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Photocatalytic Degradation of Heavy Metals Cd, Cu, Fe and Pb Using ZnO-Zeolite Nanocomposite 利用氧化锌-沸石纳米复合材料光催化降解重金属镉、铜、铁和铅
Pub Date : 2023-12-27 DOI: 10.26554/ijems.2023.7.4.147-152
Tri Karimah Ramadhini, T. Agustina, Elda Melwita, M. Wijayanti
Heavy metals are the main pollutant substances in the environment. Heavy metals are a type of metal with high density and are very dangerous to living organisms, especially humans. Living organisms can adsorb the bioaccumulative and sedimentation of heavy metals that settle in water. Some compounds which found in wastewater including Cadmium (Cd), Copper (Cu), Iron (Fe), and Lead (Pb). These heavy metals cannot naturally degrade, additional processing is required before it being released into the environment. To prevent environmental pollution impacts, wastewater containing heavy metals must be handled properly and optimally. One method that can be applied for wastewater treatment is degradation by photocatalysis, utilizing the assistance of light. This research is to investigate the effect of pH and irradiation time on the degradation of Cd (cadmium), Cu (Copper), Fe (Iron), and Pb (Lead) heavy metals. To enhance the photocatalytic activity, the synthesis of ZnO-Zeolite nanocomposites was conducted. The ZnO-Zeolite nanocomposites produced were analyzed by SEM-EDX and XRD. The utilization of ZnO-Zeolite nanocomposites is deemed effective in reducing heavy metal concentrations. The degradation with Ultraviolet (UV) light exposure runs within 15-120 minutes with pH variation between 4-8. The degradation of heavy metal runs at 60 minutes and 120 minutes showing an optimum percentage removal of metals approaching 100%. The optimum pH values for Cd, Cu, Fe, and Pb are pH 8, pH 7, pH 6, and pH 8, respectively. The sequential metal degradation percentages are 98.96%, 95.43%, 96.07%, and 95.53%, respectively.
重金属是环境中的主要污染物质。重金属是一种密度很高的金属,对生物体,尤其是人类的危害很大。生物可以吸附沉淀在水中的重金属进行生物累积和沉淀。在废水中发现的一些化合物包括镉(Cd)、铜(Cu)、铁(Fe)和铅(Pb)。这些重金属无法自然降解,需要经过额外的处理才能排放到环境中。为了防止对环境造成污染,必须对含有重金属的废水进行适当和优化处理。其中一种可用于废水处理的方法是利用光的辅助进行光催化降解。本研究旨在探讨 pH 值和照射时间对 Cd(镉)、Cu(铜)、Fe(铁)和 Pb(铅)重金属降解的影响。为了提高光催化活性,研究人员合成了氧化锌-沸石纳米复合材料。通过 SEM-EDX 和 XRD 对制备的氧化锌-沸石纳米复合材料进行了分析。利用氧化锌-沸石纳米复合材料可有效降低重金属浓度。紫外线(UV)照射下的降解时间为 15-120 分钟,pH 值变化范围为 4-8。重金属降解时间为 60 分钟和 120 分钟,金属去除率接近 100%。镉、铜、铁和铅的最佳 pH 值分别为 pH 8、pH 7、pH 6 和 pH 8。金属的连续降解率分别为 98.96%、95.43%、96.07% 和 95.53%。
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引用次数: 0
Assessment of Use Values and Propagation Methods of Native Fodder and Fruit Species in Merhabete District, Ethiopia 埃塞俄比亚 Merhabete 地区本地饲料和水果品种的使用价值和繁殖方法评估
Pub Date : 2023-12-27 DOI: 10.26554/ijems.2023.7.4.137-146
Goremsu Getachew
Native fodder and fruit species provide various products and services to local communities besides their fruit (food) and fodder supply in our country including in the study area. Although, there is rich traditional knowledge on propagation methods of native fodder and fruit species and their local use, but little recognition has been given by forestry research and extension efforts to enhance them. The general objective of the study was to investigate the use value and propagation methods of native fodder and fruit species in the Merhabete district, Ethiopia. A total of 127 households were randomly selected and interviewed about local use and propagation methods of native fodder and fruit species. The study indicated that the majority of native fodder and fruit species were used for firewood (23.9%) followed by charcoal (10.9%), timber, and construction wood (10.6%), fencing (9.3%), soil fertility improvement (9.1%), farm tool (7.1%), and medicine (3.3%). Native fodder and fruit species (42.7%) were propagated through wilding (natural regeneration) and the remainder were propagated through seedlings (7.2%), seed (6.06%), and stem cutting (4.8%). Overgrazing (46.5%) followed by overexploitation (22%), climate change/drought (20.5%), and disease and pest (11%) were the major regeneration constraints to native fodder and fruit trees/shrubs species in the study area. Therefore, proper involvement either through research or development works are essential to reduce the propagation constraint of studied species. Ziziphus spina-christi (L.) Desf. followed by Faidherbia albida (Delile) A. Chev., Cordia africana Lam., Ximenia americana L., and Acacia senegal (L.) Willd. were the most preferred species for planting by farmers in the study area. Domestication should focus on the preferred top five species to promote species conservation and sustainable use.
在我国(包括研究地区),本地饲料和水果物种除了提供水果(食物)和饲料外,还为当地社区提供各种产品和服务。虽然关于本地饲料和水果物种的繁殖方法及其在当地的使用有着丰富的传统知识,但林业研究和推广工作却很少认识到这一点。这项研究的总体目标是调查埃塞俄比亚 Merhabete 地区本地饲料和水果物种的使用价值和繁殖方法。研究人员随机选取了 127 户家庭,就本地饲料和水果物种的使用和繁殖方法进行了访谈。研究表明,大多数本地饲料和水果物种被用作木柴(23.9%),其次是木炭(10.9%)、木材和建筑木材(10.6%)、栅栏(9.3%)、土壤肥力改良(9.1%)、农具(7.1%)和药物(3.3%)。本地饲料和水果物种(42.7%)是通过野化(自然再生)繁殖的,其余则是通过育苗(7.2%)、播种(6.06%)和切茎(4.8%)繁殖的。过度放牧(46.5%)、过度开发(22%)、气候变化/干旱(20.5%)和病虫害(11%)是研究地区本地饲料和果树/灌木物种再生的主要制约因素。因此,必须通过适当的研究或开发工作来减少所研究物种的繁殖限制。Ziziphus spina-christi (L.) Desf.、Faidherbia albida (Delile) A. Chev.、Cordia africana Lam.、Ximenia americana L.和 Acacia senegal (L.) Willd.是研究地区农民最喜欢种植的树种。驯化的重点应放在首选的前五个物种上,以促进物种保护和可持续利用。
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引用次数: 0
The Measurement of the Noise Level Based on Roads Classifications in Urban Area (Case Study: Harjamukti, Depok) 基于城市地区道路分类的噪声级测量(案例研究:德包 Harjamukti)
Pub Date : 2023-12-27 DOI: 10.26554/ijems.2023.7.4.153-159
E. Hanaseta N., Laila Febrina
Harjamukti Village is located in Depok City which is a buffer zone for the capital city of DKI Jakarta, the rapidly growing housing sector shows that this location has an attractiveness. The next problem that arises is the potential for noise from vehicular traffic due to community mobility. Noise measurements carried out using SNI 8427: 2017 show the LSM value on each road: Tumaritis Road (68.87 dBA), Bungur Road (61.29 dBA), Putri Tunggal Road (73.67 dBA), Putri Tunggal District Road (65.7 dBA) and Sementara Road (61.29 dBA). This study was conducted to see the road class based on the noise and capacity parameters, so that from these two parameters, can we clearly show the road class being analyzed. The measurements were carried out for 24 hours using the standard SNI 8427: 2017. The quality standard for the residential area used was 55 Dba based on the Minister of Environment Decree No. 48 of 1996. The road capacity used is analyzed based on the number of vehicles and the class of each road. Based on the noise parameters (sig 0.006) and capacity (sig 0.000) so that from the noise parameter there is no significant difference in the 5 research locations, while the road capacity shows a significant difference from the 5 research locations. Prediction of road class cannot be determined from the noise value and road capacity, because the noise obtained needs to be analyzed for the types of activities around whether there is an influence from other activities that are also dominant, such as toll roads and road capacity, because there are local road classes whose capacity is not detected different from collector road class.
Harjamukti 村位于雅加达德波克市,该市是首都雅加达的缓冲区,快速增长的住宅产业表明该地区具有吸引力。随之而来的问题是,由于社区的流动性,车辆交通可能会产生噪音。使用 SNI 8427:2017 进行的噪声测量显示了各条道路的 LSM 值:Tumaritis 路(68.87 分贝)、Bungur 路(61.29 分贝)、Putri Tunggal 路(73.67 分贝)、Putri Tunggal 区路(65.7 分贝)和 Sementara 路(61.29 分贝)。这项研究的目的是根据噪声和容量参数来确定道路等级,以便从这两个参数中清楚地看出所分析的道路等级。测量采用 SNI 8427: 2017 标准,持续 24 小时。根据 1996 年环境部第 48 号法令,住宅区的质量标准为 55 Dba。根据车辆数量和每条道路的等级分析了所使用的道路容量。根据噪声参数(sig 0.006)和通行能力(sig 0.000),5 个研究地点的噪声参数没有显著差异,而道路通行能力则显示 5 个研究地点存在显著差异。不能根据噪声值和道路通行能力来确定道路等级的预测,因为获得的噪声需要分析周围的活动类型,是否有来自其他活动的影响,如收费公路和道路通行能力,因为有些地方道路等级的通行能力与集散道路等级没有检测出差异。
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引用次数: 0
Potential Indonesian Rice Husk for Wastewater Treatment Agricultural Waste Preparation and Dye Removal Application 印度尼西亚稻壳在废水处理、农业废弃物制备和染料去除方面的应用潜力
Pub Date : 2023-12-27 DOI: 10.26554/ijems.2023.7.4.160-165
N. Palapa, Amri Amri, Yuliza Hanifah
This study used a novel method to transform rice husk waste into a highly effective and specific adsorbent for several dyes, including malachite green, direct yellow, congo red, and rodhamine B. The rice husk was analyzed and used for the purpose of eliminating these colors from water-based solutions. The adsorbent exhibited excellent heat stability, and the sample retained the functional groups of lignin. The parameters pertaining to kinetics were also examined. The adsorption exhibited a time-dependent rise and reached its peak after 100 minutes. In the kinetics tests, the most suitable model to characterize the behavior was found to be the pseudo-first order, with a regression value near to one. The rice husk shown significant potential and selectivity in the removal of malachite green and rodhamine B, particularly in the presence of direct yellow and congo red, from aqueous solutions.
本研究采用一种新方法将稻壳废料转化为一种高效的特异性吸附剂,可吸附多种染料,包括孔雀石绿、直接黄、刚果红和鼠李糖B。该吸附剂具有出色的热稳定性,样品保留了木质素的官能团。此外,还对动力学相关参数进行了研究。吸附量的上升与时间有关,100 分钟后达到峰值。在动力学测试中,发现最适合描述吸附行为的模型是伪一阶模型,其回归值接近于 1。稻壳在去除水溶液中的孔雀石绿和鼠李糖B(尤其是在存在直接黄和刚果红的情况下)方面表现出了巨大的潜力和选择性。
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引用次数: 0
Evaluation of Domestic Solid Waste Management in Cai Rang District, Can Tho City, Vietnam 越南芹苴市才让区生活固体废物管理评估
Pub Date : 2023-12-27 DOI: 10.26554/ijems.2023.7.4.128-136
Truong Hoang Dan, Le Tran Thanh Liem, Nguyen Thi Bich Lua, Le Thi Diem Mi
The study was conducted to evaluate the management of domestic solid waste in Cai Rang district, Can Tho city. The study conducted sampling of domestic solid waste from 20 households in four wards Le Binh, Hung Phu, Ba Lang, and Tan Phu within 07 days from March 6 to 12, 2023. At the same time, three groups of subjects including 120 households, 3 Environmental Managers, and 3 employees of Urban Environment Joint Stock Company were interviewed to collect information. The result showed that the average domestic solid waste generation coefficient reached 0.28 kg/person/day, and the amount of domestic solid waste generated can reach about 11,027.3 tons by the end of 2023. Of which, up to 91% of the volume of domestic solid waste was recyclable, including 52% of biodegradable organic waste, and 39% of recyclable waste. As for domestic solid waste management, there was still a limitation in classifying waste at source, this rate only fluctuates between 43.4-86.7%. Besides, the rate of households registered for domestic solid waste collection service had a difference between urban and rural areas, fluctuating from 76.7-96.7%. After being collected, domestic solid waste was transported to the Can Tho household waste incineration plant (EB plant). Meanwhile, the remaining amount of domestic solid waste was treated using unsanitary landfill methods, and thrown into rivers, causing environmental pollution, and public health. Although propaganda activities related to domestic solid waste management were carried out in four wards in Cai Rang district, Can Tho city. However, the level of implementation of these activities was not regular. From that, the study identified a number of difficulties in domestic solid waste management, including solid waste that was not completely classified at source, and garbage collection services that were not organized throughout the area. The district lacked specialized waste collection vehicles after classification, and public propaganda, and education work were limited. This research will help local authorities come up with specific solutions to improve the quality of solid waste management in Cai Rang district, Can Tho city.
该研究旨在评估芹苴市才让区的生活固体废物管理情况。该研究在 2023 年 3 月 6 日至 12 日的 07 天内对黎平、洪福、巴朗和新福四个区的 20 户家庭进行了生活固体废物抽样调查。同时,对三组对象(包括 120 户家庭、3 名环境经理和 3 名城市环境股份公司员工)进行了访谈,以收集信息。结果显示,平均生活固体废物产生系数达到 0.28 公斤/人/天,到 2023 年底,生活固体废物产生量可达约 11,027.3 吨。其中,可回收利用的生活固废高达 91%,包括 52%的可降解有机垃圾和 39%的可回收利用垃圾。在生活固废管理方面,源头分类仍有局限性,分类率仅在 43.4%-86.7%之间波动。此外,城市和农村地区的生活垃圾收集户登记率存在差异,在 76.7-96.7% 之间波动。收集后的生活固体废物被运往芹苴市生活垃圾焚烧厂(EB 工厂)。与此同时,剩余的生活固体废弃物采用不卫生的填埋方法进行处理,并被扔进河流,造成环境污染和公众健康问题。虽然在芹苴市才让区的四个区开展了与生活固体废物管理相关的宣传活动。但是,这些活动的实施程度并不规范。由此,研究发现了生活固体废物管理中存在的一些困难,包括固体废物在源头没有完全分类,垃圾收集服务没有在整个地区组织起来。该地区缺乏分类后的专业垃圾收集车辆,公众宣传教育工作有限。这项研究将帮助当地政府提出具体的解决方案,以提高芹苴市才让区的固体废物管理质量。
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Indonesian Journal of Environmental Management and Sustainability
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