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Geraisite: The first tektite occurrence in Brazil Geraisite:在巴西发现的第一块玻陨石
IF 5.8 1区 地球科学 Q1 GEOLOGY Pub Date : 2025-12-02 DOI: 10.1130/g53805.1
Alvaro P. Crósta, Gabriel G. Silva, Ludovic Ferrière, Philippe Nonnotte, Eugen Libowitzky, Fred Jourdan
Tektites, a rare type of impact glass, are known to occur only in five distinct strewn fields on Earth. We report on the discovery of a new tektite strewn field in northeastern Brazil. This recent finding resulted in the collection of ∼500 specimens found within a strewn field at least 90 km long. Mostly black in color, the masses, hereby named “geraisites” after the Brazilian state of Minas Gerais, range from <1 g up to 85.4 g and exhibit various shapes, rarely showing lechatelierite inclusions. In terms of chemical composition, they fall in the dacite and rhyolite fields of the total alkali versus silica diagram, with similar SiO2 and slightly higher Na2O + K2O content in comparison with other known tektites. Some variations in trace elements from sample to sample, such as for Cr and Ni, are observed. Water contents of the glass are extremely low, ranging between 70 and 110 ppm. The best estimate for their age of formation measured by the 40Ar/39Ar method is currently ca. 6.3 Ma, although the possible presence of inherited 40Ar* will require more analyses to fully establish their age. Strontium, Nd, and Hf isotopic compositions as well as Nd and Hf model ages provide insights into the age and composition of the source rocks, having a continental crustal composition, most likely Mesoarchean felsic rocks.
陨石是一种罕见的撞击玻璃,已知只存在于地球上五个不同的散布区域。我们报道在巴西东北部发现了一个新的布满陨石的地区。最近的发现是在至少90公里长的散布区域内收集到约500个标本的结果。这些群众大多是黑人,因此以巴西米纳斯吉拉斯州的名字命名为“吉拉斯人”,他们的范围从&;1 g ~ 85.4 g,形态各异,很少有卵黄铜矿包裹体。在化学成分上,它们落在总碱-硅图的英安岩和流纹岩场,与其他已知的晶岩相比,SiO2含量相似,Na2O + K2O含量略高。观察到不同样品中微量元素的变化,如Cr和Ni。玻璃的含水量极低,在70到110 ppm之间。目前,用40Ar/39Ar方法对它们形成年龄的最佳估计约为6.3 Ma,尽管可能存在遗传的40Ar*需要更多的分析来完全确定它们的年龄。锶、Nd和Hf同位素组成以及Nd和Hf模式年龄提供了对烃源岩年龄和组成的见解,具有大陆地壳组成,最有可能是中太古宙长英质岩石。
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引用次数: 0
Seafloor weathering can explain the disparate durations of Snowball glaciations 海底风化可以解释雪球冰期的不同持续时间
IF 5.8 1区 地球科学 Q1 GEOLOGY Pub Date : 2025-12-02 DOI: 10.1130/g53722.1
Trent B. Thomas, Francis A. Macdonald, David C. Catling
The Cryogenian Period (720−635 Ma) witnessed two Snowball Earth glaciations: the largest known perturbations to the geologic carbon cycle in Earth history. These two runaway ice-albedo catastrophes naturally test planetary climate stability and habitability. Geochronological data show that the Sturtian glaciation lasted 56 m.y., and the Marinoan was as short as 4 m.y., which is an unexplained difference previously attributed to changing volcanic outgassing rates and dust or ice albedo. Here, we propose that this difference in duration is instead due to changes in the extent of seafloor weathering, which was elevated during both glaciations by an acidic ocean under relatively high CO2. By assuming modern volcanic outgassing rates and a conservative range of ice albedos, we find that seafloor weathering rates 25−53 times higher than modern are required to suppress atmospheric CO2 and maintain glaciation for a 56 m.y. Sturtian glaciation, whereas <15 times higher than modern are required for a 4 m.y. Marinoan glaciation. Rates were plausibly enhanced further by reduced deep-sea sedimentation and low marine sulfate, which would have prevented hydrothermal anhydrite production and created more porous, weatherable oceanic crust. Geochemical data indicate low marine sulfate (<2 mM) during the Sturtian, which rebounded for the Marinoan (up to ∼30 mM), and can account for the different seafloor weathering rates required by our model. Thus, our results suggest seafloor weathering and evolving ocean redox chemistry are critical for determining the duration of Snowball Earth glaciations.
低温期(720 ~ 635 Ma)见证了两次雪球地球冰期,这是地球历史上已知的对地质碳循环最大的扰动。这两个失控的冰反照率灾难自然地测试了行星气候的稳定性和可居住性。地质年代学数据显示,斯图特冰期持续了56英里,而马里诺冰期仅持续了4英里,这是一个无法解释的差异,之前将其归因于不断变化的火山排气率和尘埃或冰的反照率。在这里,我们提出这种持续时间的差异是由于海底风化程度的变化,在两个冰期期间,酸性海洋在相对高的二氧化碳下使海底风化程度升高。通过假设现代火山释气速率和保守的冰反照率范围,我们发现海底风化速率需要比现代高25 - 53倍,以抑制大气中的二氧化碳并维持56 m. Sturtian冰期的冰川。一个4米长的马里诺冰川需要比现在高15倍的水。深海沉积的减少和海洋硫酸盐的减少似乎进一步提高了速率,这将阻止热液硬石膏的产生,并创造出更多孔、更耐候的海洋地壳。地球化学数据表明,在Sturtian时期,海洋硫酸盐含量较低(<2 mM),而在Marinoan时期,海洋硫酸盐含量反弹(高达~ 30 mM),这可以解释我们的模型所要求的不同海底风化速率。因此,我们的研究结果表明,海底风化和不断演变的海洋氧化还原化学对于确定雪球地球冰期的持续时间至关重要。
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引用次数: 0
Mantle-driven, climatically modulated landscape evolution in Southern Patagonia 南巴塔哥尼亚地幔驱动、气候调节的景观演化
IF 5.8 1区 地球科学 Q1 GEOLOGY Pub Date : 2025-12-02 DOI: 10.1130/g53764.1
Victoria M. Fernandes, Andreas Ruby, Fergus McNab, Hella Wittmann, Andrew D. Wickert, Lennart Grimm, Taylor Schildgen
We explore the relative importance of tectonic, geodynamic, and surface processes in driving landscape evolution in Argentine Patagonia using 64 new 10Be exposure ages of fluvial terraces preserved over &gt;250 km along the Shehuén and Santa Cruz rivers (50°S). Terrace ages range from 33 ka to 1.5 Ma and coincide with Patagonian glaciations. We demonstrate that landscapes can respond directly to changes in climate forcing driven by the Mid-Pleistocene Transition: our results reveal a transition to 100-k.y. terrace periodicity, and a transient phase of accelerated incision starting at ca. 1 Ma. A regionally uniform incision rate of 130−180 m m.y.−1 since 1 Ma suggests uplift linked to asthenospheric heating in the Patagonian slab window, while transient accelerated incision suggests convective instabilities in a low-viscosity mantle. We establish a temporal link between climate oscillations, fluvial incision, and mantle-driven epeirogenic uplift.
我们利用在阿根廷巴塔哥尼亚保存的64个新的10Be暴露年代的河流阶地,探讨了构造、地球动力学和地表过程在驱动景观演化中的相对重要性。沿shehusamn河和Santa Cruz河(50°S) 250公里。阶地年龄在33 ~ 1.5 Ma之间,与巴塔哥尼亚冰期吻合。我们证明了景观可以直接响应由中更新世过渡驱动的气候强迫变化:我们的结果揭示了一个100公里/小时的过渡。阶地周期性,以及从约1 Ma开始的加速切口的瞬态阶段。自1 Ma以来,区域均匀切割速率为130 - 180 m m.y. - 1,表明巴塔哥尼亚板块窗的抬升与软流圈加热有关,而瞬变加速切割表明低粘度地幔的对流不稳定。我们建立了气候振荡、河流切割和地幔驱动的造陆隆升之间的时间联系。
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引用次数: 0
Xenolith hydrogen isotope evidence for lower crustal hydration during cycles of flat slab subduction 平板俯冲旋回期间下地壳水化作用的捕虏体氢同位素证据
IF 5.8 1区 地球科学 Q1 GEOLOGY Pub Date : 2025-12-02 DOI: 10.1130/g53815.1
Shelby D. Litton, Dennis L. Newell, Kevin Mahan, Benoit Gasnier, Philippe Goncalves
Dehydrating slabs release aqueous fluids that can cause widespread metasomatism of the overlying lithosphere. Studies of mantle and crustal xenoliths provide critical mineralogical and geochemical constraints on these processes. The Colorado Plateau is a natural laboratory for documenting how chemical modification to the lithosphere impacted tectono-magmatic and geodynamic phenomena in the western United States since the latest Cretaceous. Diatremes of the Oligocene Navajo volcanic field host lower crustal xenoliths with evidence of pre- (M1) and post-hydration (M2) metamorphic textures and mineral assemblages. New hydrogen stable isotope results from hydrous minerals in felsic and mafic lower crustal xenoliths hosted in serpentinized ultramafic microbreccia diatremes show deuterium enrichment during M2. M1 minerals have δD values (Vienna standard mean ocean water, VSMOW) from −103‰ to −69‰ (−82‰ ± 12‰; mean ± 1σ), compared to M2 hydrous phases with values from −81‰ to −23‰ (−50‰ ± 14‰). Using available thermobarometry-based temperature constraints of ∼500 °C for M2, we estimate the δD values of the hydrous fluids as ∼−17‰ ± 15‰. We suggest that Laramide-age, slab-derived aqueous fluids permeated into the lower crust of the Colorado Plateau and that shallow subduction transports and releases water far inboard from subduction zones. Results suggest that this part of the global subduction cycle facilitates hydrous metasomatism of large swaths of continental lithosphere with implications for de-densification and uplift of continental plateaus, subsequent magmatism, and transport of volatiles and metals in modern and ancient flat slab systems.
脱水的板块会释放出含水流体,导致上覆岩石圈的广泛交代作用。地幔和地壳捕虏体的研究为这些过程提供了关键的矿物学和地球化学约束。科罗拉多高原是一个天然的实验室,用于记录自白垩纪晚期以来岩石圈的化学变化如何影响美国西部的构造-岩浆和地球动力学现象。渐新世纳瓦霍火山场的双缝岩中含有下地壳捕虏体,具有水化前(M1)和水化后(M2)变质结构和矿物组合的证据。在蛇纹石化超镁铁质微角砾岩中,长英质和基性下地壳捕虏体中含水矿物的新氢稳定同位素结果显示M2期氘富集。M1矿物的δD值(维也纳标准平均海水,VSMOW)为- 103‰~ - 69‰(- 82‰±12‰,平均值±1σ),而M2水相的δD值为- 81‰~ - 23‰(- 50‰±14‰)。利用现有的基于温度计的温度约束(M2为~ 500°C),我们估计含水流体的δD值为~ - 17‰±15‰。我们认为laramide时代的、板块衍生的含水流体渗透到科罗拉多高原的下地壳中,并且浅层俯冲将水从俯冲带向内部输送和释放。结果表明,全球俯冲旋回的这一部分促进了大陆岩石圈的大面积含水交代作用,这意味着大陆高原的脱密和隆升、随后的岩浆作用以及现代和古代平板系统中挥发物和金属的运输。
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引用次数: 0
Strain controls the electrical conductivity distribution in the lithosphere 应变控制着岩石圈的电导率分布
IF 5.8 1区 地球科学 Q1 GEOLOGY Pub Date : 2025-11-28 DOI: 10.1130/g53957.1
Sinan Özaydın, Patrice F. Rey, Vasileios Chatzaras
Magnetotellurics (MT) utilize measurements of electromagnetic fields at Earth’s surface to image the electrical conductivity distribution at depths from a few meters to ∼200 km. MT is especially powerful for mapping mineralized fluid pathways, as it is sensitive to interconnected minor conductive phases such as fluids, melts, or sulfides. However, conductivity anomalies documented by lithosphere-scale MT surveys do not necessarily capture the geometry of conductivity structures at depth and are often hard to interpret. To address this limitation, we developed a new approach that integrates laboratory-based conductivity with 3-D thermomechanical modeling. Our aim was to test the relationship between strain and conductivity in the case of a pull-apart basin. We show that networks of high-strain zones, which largely govern fluid transfer across the lithosphere, exert a first-order control on spatial distribution of conductivity anomalies. When compared to real MT data from the Marmara pull-apart basin along the North Anatolian fault (northwestern Türkiye), our synthetic survey shows good agreement with observed conductivity anomalies. This relationship suggests that strain plays a key role in controlling electrical conductivity distribution in the lithosphere by facilitating the interconnectivity of conductive phases.
大地电磁学(MT)利用地球表面的电磁场测量来成像从几米到200公里深度的电导率分布。MT对于绘制矿化流体路径尤其有效,因为它对相互连接的次要导电相(如流体、熔体或硫化物)非常敏感。然而,岩石圈尺度的MT测量记录的电导率异常并不一定能捕捉到深度电导率结构的几何形状,而且通常很难解释。为了解决这一限制,我们开发了一种新方法,将基于实验室的电导率与三维热力学建模相结合。我们的目的是测试在拉分盆地的情况下应变和电导率之间的关系。我们发现,在很大程度上控制岩石圈流体传递的高应变带网络对电导率异常的空间分布施加了一级控制。与北安那托利亚断层(西北基耶)马尔马拉拉分盆地的真实MT数据相比,我们的综合测量结果与观测到的电导率异常吻合良好。这种关系表明,应变通过促进导电相的相互联系,在控制岩石圈电导率分布中起着关键作用。
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引用次数: 0
Global distribution, hierarchical clustering classification, and significance of Holocene braid deltas 全新世辫状三角洲全球分布、层次聚类分类及其意义
IF 5.8 1区 地球科学 Q1 GEOLOGY Pub Date : 2025-11-28 DOI: 10.1130/g53851.1
Jason G. Muhlbauer, Christopher M. Fedo
Braid deltas, environments that form where braided rivers meet base level, are more abundant on Holocene Earth than previously appreciated. A worldwide survey identified 786 braid deltas with feeder systems &gt;500 m wide. Braid deltas occur at all latitudes north of the Antarctic Circle and are most abundant by land area in the 45°S−60°S and 60°N−90°N latitude bands. Marine-associated braid deltas compose 71% of the dataset, with the remainder in marginal lacustrine settings. Half of the observed braid deltas do not form radial terminal delta-plain geometry. Hierarchical clustering analysis separates braid deltas into nine clusters that define a classification scheme. Drivers of differentiation include basin type, embayment, sediment supply, and flow intermittence. The classified dataset provides analogues to ancient, nonvegetated deltaic environments and the essential framework for development of braid-delta facies models.
辫状三角洲是在辫状河流与基准面交汇的地方形成的环境,在全新世地球上的辫状三角洲比以前所认识到的要丰富得多。一项全球调查确定了786个辫状三角洲有支线系统。500米宽。辫状三角洲分布于南极圈以北的所有纬度,在45°S ~ 60°S和60°N ~ 90°N纬度带陆地面积最多。与海洋相关的辫状三角洲占数据集的71%,其余的在边缘湖泊环境中。观察到的辫状三角洲中有一半不形成径向末端三角洲平原几何形状。分层聚类分析将辫状三角洲分为9个聚类,这些聚类定义了分类方案。分异的驱动因素包括盆地类型、河口、泥沙供应和水流间断性。分类数据集提供了古无植被三角洲环境的类似物,并为辫状三角洲相模型的发展提供了基本框架。
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引用次数: 0
Intraplate volcanism induced by magmatic solitary waves ascending from the mantle transition zone 由地幔过渡带上升的岩浆孤立波诱发的板内火山活动
IF 5.8 1区 地球科学 Q1 GEOLOGY Pub Date : 2025-11-28 DOI: 10.1130/g53800.1
Changyeol Lee, Nestor G. Cerpa, Jaehoon Lee, Minyoung Huh
Scattered non-age-progressive intraplate volcanism (SIV) is globally widespread, yet its underlying mechanism remains poorly understood. A hypothesis posits that the magma feeding this volcanism originates from hydrous melting of upwelling mantle from the mantle transition zone (MTZ), driven by subduction-induced return flow. Here, we test this hypothesis using a two-dimensional numerical model of passive MTZ upwelling that incorporates magma formation and transport based on two-phase flow theory. Our results show that dehydration of the upwelling MTZ mantle at the 410 km discontinuity initially forms a large, horizontally elongated magmatic solitary wave. Driven by buoyancy, this wave ascends and subsequently disintegrates into multiple, smaller (∼10−20 km in diameter) magmatic solitary waves. These discrete waves ascend randomly through the asthenosphere in a process akin to “mantle rain,” reaching the lithosphere base in ∼10 m.y. Our model provides a viable explanation for SIV.
分散的非年龄进行性板内火山作用(SIV)在全球范围内广泛存在,但其潜在机制尚不清楚。有一种假说认为,供给这种火山活动的岩浆来自地幔过渡带(MTZ)上涌地幔的含水熔融,由俯冲诱导的回流驱动。在这里,我们使用一个基于两相流理论的被动MTZ上涌的二维数值模型来验证这一假设,该模型包含岩浆的形成和运输。结果表明,在410 km不连续处,上升流MTZ地幔的脱水最初形成一个大的、水平伸长的岩浆孤立波。在浮力的驱动下,这种波上升并随后分解成多个较小的(直径约10 - 20公里)岩浆孤立波。这些离散波在一个类似于“地幔雨”的过程中随机地通过软流层上升,在大约10米的时间内到达岩石圈底部。我们的模型为SIV提供了一个可行的解释。
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引用次数: 0
Decoupled monazite and garnet petrochronology reveals short-duration, high-temperature Acadian metamorphism in the Manhattan Schist, New York City, USA 解耦的独居石和石榴石岩石年代学揭示了美国纽约曼哈顿片岩短时间高温阿卡迪亚变质作用
IF 5.8 1区 地球科学 Q1 GEOLOGY Pub Date : 2025-11-25 DOI: 10.1130/g53777.1
Adrian E. Castro, Daniel R. Viete, Stephanie Walker, Steven J. Jaret, Isabella Brunet, Katherine Morin, Dana C. Brenner, Supratik Roy, Ethan F. Baxter, Oliver M. Wolfe, Jay Thomas
The Manhattan Prong (a belt of ancient rock in southern New York, USA) underlies one of the largest population bases in North America yet its tectonometamorphic history remains poorly understood. We performed monazite U-Pb and garnet Sm-Nd petrochronology in association with garnet diffusion chronometry on a sample of the Manhattan Schist from Central Park, New York City. Monazite included in both garnet and matrix yielded a 206Pb/238U date of ca. 438 Ma, though one matrix grain yielded a distinctly younger date of ca. 391 Ma; all monazite analyzed showed identical rare earth element compositions. Garnet yielded a robust isochron date of ca. 386 Ma, interpreted to constrain the timing of garnet growth at near-peak metamorphic conditions. Retention of manganese zoning in 1-mm-scale garnet requires that near-peak metamorphic conditions at ca. 386 Ma persisted for &lt;5 m.y. The Manhattan Schist records a polymetamorphic history involving Taconic greenschist-facies metamorphism at ca. 438 Ma, recorded by relict monazite, then short-lived Acadian kyanite-grade metamorphism at ca. 386 Ma, recorded by garnet and the major rock-forming assemblage. These results are consistent with tectonic models that involve localized, episodic heating of the middle crust, rather than gradual and more pervasive processes of heating and cooling. Our study is an example of the nuanced tectonometamorphic understanding that can be gained by combining accessory and major phase petrochronology.
曼哈顿尖角(美国纽约南部的古岩石带)是北美最大的人口基地之一,但其构造变质史仍鲜为人知。我们对纽约中央公园曼哈顿片岩样品进行了单独居石U-Pb和石榴石Sm-Nd岩石年代学和石榴石扩散年代学。石榴石和基体中含有的独居石的206Pb/238U年代值约为438 Ma,尽管一个基体颗粒的年代值明显较低,约为391 Ma;所有分析的独居石显示相同的稀土元素组成。石榴石产生了大约386 Ma的可靠等时线日期,解释为限制石榴石在近峰变质条件下生长的时间。1毫米尺度石榴石中锰分带的保留要求约386 Ma的近峰变质条件持续了1年。曼哈顿片岩记录了一个多变质史,其中包括约438 Ma的塔科绿片岩相变质作用,由残余的独居石记录,然后是约386 Ma的短暂的阿卡迪亚蓝晶石级变质作用,由石榴石和主要的造岩组合记录。这些结果与构造模型相一致,这些模型涉及局部的、偶发的中地壳加热,而不是渐进的、更普遍的加热和冷却过程。我们的研究是通过结合副相和主相岩石年代学来获得细致的构造变质学理解的一个例子。
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引用次数: 0
Not much to show for it: Late Pleistocene dynamics of migrating megadunes in the Rub’ al-Khali, Saudi Arabia, indicate minimal preservation of their deposits 这方面的证据并不多:在沙特阿拉伯的Rub ' al-Khali,晚更新世迁移的巨型沙丘的动态表明,它们的沉积物保存得很少
IF 5.8 1区 地球科学 Q1 GEOLOGY Pub Date : 2025-11-20 DOI: 10.1130/g53651.1
Charlie Bristow, Nicholas Lancaster, Khalid Al-Ramadan, Christina Neudorf, Amanda Keen-Zebert
Luminescence dating of interdune sabkha sediments and cross strata deposited on the lee face of a 160-m-high mega-crescentic dune in the eastern Rub’ al-Khali sand sea provides information on dune dynamics and preservation potential. Optically stimulated luminescence ages show that the rates of dune accumulation varied during the latest Pleistocene and Holocene. Sedimentary structures indicate that megadune migration was the result of strong northwesterly “Shamal” winds. During the same interval of the late Pleistocene and early Holocene, linear dunes in the northeastern United Arab Emirates were also accumulating rapidly, indicating that the period 16−9 ka was characterized by regionally widespread dune formation and/or reworking. The dune has subsequently migrated to the SSE almost 900 m since the early Holocene, at an average rate of 77 m/k.y., indicating persistence of the Shamal wind system for at least 20 k.y. Rates of megadune migration and wet sabkha accumulation reveal that, despite their very large size, less than 1% of the megadune would be preserved in a sedimentary record.
rubal - khali沙海东部一个160米高的巨型新月形沙丘背风面沉积的丘间sabkha沉积物和交叉地层的发光测年提供了沙丘动力学和保存潜力的信息。光激发发光年龄表明,在最新更新世和全新世期间,沙丘堆积的速率发生了变化。沉积构造表明,大迁移是强烈的西北“沙马”风的结果。在晚更新世-全新世早期的同一时期,阿联酋东北部线状沙丘也在快速堆积,表明16 ~ 9 ka时期是一个区域性广泛的沙丘形成和改造的时期。自全新世早期以来,沙丘以77 m/ ky的平均速率向东南海带迁移了近900 m。,表明沙马风系统的持续时间至少为20ky。大旋风的迁移速率和湿沙伯卡的积累速率表明,尽管它们的规模非常大,但只有不到1%的大旋风会被保存在沉积记录中。
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引用次数: 0
Mantle chlorine isotope signature and melt−rock interaction revealed by apatite at the Southwest Indian Ridge 西南印度洋脊磷灰石揭示的地幔氯同位素特征及熔融岩相互作用
IF 5.8 1区 地球科学 Q1 GEOLOGY Pub Date : 2025-11-19 DOI: 10.1130/g53563.1
Naixiao Xu, Hao Cheng, Geoffrey D. Bromiley, Henry J.B. Dick, Lingmin Zhang
The extent of chlorine isotope heterogeneity within Earth’s mantle remains a subject of active debate. To contribute to this discussion, we present the first in situ chlorine isotope measurements of apatite from Integrated Ocean Drilling Program Hole U1473A (Southwest Indian Ridge) gabbros. The apatites record a pristine mantle δ37Cl value of −0.51‰ ± 0.04‰, consistent with global mid-ocean ridge basalt averages. Systematic negative covariations between δ37Cl and Cl content across lithological boundaries cannot be explained by fractional crystallization alone. Compared to altered gabbros from Ocean Drilling Program Hole 735B (Atlantis Bank), apatites from U1473A show lower δ37Cl values. The preservation of euhedral textures and constant OH concentrations in these apatites, combined with amphibole geochemistry, rules out lower-temperature seawater alteration. Instead, these trends reflect high-temperature processes, including melt−rock interaction, brine assimilation, or mantle heterogeneity. Our findings demonstrate that δ37Cl variability in mantle-derived apatites records both crustal recycling and intrinsic mantle heterogeneity, confirming their utility as reliable tracers of deep Earth volatile cycling.
地幔中氯同位素非均质性的程度仍然是一个积极争论的主题。为了促进这一讨论,我们提出了综合海洋钻井计划U1473A孔(西南印度岭)辉长岩磷灰石的首次原位氯同位素测量。磷灰石的原始地幔δ37Cl值为- 0.51‰±0.04‰,与全球洋中脊玄武岩平均值一致。δ37Cl和Cl含量在岩性边界上的系统负共变不能仅用分馏结晶来解释。与大洋钻探计划735B孔(亚特兰蒂斯滩)蚀变辉长岩相比,U1473A磷灰石的δ37Cl值较低。这些磷灰石中保存的自面体结构和恒定的OH浓度,结合角闪洞地球化学,排除了低温海水蚀变的可能性。相反,这些趋势反映了高温过程,包括熔体-岩石相互作用、盐水同化或地幔非均质性。研究结果表明,地幔源磷灰石的δ37Cl变化记录了地壳再循环和固有地幔非均质性,证实了它们作为深部地球挥发循环可靠示踪剂的实用性。
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引用次数: 0
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Geology
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