma, Jiayi Yin, Yilong Liu, Xiaoqi Du, Shibo Liu, Ruiwen Zong
Abstract Encrinurids are common in Ordovician and Silurian strata but whether they survived into the Early Devonian is still controversial. This paper documents the encrinurid Batocara sp. near the Silurian–Devonian boundary in western Junggar, Xinjiang. The highest horizon of Batocara sp. is located above the first appearance datum of the Devonian conodont Caudicriodus , confirming that encrinurids may cross the Silurian–Devonian boundary. The presence of Caudicriodus angustoides bidentatus , Zieglerodina planilingu and plate-type loboliths of scyphocrinoids above the highest horizon of Batocara sp. indicates that encrinurids here extend only into the lower part of the first conodont zone of the Lochkovian (i.e., Caudicriodus hesperius Biozone). Encrinurids are widely distributed and easily recognized, and unlike graptolites and conodonts are not controlled by lithofacies. Therefore, it might be possible to use the highest horizon of encrinurids as indicator fossils to identify the approximate position of the Silurian–Devonian boundary in areas or sections where graptolites and conodonts are not present, and at least in northwest China.
摘要:在奥陶系和志留系地层中普遍存在着隐石,但它们是否存在于早泥盆世仍存在争议。本文记录了新疆准噶尔西部志留系—泥盆系界线附近的巴托卡拉族。Batocara的最高层位位于泥盆纪牙形刺Caudicriodus的首次出现基准面之上,证实了encrinurids可能跨越志留纪-泥盆纪界线。在Batocara属的最高层位以上,存在着Caudicriodus angustoides bidentatus、Zieglerodina planilingu和scyphocriinoids的板状小石,表明此处的齿形小石仅延伸到Lochkovian第一个牙形带的下部(即Caudicriodus hesperius Biozone)。石屑分布广泛,易识别,与笔石、牙形刺不同,不受岩相控制。因此,在笔石和牙形刺不存在的地区或剖面上,至少在中国西北地区,或许可以利用笔石的最高层位作为指示化石,来确定志留纪-泥盆纪界线的大致位置。
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引用次数: 0
Lattice preferred orientation of quartz in granitic gneisses from Tso Morari Crystalline Complex, Eastern Ladakh, trans-Himalaya: evaluating effect of Dauphiné twin in dynamic recrystallization during exhumation 东拉达克Tso Morari杂岩花岗质片麻岩中石英的晶格优选取向:挖掘过程中dauphin<s:1>孪晶对动态再结晶的影响评价
3区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2023-10-04 DOI: 10.1017/s0016756823000560
Alosree Dey, Koushik Sen, Manish A. Mamtani
Abstract The Tso Morari Crystalline complex (TMCC) of eastern Ladakh, India, is part of the north Indian continental margin and is characterized by eclogitic enclaves embedded within ortho- and paragneisses known as the Puga Gneiss. Two fault zones bound the TMCC: the Karzok fault to the southwest and the Zildat fault to the northeast. In the present study, we carried out Electron Backscatter Diffraction study of quartz of 10 samples collected from the Puga Gneiss. The relict and recrystallized quartz grains were treated separately to understand the deformation conditions of the Puga Gneiss during early and late deformation stages related to UHP metamorphism and final stage of exhumation during retrogression, respectively. Microstructural observations suggest dynamic recrystallization in quartz and plagioclase at different temperature ranges. Misorientation analysis of both relict and recrystallized quartz grains reveals presence of Dauphiné Twins. Lattice preferred Orientation (LPO) of axis of relict quartz grains generally shows more than one point maxima indicating that the relict grains preserve LPO developed during different stages of metamorphism/deformation. On the other hand, LPO of axis of recrystallized grains from Karzok and Zildat fault zones shows asymmetric single girdle either normal or at an angle to the foliation plane, which suggests simple shear. We conclude that grain size reduction and recrystallization of the Puga Gneiss was greatly influenced by Dauphiné Twin and the final exhumation of the TMCC took place in a simple shear environment aided by activity along its two binding fault zones.
印度拉达克东部的Tso Morari结晶复合体(TMCC)是印度北部大陆边缘的一部分,其特征是嵌在正长和副长片麻岩中的榴辉岩包体,被称为普加片麻岩。两个断裂带束缚着TMCC:西南部的Karzok断裂和东北部的Zildat断裂。在本研究中,我们对从普格片麻岩中采集的10个样品的石英进行了电子背散射衍射研究。通过对残余石英颗粒和再结晶石英颗粒的处理,分别了解了普加片麻岩在超高压变质作用的早期变形阶段和晚期变形阶段以及退变过程中挖掘的最后阶段的变形条件。显微结构观察表明,石英和斜长石在不同温度范围内发生了动态再结晶。残晶和再结晶石英晶粒的取向错误分析表明,存在道菲英钻孪晶。<c>残余石英颗粒轴线一般出现一个以上的最大值,表明残余颗粒保存了变质/变形不同阶段发育的LPO。另一方面,LPO <c>卡尔佐克断裂带和兹尔达特断裂带的再结晶颗粒轴线呈不对称的单带,或与片理面垂直,或与片理面成一定角度,表明其为单纯剪切。我们认为,普加片麻岩的晶粒尺寸减小和再结晶在很大程度上受道菲因纳双胞胎的影响,而TMCC的最终出露是在一个简单的剪切环境中进行的,并伴随着其两个结合断裂带的活动。
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引用次数: 0
Provenance of the early Palaeozoic volcano-sedimentary successions from eastern part of the Central Sudetes: implications for the tectonic evolution of the NE Bohemian Massif 中苏台德东部早古生代火山-沉积序列的物源:对东波希米亚地块构造演化的启示
3区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2023-10-02 DOI: 10.1017/s0016756823000523
Jacek Szczepański, Gabriela Kaszuba, Robert Anczkiewicz, Sławomir Ilnicki
Abstract The Kamieniec Metamorphic Belt (KMB) and the Doboszowice Metamorphic Complex (DMC) expose a fragment of the pre-Variscan volcano-sedimentary cover preserved in the Fore-Sudetic Block in the NE part of the Bohemian Massif. We present the age of detrital and magmatic zircon grains and the bulk rock chemical composition of rock samples from the KMB and the DMC to better understand the evolution of the early Palaeozoic Gondwana margin. The zircon age spectra were acquired by U–Pb LA–ICP–MS dating and represent two groups that differ by maximum depositional age (MDA). The paragneiss from the DMC displays the MDA at 456 Ma, whereas the mica shist from the KMB displays the MDA at 529 Ma. Older age peaks in both groups of samples are represented by the Neoproterozoic and less frequent the Paleoproterozoic and Archean. The data presented indicate that the rock successions were sourced from the Cadomian orogen and deposited in the basins that developed on the Gondwana margin. Our results support the suggestion that the crystalline basement in the eastern part of the Fore-Sudetic Block has an affinity to the Trans-Saharan Belt or West African Craton and was part of a Gondwana shelf. The final stage of evolution of the studied successions was related to the Variscan thermal overprint. Based on presented data, we support the idea that the suture separating the Brunovistulian domain from the rest of the Gondwana-derived terranes is not related to the closure of the Rheic Ocean and represents a local feature.
在波希米亚地块东北部,Kamieniec变质带(KMB)和Doboszowice变质杂岩(DMC)暴露了前苏德海地块中保存的前variscan火山-沉积盖层碎片。为了更好地了解早古生代冈瓦纳边缘的演化,我们提出了KMB和DMC的碎屑和岩浆锆石颗粒的年龄以及岩石样品的整体岩石化学成分。通过U-Pb LA-ICP-MS测年获得了锆石年龄谱,显示出最大沉积年龄(MDA)不同的两组锆石年龄。DMC的副长岩显示MDA为456 Ma,而KMB的云母片岩显示MDA为529 Ma。两组样品的年龄峰值均以新元古代为代表,而古元古代和太古代则较少出现。研究结果表明,这些岩石序列来源于卡多米亚造山带,沉积在冈瓦纳边缘发育的盆地中。我们的研究结果支持了前苏台德地块东部的结晶基底与跨撒哈拉带或西非克拉通有亲缘关系,并且是冈瓦纳陆架的一部分的建议。研究序列演化的最后阶段与瓦里斯坎热叠印有关。根据现有资料,我们支持这样的观点,即将布鲁诺维斯特域与冈瓦纳衍生地体的其他部分分开的缝合线与Rheic Ocean的闭合无关,而是代表了一个局部特征。
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引用次数: 0
Provenance of a Late Permian retroarc foreland basin along the eastern Gondwanan margin: northern Sydney Basin, eastern Australia 冈瓦南东部边缘晚二叠世弧后前陆盆地物源:澳大利亚东部悉尼盆地北部
3区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2023-09-26 DOI: 10.1017/s0016756823000535
Angelos G. Maravelis, Robin Offler, Chrysanthos Botziolis, George Pantopoulos, Alexandra Scott, Bill Landenberger, William J. Collins
Abstract The Upper Permian sedimentary successions in the northern Sydney Basin have been the subject of several stratigraphic, sedimentological and coal petrographic studies, and recently, extensive U-Pb zircon dating has been carried out on tuffs in the Newcastle Coal Measures. However, detailed petrographic and geochemical studies of these successions are lacking. These are important because a major change in tectonic setting occurred prior to the Late Permian because of the Hunter-Bowen Orogeny that caused the uplift of the Carboniferous and Devonian successions in the Tamworth Group and Tablelands Complex adjacent to the Sydney Basin. This should be reflected in the detrital makeup of the Upper Permian rocks. This study provides data that confirms major changes did take place at this time. Petrographic analysis indicates that the source area is composed of sedimentary, felsic volcanic and plutonic and low-grade metamorphic rocks. Conglomerate clast composition analysis confirms these results, revealing a source region that is composed of felsic volcanics, cherts, mudstones and sandstones. Geochemical analysis suggests that the sediments are geochemically mature and have undergone a moderate degree of weathering. The provenance data presented in this paper indicate that the southern New England Orogen is the principal source of detritus in the basin. Discrimination diagrams confirm that the source rocks derive from an arc-related, contractional setting and agree with the provenance analyses that indicate sediment deposition in a retroarc foreland basin. This study offers new insights on the provenance and tectonic setting of the Northern Sydney Basin, eastern Australia.
摘要悉尼盆地北部的上二叠统沉积序列一直是地层学、沉积学和煤岩学研究的主题,最近对纽卡斯尔煤系的凝灰岩进行了广泛的U-Pb锆石定年。然而,对这些演替还缺乏详细的岩石学和地球化学研究。这一点很重要,因为在晚二叠纪之前,由于亨特-鲍文造山运动导致了塔姆沃思群和毗邻悉尼盆地的高原复群石炭系和泥盆系的抬升,构造环境发生了重大变化。这应反映在上二叠统岩石的碎屑组成上。这项研究提供的数据证实了这一时期确实发生了重大变化。岩相分析表明,烃源区主要由沉积岩、长英质火山岩、深裂岩和低变质岩组成。砾岩碎屑成分分析证实了这些结果,揭示了一个由长英质火山岩、燧石、泥岩和砂岩组成的源区。地球化学分析表明,沉积物地球化学成熟,风化程度中等。本文的物源资料表明,南新英格兰造山带是盆地碎屑岩的主要来源。判别图证实烃源岩来自与弧相关的收缩环境,与弧后前陆盆地沉积物沉积的物源分析一致。这项研究为澳大利亚东部北悉尼盆地的物源和构造环境提供了新的认识。
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引用次数: 0
The genesis of calcite and dolomite carbonatite-forming magma by liquid immiscibility: a critical appraisal 方解石和白云石碳酸盐岩岩浆的液体不混溶成因:一种批判性评价
3区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2023-09-15 DOI: 10.1017/s001675682300050x
John Gittins, Roger H. Mitchell
Abstract Liquid immiscibility has become the preferred mode of genesis for the carbonatite rocks, which commonly, but not exclusively, accompany silicate rocks in alkaline-rock complexes. This concept has been universally based on the presumption that nephelinitic and phonolitic magmas can evolve to a stage where two conjugate immiscible liquids separate. It is assumed that these two liquids separate quickly, or even instantaneously, into discrete bodies of magma capable of being intruded or extruded with subsequent independent crystallization. Supporting evidence generally given is: alleged consanguinity as discrete occurrence of the two rock types; similarity of radiogenic isotope ratios; trace element contents similar to those predicted from experimentally derived partition coefficients. We do not accept that a general case for liquid immiscibility has been demonstrated; although we do accept that silicate and carbonate liquids are inherently immiscible, we maintain that they are not conjugate in a petrogenetic context. We have reviewed and critically examined the experimental data purporting to establish liquid immiscibility and find that when applied to natural rocks, they are based on inappropriate experimental designs, which are not relevant to the genesis of calcite or dolomite carbonatites, although they might have some relevance to Oldoinyo Lengai nyerereite–gregoryite lavas. The design of these experiments guarantees immiscibility and ensures that the carbonate liquids formed will be calcitic or sodium-rich. We dispute the validity of comparing the trace element contents of natural rocks, which in many instances do not represent liquid compositions, to experimentally determine partition coefficients. We consider that experimental design inadequacies, principally assuming but not proving, that the liquids involved are conjugate, indicate that these coefficients are merely an expression of the preference of certain elements for particular liquids, regardless of how the liquids formed. Proof of consanguinity in alkaline complexes requires more accurate age determinations on the relevant rock types than has generally been the case, and in most complexes, consanguinity can be discounted. We dispute the contention that melt inclusions represent parental melts, although they might elucidate the character of magmas undergoing fractional crystallization from magmatic to carbothermal stages. Radiogenic isotope data are shown to be too widely variable to support a case for liquid immiscibility. We address the contention that calcite cannot crystallize from a dolomitic liquid formed by direct mantle melting, and must therefore have crystallized from a calcite carbonate liquid generated by liquid immiscibility, and demonstrate that it is an unsupported hypothesis as calcite can readily crystallize from dolomitic liquids. We observe that, because immiscible dolomite liquids have never been produced experimentally, the liquid immiscibility propositio
摘要液体非混相作用已成为碳酸盐岩的首选成因模式,碳酸盐岩通常(但并非全部)伴随在碱性岩杂岩中的硅酸盐岩中。这一概念普遍基于这样的假设,即辉石质和声母质岩浆可以演化到两种共轭不混溶液体分离的阶段。据推测,这两种液体会迅速分离,甚至是瞬间分离,成为能够被侵入或挤压并随后独立结晶的岩浆体。通常给出的支持性证据是:两种岩石类型的分离产状有所谓的亲缘关系;放射性成因同位素比值相似性;微量元素含量与实验推导的分配系数预测的相似。我们不接受已经证明了液体不混相的一般情况;虽然我们承认硅酸盐和碳酸盐液体本质上是不可混溶的,但我们认为它们在成岩环境中不是共轭的。我们对旨在建立液体不混溶性的实验数据进行了回顾和批判性检查,发现当将其应用于天然岩石时,它们基于不适当的实验设计,与方解石或白云岩碳酸岩的成因无关,尽管它们可能与Oldoinyo Lengai镍辉石辉长岩熔岩有一定的相关性。这些实验的设计保证了不混溶性,并确保形成的碳酸盐液体将是钙质或富钠的。我们争论比较天然岩石的微量元素含量的有效性,在许多情况下不代表液体成分,实验确定分配系数。我们认为,实验设计的不足,主要是假设而不是证明,所涉及的液体是共轭的,表明这些系数仅仅是某些元素对特定液体的偏好的表达,而不管液体是如何形成的。在碱性复合体中,血缘关系的证明需要对相关岩石类型进行更精确的年龄测定,而在大多数复合体中,血缘关系可以忽略不计。我们对熔融包裹体代表母熔体的观点提出了质疑,尽管它们可能说明岩浆阶段到碳热阶段分步结晶的岩浆特征。放射性成因同位素数据显示变化太大,不能支持液体不混相的情况。我们解决了方解石不能从直接地幔熔融形成的白云岩液体中结晶的争论,因此必须从液体不混溶产生的方解石碳酸盐液体中结晶,并证明了这是一个不被支持的假设,因为方解石可以很容易地从白云岩液体中结晶。我们观察到,由于在实验中从未产生过不混溶的白云岩液体,因此液体不混溶的主张充其量只能应用于方解石碳酸盐,从而无法解释大量的白云岩碳酸盐和不伴有碱性硅酸盐岩石的任何一种类型的白云岩。碱岩碳酸盐岩杂岩双峰性的假设被认为是错误的,在这些杂岩中没有明显的不混相作用的实际地质或岩石学证据。对提出不混相的碱性碳酸盐岩杂岩的几个例子进行了严格的评价,并表明试图将它们建立为不混相的例子是失败的。我们的结论是,没有实际的地质或实验数据存在,以确定液体不混溶性参与方解石或白云岩碳酸盐岩形成岩浆的成因。
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引用次数: 0
Structure of the Assynt window, Moine Thrust Zone and relationship of thrusts to alkaline igneous complexes, Caledonian orogeny, NW Scotland 苏格兰西北部加里东造山带逆冲构造与碱性火成岩杂岩的关系
3区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2023-09-12 DOI: 10.1017/s0016756823000511
Michael P. Searle
Abstract The Moine Thrust Zone forms the Caledonian orogenic thrust front where the Moine Supergroup metamorphic rocks have been thrust westward across the Laurentia plate stable foreland, comprising Archean-Proterozoic granulite and amphibolite facies rocks (Lewisian gneisses), with unconformably overlying Mesoproterozoic and Neoproterozoic Torridonian clastic sediments and Cambrian-Ordovician passive margin sedimentary rocks. Four major thrusts beneath the Moine thrust in the Assynt window include the (i) Ben More Thrust, which places the Loch Ailsh syenite intruded into Lewisian basement and Cambrian-Ordovician sedimentary rocks over the Sole thrust sheet, (ii) Glencoul thrust, which places Lewisian basement and folded cover rocks over Cambrian-Ordovician sedimentary rocks, (iii) Borralan thrust, which carries a large alkaline syenite intrusion beneath the Ben More roof thrust and (iv) the Sole thrust sheet, which carries imbricated Cambrian-Ordovician sedimentary rocks and lamprophyre sills over the stable foreland. Three further thrust sheets within the Lewisian basement gneisses are now recognised through restoration of balanced cross-sections, which were responsible for doming of the Assynt window. Although the Moine thrust is mapped as a single line on the map it encompasses, (a) deep ductile shear zone formed of mylonites derived from hangingwall Moine schists, footwall Cambrian quartzites and Ordovician limestones, and basement Lewisian gneisses, (b) roof thrust of the Glencoul and Ben More Thrust sheets and (c) brittle out-of-sequence motion where the Moine schists have been thrust over mylonites, which directly overlie the stable foreland (Knockan Crag).
摩因逆冲带形成加里东造山逆冲前缘,摩因超群变质岩向西冲过劳伦提亚板块稳定前陆,由太古宙-元古代麻粒岩和角闪岩相岩(刘易斯片麻岩)组成,上覆中元古代-新元古代陶里屯碎屑沉积物和寒武系-奥陶系被动边缘沉积岩。在阿辛特窗口,摩因冲断构造下的4个主要冲断构造包括(1)本莫尔冲断构造,它将艾尔什湖正长岩侵入到詹姆斯基底和寒武系-奥陶系沉积岩之上;(2)Glencoul冲断构造,它将詹姆斯基底和褶皱盖岩置于寒武系-奥陶系沉积岩之上;(3)Borralan冲断构造,它在本莫尔顶板冲断构造下携带大量碱性正长岩侵入;在稳定的前陆上携带寒武-奥陶系叠瓦状沉积岩和煌斑岩。通过平衡截面的恢复,现在可以识别出刘易斯基底片麻岩中的三个进一步的逆冲层,这些逆冲层负责Assynt窗口的圆顶。虽然摩因逆冲作用在地图上被绘制为单线,但它包括(a)由上盘摩因片岩衍生的糜棱岩、下盘寒武系石英岩和奥陶系灰岩以及基底Lewisian片麻岩形成的深部韧性剪切带,(b) Glencoul逆冲岩和Ben More逆冲岩的顶板逆冲作用,以及(c)摩因片岩逆冲作用于糜棱岩上的脆性脱序运动,糜棱岩直接位于稳定的前陆(Knockan岩)之上。
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引用次数: 0
GEO volume 160 issue 9 Cover and Back matter 全球环境展望》第 160 卷第 9 期封面和封底
IF 2.3 3区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2023-09-01 DOI: 10.1017/s0016756823000821
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引用次数: 0
GEO volume 160 issue 9 Cover and Front matter 全球环境展望》第 160 卷第 9 期封面和封底
IF 2.3 3区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2023-09-01 DOI: 10.1017/s001675682300081x
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引用次数: 0
Chemotrophy-based phosphatic microstromatolites from the Mississippian at Drewer, Rhenish Massif, Germany 来自德国莱茵山脉德鲁尔的密西西比系磷化微叠层石
IF 2.3 3区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2023-08-24 DOI: 10.1017/s0016756823000493
J. Zwicker, D. Smrzka, Matthias Gothieu, E. Libowitzky, M. Joachimski, Michael Ernst Böttcher, Jörn Peckmann
The Drewer quarry located in the Rhenish Massif is a well-studied outcrop that comprises Upper Devonian (Famennian) to Lower Carboniferous (Viséan) strata. Within the Drewer deposits two black shale intervals have been described that are linked to two global oceanic anoxic events, the Hangenberg Event and the Lower Alum Shale Event. The black shales associated with the Middle Tournaisian Lower Alum Shale Event contain abundant phosphatic concretions, which were investigated using thin section petrography, powder X-ray diffraction, Fourier-transform infrared spectrometry and scanning electron microscopy. The concretions formed during several growth phases under anoxic and at least episodically sulphidic conditions within the sediment and served as a substrate for subsurface microbial mats that formed phosphatic microstromatolites. The microstromatolites occur either as partially branched columns of up to 600 µm in length attached to the phosphatic concretions or as smaller, bulbous aggregates surrounding the concretions. Element mapping identified the presence of pyrite and other metal sulphides within the phosphatic microstromatolites. The carbon and oxygen stable isotopic composition of phosphate-associated carbonate within the phosphatic microstromatolites suggests that the mat-forming microorganisms were probably anaerobic, chemotrophic microbial communities dwelling in the anoxic environment during the Lower Alum Shale Event. Such interpretation agrees with the deeper-water depositional setting of the Lower Alum Black Shale and its high content of organic matter, suggesting that chemotrophic microbial mats are potent agents of phosphogenesis in general, and of the formation of phosphatic stromatolites in particular.
德鲁尔采石场位于莱茵河地块,是一个研究充分的露头,包括上泥盆统(法门统)至下石炭统(vissaman)地层。在Drewer矿床中,已经描述了两个黑色页岩层段,它们与两个全球海洋缺氧事件(Hangenberg事件和下明矾页岩事件)有关。利用薄片岩石学、粉末x射线衍射、傅里叶变换红外光谱和扫描电镜对中图尔纳世下明矾页岩事件相关的黑色页岩中含有丰富的磷结块进行了研究。这些固结物是在沉积物中缺氧和至少偶尔硫化物条件下的几个生长阶段形成的,并作为形成磷微叠层石的地下微生物垫的基质。微叠层石要么以部分分枝的柱体形式出现,长度可达600µm,要么以较小的球状聚集体形式出现,围绕在磷酸盐结块周围。元素图确定了磷化微叠层石中黄铁矿和其他金属硫化物的存在。磷化微叠层石中磷酸盐伴生碳酸盐的碳氧稳定同位素组成表明,形成垫层的微生物可能是下明矾页岩事件时期生活在缺氧环境中的厌氧化养微生物群落。这一解释与下明矾黑色页岩的深水沉积环境及其高有机质含量相一致,表明化养微生物席通常是产磷的有力媒介,特别是磷叠层石的形成。
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Geological Magazine
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