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Oil quality characterization of the Arauco variety from the main olive growing areas of Mendoza (Argentina) 阿根廷门多萨主要橄榄种植区阿劳科(Arauco)品种油质特征
IF 1.4 4区 农林科学 Q4 CHEMISTRY, APPLIED Pub Date : 2022-01-13 DOI: 10.3989/gya.0773201
A. Banco, C. Puertas, E. Trentacoste, R. Monasterio
‘Arauco’ forms part of the over two thousand olives (Olea europaea L.) varieties identified worldwide with the peculiarity of being the only recognized variety from Argentina. In this work, the fruit and oil characteristics from the ‘Arauco’ variety cultivated in the three main olive growing zones of Mendoza province (Argentina) were evaluated over two harvests (2016 and 2017). The characteristics assessed were oil and water concentrations, pulp/pit ratio, industrial yield, oxidative stability, fatty acid profile, total phenols and total flavonoids, among others. The results showed relatively high oleic acid and phenolic contents, together with low acidity and extinction coefficients (K232 and K270), as well as a well-balanced fatty acid profile. In addition, three interesting relationships among oxidative stability and ratios of monounsaturated fatty acids/polyunsaturated fatty acids (R2=0.96), oleic/linoleic (R2=0.96) and stearic acid (R2=0.93) were observed. These results showed that the ‘Arauco’ variety cultivated in Mendoza provides excellent oil quality.
“Arauco”是世界上两千多种橄榄(Olea europaea L.)品种中的一种,它是唯一被认可的来自阿根廷的品种。在这项工作中,对阿根廷门多萨省三个主要橄榄种植区种植的“阿劳科”品种的果实和油脂特性进行了两次收获(2016年和2017年)的评估。评估的特性包括油和水浓度、浆/坑比、工业产率、氧化稳定性、脂肪酸谱、总酚和总黄酮等。结果表明,油酸和酚类含量较高,酸度和消光系数(K232和K270)较低,脂肪酸分布平衡良好。此外,氧化稳定性与单不饱和脂肪酸/多不饱和脂肪酸比值(R2=0.96)、油酸/亚油酸比值(R2=0.96)和硬脂酸比值(R2=0.93)之间存在3个有趣的关系。这些结果表明,在门多萨种植的“阿劳科”品种提供了优良的油品质。
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引用次数: 0
Fatty acid composition, phytochemicals and antioxidant potential of Capparis spinosa sedes 刺山柑的脂肪酸组成、植物化学物质及抗氧化潜力
IF 1.4 4区 农林科学 Q4 CHEMISTRY, APPLIED Pub Date : 2022-01-13 DOI: 10.3989/gya.0890201
A. Bodaghzadeh, K. Alirezalu, S. Amini, A. Alirezalu, R. Domínguez, J. Lorenzo
The present study evaluates the contents in bioactive compounds, antioxidant activity, oil content and fatty acid composition of Capparis spinosa seeds. Samples were collected from 5 different habitats (AH: Ahar; KU: Kurdistan; U1, U2 and U3: Urmia) in Iran. The oil content in the seeds ranged from 16 to 27%. The predominant fatty acid was linoleic acid (45-50%) followed by oleic acid (30-39%), palmitic acid (2-8%) and stearic acid (2-3%). Total phenolic content (TPC) varied from 16.3 to 24.2 mg GAE/ g DW; total flavonoid content (TFC) ranged from 1.48 to 3.05 mg QE/g DW; and the antioxidant activity (DPPH assay) of the seeds was between 35 and 63%. The compounds obtained from different genotypes of C. spinosa seeds had different compositions, great antioxidant capacity and unsaturated fatty acids, and therefore could be a prospective source of natural bioactive molecules for the food and health industry.
本研究对刺山柑种子的生物活性成分、抗氧化活性、含油量和脂肪酸组成进行了评价。从伊朗的5个不同栖息地(AH:Ahar;KU:库尔德斯坦;U1、U2和U3:Urmia)采集样本。种子中的含油量在16%到27%之间。主要的脂肪酸是亚油酸(45-50%),其次是油酸(30-39%)、棕榈酸(2-8%)和硬脂酸(2-3%)。总酚含量(TPC)在16.3至24.2mg GAE/g DW之间变化;总黄酮含量(TFC)范围为1.48至3.05mg QE/g DW;种子的抗氧化活性(DPPH测定)在35%和63%之间。从不同基因型C。刺五加种子具有不同的成分、强大的抗氧化能力和不饱和脂肪酸,因此可能成为食品和保健行业天然生物活性分子的潜在来源。
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引用次数: 1
Effects of an integrated harvest system on the quality of olive fruit for small producers 综合收获系统对小生产者橄榄果实质量的影响
IF 1.4 4区 农林科学 Q4 CHEMISTRY, APPLIED Pub Date : 2022-01-12 DOI: 10.3989/gya.1006202
E. Plasquy, G. Blanco-Roldán, M. C. Florido, J. García
Small producers confront specific challenges when they opt to produce high-quality olive fruit. Limited resources for investing in harvest machinery and manpower are the main reasons for continuing a traditional harvest method that puts the final product and its economic value at risk. This paper discusses the efficiency of an integrated harvest system as a possible solution to these specific challenges. The system is formed by a newly designed manual harvesting device and the use of a cooling room near the olive grove. Both systems were evaluated to assess their feasibility for optimum conditions before processing. The combined effect of the harvesting method and cold storage on the fruit characteristics (incidence of decay, skin color, weight loss, firmness, respiration, and ethylene production) was evaluated on three different varieties (‘Arbequina’, ‘Picual’ and ‘Verdial’) and four different storage times (0, 4, 8, and 14 days). The results indicate that the proposed harvesting method in combination with an appropriate cooling system offers an affordable alternative for obtaining fruit with the best physiological characteristics.
当小生产者选择生产高质量的橄榄果时,他们面临着特殊的挑战。投资于收获机械和人力的资源有限是继续采用传统收获方法的主要原因,这种方法会使最终产品及其经济价值面临风险。本文讨论了综合收获系统的效率,作为应对这些具体挑战的可能解决方案。该系统由一个新设计的手动收割装置和橄榄林附近的冷却室组成。对这两种系统进行了评估,以评估其在加工前最佳条件下的可行性。在三个不同品种(“Arbequina”、“Picual”和“Verdial”)和四个不同的贮藏时间(0、4、8和14天)上,评估了收获方法和冷藏对果实特性(腐烂发生率、肤色、体重减轻、硬度、呼吸和乙烯生成)的综合影响。结果表明,所提出的收获方法与适当的冷却系统相结合,为获得具有最佳生理特性的水果提供了一种负担得起的替代方案。
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引用次数: 0
Bioactivity of betulinic acid nanoemulsions on skin carcinogenesis in transgenic mice K14E6 白桦酸纳米乳对转基因小鼠K14E6皮肤癌变的生物活性
IF 1.4 4区 农林科学 Q4 CHEMISTRY, APPLIED Pub Date : 2022-01-12 DOI: 10.3989/gya.0553201
B. Agame-Lagunes, M. Alegria-Rivadeneyra, A. Alexander-Aguilera, R. Quintana-Castro, C. Torres-Palacios, P. Grube-Pagola, C. Cano-Sarmiento, R. García-Varela, H. García
Alternative therapies for cancer treatment have been developed using bioactive compounds such as betulinic acid (BA). The objective of this study was to investigate the bioactivity of BA in its free form and compare it with its nano-encapsulated form under a skin carcinogenesis protocol in a genetically modified murine model. K14E6 and FVB mice were divided into four groups to be treated with free BA and with betulinic acid nanoemulsion (BANE). Lecithin enriched with medium chain fatty acids (MCFAs) was employed as an emulsifier to prepare the nanoemulsions with a mean droplet size of 40 nm. Skin tumors were induced by exposure to DMBA and TPA directly to the transgenic mice. Tumor development was completely inhibited by BANE and by 70% with free BA. This was validated by histological sections and the gene expression of the Cdk4 and Casp8 genes.
利用生物活性化合物,如白桦酸(BA),已经开发出癌症治疗的替代疗法。本研究的目的是在转基因小鼠模型中研究游离形式的BA的生物活性,并将其与纳米封装形式的BA在皮肤致癌机制下进行比较。将K14E6和FVB小鼠分为4组,分别给予游离BA和白桦酸纳米乳。以富含中链脂肪酸的卵磷脂为乳化剂,制备了平均粒径为40 nm的纳米乳液。转基因小鼠直接暴露于DMBA和TPA诱导皮肤肿瘤。贝恩完全抑制了肿瘤的发展,游离BA抑制了70%。通过组织切片和Cdk4和Casp8基因的表达证实了这一点。
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引用次数: 0
Development and characterization of ethanol-free spearmint essential oil nanoemulsion for food applications using the low energy technique 利用低能技术开发和表征食品用无乙醇留兰香精油纳米乳液
IF 1.4 4区 农林科学 Q4 CHEMISTRY, APPLIED Pub Date : 2022-01-12 DOI: 10.3989/gya.0666201
A. Edris
Different emulsifiable concentrates containing spearmint essential oil (SEO) were made and evaluated for their potential for giving ethanol-free nanoemulsion spontaneously upon dilution into water. Each one of these formulas had its specific composition regarding the type of excipients, surfactants, surfactant/SEO ratio and surfactant concentration. The results of this evaluation indicated that the chemical composition of SEO has a profound effect on the formation and physical stability of the nanoemulsion. The incorporation of excipients such as long chain triglyceride and propylene glycol into the emulsifiable concentrates at only 1.0% can lead to a stable nanoemulsion that resists Ostwald ripening. A particle size measurement showed that the diameter of SEO in the nanoemulsion was 28.2 nm and its nanostructure was maintained for 3 months. The application of a mixture of binary nonionic food-permitted surfactants enhanced the thermal stability of the nanoemulsion at up to 50 ᵒC. The developed ethanol-free SEO nanoemulsion has promising industrial applications in food and beverage flavoring.
制备了含有留兰香精油(SEO)的不同乳油,并评估了它们在稀释到水中后自发产生无乙醇纳米乳液的潜力。这些配方中的每一种都有其关于赋形剂类型、表面活性剂、表面活性素/SEO比率和表面活性剂浓度的特定组成。该评价结果表明,SEO的化学组成对纳米乳液的形成和物理稳定性有着深远的影响。将赋形剂如长链甘油三酯和丙二醇仅以1.0%的比例掺入可乳化浓缩物中,可以产生稳定的纳米乳液,从而抵抗奥斯特瓦尔德熟化。粒度测量显示纳米乳液中SEO的直径为28.2nm,并且其纳米结构保持3个月。二元非离子食品表面活性剂混合物的应用提高了纳米乳液的热稳定性,最高可达50ᵒC.所开发的无乙醇SEO纳米乳液在食品和饮料调味品中具有很好的工业应用前景。
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引用次数: 2
Phenolic variability in fruit from the ‘Arbequina’ olive cultivar under Mediterranean and Subtropical climatic conditions 地中海和亚热带气候条件下“Arbequina”橄榄品种果实中酚类物质的变异性
IF 1.4 4区 农林科学 Q4 CHEMISTRY, APPLIED Pub Date : 2022-01-12 DOI: 10.3989/gya.1002202
G. Medina, C. Sanz, L. León, Á. Pérez, R. de la Rosa
In the present work, we compared the phenol content and composition of fruit from the ‘Arbequina’ cultivar in four Mediterranean (in Andalucía, Southern Iberian Peninsula) and two Sub-Tropical (Canary Islands) locations throughout the harvest period. Two Mediterranean and two Sub-Tropical locations were maintained with drip irrigation, while the remaining two Mediterranean locations were in dry farming. Water availability and harvest date seemed to play more important roles than air temperature on the phenolic content and most of the studied components. The variability associated with location was a result of the high values observed in the two Mediterranean locations in dry farming, with respect to the other four maintained with drip irrigation. Few differences were found among the four drip-irrigated locations, despite the fact that two were Mediterranean and the other two Sub-Tropical. In addition, a sharp decrease was observed during the harvest period for phenolic content and most of the phenolic compounds.
在目前的工作中,我们比较了“Arbequina”品种在四个地中海(位于安达鲁西亚、伊比利亚半岛南部)和两个亚热带(加那利群岛)的水果在整个收获期的酚含量和成分。两个地中海和两个亚热带地区采用滴灌,其余两个地中海地区采用旱地。水分有效性和收获日期对酚类含量和大多数研究组分的影响似乎比空气温度更重要。与位置相关的可变性是由于在地中海的两个地方观察到的旱地农业的高值,而其他四个地方则采用滴灌。四个滴灌地点之间几乎没有发现差异,尽管其中两个是地中海地区,另外两个是亚热带地区。此外,在收获期间,观察到酚类化合物和大多数酚类化合物的含量急剧下降。
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引用次数: 4
A novel bleaching approach: Microwave assisted sunflower oil bleaching and optimization 一种新的漂白方法:微波辅助葵花籽油漂白及优化
IF 1.4 4区 农林科学 Q4 CHEMISTRY, APPLIED Pub Date : 2022-01-12 DOI: 10.3989/gya.1004202
Ş. S. Seçilmiş, D. Koçak Yanık, S. Fadıloğlu, F. Göğüş
The factors affecting the microwave bleaching of sunflower oil and the interaction between them were investigated and optimized by response surface methodology using a three-factor five-level central composite rotatable design. Microwave power, time and the amount of bleaching clay were selected as independent variables studied in the range of 70-120 W, 2-15 min, and 0.01-0.5%. The dependent variables that measure the bleaching efficiency and oil quality were evaluated as hue angle, chroma and totox value. Optimization was carried out by minimizing totox and chroma and maximizing hue angle. Hue angle, chroma and totox were found as 96.91, 37.66 and 23.31 under optimal conditions. Optimal microwave bleaching was successfully performed by using less bleaching clay (0.4%) and a shorter time (8 min) compared to the current industrial application without any adverse effect on oil quality. Hence, microwave bleaching is thought to be an alternative method for the bleaching of edible oils.
采用三因素五水平中心复合可旋转设计,采用响应面法对影响葵花籽油微波漂白的因素及其相互作用进行了研究和优化。选取微波功率、时间和漂白粘土用量为自变量,在70 ~ 120 W、2 ~ 15 min、0.01 ~ 0.5%范围内进行研究。以色相角、色度和毒素值作为衡量漂白效率和油脂质量的因变量。通过最小化毒素和色度,最大化色相角进行优化。在最佳条件下,色相角、色度和毒度分别为96.91、37.66和23.31。与目前的工业应用相比,使用较少的漂白粘土(0.4%)和较短的时间(8 min),成功地实现了最佳微波漂白,且对油的品质没有任何不利影响。因此,微波漂白被认为是食用油漂白的一种替代方法。
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引用次数: 1
Enzymatic pre-treatment of grape seeds for an oil with higher antioxidant activity 酶法预处理葡萄籽制备具有较高抗氧化活性的油
IF 1.4 4区 农林科学 Q4 CHEMISTRY, APPLIED Pub Date : 2022-01-12 DOI: 10.3989/gya.1000202
M. Tociu, A. Hirtopeanu, M. Stanescu
The paper investigates the effect of the enzymatic pre-treatment of grape seeds from six Romanian cultivars on the oil extracted. The grape seeds of some white and red Romanian grape varieties were separated from winery waste, washed, dried and ground, with the oil then obtained by extraction with petroleum ether. The extraction was performed directly or after a preliminary treatment with a commercial pectin lyase. The enzymatic procedure applied was more cost effective compared to other treatments previously described in which a cocktail of enzymes was used. The quantity of the extracted oil was measured in both types of processing, with an increase being observed for pre-treated samples. The fatty acid profiles (FAPs) of the oils resulted for the treated and untreated seeds were determined. No change in the composition was noticed. The reductive power of these oils was also investigated. Compared to the untreated samples for the same variety, the enzyme pre-treatment resulted in a superior antioxidant capacity.
研究了罗马尼亚6个葡萄品种的葡萄籽经酶促预处理后对油脂提取的影响。罗马尼亚一些白葡萄和红葡萄品种的葡萄籽从酿酒厂废料中分离出来,经过洗涤、干燥和研磨,然后用石油醚提取得到油。提取是直接进行的或在用商业果胶裂解酶初步处理后进行的。与先前描述的使用酶混合物的其他处理相比,所应用的酶促程序更具成本效益。在这两种类型的处理中都测量了提取的油的量,观察到预处理样品的量有所增加。测定了经处理和未经处理的种子的油的脂肪酸谱(FAPs)。成分没有变化。还研究了这些油的还原能力。与同一品种的未处理样品相比,酶预处理产生了优越的抗氧化能力。
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引用次数: 1
Enzymatic pre-treatment in cold pressing: Influence on flaxseed, apricot kernel and grape seed oils 冷榨中的酶预处理:对亚麻籽、杏仁和葡萄籽油的影响
IF 1.4 4区 农林科学 Q4 CHEMISTRY, APPLIED Pub Date : 2021-12-27 DOI: 10.3989/gya.0891201
A. Candan, D. Arslan
A commercial enzyme preparation consisting of pectolytic, cellulotic and hemicellulotic enzymes was applied to the oil extraction by cold pressing from apricot kernel, flaxseed and grape seed. The effects of enzyme pre-treatment varied depending on the different oil seed used as raw material. Although the increase in free fatty acidity can be considered as a negative effect (from 0.37 to 0.52), the decrease in peroxide number and p-anisidine values, increase in oil yield (22.75%), higher levels of total carotenoids and tocopherols, as well as a remarkable increase in phenolic content (x1.68) and radical scavenging effect (including hydrophilic and lipophilic-induced and total antioxidant capacity) showed that the use of enzyme application in the cold pressing of apricot kernel oil would be beneficial. Many of these positive results could not be achieved in the pressing of flaxseed or grape seed oils under the same conditions. A high negative correlation (r=-92.2) was found between p-anisidine value and δ-tocopherol for grapeseed oil. Hydrophilic and lipophilic antioxidant capacity, total phenolics, and total carotenoids negatively correlated well (r values above 80) with peroxide values for apricot seed oil. Correlation results showed that carotenoids play an important role in the oxidative stability of the oils, where it was much more evident for apricot seed oil (r=-97.5).
将一种由果胶、纤维素和半纤维素酶组成的市售酶制剂应用于杏仁、亚麻籽和葡萄籽的冷榨油脂提取。酶预处理的效果因用作原料的不同油籽而异。尽管游离脂肪酸的增加可以被认为是一种负面影响(从0.37到0.52),但过氧化值和对茴香胺值的降低,油产量的增加(22.75%),总类胡萝卜素和生育酚的水平更高,以及酚类物质含量(x1.68)和自由基清除作用(包括亲水性和亲脂性诱导和总抗氧化能力)的显著增加表明,将酶应用于杏仁油的冷榨是有益的。在相同的条件下,亚麻籽或葡萄籽油的压榨无法获得许多积极的结果。葡萄籽油中对茴香胺值与δ-生育酚呈高度负相关(r=-92.2)。杏籽油的亲水性和亲脂性抗氧化能力、总酚类和总类胡萝卜素与过氧化值呈良好的负相关(r值大于80)。相关结果表明,类胡萝卜素在油脂的氧化稳定性中起着重要作用,其中杏籽油的氧化稳定性更为明显(r=-97.5)。
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引用次数: 2
Seasonal effects of the fatty acid composition of phospholipid and triacylglycerol in the muscle and liver of male Salmo trutta macrostigma 雄性大柱头鲑肌肉和肝脏磷脂和甘油三酯脂肪酸组成的季节效应
IF 1.4 4区 农林科学 Q4 CHEMISTRY, APPLIED Pub Date : 2021-11-26 DOI: 10.3989/gya.0779201
S. Kaçar, H. Kaya, M. Başhan
The seasonal effects on the fatty acid composition of triacylglycerol (TAG) and phospholipid (PL) in the muscle and liver of male Salmo trutta macrostigma were determined using the gas chromatographic (GC) method. The fatty acid (FA) compositions of total lipid, PL and TAG fractions were determined in muscle and liver tissues of S. trutta macrostigma. The phospholipids contained a higher proportion of 16:0 compared to the TAG in the muscle tissue of S. trutta macrostigma. Docosahexaenoic acid (22:6 ω-3) and eicosapentaenoic acid (20:5 ω-3) contents were high in both muscle and liver tissues. The total lipid contents in the muscle and liver were 1.07-2.45 and 3.00-4.64%, respectively. S. trutta macrostigma is a rich source of ω-3 and ω-6, polyunsaturated fatty acids (PUFA) with numerous benefits to human health.
采用气相色谱(GC)法测定了季节对雄性大柱头鲑肌肉和肝脏中甘油三酯(TAG)和磷脂(PL)脂肪酸组成的影响。测定了巨柱头海苔(s.trutta macro柱头)肌肉和肝脏组织中总脂、PL和TAG组分的脂肪酸(FA)组成。巨柱头棘肌组织中磷脂含量比TAG高16:0。肌肉和肝组织中二十二碳六烯酸(22:6 ω-3)和二十碳五烯酸(20:5 ω-3)含量较高。肌肉和肝脏总脂含量分别为1.07 ~ 2.45%和3.00 ~ 4.64%。长柱头草富含ω-3和ω-6多不饱和脂肪酸(PUFA),对人体健康有许多好处。
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引用次数: 3
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Grasas y Aceites
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