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Sodic nature of carbonatite melts and the origin of calcite versus dolomite carbonatites 碳酸盐岩熔体的钠质性质及方解石与白云石碳酸盐岩的成因
IF 5.8 1区 地球科学 Q1 GEOLOGY Pub Date : 2025-12-22 DOI: 10.1130/g53916.1
Simone Marioni, Gino Sartori, Max W. Schmidt
Carbonatites are magmatic rocks that host most economic rare earth element (REE) deposits and bear on the deep Earth volatile cycle. Yet, the cumulative character of plutonic carbonatites and the rapid posteruptive alteration of volcanic carbonatites impede a direct determination of the melt compositions crystallizing these rocks. This study focused on sodium in carbonatite melts, a critical component for their genesis, magmatic evolution, and also for REE mobility, given that most carbonatite-hosted REE mineralizations are formed by alkali-rich fluids. Through experiments at subvolcanic conditions (100−200 MPa, 800−1000 °C), we determined the partition coefficient of Na between apatite and carbonatite melt, DNaapatite/carbonatite, which is rather uniformly 0.010 ± 0.003 at temperatures ≥800 °C. Applying our DNaapatite/carbonatite value to natural samples yields 8−22 wt% Na2O for the melts forming calcic carbonatites and 26−32 wt% Na2O for melts forming dolomite carbonatites. The latter are hence more evolved than calcic carbonatite melts, increasing their potential to shed alkali-rich fluids. A model accounting for calcite fractionation from calcite carbonatite melts prior to apatite saturation indicates primary Na2Omelt contents of 16−23 wt% at 900 °C and 9−11 wt% at 1100 °C, consistent with formation by liquid immiscibility from alkaline silicate magmas, but inconsistent with direct mantle derivation, in particular for dolomitic melts.
碳酸盐岩是承载最具经济价值的稀土元素(REE)矿床的岩浆岩,与地球深部的挥发旋回有关。然而,深成岩碳酸盐岩的累积特征和火山碳酸盐岩的快速后向蚀变阻碍了对这些岩石结晶的熔体成分的直接测定。考虑到大多数碳酸盐岩中的稀土矿化是由富碱流体形成的,本研究的重点是碳酸盐岩熔体中的钠,这是碳酸盐岩成因、岩浆演化和稀土流动性的关键组成部分。通过次火山条件下(100 ~ 200 MPa, 800 ~ 1000℃)的实验,我们确定了磷灰石和碳酸盐岩熔体之间Na的分配系数,DNaapatite/carbonatite,在≥800℃时,Na的分配系数相当均匀,为0.010±0.003。将我们的DNaapatite/carbonatite值应用于天然样品,形成钙碳酸盐的熔体得到8 - 22 wt% Na2O,形成白云岩碳酸盐的熔体得到26 - 32 wt% Na2O。因此,后者比钙碳酸盐熔体更进化,增加了它们释放富碱液体的潜力。考虑方解石碳酸盐熔体在磷灰石饱和前方解石分馏的模型表明,在900℃时,原生na2ommelt的含量为16 - 23wt %,在1100℃时,na2ommelt的含量为9 - 11wt %,这与碱性硅酸盐岩浆的液体不混溶形成一致,但与直接地幔衍生不一致,特别是对于白云质熔体。
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引用次数: 0
Geologically constrained data-driven modeling for mineral prospectivity mapping 地质约束数据驱动的矿产远景填图建模
IF 5.8 1区 地球科学 Q1 GEOLOGY Pub Date : 2025-12-22 DOI: 10.1130/g53947.1
Luoqi Wang, Tianyi Li, Sensen Wu, Jie Yang, Yanhua Hu, Linshu Hu, Yijun Chen, YunZhao Ge, Yunfeng Chen, Can Rao, Zhenhong Du
The discovery and development of mineral resources are critical for sustaining modern energy demands. However, the geological processes that control mineralization are inherently complex, introducing considerable spatial variability that presents significant challenges for predictive modeling. While machine learning approaches have been increasingly applied to mineral prospectivity, many fail to explicitly incorporate key geological constraints, limiting their capacity to resolve the nonlinear and directionally dependent nature of mineralizing systems. Here we present a geologically constrained data-driven method that explicitly accounts for the spatial non-stationarity and anisotropy in ore-forming processes. In the benchmark case study from Canada, our method demonstrates a 7.4% improvement in recall performance compared with existing models. This robust performance is also observed in applications to the southern Cordillera region. Furthermore, the method elucidates regional ore-forming controls and quantifies spatial anisotropy in porphyry copper systems. Our findings demonstrate that incorporating geological constraints into data-driven models enhances both the accuracy and interpretability of mineral prospectivity assessments, offering a robust path forward in resource exploration.
矿产资源的发现和开发是维持现代能源需求的关键。然而,控制矿化的地质过程本质上是复杂的,引入了相当大的空间变异性,这对预测建模提出了重大挑战。虽然机器学习方法越来越多地应用于矿产勘探,但许多方法未能明确纳入关键的地质约束,限制了它们解决矿化系统的非线性和方向依赖性的能力。在这里,我们提出了一种地质约束的数据驱动方法,明确地说明了成矿过程的空间非平稳性和各向异性。在加拿大的基准案例研究中,我们的方法与现有模型相比,召回性能提高了7.4%。在南科迪勒拉地区的应用中也观察到这种强劲的性能。此外,该方法阐明了区域成矿控制因素,量化了斑岩型铜系统的空间各向异性。我们的研究结果表明,将地质约束纳入数据驱动模型可以提高矿产远景评估的准确性和可解释性,为资源勘探提供了一条强有力的前进道路。
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引用次数: 0
Large domal stromatolites in the Paleoarchean ocean at 3.47 Ga 3.47 Ga古太古代海洋中的大型穹窿叠层石
IF 5.8 1区 地球科学 Q1 GEOLOGY Pub Date : 2025-12-22 DOI: 10.1130/g53960.1
Eva E. Stüeken, Anthony R. Prave, Liam O’Connor, Jonas Kaempf, Anthony Clarke, Tim E. Johnson, Christopher L. Kirkland
Stromatolites are indicators of life on Earth since at least 3.5 Ga and possibly 3.7 Ga. From the mid-Archean onward, records of stromatolites display a range of morphologies and sizes, indicating that microorganisms were present in a variety of habitats. By comparison, the existing Paleoarchean stromatolite record is limited to small decimeter-scale domes, cones, and tufts that occur in evaporitic environments. Here, we document large domal stromatolites with ∼1.5 m width and 0.8 m height from a chert-jasper-carbonate member in the Paleoarchean (ca. 3.47 Ga) Mount Ada Basalt, Pilbara craton, Western Australia. Sedimentological features and trace-element chemistry show that the stromatolites grew on seafloor pillow basalts in an anoxic environment with hydrothermal influence. Aqueous alteration of basaltic-komatiitic crust likely supplied key nutrients, extending benthic microbial habitats into the deeper Paleoarchean ocean and supporting a thriving biosphere independent of continental exposure.
叠层石是地球上生命的标志,至少从3.5 Ga到3.7 Ga。从太古宙中期开始,叠层石的记录显示出一系列的形态和大小,表明微生物存在于各种各样的栖息地。相比之下,现有的古太古代叠层石记录仅限于发生在蒸发环境中的小分米尺度的圆顶,锥状和簇状。在这里,我们记录了来自西澳大利亚皮尔巴拉克拉通阿达山玄武岩古太古代(约3.47 Ga)的燧石-玉石-碳酸盐段的大型穹状叠层石,宽约1.5 m,高约0.8 m。沉积学特征和微量元素化学特征表明,叠层石生长在受热液影响的缺氧环境下的海底枕玄武岩上。玄武岩-科马长岩壳的水蚀变可能提供了关键的营养物质,将底栖微生物栖息地扩展到更深处的古太古代海洋,并支持一个独立于大陆暴露的繁荣生物圈。
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引用次数: 0
Asymmetric growth of strike-slip faults controlled by 3-D fault structure: Insights from the Mw 7.8 2023 Kahramanmaraş (Turkey) earthquake 三维断层结构控制下的走滑断层不对称生长:来自2023年土耳其kahramanmaraku 7.8级地震的启示
IF 5.8 1区 地球科学 Q1 GEOLOGY Pub Date : 2025-12-18 DOI: 10.1130/g53724.1
Giovanni Camanni, Efstratios Delogkos, Stefano Tavani, Ester Piegari, Muhammed Kösen
The reactivation of deep-seated, throughgoing strike-slip faults produces highly segmented fault zones at shallower levels, yet how displacement is partitioned among segments as the fault grows remains poorly constrained. We address this by examining a ∼160-m-long section of the East Anatolian fault surface rupture of the Mw 7.8 2023 Kahramanmaraş strike-slip earthquake (Turkey). The rupture offsets meter-spaced ridges and furrows in a ploughed field, providing a unique opportunity for detailed displacement measurements, which were obtained from an orthophoto and a digital elevation model (DEM) built for this study. The surface rupture consists of ten primary segments separated by nine restraining stepovers and is associated with a 3-D strain field dominated by ∼3.5 m of left-lateral offset. Displacement patterns allow us to derive a new model for strike-slip fault growth in which deformation is asymmetric and controlled by the 3-D structure of the fault—specifically, by the position of the underlying fault relative to shallow fault segments. Initially, displacement is accommodated by contraction within restraining stepovers. With increasing displacement, fault segments located closer to the trace of the underlying fault consistently accumulate greater displacement. This asymmetry is facilitated by enhanced synthetic rotation within stepovers. With further displacement, the higher-displacement segment bounding a stepover becomes dominant, while the other one is bypassed and layer rotation ceases. These results not only improve fault growth models but could also inform seismic hazard models and impact industrial applications dealing with subsurface faulted reservoirs.
深层走滑断层的重新激活在浅层产生了高度分段的断裂带,但随着断层的增长,位移如何在分段之间划分仍然没有得到很好的约束。我们通过检查2023年kahramanmaraki Mw 7.8走滑地震(土耳其)东安纳托利亚断层表面破裂的约160米长的剖面来解决这个问题。断裂偏移了耕地中米间距的山脊和犁沟,为详细的位移测量提供了独特的机会,这些位移测量是通过正射影像仪和为本研究建立的数字高程模型(DEM)获得的。地表破裂由10个主要部分组成,由9个抑制台阶分隔,并与以约3.5 m的左侧偏移为主的3-D应变场有关。位移模式使我们能够推导出一种新的走滑断层生长模型,其中变形是不对称的,由断层的三维结构控制,特别是由下伏断层相对于浅断层段的位置控制。最初,位移是通过收缩来调节的。随着位移的增加,离下伏断层迹更近的断层段不断积累更大的位移。这种不对称是通过加强炉内的合成旋转来促进的。随着位移的增加,高位移段包围一个阶梯的部分占据主导地位,而另一个部分被绕过,层旋转停止。这些结果不仅可以改进断层生长模型,还可以为地震危险模型提供信息,并影响地下断层储层的工业应用。
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引用次数: 0
Authigenic clays shaped Ediacara-style exceptional fossilization 自生粘土形成的埃迪卡拉风格的特殊化石
IF 5.8 1区 地球科学 Q1 GEOLOGY Pub Date : 2025-12-15 DOI: 10.1130/g53967.1
Lidya G. Tarhan, Thomas H. Boag, Boriana Kalderon-Asael
The Ediacara Biota—Earth’s earliest fossilized ecosystems of complex, macroscopic organisms—has played a key role in shaping understanding of the transition between the Precambrian and early Paleozoic radiations of animal diversity. The majority of Ediacara Biota Lagerstätten are exceptionally preserved in the distinctive Ediacara style as three-dimensional casts and molds in sandstones. However, the factors responsible for the fossilization of these soft-bodied organisms—in particular, for their preservation in compositionally immature sandstones and heterolithic strata—remain debated. In this study, we investigate the taphonomic importance of clay minerals in fostering Ediacara-style fossilization in classic Ediacara Biota fossil assemblages in Newfoundland and northwestern Canada. Using a combination of electron microscopy, X-ray diffraction, and major and trace element and lithium isotope analyses, we describe evidence for both detrital and early diagenetic clay minerals associated with these fossils. In particular, we document iron- and magnesium-rich clays, including chamosite and other chlorite-group minerals, which may reflect an authigenic precursor such as berthierine, a mineral that has also been implicated in other modes of exceptional preservation. Lithium isotope data corroborate the importance of detrital and marine authigenic clays in shaping the moldic preservation of these fossils. These results provide a broader view of potential drivers of the Ediacara-style fossil record and suggest that authigenic clay mineralization may have shaped multiple windows of exceptional fossilization across the Neoproterozoic−Paleozoic transition.
埃迪卡拉生物群是地球上最早的复杂宏观生物化石生态系统,在形成对前寒武纪和早期古生代动物多样性辐射过渡的理解方面发挥了关键作用。大多数埃迪卡拉生物群Lagerstätten都以独特的埃迪卡拉风格保存下来,作为砂岩中的三维模型和模具。然而,导致这些软体生物石化的因素,特别是它们在成分不成熟的砂岩和异质层中保存下来的因素,仍然存在争议。在这项研究中,我们研究了在纽芬兰和加拿大西北部的经典埃迪卡拉生物群化石组合中,粘土矿物对促进埃迪卡拉类化石形成的地学意义。结合电子显微镜、x射线衍射、主微量元素和锂同位素分析,我们描述了与这些化石相关的碎屑和早期成岩粘土矿物的证据。特别地,我们记录了富含铁和镁的粘土,包括绿泥石和其他绿泥石群矿物,它们可能反映了自生前体,如berthierine,一种也涉及其他特殊保存模式的矿物。锂同位素数据证实了碎屑和海相自生粘土在塑造这些化石的模态保存中的重要性。这些结果为埃迪卡拉式化石记录的潜在驱动因素提供了更广泛的视角,并表明自生粘土矿化可能在新元古代-古生代过渡期间形成了多个特殊的化石窗口。
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引用次数: 0
Lithium isotopes reveal enhanced weathering fluxes in North America during the Paleocene−Eocene Thermal Maximum 锂同位素显示古新世—始新世热极大期北美风化通量增强
IF 5.8 1区 地球科学 Q1 GEOLOGY Pub Date : 2025-12-11 DOI: 10.1130/g53708.1
Rocio Jaimes-Gutierrez, Lucas Vimpere, David J. Wilson, Patrick Blaser, Philip A.E. Pogge von Strandmann, Thierry Adatte, Swapan Sahoo, Sébastien Castelltort
Silicate weathering regulates Earth’s long-term climate by removing atmospheric CO2. Understanding changes in weathering regimes and rates is key to predicting climate response time scales. We investigated the reactivity of the North American source-to-sink system and the chemical weathering regime during the Paleocene−Eocene Thermal Maximum (PETM). We measured the detrital lithium isotope composition (δ7Li) in a deep-marine sediment core from the Gulf of Mexico, tracking changes in the formation of clay minerals, alongside neodymium isotopes (εNd), to constrain sediment provenance. We find a buffered negative δ7Li excursion during the PETM body, likely reflecting the mixing of neoformed and reworked clays from continental floodplains, followed by a stronger negative δ7Li excursion during the recovery phase. This pattern aligns with the continental Bighorn Basin (Wyoming, USA) δ7Li record, indicating rapid propagation of enhanced weathering and erosion fluxes in response to the PETM, which would have contributed to efficient CO2 drawdown.
硅酸盐风化作用通过去除大气中的二氧化碳来调节地球的长期气候。了解风化机制和速率的变化是预测气候响应时间尺度的关键。研究了古新世—始新世极热期(PETM)北美源-汇体系的反应性和化学风化机制。我们测量了墨西哥湾深海沉积物岩心中的碎屑锂同位素组成(δ7Li),跟踪了粘土矿物形成的变化,以及钕同位素(εNd),以约束沉积物的来源。我们找到一个缓冲-δ7李游览古新世-始新世极热时期的身体,可能反映了混合neoformed和改写粘土从大陆泛滥平原,紧随其后的是更强的李-δ7游览在复苏阶段。这一模式与大角盆地(美国怀俄明州)大陆的δ7Li记录一致,表明在PETM时期,增强的风化和侵蚀通量迅速传播,这将有助于有效的二氧化碳吸收。
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引用次数: 0
3-D electromagnetic imaging of highly deformed fluid-rich weak zones and locked section of the North Anatolian fault beneath the Marmara Sea 马尔马拉海下北安纳托利亚断层高变形富流体弱带和锁断段的三维电磁成像
IF 5.8 1区 地球科学 Q1 GEOLOGY Pub Date : 2025-12-08 DOI: 10.1130/g52995.1
Tülay Kaya-Eken, Yasuo Ogawa, Yoshiya Usui, Takafumi Kasaya, M. Kemal Tunçer, Yoshimori Honkura, Naoto Oshiman, Masaki Matsushima, Weerachai Siripunvaraporn
Reliable knowledge of the crustal properties beneath the North Anatolian fault (NAF), seismically silent for more than 250 years beneath the Marmara Sea (MS), is crucial for understanding seismic hazard and mitigating the potential for disaster on an enormous scale. In the present work, the first three-dimensional inverse modeling performed on a magnetotelluric dataset of the MS has unveiled localized weak and locked fault segments along this shear deformation zone. Low-resistivity regions along the northern branch of the NAF beneath the Central and Çınarcık-Imralı basins are likely attributed to the presence of fluids, which may represent a fault zone conductor in a fractured zone and can explain the densely populated microseismicity. These low-resistivity anomalies surrounded by higher resistivity structures imply that the segmented, multi-branched NAF system extends beneath the MS, following the Intra-Pontide suture zone. The resistive anomalies, between the Central and Çınarcık basins, along with those at the western and eastern extremities of the MS, presumably signify regions of stress accumulation, shedding light on the ongoing processes of fault mechanics at play in this critical region.
北安那托利亚断层(NAF)位于马尔马拉海(MS)下方,在250多年的时间里没有发生地震,对其地壳性质的可靠了解对于了解地震危险和减轻大规模灾难的可能性至关重要。在本研究中,首次对MS大地电磁数据集进行了三维逆建模,揭示了沿该剪切变形带的局部弱断层段和锁定断层段。沿NAF北部分支的低电阻率区域位于中部和Çınarcık-Imralı盆地下方,可能是由于流体的存在,这些流体可能代表断裂带中的断裂带导体,可以解释密集的微地震活动。这些被高电阻率结构包围的低电阻率异常表明,分段的、多分支的NAF系统沿着pontide缝合带延伸到MS下方。在中部和Çınarcık盆地之间,以及在MS的西部和东部极端,电阻率异常可能表明应力聚集区域,揭示了在这个关键区域正在进行的断层力学过程。
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引用次数: 0
Investigating the response of Glycymeris septentrionalis (Bivalvia) and Terebratalia transversa (Brachiopoda) to euxinia: Implications for mass extinctions 双壳目Glycymeris septentrionalis(双壳目)和Terebratalia transversa(腕足目)对euxinia的反应研究:对大灭绝的影响
IF 5.8 1区 地球科学 Q1 GEOLOGY Pub Date : 2025-12-08 DOI: 10.1130/g53911.1
Kemi Ashing-Giwa, Jonathan L. Payne, Erik A. Sperling
In the wake of the end-Permian mass extinction, bivalves replaced articulate brachiopods as the dominant benthic marine filter-feeders, despite morphological and ecological similarities. Several factors have been suggested as drivers of the extinction’s selectivity, including competition, ocean acidity, CO2 poisoning, and differing reproductive potential. The spread of sulfidic water (euxinia) has been proposed as a general kill mechanism, but its physiological selectivity has not been investigated. Survival studies of the co-occurring bivalve Glycymeris septentrionalis and articulate brachiopod Terebratalia transversa from San Juan Island, Washington, USA, were carried out in anoxic and euxinic environments at 13.7, 16, and 22 °C. In colder anoxic conditions without sulfide, the brachiopod exhibited greater survival than the bivalve, but at higher temperatures, the bivalve generally outlasted the brachiopod, and by a greater margin in euxinia. The alignment between physiological tolerance in experimental settings and survival patterns in the paleontological record indicates that euxinia may have played a role in end-Permian extinction severity and selectivity, serving as an additional stressor in already warm, oxygen-depleted oceans.
在二叠纪末大灭绝之后,尽管形态和生态相似,双壳类动物取代了关节腕足类动物,成为主要的底栖海洋滤食性动物。有几个因素被认为是灭绝选择性的驱动因素,包括竞争、海洋酸度、二氧化碳中毒和不同的繁殖潜力。硫化物水(euxinia)的扩散被认为是一种普遍的杀伤机制,但其生理选择性尚未研究。对来自美国华盛顿圣胡安岛的双壳类Glycymeris septentrionalis和关节腕足类Terebratalia transversa在13.7、16和22°C的缺氧和缺氧环境下的生存进行了研究。在较冷的无硫化物缺氧条件下,腕足类动物比双壳类动物存活时间长,但在较高的温度下,双壳类动物通常比腕足类动物存活时间长,而在无硫化物缺氧条件下,双壳类动物的存活时间更长。实验环境中的生理耐受性与古生物记录中的生存模式之间的一致性表明,euxinia可能在二叠纪末灭绝的严重性和选择性中发挥了作用,在已经温暖,缺氧的海洋中充当了额外的压力源。
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引用次数: 0
Forest-floor burial in 1507 by the largest Mount Rainier lahar of the past millennium 1507年被过去一千年里最大的雷尼尔火山泥流埋在森林里
IF 5.8 1区 地球科学 Q1 GEOLOGY Pub Date : 2025-12-08 DOI: 10.1130/g53721.1
Bryan A. Black, Patrick T. Pringle, James W. Vallance
New dating of lahar-killed trees underscores volcano hazards in the Puget Sound metropolitan area. Beginning as a landslide from the west flank of Mount Rainier, Washington, USA, the Electron Mudflow, which was the largest lahar of the last millennium, swept more than 60 km down the Puyallup River drainage into areas now densely populated. Wiggle matching of seven radiocarbon ages from buried, bark-bearing Douglas-fir (Pseudotsuga menziesii) trees brackets the mudflow’s age between 1477 and 1522 CE with 99.7% certainty. To narrow this date, we applied dendrochronology crossdating on samples collected from 21 trees killed by the lahar, measuring 86 time series for statistical verification. The four bark-bearing trees died the same year while the final rings in all other trees had decayed, exposing rings formed in earlier years. When averaged together, the crossdated measurements form a 475 yr master chronology that was correlated against absolutely dated tree-ring chronologies in the region. The Electron chronology best matched with chronologies from low-elevation sites, especially a Douglas-fir chronology from Vancouver Island, Canada, to show that the Electron trees died in 1507 CE. Latewood in the final ring was beginning to form, indicating the mudflow likely occurred in the late-summer months. What caused the Electron Mudflow is unknown, but this precise date will help to assess possible relationships with other events, assist in interpreting Indigenous narratives about the mudflow, and increase awareness of potential lahar hazards.
火山泥流杀死的树木的新年代强调了普吉特海湾大都市区的火山危险。电子泥石流起源于美国华盛顿州雷尼尔山西侧的一次滑坡,是上个千年来最大的火山泥流,沿着普雅鲁普河流域冲了60多公里,进入了现在人口密集的地区。对埋藏的、带树皮的道格拉斯杉树(假杉树)的7棵放射性碳年龄进行了摆动匹配,结果表明,泥石流的年龄在公元1477年至1522年之间,有99.7%的确定性。为了缩小这个日期,我们对从21棵被火山泥流杀死的树木收集的样本进行了树木年代学交叉测年,测量了86个时间序列进行统计验证。这四棵有树皮的树在同一年死去,而其他所有树木的最后一个年轮都腐烂了,暴露出早年形成的年轮。把这些交叉年代的测量结果加起来平均,就形成了一个475年的主年表,与该地区绝对确定的树木年轮年表相关联。电子树年代学与来自低海拔地区的年代学最吻合,尤其是来自加拿大温哥华岛的道格拉斯冷杉年代学,表明电子树死于公元1507年。最后一环的拉特伍德开始形成,表明泥石流可能发生在夏末的几个月。导致电子泥流的原因尚不清楚,但这个精确的日期将有助于评估与其他事件的可能关系,有助于解释关于泥流的土著叙述,并提高对潜在火山泥流危害的认识。
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引用次数: 0
As it ever was: Calcium isotope constraints on Mesoarchean seawater chemistry 一如既往:钙同位素对中太古代海水化学的约束
IF 5.8 1区 地球科学 Q1 GEOLOGY Pub Date : 2025-12-08 DOI: 10.1130/g53945.1
Anne-Sofie C. Ahm, Philip Fralick, John A. Higgins
Earth’s long-term climate is closely tied to the formation of carbonate sediments in the ocean, driving the ocean’s ability to moderate atmospheric CO2 levels. It has been hypothesized that in the Precambrian, this process was controlled by a “hidden” deep-sea carbonate sink. However, our results indicate that shallow-marine platforms have been the dominant mode of carbonate formation since the Mesoarchean. This conclusion is based on Ca isotopes from 2.8 Ga carbonates, which constrain the Ca isotope value of Mesoarchean seawater to −0.5‰ relative to modern values, strikingly similar to pre-Mesozoic values and suggesting that carbonate deposition mainly was confined to shallow-water platforms until the evolution of pelagic calcifiers in the Mesozoic.
地球的长期气候与海洋中碳酸盐沉积物的形成密切相关,这推动了海洋调节大气二氧化碳水平的能力。据推测,在前寒武纪,这一过程是由一个“隐藏”的深海碳酸盐汇控制的。然而,我们的研究结果表明,自中太古代以来,浅海台地一直是碳酸盐岩的主要形成模式。这一结论是基于2.8 Ga碳酸盐岩的Ca同位素,将中太古代海水的Ca同位素值限制在相对于现代值的- 0.5‰,与中生代前的值惊人地相似,表明在中生代中上层钙化物演化之前,碳酸盐岩沉积主要局限于浅水台地。
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引用次数: 0
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