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A method for simultaneous measurements of compressional wave and shear wave velocities in rocks and minerals at high pressure and high temperature: A modification to the combined transmission-reflection method 在高压和高温下同时测量岩石和矿物中纵波和横波速度的方法:对透射-反射联合法的改进
IF 1.1 4区 工程技术 Q4 Engineering Pub Date : 2022-01-01 DOI: 10.32908/hthp.v51.1249
Wei Song, Qizhe Tang, Chang Su, Xiang Chen, Yonggang Liu
We present a modification to the combined transmission-reflection method, which is frequently used to measure the elastic wave velocities in rocks and minerals at high pressure and high temperature in multi-anvil apparatus. The modification mainly focuses on the adoption of dual-mode ultrasonic transducer and new backing reflector (a molybdenum foil), the former was used to simultaneously measure the travel times of compressional wave and shear wave in the sample, and the latter was used to intensify the reflection signals of the buffer rod. The correction time of the molybdenum foils was determined using the equation of state and highpressure velocities of molybdenum. In addition, the length change of sample under high pressure was also taken into account. Using this method, we simultaneously measured the compressional wave and shear wave velocities in Z-cut a-quartz single crystal to 2 GPa at room temperature, and natural mafic granulite sample to 1.4 GPa and 500�C in a multianvil apparatus. The results of this work agree well with those of previous measurements and demonstrate the feasibility of this new method. We believe that by using this method, more accurate elastic properties of rocks and minerals under high pressure and high temperature can be obtained, especially Poisson�s ratio.
本文对多砧测井仪中常用的测量岩石和矿物在高压高温下的弹性波速的联合透射-反射法进行了改进。改进主要是采用双模超声换能器和新型背衬反射器(钼箔),前者用于同时测量样品中纵波和横波的传播时间,后者用于增强缓冲棒的反射信号。利用状态方程和钼的高压速度,确定了钼箔的校正时间。此外,还考虑了试样在高压下的长度变化。利用这种方法,我们在多砧仪器中同时测量了z -切割石英单晶在室温下2 GPa的纵波和横波速度,以及天然基性麻粒岩样品在1.4 GPa和500℃下的纵波和横波速度。所得结果与以往的测量结果吻合较好,证明了新方法的可行性。我们相信,用这种方法可以得到更精确的岩石和矿物在高压和高温下的弹性特性,特别是泊松比。
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引用次数: 0
Thermal conductivity measurement of VO2 nanofluid using bidirectional 3ω method 用双向3ω法测量VO2纳米流体的导热系数
IF 1.1 4区 工程技术 Q4 Engineering Pub Date : 2021-01-01 DOI: 10.32908/hthp.v50.1071
Duk Hyung Lee, D. Oh, Sok-Won Kim, Yeon Suk Choi
Nanofluids containing vanadium dioxide (VO2) are used in applications such as actuators, smart windows, and gastrointestinal tracts. Therefore, measuring the thermal conductivity of nanofluids with VO2 characteristics is important in various environmental industries. In this study, the bidirectional 3 omega (3ω) method was used to measure the thermal conductivity of nanofluids. Experimental equipment for measuring VO2 nanofluids in various environments was designed and fabricated. The effectiveness of the bidirectional 3ω equipment was verified by measuring the thermal conductivity of ethylene glycol, which has been extensively reported in the literature. The effects of elapsed time, specimen thickness, and operation temperature on the thermal conductivity are discussed in this paper. In addition, the measuring error was investigated with regard to the precipitation of particles in the suspension.
含有二氧化钒(VO2)的纳米流体用于执行器、智能窗口和胃肠道等应用。因此,测量具有VO2特性的纳米流体的导热性在各种环境工业中具有重要意义。本研究采用双向3ω (3ω)法测量纳米流体的导热系数。设计并制作了不同环境下纳米流体VO2测量实验装置。通过测量乙二醇的导热系数验证了双向3ω设备的有效性,这在文献中得到了广泛的报道。本文讨论了运行时间、试样厚度和操作温度对导热系数的影响。此外,还研究了悬浮液中颗粒析出的测量误差。
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引用次数: 0
Thermal and mechanical behavior of graphene loaded synthetic graphite/polyphenylene sulfide (PPS) composites 石墨烯负载合成石墨/聚苯硫醚(PPS)复合材料的热力学性能
IF 1.1 4区 工程技术 Q4 Engineering Pub Date : 2021-01-01 DOI: 10.32908/hthp.v50.1089
L. Altay, G. S. Tantug, H. Cekin, Y. Seki, M. Sarıkanat
Thermoplastics when they become thermally conductive, have a great potential to be used in thermal management applications due to their low cost, lightweight, and flexibility. Here, synthetic graphite and graphene are used as thermally conductive fillers to fabricate Polyphenylene Sulfide- (PPS) based composite materials with high thermal conductivity. Graphene and graphite added PPS composites were manufactured by using a twinscrew extruder and injection molding machine. Physical, thermal, mechanical, and morphological properties of the composites were investigated by several characterization methods including thermogravimetric analysis, differential scanning calorimetry, thermomechanical analysis, scanning electron microscopy, thermal diffusivity measurement, and tensile and flexural tests, The in-plane and through-plane thermal conductivity coefficient of graphene (5 wt. %) loaded synthetic graphite (40 wt. %)/PPS composites are greatly improved to 26.45 and 5.02 W/mK, respectively compared to that of neat PPS. The outstanding in-plane thermal conductivity of graphene loaded graphite/PPS composites is attributed to the formation of an effective thermal conductive pathway due to the alignment of the layered structure of graphene and graphite fillers in the flow direction.
当热塑性塑料成为导热材料时,由于其低成本、轻量化和灵活性,在热管理应用中具有很大的潜力。本文以合成石墨和石墨烯为导热填料,制备高导热聚苯硫醚(PPS)基复合材料。采用双螺杆挤出机和注塑机制备了石墨烯和石墨添加PPS复合材料。通过几种表征方法,包括热重分析、差示扫描量热法、热力学分析、扫描电子显微镜、热扩散率测量、拉伸和弯曲测试,研究了复合材料的物理、热、力学和形态性能。石墨烯(5 wt. %)负载的合成石墨(40 wt. %)/PPS复合材料的面内和透面导热系数分别达到26.45 W/mK和5.02 W/mK。石墨烯负载的石墨/PPS复合材料具有出色的面内导热性,这是由于石墨烯和石墨填料的层状结构在流动方向上的对齐形成了有效的导热通道。
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引用次数: 0
Measurement of thermo-optic coefficient of vanadium dioxide nanofluids using an interferometer 用干涉仪测量二氧化钒纳米流体的热光学系数
IF 1.1 4区 工程技术 Q4 Engineering Pub Date : 2021-01-01 DOI: 10.32908/hthp.v50.1045
Hyunki Kim, Taesung Kim, Sok-Won Kim
The change in refractive index with respect to temperature (dn/dT) is defined as the thermo-optic coefficient. It varies according to the light wavelength and temperature, so it is a very important physical quantity that influences light propagation. In this study, we observed the metal-insulator transition (MIT) effect of VO2 on the optical properties of VO2 nanofluid and the thermo-optic coefficient of pure ethylene glycol (EG). We prepared two concentrations (1 × 10–3 mol% and 1 × 10–2 mol%) of EG + VO2 nanofluids by dispersing 50-nm VO2 nano-spheres and injecting them into a cubic glass cell (1 × 1 × 4 cm3). The thermo-optic coefficient was measured by counting the number of interference fringe movements with a Michelson interferometer. The thermo-optic coefficient obtained for pure EG agreed with the literature value within 13.3%. Below 60˚C, the thermo-optic coefficients of EG + VO2 were smaller than that of pure EG, but they increased rapidly as the temperature increased. Above 60˚C, the thermo-optic coefficients of both EG + VO2 nanofluids rapidly changed and showed a peak and valley near 62˚C and 67˚C, respectively. We used the maximum value of the derivative of the thermo-optic coefficient (d2n/dT2) to obtain the phase transition temperatures of the VO2 nanofluids, which were 64.6˚C and 65.0˚C in the samples with 1 × 10–3 mol% and 1 × 10–2 mol%, respectively.
折射率随温度的变化(dn/dT)定义为热光学系数。它随光的波长和温度而变化,是影响光传播的一个非常重要的物理量。在这项研究中,我们观察了VO2的金属-绝缘体跃迁(MIT)对VO2纳米流体光学性质和纯乙二醇(EG)的热光学系数的影响。我们将50 nm的VO2纳米球分散并注入到1 × 1 × 4 cm3的立方玻璃池中,制备了两种浓度(1 × 10-3 mol%和1 × 10-2 mol%)的EG + VO2纳米流体。热光学系数是用迈克尔逊干涉仪计算干涉条纹运动的次数来测量的。纯EG的热光学系数与文献值在13.3%以内一致。在60℃以下,EG + VO2的热光学系数小于纯EG,但随着温度的升高热光学系数迅速增大。在60℃以上,EG + VO2纳米流体的热光系数迅速变化,分别在62℃和67℃附近出现峰谷。利用热光系数导数的最大值(d2n/dT2)得到了VO2纳米流体的相变温度,在1 × 10-3 mol%和1 × 10-2 mol%的样品中分别为64.6℃和65.0℃。
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引用次数: 0
Thermal performance of solar collector based on volumetric absorption harvesting method using Fe3O4 nanofluid 基于Fe3O4纳米流体体积吸收集热器热性能研究
IF 1.1 4区 工程技术 Q4 Engineering Pub Date : 2021-01-01 DOI: 10.32908/hthp.v50.1061
J. Ham, Yunchan Shin, Honghyun Cho
In this study, the characteristics of volumetric absorption for solar harvesting using a Fe3O4@polyacrylic acid (PAA) nanofluid (NF) are investigated experimentally. The concentration of the Fe3O4@PAA NF was varied from 0 to 0.2wt%, and its mass flow rate was set to 0.0025 and 0.005 kg/s. As a result, the average efficiency of the solar collector at the Fe3O4@PAA NF of 0.05wt% was the highest at the mass flow rates of 0.0025 kg/s and 0.005 kg/s and the improvement ratio of average efficiency was 1.15 and 1.19, respectively, compared to water. The collector performance of the solar thermal harvesting improved owing to the improvement in the solar absorption and heat transfer, as well as the uniform temperature at the receiver tube as the concentration of the Fe3O4@PAA NF increased to a concentration of 0.05wt%. However, the collector performance of the solar thermal harvesting decreased for the 0.05wt% Fe3O4@PAA NF because of the increase in heat loss by the non-uniform temperature at the receiver tube and heat transfer. The increase in mass flow rate can reduce the heat loss by the decrease in temperature in the receiver tube; consequently, the efficiency of the solar collector using NFs is improved.
在本研究中,实验研究了Fe3O4@polyacrylic酸(PAA)纳米流体(NF)的体积吸收特性。Fe3O4@PAA NF的浓度为0 ~ 0.2wt%,质量流量分别为0.0025和0.005 kg/s。结果表明,当质量流量为0.0025 kg/s和0.005 kg/s时,太阳能集热器在Fe3O4@PAA NF下的平均效率最高,为0.05wt%,平均效率比水分别提高1.15和1.19。当Fe3O4@PAA纳滤膜的浓度增加到0.05wt%时,由于太阳能吸收和传热的改善以及接收管温度的均匀性,太阳能热收集的集热器性能得到改善。然而,在0.05wt% Fe3O4@PAA NF时,由于接收管温度不均匀和传热导致热损失增加,太阳能热收集的集热器性能下降。质量流量的增加可以通过降低接收管内温度来减少热损失;因此,利用NFs提高了太阳能集热器的效率。
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引用次数: 0
In Memoriam Professor Ismail Hakki Tavman 纪念伊斯梅尔·哈基·塔夫曼教授
IF 1.1 4区 工程技术 Q4 Engineering Pub Date : 2021-01-01 DOI: 10.32908/hthp.v50.1201
   
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引用次数: 0
Development of a new method to measure surface tension of molten oxides 建立了一种测量熔融氧化物表面张力的新方法
IF 1.1 4区 工程技术 Q4 Engineering Pub Date : 2021-01-01 DOI: 10.32908/hthp.v50.857
Toshiki Kondo, H. Muta, Y. Ohishi
Physical properties of molten oxides such as viscosity and surface tension are important in various fields. However, it is very difficult to measure the properties of molten oxides owing to their high melting points, high reactivity, and high vapor pressure. Hence, the physical properties of molten oxides are scarcely reported. Therefore, we developed a new method, termed the �impingement method,� for measuring the surface tension of molten oxides in a very short time, using the aerodynamic levitation technique. In this work, we developed an apparatus for measuring the surface tension of molten Al2O3 and compared the value with that of other methods, considered as reference values. Results showed that the surface tension of molten Al2O3 was approximately 0.72 N/m at around 2500 K, which is close to the reference value; moreover, the measurements could be obtained in a very short time (approximately 80 ms). Thus, it is expected that the surface tension of molten materials with high vapor pressures such as ZrO2 and UO2 can be measured using this method.
熔融氧化物的物理性质,如粘度和表面张力,在各个领域都很重要。然而,由于熔融氧化物的高熔点、高反应性和高蒸气压,测量其性质是非常困难的。因此,熔融氧化物的物理性质很少被报道。因此,我们开发了一种新方法,称为“撞击法”,用于在很短的时间内测量熔融氧化物的表面张力,使用空气动力学悬浮技术。在这项工作中,我们开发了一种测量熔融Al2O3表面张力的装置,并将其与其他方法的测量值进行了比较,作为参考值。结果表明:在2500 K左右,Al2O3熔液的表面张力约为0.72 N/m,接近参考值;此外,可以在很短的时间内(大约80毫秒)获得测量结果。因此,可以期望使用该方法测量ZrO2和UO2等高蒸汽压熔融材料的表面张力。
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引用次数: 3
The elastic and thermodynamic properties of TbAl and DyAl under high pressure TbAl和DyAl在高压下的弹性和热力学性质
IF 1.1 4区 工程技术 Q4 Engineering Pub Date : 2021-01-01 DOI: 10.32908/hthp.v50.903
Lili Liu, Cai Chen, Liwan Chen, Y. Wen
The elastic and thermodynamic properties of TbAl and DyAl under high pressure and temperature are investigated using the density-functional theory (DFT) and the density-functional perturbation theory (DFPT) within the quasi-harmonic approximation (QHA). The calculated lattice and elastic constants at ground state (0 GPa and 0 K) are in agreement with the experimental data and previous theoretical results. Finally, when the pressure is given, all the thermodynamic quantities except for the bulk modulus increase with temperature, but the increase of the thermal expansion coefficient and the heat capacity with temperature becomes smaller. Besides, the effects of pressure on the elastic constants and the thermodynamic quantities are opposite with those of the temperature on them for TbAl and DyAl.
利用准谐波近似(QHA)中的密度泛函理论(DFT)和密度泛函微扰理论(DFPT)研究了TbAl和DyAl在高压和高温下的弹性和热力学性质。计算得到的基态(0 GPa和0 K)晶格常数和弹性常数与实验数据和先前的理论结果一致。最后,当压力一定时,除体积模量外,其他热力学量均随温度升高而增大,但热膨胀系数和热容随温度升高的增量变小。此外,压力对TbAl和DyAl的弹性常数和热力学量的影响与温度的影响相反。
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引用次数: 1
Analysis of thickness and interfacial thermal resistance of Au microheater on glass or polyimide substrate 玻璃或聚酰亚胺基板上金微加热器厚度及界面热阻分析
IF 1.1 4区 工程技术 Q4 Engineering Pub Date : 2021-01-01 DOI: 10.32908/hthp.v50.1073
H. Kim, Woong Ko, D. Oh
The 3ω method is widely used for measuring the thermal properties of a substrate or thin film on which a microheater is deposited. Recently, samples with non-formal shapes and has a thermal conductivity of 1 W/mK or below have been analyzed using the bidirectional 3ω method. In measuring the thermal conductivity of such samples, the measurement sensitivity and accuracy can be increased using a 3ω sensor fabricated on a low thermal conductivity substrate such as glass or polyimide. In this study, thermal characterization is conducted on a microheater deposited on glass and polyimide substrates for a 3ω sensor. The effects of the microheater thickness and the interfacial thermal resistance between the substrate and microheater, on the temperature amplitude and phase lag are analyzed. Results from analytic solutions considering the microheater thickness and the interfacial thermal resistance are compared with results from numerical analysis of two-dimensional conduction heat transfer and experiment.
3ω方法被广泛用于测量衬底或薄膜的热性能,在衬底或薄膜上沉积了微加热器。最近,使用双向3ω方法分析了具有非正式形状且导热系数为1 W/mK或以下的样品。在测量此类样品的热导率时,可以使用在低热导率衬底(如玻璃或聚酰亚胺)上制造的3ω传感器来提高测量灵敏度和精度。在本研究中,对沉积在玻璃和聚酰亚胺基板上的微加热器进行了热表征,用于3ω传感器。分析了微加热器厚度和衬底与微加热器之间的界面热阻对温度幅值和相位滞后的影响。将考虑微加热器厚度和界面热阻的解析解与二维导热数值分析和实验结果进行了比较。
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引用次数: 2
Push-rod dilatometer calibration and thermal expansion coefficient measurement of standard material 推杆式膨胀计校准及标准材料热膨胀系数测量
IF 1.1 4区 工程技术 Q4 Engineering Pub Date : 2021-01-01 DOI: 10.32908/hthp.v50.1075
Joo-Chul Lee, Daeho Kim
The linear thermal expansion coefficient (LTEC) is a very important thermal property in the field of length standard, precision engineering and novel material science. There are several methods in measuring the LTEC of a material and the push-rod type is a one of the frequently used method. In this work, the calibration and the measurement procedures of the SRM 736 which is a certified material provided from NIST are carried out with push-rod type dilatometer (Dil402, NETZSCH) and the results are presented in the temperature range from 300°C to 500°C. The calibration of thermocouple and a linear variable differential transformer (LVDT) sensor have been performed with the melting point of the pure metals and the calibration device consisting of the rod and micrometer provided from the NETZSH.
线性热膨胀系数(LTEC)在长度标准、精密工程和新材料科学等领域是一项非常重要的热性能。测量材料LTEC的方法有很多种,推杆法是常用的一种方法。在这项工作中,SRM 736是NIST提供的认证材料,使用推杆式膨胀计(Dil402, NETZSCH)进行校准和测量程序,结果显示在300°C至500°C的温度范围内。用纯金属的熔点和NETZSH提供的由棒和千分尺组成的校准装置对热电偶和线性可变差动变压器(LVDT)传感器进行了校准。
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引用次数: 0
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High Temperatures-high Pressures
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