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Effect of silica particle size and filler content on the fracture properties of epoxy resin composite 二氧化硅粒径和填料含量对环氧树脂复合材料断裂性能的影响
IF 1.1 4区 工程技术 Q4 Engineering Pub Date : 2021-01-01 DOI: 10.32908/hthp.v50.999
Zafer Azem, U. Malayoğlu, B. Uyulgan
Silica particles were used as a filler to produce silica-epoxy composite. Silica particles with two mean diameters of 1 μm and 37 μm and filler content of 20, 30, 40, and 60 wt. % were used to investigate the effect of particle size and filler content on the fracture behavior of epoxy resin composite, respectively. The fractural behavior of composites was characterized by linear elastic fracture mechanics according to standard of ASTM-D5045 in which three-point bending test procedure was used to investigate plane-strain fracture toughness (Kıc) and strain energy release rate (Gıc) of the composite specimens. Glass transient temperatures of the samples were evaluated by using differential scanning calorimetry (DSC). Fracture surfaces of the produced specimens were examined by SEM. The highest Young’s modulus value was 10.48 GPa for the sample produced with 37 μm particle size and 60 wt. % filler content and it was found that a considerable increase was obtained according to the 3.05 MPa values of the unfilled epoxy. Experimental results show that fracture toughness value of the silica filled epoxy composite was improved by 98% compared to unfilled epoxy.
用二氧化硅颗粒作为填料制备了硅-环氧复合材料。采用粒径分别为1 μm和37 μm,填料含量分别为20、30、40和60 wt. %的二氧化硅颗粒,研究了粒径和填料含量对环氧树脂复合材料断裂行为的影响。采用ASTM-D5045标准的线弹性断裂力学方法表征复合材料的断裂行为,采用三点弯曲试验方法对复合材料的平面应变断裂韧性(Kıc)和应变能释放率(Gıc)进行了测试。用差示扫描量热法(DSC)测定了样品的玻璃化瞬态温度。用扫描电镜对试样的断口形貌进行了分析。当填充量为60 wt. %、粒径为37 μm时,杨氏模量最高为10.48 GPa,而未填充的环氧树脂的杨氏模量为3.05 MPa时,杨氏模量有较大的提高。实验结果表明,二氧化硅填充的环氧复合材料的断裂韧性值比未填充的环氧复合材料提高了98%。
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引用次数: 0
Inter-laboratory comparison on thermal conductivity measurements by the guarded hot plate method between LNE and Institute VINČA LNE和研究所用保护热板法测量导热系数的实验室间比较VINČA
IF 1.1 4区 工程技术 Q4 Engineering Pub Date : 2021-01-01 DOI: 10.32908/hthp.v50.1001
B. Hay, N. Milošević, J. Hameury, N. Stepanić, G. Failleau, Y. Garcia, A. Koenen, J. Filtz
An inter-laboratory comparison has been organized between LNE and Institute VINČA, respectively French National Metrology Institute and Serbian Designated Institute for thermal properties metrology, on thermal conductivity measurements by the guarded hot plate method. The main objective was to validate the measurement capabilities of VINČA in terms of thermal conductivity in the temperature range from 10 °C to 50 °C by using the facility improved in the frame of the European project Eura-Thermal. The measurements were carried out on expanded polystyrene boards using guarded hot plate apparatuses (two-specimen GHP apparatuses) in accordance with the international standard ISO 8302. The measurement programme was defined taking into account the major characteristics of the guarded hot plate apparatuses used, such as specimen dimensions and temperature and thermal conductivity ranges. Specimens were machined by LNE from a same batch for both participants. Prior to the measurements, the homogeneity of the set of specimens, as well as the influence of a variation of density of the expanded polystyrene on the thermal conductivity measurements were studied by VINČA.
LNE和法国国家计量研究所VINČA和塞尔维亚指定的热特性计量研究所就用保护热板法测量热导率进行了实验室间比较。主要目的是通过使用欧洲项目Eura-Thermal框架中改进的设备,验证VINČA在10°C至50°C温度范围内的热导率测量能力。根据国际标准ISO 8302,使用防护热板仪器(双试样GHP仪器)在膨胀聚苯乙烯板上进行测量。测量程序的定义考虑了所使用的保护热板设备的主要特性,如试样尺寸、温度和导热系数范围。两个参与者的标本都是由同一批次的LNE加工的。在测量之前,通过VINČA研究了试样的均匀性,以及膨胀聚苯乙烯密度变化对导热系数测量的影响。
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引用次数: 0
Exergy and energy analysis on coal/biomass co-gasification in supercritical water 煤/生物质在超临界水中共气化的能能分析
IF 1.1 4区 工程技术 Q4 Engineering Pub Date : 2021-01-01 DOI: 10.32908/hthp.v50.927
Jieren Luo, Qiuhui Yan, Zhao-zan Feng, M. Zhang, Yaxin Yang
Supercritical water gasification (SCWG) is a promising technology for clean and efficient utilization of carbonaceous organic materials at high temperature and pressure. Coal/biomass co-gasification in supercritical water (SCW) is a better choice for both coal and biomass to offset their disadvantages. Therefore, based on the experimental results of coal/carboxymethylcellulose (CMC, as a model compound of biomass) co-gasification in SCW by continuous flow thermal-catalytic reaction system at a reactor wall temperature of 650 �C, pressure of 25 MPa, a residence time 30 s and 0.1 wt% NaOH additive, the effects of heat transfer efficiency, heat supply methods, and CMC fraction on exergy and energy efficiency of reactor (the core device in reaction system) were investigated. The results show that energy and exergy efficiencies are in excess of 69% and 43%, respectively. The priority order of heat supply for the reactor is as follow: lower temperature heat source > higher temperature heat source > direct electricity heat supply method. The heat transfer efficiency has great influence on the energy and exergy efficiencies in terms of thermophysics. The higher CMC fraction is helpful to improve exergy efficiency.
超临界水气化(SCWG)是一种在高温高压下清洁高效利用含碳有机材料的技术。煤/生物质在超临界水中共气化是煤和生物质弥补各自缺点的较好选择。因此,基于实验结果的煤/羧甲基纤维素(CMC作为模型化合物的生物质能)co-gasification标准铜线的连续流thermal-catalytic反应系统的反应器壁温650�C, 25 MPa的压力,停留时间30年代和0.1 wt %氢氧化钠添加剂,传热效率的影响,供热方法,CMC分数(火用)和能源效率的反应堆的核心设备(反应系统)。结果表明,能源效率和火用效率分别超过69%和43%。反应器的供热优先顺序为:低温热源>高温热源>直接电供热方式。从热物理的角度来看,传热效率对能量效率和火用效率有很大的影响。较高的CMC分数有利于提高火用效率。
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引用次数: 3
Phononic, electronic, elastic and thermodynamic properties of ScSi under high pressure via first principles calculations 通过第一性原理计算高压下ScSi的声子、电子、弹性和热力学性质
IF 1.1 4区 工程技术 Q4 Engineering Pub Date : 2021-01-01 DOI: 10.32908/hthp.v50.939
Jinjuan Sun, Shaobo Chen, K. Yao, Ying Chen, X. Yao
In present paper, we perform first principles based on density functional theory to investigate the effect of high pressure on phononic, electronic, elastic and thermodynamic properties of ScSi. It is found that phonon dispersion curve of ScSi has no virtual frequency within a given pressure range from 0 GPa to 35 GPa, indicating that the material is thermodynamically stable. When a given pressure is larger than 40 GPa, ScSi is thermodynamically instable and will occurs phase transition. Band structure and density of states confirm that ScSi is metallic. The elastic constant Cij increases with increasing pressure, and meets the Born�s criterion, which shows that ScSi possesses mechanical stability. Meanwhile, the ductility and toughness of material increase with increasing pressure, which is very conducive to industrial applications. In addition, Debye temperature and sound velocity increase linearly with pressures, indicating that appropriate pressure can improve elasticity, hardness, melting point and specific heat.
本文基于密度泛函理论,运用第一性原理研究了高压对ScSi声子、电子、弹性和热力学性质的影响。在给定的压力范围内(0 ~ 35 GPa), ScSi声子色散曲线没有虚频率,表明材料是热力学稳定的。当给定压力大于40gpa时,ScSi是热力学不稳定的,并且会发生相变。能带结构和态密度证实ScSi是金属的。弹性常数Cij随压力的增大而增大,符合Born准则,表明ScSi具有力学稳定性。同时,材料的延展性和韧性随压力的增大而增大,非常有利于工业应用。此外,德拜温度和声速随压力线性增加,表明适当的压力可以提高弹性、硬度、熔点和比热。
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引用次数: 0
Obituary: Academician Vladimir E. Fortov (1946–2020) 讣告:弗拉迪米尔·e·福托夫院士(1946-2020)
IF 1.1 4区 工程技术 Q4 Engineering Pub Date : 2021-01-01 DOI: 10.32908/hthp.v50.1171
   
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引用次数: 0
Wetting property of liquid Pb on different steel candidates as structural materials for the Generation IV nuclear reactors 液态铅在第四代核反应堆不同候选钢结构材料上的润湿性能
IF 1.1 4区 工程技术 Q4 Engineering Pub Date : 2021-01-01 DOI: 10.32908/hthp.v50.871
D. Giuranno, S. Amore, R. Novakovic, Corrado Tomasi, E. Ricci
Conventional high-chromium ferritic / martensitic steels, such as T91 and AISI 316 L as well as the new oxide dispersed strengthened (ODS) steels, i.e. Fe-Cr (ferritic or martensitic) with a fine Y2O3 dispersion, are promising candidates as structural materials for applications in aggressive environments. In order to improve the efficiency and lifetime of structural materials for liquid metal fast reactor (LMFR), where liquid lead (Pb) is used as coolant, the investigations are currently focused on the interfacial phenomena occurring at the liquid Pb/steel interfaces. The better understanding of the interfacial phenomena is the key issue for the selection of structural materials meeting the requirements of the demanding application. In the present work, a fundamental study on the wetting characteristics and the interfacial phenomena of liquid Pb in contact with T91, AISI 316L, ODS- 12Cr and ODS-14Cr steels over the temperature range 550�820�C and under different oxygen containing atmospheres is reported.
传统的高铬铁素体/马氏体钢,如T91和AISI 316 L,以及新的氧化物分散强化(ODS)钢,即具有良好Y2O3分散的Fe-Cr(铁素体或马氏体),是在侵蚀环境中应用的有前途的结构材料。为了提高液态铅作为冷却剂的液态金属快堆(LMFR)结构材料的效率和寿命,目前研究的重点是液态铅/钢界面上发生的界面现象。更好地了解界面现象是选择满足苛刻应用要求的结构材料的关键问题。本文对液态铅在550 ~ 820℃和不同含氧气氛下与T91、AISI 316L、ODS- 12Cr和ODS- 14cr钢接触时的润湿特性和界面现象进行了基础研究。
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引用次数: 1
Thermal expansion, heat capacity and Gr�neisen parameter of grossular at high temperature and high pressure 高温高压下的热膨胀、热容和格氏参数
IF 1.1 4区 工程技术 Q4 Engineering Pub Date : 2021-01-01 DOI: 10.32908/hthp.v50.957
Chang Su, Yonggang Liu
The thermodynamic properties of grossular garnet (Ca3Al2Si3O12) were determined as a function of pressure and temperature in this study. With a numerical iterative procedure, the unit-cell volume, adiabatic bulk modulus, thermal expansion, heat capacity, and Gr�neisen parameters of grossular up to 25 GPa, 2000 K were extracted from experimental elastic wave velocities at high temperature and high pressure conditions. The calculated unit-cell volume and adiabatic bulk modulus agree well with the previous studies. The results imply that our calculated thermal expansion, heat capacity, and Gr�neisen parameters of grossular are all decrease with elevated pressure, and both thermal expansion and heat capacity show nonlinear pressure dependences. On the other hand, the Gr�neisen parameter shows a linear pressure dependence. The pressure derivative of thermal expansion display a regularity increase with temperature, while the pressure derivatives of heat capacity and Gr�neisen parameters display a rapid decrease at low temperature and a slow growth above ~1000 K.
本研究确定了粗晶石榴石(Ca3Al2Si3O12)的热力学性质随压力和温度的变化。采用数值迭代的方法,从高温高压条件下的实验弹性波速中提取了高达25 GPa、2000 K时的单胞体积、绝热体模量、热膨胀、热容和Gr - neisen参数。计算得到的单胞体积和绝热体积模量与前人的研究结果吻合较好。结果表明:计算得到的热膨胀、热容和Gr - neisen参数均随压力升高而减小,且热膨胀和热容均表现出非线性的压力依赖性。另一方面,格鲁尼森参数表现出线性压力依赖关系。热膨胀的压力导数随温度的升高有规律地增大,而热容和格氏参数的压力导数在低温下迅速减小,在~1000 K以上增长缓慢。
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引用次数: 1
Computational-analytical simulation of microsystems in process intensification 过程强化中微系统的计算分析模拟
IF 1.1 4区 工程技术 Q4 Engineering Pub Date : 2021-01-01 DOI: 10.32908/hthp.v50.1189
R. M. Cotta, P. C. Pontes, Adam H. R. Sousa, C. Naveira-Cotta, K. Lisboa
Heat and mass transfer enhancement techniques, either passive or active, have an important role in the more general goal of process intensification in modern engineering developments. In this context, the study of transport phenomena at the nano- and micro-scales aims far beyond the plain miniaturization of devices, being mainly directed towards process efficiency improvement and lower energy and raw materials consumption. The analysis of heat and mass transfer at such scales has required the development or extension of both theoretical and experimental methodologies. In light of the inherent multiscale nature of microfluidic devices, classical fully numerical methodologies often require large refined meshes with associated costly computations. A hybrid numerical-analytical approach for the analysis of microfluidic and thermal micro-systems is here reviewed, which includes a computational-analytical integral transform method for partial differential direct problems, that, together with mixed symbolic-numerical computations, lead to robust cost-effective algorithms for micro-scale transport phenomena analysis. Examples of this hybrid approach in selected applications are then examined more closely, including micro-reactors for continuous biodiesel synthesis with multiple reactive interfaces and three-dimensional thermal micro-devices with solid-fluid thermal conjugation.
在现代工程发展中,无论是被动的还是主动的传热传质强化技术,在过程强化这一更普遍的目标中都起着重要的作用。在这种背景下,纳米和微观尺度上的输运现象研究的目标远远超出了设备的简单小型化,主要是为了提高工艺效率和降低能源和原材料的消耗。在这种尺度上对传热传质的分析需要理论和实验方法的发展或扩展。鉴于微流控装置固有的多尺度性质,经典的全数值方法通常需要大量的精细网格,并伴有昂贵的计算。本文回顾了用于微流体和热微系统分析的混合数值-解析方法,其中包括用于偏微分直接问题的计算-解析积分变换方法,该方法与混合符号-数值计算一起,导致了用于微尺度输运现象分析的鲁棒经济算法。然后更仔细地研究了这种混合方法在选定应用中的例子,包括用于连续合成生物柴油的具有多个反应界面的微反应器和具有固-流热共轭的三维热微装置。
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引用次数: 2
Energy bandgap variation in semiconductor compound nanomaterials 半导体化合物纳米材料的能带变化
IF 1.1 4区 工程技术 Q4 Engineering Pub Date : 2021-01-01 DOI: 10.32908/hthp.v50.861
P. Chaturvedi, M. Goyal
In the present work, we have used phenomological models for analyzing the impact of shape and size on energy band gap in semiconducting nanomaterial compounds. The models used presently are Qi model, Bond energy model and Guisbiers model. The extension of melting temperature expression for nanomaterials of the models considered is done and shape and size dependent expression of energy band gap is obtained. In this paper, we have taken group III-V semiconductor compound nanomaterials i.e., AlN, GaN, InN, GaAs and InAs. It is clear from the results obtained that decrease in the size of the semiconductor compound nanomaterials led to band gap expansion and this increase is significant for particle size below 5 nm. Comparison of the results predicted using different models with the available experimental and simulated results is done. Guisbiers model is found best out of the models considered to study the band gap expansion in semiconducting nanomaterial compounds. The energy band gap shift in valence and conduction band with size is determined in nanosemiconductors.
在目前的工作中,我们使用物候模型来分析半导体纳米材料化合物的形状和尺寸对能带隙的影响。目前使用的模型有Qi模型、Bond能模型和Guisbiers模型。对所考虑的模型中纳米材料的熔化温度表达式进行了推广,得到了能带隙随形状和尺寸的表达式。本文采用了III-V族半导体化合物纳米材料,即AlN、GaN、InN、GaAs和InAs。从结果可以清楚地看出,半导体化合物纳米材料尺寸的减小导致带隙的扩大,并且对于粒径小于5 nm的带隙的增加是显著的。将不同模型的预测结果与现有的实验和模拟结果进行了比较。Guisbiers模型被认为是研究半导体纳米材料中带隙扩展的最佳模型。测定了纳米半导体中价带和导带的能带隙随尺寸的变化。
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引用次数: 0
Volume-independent contact angle prediction 与体积无关的接触角预测
IF 1.1 4区 工程技术 Q4 Engineering Pub Date : 2021-01-01 DOI: 10.32908/hthp.v50.1021
N. Çobanoğlu, Alper Genc, S. Korkut, Z. H. Karadeniz, M. Buschmann
The contact angle of droplets attracts attention as one of the relevant thermophysical properties describing the wettability behaviour of the fluids. The contact angle depends on the surface characteristics such as surface type and roughness as well as on the liquid type and surrounding atmosphere. This study aims to correct the error in the coefficient of the theoretical model developed for droplet shape prediction by Vafaei and Podowski [1]. The corrected model is also rearranged by non-dimensional numbers. The contact angle and the shape of water droplets for different volumes and surface types are predicted by the rearranged model and validated by experimental results. Contact angles have been over-estimated compared to experimental results because of measurement errors in geometrical parameters. It is found that the contact angle model is too sensitive to geometrical parameters. Moreover, the contact angle is found to be independent of the volume.
液滴的接触角作为描述流体润湿性的相关热物理性质之一引起了人们的关注。接触角取决于表面特性,如表面类型和粗糙度,以及液体类型和周围的大气。本研究旨在修正由Vafaei和Podowski等人建立的液滴形状预测理论模型的系数误差。修正后的模型也被无因次数重新排列。利用重新排列的模型预测了不同体积和表面类型下的接触角和水滴形状,并通过实验结果进行了验证。由于几何参数的测量误差,与实验结果相比,接触角的估计过高。研究发现,接触角模型对几何参数过于敏感。此外,发现接触角与体积无关。
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引用次数: 1
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High Temperatures-high Pressures
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