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The degradation of some volatile compounds in evening primrose oil under UV/TiO2 process UV/TiO2工艺降解月见草油中部分挥发性化合物
4区 农林科学 Q4 CHEMISTRY, APPLIED Pub Date : 2023-10-10 DOI: 10.3989/gya.0992221
F.G. Pan, X.M. Chen, E.Q. Yang, B.Q. Liu
Off-flavor is one of the limiting factors in the quality and commercial acceptability of evening primrose oil (EPO). The results of this study demonstrated that ultraviolet light irradiated with titanium dioxide (UV/TiO2) was able to effectively reduce odorous aldehyde concentrations, which would produce undesired flavors. Specifically, reductions in the E-2-Decenal, 1-octen-3-ol and hexanoic acid in EPO reached 50, 75.2 and 61.4% after a UV/TiO2 process of 5 min, respectively. The odor active values (OAV) and hierarchical cluster analysis (HCA) showed that the result of the 5 min group was similar to that of the original oil. In addition, the physicochemical characteristics of EPO after processing did not change significantly. The result of the aroma profile analysis was consistent with the OAV and HCA results. Therefore, it has been concluded that 5 min UV/TiO2 treatment could degrade some volatile compounds and provide a potential deodorization method for industry.
难闻的味道是制约月见草油质量和商业可接受性的因素之一。本研究的结果表明,用二氧化钛(UV/TiO2)照射的紫外光能够有效地降低会产生不良风味的臭醛浓度。在UV/TiO2作用5 min后,EPO中e -2-癸烯醛、1-辛烯-3-醇和己酸的还原率分别达到50%、75.2和61.4%。气味活性值(OAV)和层次聚类分析(HCA)结果表明,5 min组的气味活性值与原始油相似。此外,EPO加工后的理化特性没有明显变化。香气谱分析结果与OAV和HCA分析结果一致。综上所述,5min UV/TiO2处理可降解部分挥发性化合物,为工业脱臭提供了一种潜在的方法。
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引用次数: 0
Stabilization of organic extra virgin olive oil using maceration and ultrasound-assisted extraction of natural antioxidants from Artemisia absinthium leaves 用浸渍法和超声波辅助提取苦艾叶中的天然抗氧化剂来稳定有机特级初榨橄榄油
4区 农林科学 Q4 CHEMISTRY, APPLIED Pub Date : 2023-10-10 DOI: 10.3989/gya.0984221
A. Bezzezi, M. Boulares, M. Arfaoui, O. Ben Moussa, M. Hassouna
Olive oil is the most popular product derived from Olea europaea L. due to its organoleptic characteristics and its beneficial effects on human health. Nowadays, there is a growing interest in olive oil enrichment with medicinal plants. In this regard, Artemisia absinthium L. is an edible source of antioxidants. The aim of the present study was to improve the oxidative stability and the nutritional value of Organic Tunisian Chetoui Olive oil by its enrichment with the phenolic compounds in Artemisia absinthium. The enrichment carried out by maceration and ultrasound-assisted extraction did not affect the organic criteria of olive oil. The comparative study, performed during one year of storage, showed that ultrasound-assisted extraction led to the lowest final peroxide and extinction coefficient values. At the end of storage, this method increased oleic acid content and biophenol contents. Furthermore, the anti-radical activities of enriched samples were higher than the control.
橄榄油是欧洲油橄榄中最受欢迎的产品,因为它的感官特性和对人体健康的有益作用。如今,人们对用药用植物富集橄榄油越来越感兴趣。在这方面,苦艾草是抗氧化剂的可食用来源。本研究的目的是通过添加苦艾草中的酚类化合物来提高突尼斯Chetoui有机橄榄油的氧化稳定性和营养价值。浸渍和超声辅助提取对橄榄油的有机标准没有影响。在一年的储存期间进行的比较研究表明,超声辅助提取导致最低的最终过氧化物和消光系数值。在贮藏末期,该方法提高了油酸含量和生物酚含量。此外,富集样品的抗自由基活性高于对照组。
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引用次数: 0
Rapid detection of argan oil adulteration by frying oils using laser induced fluorescence spectroscopy combined with chemometrics tools 激光诱导荧光光谱结合化学计量学快速检测油炸油中摩洛哥坚果油的掺假
4区 农林科学 Q4 CHEMISTRY, APPLIED Pub Date : 2023-10-10 DOI: 10.3989/gya.0565221
S. Farres, L. Srata, M. Chikri, S. Addou, F. Fethi
There is a contentious need for robust and rapid methodologies for maintaining the authenticity of foods. The aim of this study was to detect and quantify argan oil adulteration using Laser Induced Fluorescence (LIF) spectroscopy coupled with chemometric methods. Principal Component Analysis (PCA) and Partial Least Squares Regression (PLSR) were used to assess argan oil authenticity; PCA was used to classify samples according to their quality and the PLS model to determine the amount of adulterants in pure argan oil. The correlation coefficient of the obtained model was about 0.99, with Root Mean Square Error of Prediction (RMSEP) and Standard Error of Prediction (SEP) of 2%. This study demonstrated the feasibility of LIF spectroscopy combined with chemometric tools to identify adulterants in pure argan oil from a percentage of adulteration, of 0.35 % without the need to destruct samples.
有一个有争议的需要稳健和快速的方法来维持食品的真实性。本研究的目的是利用激光诱导荧光(LIF)光谱结合化学计量方法检测和定量摩洛哥坚果油的掺假。采用主成分分析(PCA)和偏最小二乘回归(PLSR)评估摩洛哥坚果油的真实性;用主成分分析法对样品进行质量分类,用PLS模型确定纯摩洛哥坚果油中掺假物的含量。所得模型的相关系数约为0.99,预测均方根误差(RMSEP)和预测标准误差(SEP)均为2%。本研究证明了LIF光谱结合化学计量工具在不破坏样品的情况下,在掺假率为0.35%的纯摩洛哥坚果油中识别掺假的可行性。
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引用次数: 0
Antioxidant and anticancer activities of peanut (Arachis hypogaea L.) skin ultrasound extract 花生皮肤超声提取物的抗氧化和抗癌活性
4区 农林科学 Q4 CHEMISTRY, APPLIED Pub Date : 2023-10-10 DOI: 10.3989/gya.0990221
K.S.M. Hammad, A.M. El-Roby, S.M. Galal
This study evaluates the effect of ultrasound-assisted extraction on the extractability of polyphenols from peanut skins (PS) and their antioxidant, and anticancer activities. The extraction was performed with solid/solvent ratios of 1:20 and 1:30 (w/v) at ultrasound intensity ranging from 5.8 to 15.4 W/cm2 for different extraction times (10, 20, 30 and 40 min). The highest polyphenol yield was 167.46 mg GAE/g dried PS. The most abundant polyphenols were catechin, syringic acid, and vanillic acid. The PS ultrasound extract (PSUE) increased the oxidative stability of sunflower oil by four times its initial level. PSUE possessed high inhibitory activity against MCF-7, HepG-2, HCT-116, and PC-3 cancer cell lines, with IC50 ranging from 1.85 ± 0.13 to 6.1 ± 0.43 μg/ml. In addition, the cytotoxicity of PSUE was examined on HFB4 human normal melanocytes using the MTT assay. These results suggest that PSUE can be used as a natural antioxidant and anticancer agent.
研究了超声辅助提取对花生皮中多酚类物质提取率及其抗氧化、抗癌活性的影响。超声强度为5.8 ~ 15.4 w/ cm2,料液比分别为1:20和1:30 (w/v),提取时间为10、20、30、40 min。其多酚含量最高,为167.46 mg GAE/g,含量最高的是儿茶素、丁香酸和香草酸。PS超声提取物(PSUE)使葵花籽油的氧化稳定性提高到初始水平的4倍。PSUE对MCF-7、HepG-2、HCT-116、PC-3等癌细胞均有较高的抑制活性,IC50范围为1.85±0.13 ~ 6.1±0.43 μg/ml。此外,采用MTT法检测PSUE对HFB4人正常黑素细胞的细胞毒性。这些结果表明,PSUE可以作为天然的抗氧化剂和抗癌剂。
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引用次数: 0
Untargeted lipidomics approach using LC-Orbitrap HRMS to discriminate lard from beef tallow and chicken fat for the authentification of halal 非靶向脂质组学方法,使用LC-Orbitrap HRMS区分猪油、牛油和鸡脂肪,用于清真认证
4区 农林科学 Q4 CHEMISTRY, APPLIED Pub Date : 2023-10-10 DOI: 10.3989/gya.0980221
A. Windarsih, N.K.A. Bakar, A. Rohman, F.D.O. Riswanto, Y. Erwanto
This research aimed to perform a lipidomics study using liquid chromatography-high resolution mass spectrometry (LC-HRMS) to identify lard, beef tallow and chicken fat. A total of 292, 345, and 403 lipid compounds were observed in lard, beef tallow, and chicken fat, respectively. The lipid groups of AcHexStE (acyl hexosyl stigmasterol ester), biotinylPE (biotinylphosphoetanolamine), LPC (lysophosphatidylcholine), MePC (monoetherphosphatidylcholine), PC (phosphatidylcholine) and PI (phosphoinocitol) were found to be specific for lard. The principal component analysis (PCA) and partial least square-discriminant analysis (PLS-DA) successfully differentiated lard from beef tallow and chicken fat. This research suggested that the untargeted lipidomics technique using LC-HRMS combined with chemometrics could be used to discriminate lard from beef tallow and chicken fat. This method is a promising technique for the detection of lard adulteration in beef tallow and chicken fat for halal authentication purposes.
本研究旨在采用液相色谱-高分辨率质谱(LC-HRMS)技术对猪油、牛油和鸡脂肪进行脂质组学鉴定。在猪油、牛脂和鸡脂中分别检测到292、345和403种脂质化合物。发现猪油特异性的脂质基团为AcHexStE(酰基己糖基豆甾醇酯)、biotinylPE(生物素基磷酸乙醇胺)、LPC(溶血磷脂酰胆碱)、MePC(单醚磷脂酰胆碱)、PC(磷脂酰胆碱)和PI(磷酸菌醇)。主成分分析(PCA)和偏最小二乘判别分析(PLS-DA)成功地将猪油与牛脂和鸡脂区分开来。本研究表明,LC-HRMS结合化学计量学的非靶向脂质组学技术可用于猪油、牛脂和鸡脂的鉴别。该方法是一种很有前途的技术检测猪油掺假牛油和鸡脂肪的清真认证目的。
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引用次数: 0
Estimation of mass transfer terms in the lycopene recovery employing Moringa oleifera Lam oil as solvent 以辣木油为溶剂回收番茄红素的传质项估算
4区 农林科学 Q4 CHEMISTRY, APPLIED Pub Date : 2023-10-10 DOI: 10.3989/gya.0223221
Y. Sariego, A. Pita, M. González, G. Acosta, B. Zumalacárregui, L. Cruz
The aim of this work was to assess the terms associated with mass transfer in the lycopene recovery from the waste of a tomato canning plant. Moringa oleifera Lam oil was employed as solvent. An ultrasonic extraction was carried out on skin and seeds. The operational variables were temperature (skin: 45, 60, 75, 90 ºC; seed: 45, 60, 75 ºC), matrix/solvent ratio (m/v) (1:20, 1:25, 1:30), particle size (skin: < 1, 1-2, > 3.15 mm; seed: < 1, 1-2, > 2 mm) and extract separation method (filtration and centrifugation). Kinetic constant, lycopene concentration on the solid surface, volumetric coefficient of mass transfer and effective diffusivity were determined. The more the kinetic constant increased, the higher the volumetric coefficient of mass transfer was. Effective diffusivity increased with temperature. Activation energy values suggest a possible deterioration of lycopene at temperatures higher than the optimum. The use of M. oleifera oil as solvent should increase the biological value of the lycopene extracts.
本研究的目的是评估从番茄罐头厂废料中回收番茄红素过程中与传质有关的条件。以辣木油为溶剂。采用超声提取法对果皮和种子进行了提取。操作变量为温度(皮肤:45、60、75、90℃;种子:45、60、75ºC),基质/溶剂比(m/v)(1:20、1:25、1:30),粒径(皮:<1,1 -2, >3.15毫米;种子:& lt;1,1 -2, >2 mm)和萃取分离方法(过滤和离心)。测定了动力学常数、固体表面番茄红素浓度、体积传质系数和有效扩散系数。动力学常数越大,传质体积系数越大。有效扩散系数随温度升高而增大。活化能值表明番茄红素在高于最佳温度时可能变质。利用油橄榄油作为溶剂,可以提高番茄红素提取物的生物学价值。
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引用次数: 0
Optimization and evaluation of a hydration method for producing high quality oil and defatted meal from hemp seed kernels 从大麻籽仁中提取高品质油和脱脂粕的水化方法的优化与评价
4区 农林科学 Q4 CHEMISTRY, APPLIED Pub Date : 2023-10-10 DOI: 10.3989/gya.1128212
S. Wang, W. Wu
A green and efficient method for producing high quality oil and defatted meal is in high demand, which has promoted the development of a hydration method for extracting oils from hem seed kernels. The hydration method optimized in this study recovered > 96% oil, which was further proved by infrared spectra, and extracted > 91% tocopherols, vitamin A, carotenoids, coenzyme Q10, phytosterols and squalene into the oil phase; while only small portions of flavonoids, other phenolic compounds and free fatty acids were extracted. The defatted meal was rich in water-soluble vitamins (including thiamin, riboflavin, niacin, pyridoxine, folate and vitamin C), proteins, dietary carbohydrates and phospholipids. The hydration method produced oils with lower AV or PV compared to solvent extraction, supercritical CO2 and cold-pressing methods and a defatted meal with a protein content (52.69%) which was significantly higher than that obtained by supercritical CO2 and cold-pressing methods. The hydration method is a type of green technology for sustainablly processing hempseeds.
人们迫切需要一种绿色高效的方法来生产高质量的油脂和脱脂粕,这促进了水合提取法的发展。本研究优化的水化方法回收了>96%的油,经红外光谱进一步证实,提取>91%生育酚、维生素A、类胡萝卜素、辅酶Q10、植物甾醇和角鲨烯成油相;而黄酮类化合物、其他酚类化合物和游离脂肪酸只提取了一小部分。脱脂餐富含水溶性维生素(包括硫胺素、核黄素、烟酸、吡哆醇、叶酸和维生素C)、蛋白质、膳食碳水化合物和磷脂。与溶剂萃取、超临界CO2和冷压法相比,水化法得到的油的AV和PV值较低,而脱脂粕的蛋白质含量(52.69%)显著高于超临界CO2和冷压法。水化法是一种可持续加工大麻籽的绿色技术。
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引用次数: 0
What are the most effective biotic and abiotic factors affecting fatty acid composition of Garra rufa (Heckel, 1843)? 影响鹿茸脂肪酸组成的最有效的生物和非生物因素是什么(Heckel, 1843)?
4区 农林科学 Q4 CHEMISTRY, APPLIED Pub Date : 2023-10-10 DOI: 10.3989/gya.0224221
N. Şen Özdemir
Specimens of Garra rufa were collected from a warm river and a cool stream in the Bingöl Province, Turkey, once a month over a period of one year. The effects of month, season, gender and location on the fatty acid composition in the muscle and the lipid content were investigated and dietary marker fatty acids were used to obtain dietary preferences in different locations (Ilıcalar, Garip) and periods. Total lipid change was seasonally significant (ANOSIM-R=0.49) at both locations and 18:1ω9, 20:5ω3 and 20:6ω3 were the most abundant dietary fatty acids. Although G. rufa are predominantly herbivores, they can also feed omnivorously on mixed diets depending on the presence and absence of their primary diet. The effect of season was significant on fatty acid composition, regardless of the location (Pperm=0.001). Significant seasonal changes in all the fatty acid compositions could be attributed to seasonal changes in the abundance and diversity of dietary sources in the environment due to the effect of temperature.
在一年的时间里,每个月从土耳其Bingöl省的一条温暖的河流和一条凉爽的溪流中采集Garra rufa的标本。研究了月份、季节、性别和地点对肌肉脂肪酸组成和脂肪含量的影响,并利用膳食标志物脂肪酸获得不同地点(Ilıcalar、Garip)和时期的饮食偏好。两个地点的总脂质变化具有显著的季节差异(ANOSIM-R=0.49),其中18:1ω9、20:5ω3和20:6ω3是最丰富的膳食脂肪酸。虽然芦花草主要是食草动物,但它们也可以根据其主要饮食的存在和缺失,以混合饮食为食。季节对脂肪酸组成的影响是显著的,与地点无关(Pperm=0.001)。所有脂肪酸组成的显著季节性变化可归因于温度影响下环境中膳食来源丰度和多样性的季节性变化。
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引用次数: 0
Effects of diets rich in monounsaturated fatty acids on the management and prevention of insulin resistance: A systematic review 富含单不饱和脂肪酸的饮食对胰岛素抵抗管理和预防的影响:一项系统综述
4区 农林科学 Q4 CHEMISTRY, APPLIED Pub Date : 2023-10-10 DOI: 10.3989/gya.1125212
E.L.L. Ramos, M.F.C. Lima, A.C.S.F. Azevedo, M.G.F. Lopes, A.P.B. Moreira, C.T. Souza
Insulin resistance (IR), which is linked to obesity, is a mechanism associated with metabolic diseases, mainly type 2 diabetes mellitus. Studies have shown that monounsaturated fatty acids (MUFAs) have anti-inflammatory and anti-oxidative properties which positively affect IR. This systematic review examined the effects of MUFAs from different sources on IR in obese or overweight patients with or without metabolic syndrome. A search was carried out in the PubMed/Medline and Bireme/VHL databases, and data from 16 studies were analysed according to the Preferred Reporting Items for Systematic Reviews and Meta-Analyses guidelines. The intervention time ranged from 1 day to 5.2 years. All participants were overweight or obese; some had central obesity, a moderate risk of cardiovascular disease, low high-density lipoprotein levels, altered fasting glucose levels, prediabetes or type 2 diabetes mellitus. This systematic review provides evidence that MUFA-rich diets can improve IR.
胰岛素抵抗(IR)与肥胖有关,是一种与代谢性疾病(主要是2型糖尿病)相关的机制。研究表明,单不饱和脂肪酸(MUFAs)具有抗炎和抗氧化特性,对IR有积极影响。本系统综述研究了不同来源的MUFAs对伴有或不伴有代谢综合征的肥胖或超重患者IR的影响。检索PubMed/Medline和Bireme/VHL数据库,并根据系统评价和荟萃分析指南的首选报告项目对16项研究的数据进行分析。干预时间为1天至5.2年。所有参与者都超重或肥胖;其中一些人患有中枢性肥胖,心血管疾病风险中等,高密度脂蛋白水平低,空腹血糖水平改变,患有前驱糖尿病或2型糖尿病。这一系统综述提供了富含mufa的饮食可以改善IR的证据。
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引用次数: 0
Palm olein and perilla seed oil blends for the improvement of nutritional and thermal stability 棕榈油和紫苏籽油混合用于改善营养和热稳定性
4区 农林科学 Q4 CHEMISTRY, APPLIED Pub Date : 2023-10-10 DOI: 10.3989/gya.0220221
A. Dhyani, R. Chopra, P.K. Singh, M. Garg
This study aimed to develop a healthy blended oil with a balanced fatty acid ratio, as well as high thermal and oxidative stability. The blending of highly saturated Palm olein (PO) with polyunsaturated fatty acid-rich (PUFA) Perilla seed oil (PeO) in two different proportions, 70:30 (B1) and 80:20 (B2) v/v was studied. The physicochemical parameters, fatty acid composition, and oxidative stability of cold-pressed perilla seed oil (PeO), palm olein, and their blends were analyzed. The blends presented higher oxidative stability (6.5 h) with enhanced α-linolenic acid content (18%) than pure oils. The fatty acid ratio in both blend (B1- 1:1.4:1 and B2- 1.5:1.5:1) was found close to the WHO recommended ratio i.e., 1:1-5:1. The evaluation of the thermal stability of the blended oils revealed that PeO oxidized quickly during heating (Peroxide value-15.16 meq O2/kg); whereas thermal stability improved with blending (Peroxide value: B1-7.92 and B2- 7.69 meq O2/kg).
本研究旨在开发一种脂肪酸比例平衡、热稳定性和氧化稳定性高的健康混合油。研究了高饱和棕榈油(PO)与富含多不饱和脂肪酸(PUFA)的紫苏籽油(PeO)以70:30 (B1)和80:20 (B2)两种不同比例的共混。对冷榨紫苏籽油(PeO)、棕榈油及其共混物的理化参数、脂肪酸组成和氧化稳定性进行了分析。与纯油相比,共混物具有更高的氧化稳定性(6.5 h)和α-亚麻酸含量(18%)。发现两种混合物中的脂肪酸比例(B1- 1:1.4:1和B2- 1.5:1.5:1)接近世界卫生组织推荐的比例,即1:1-5:1。混合油的热稳定性评价表明,PeO在加热过程中氧化迅速(过氧化值为15.16 meq O2/kg);过氧化值分别为B1-7.92和B2- 7.69 meq O2/kg。
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引用次数: 0
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Grasas y Aceites
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