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Syntheses and applications of graft copolymers from poly(1,1-diphenylethylene-co-divinylbenzene)s 聚(1,1-二苯乙烯-共二乙烯基苯)接枝共聚物的合成及应用
Pub Date : 1986-06-01 DOI: 10.1021/I300022A003
K. Hatada, T. Kitayama, S. Sasaki, Y. Okamoto, Eiji Masuda, Yoichi Kobayashi, Akihisa Nakajima, H. Aritome, S. Namba
Greffage de monomeres vinyliques sur les copolymeres du titre; applications comme emulsifiant polymere et electoresist negatif
乙烯基单体接枝到标题共聚物上;用作聚合物乳化剂和阴性选民
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引用次数: 4
Water immersion of polysulfide sealants. 1. Effect of temperature on swell and adhesion 聚硫密封胶的水浸性能。1. 温度对膨胀和粘附的影响
Pub Date : 1986-06-01 DOI: 10.1021/I300022A034
P. Hanhela, Robert H. E. Huang, D. Paul
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引用次数: 7
Two-stage reaction system for synthesis gas conversion to gasoline 合成气转化为汽油的两级反应系统
Pub Date : 1986-06-01 DOI: 10.1021/I300022A023
K. Fujimoto, K. Asami, H. Saima, T. Shikada, H. Tominaga
Etude experimentale du procede STG en deux etapes; dans un premier reacteur le gaz de synthese est converti en un melange methanol, dimethyl ether qui est ensuite transforme en hydrocarbures
两阶段STG工艺的实验研究;在第一个反应器中,合成气转化为甲醇、二甲基醚的混合物,然后再转化为碳氢化合物。
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引用次数: 19
Isotopic assessment of methanation over molybdenum sulfide catalysts 硫化钼催化剂上甲烷化的同位素评价
Pub Date : 1986-06-01 DOI: 10.1021/I300022A016
J. Happel, Motozou Yoshikiyo, F. Yin, M. Otarod, H. Y. Cheh, M. Hnatow, L. Bajars, H. Meyer
Les resultats experimentaux montrent qu'une concentration elevee d'hydrogene est absorbee sur les catalyseurs. L'addition de soufre et d'un element stabilisant augmente l'adsorption d'hydrogene et l'activite du sulfure de molybdene pur. Les catalyseurs de ce type ne sont pas empoisonne par les compose soufres et ne presentent pas de probleme de depots carbones
实验结果表明,催化剂吸收了高浓度的氢。硫和稳定元素的加入增加了纯硫化钼对氢的吸附和活性。这种类型的催化剂不会被含硫化合物毒害,也不会出现碳沉积的问题。
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引用次数: 13
Failure mechanisms for organic coatings subjected to 0.1 M sulfuric acid 0.1 M硫酸作用下有机涂层的失效机理
Pub Date : 1986-06-01 DOI: 10.1021/I300022A001
M. L. White, H. Vedage, R. Granata, H. Leidheiser
On a evalue l'aptitude d'un polymere fluore et d'un revetement epoxyde a proteger l'acier contre la corrosion dans une solution sulfurique a l'aide de quatre methodes: delamination cathodique, adhesion sous traction, vitesse de formation de cloques, analyse des gaz des cloques. Les donnees recueillies montrent que l'acide diffuse a travers le revetement pour reagir sur l'acier avec formation d'hydrogene. Les vitesses de formation et de diffusion de H 2 controlent le cloquage ou le decollement du feuil
用阴极分层、拉伸粘附、水泡形成速率和水泡气体分析四种方法评价了氟聚合物和环氧涂层在硫酸溶液中保护钢不受腐蚀的能力。收集的数据表明,酸通过涂层扩散,与钢发生反应,形成氢。h2的形成和扩散速度控制着薄板的关闭或脱落
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引用次数: 9
Properties of styrene-maleic anhydride copolymers 苯乙烯-马来酸酐共聚物的性能
Pub Date : 1986-06-01 DOI: 10.1021/I300022A033
E. R. Moore
Masses moleculaires, transitions vitreuses, temperatures de flechissement sous charge, stabilite thermique et viscosite au fondu
分子质量,玻璃化转变,负载下的屈曲温度,热稳定性和熔体粘度
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引用次数: 17
Detailed chemical kinetic study of the effect of molecular structure on autoignition of fuel-air mixtures 分子结构对燃料-空气混合物自燃影响的详细化学动力学研究
Pub Date : 1986-06-01 DOI: 10.1021/I300022A007
C. Westbrook, W. Pitz
Kinetic model is used to simulate the ignition of n-butane, isobutane, and n-pentane in air. Computed results are compared with data from shock tube experiments for the two n-alkanes, with very good agreement obtained. Model calculations under conditions of pressure and temperature encountered in internal combustion engines are reported. The influences of fuel molecular size and structure on autoignition rates are discussed in detail in terms of the site-specific H atom abstraction rates and subsequent fragmentation patterns of the alkyl radicals for each of the fuels considered.
采用动力学模型模拟了正丁烷、异丁烷和正戊烷在空气中的点火过程。计算结果与激波管实验结果进行了比较,结果吻合较好。本文报道了内燃机在压力和温度条件下的模型计算。燃料分子的大小和结构对自燃率的影响进行了详细的讨论,根据特定位点的H原子萃取率和随后的烷基自由基的断裂模式为每一个考虑的燃料。
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引用次数: 6
Deactivation of a vanadia-alumina catalyst for nitric oxide reduction by ammonia 氨还原一氧化氮的钒氧化铝催化剂失活研究
Pub Date : 1986-06-01 DOI: 10.1021/I300022A012
I. Nam, J. Eldridge, J. Kittrell
Role de SO 2 : agent desactivant de catalyseur. Il s'associe avec l'oxygene de maniere a former Al 2 (SO 4 ) 3 qui se fixe sur le lit catalytique
so2的作用:催化剂失活剂。它与氧结合形成al2 (so4) 3,并附着在催化床上
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引用次数: 58
Structural and cracking properties of REHY zeolites. Activity, selectivity, and catalyst-decay optimization for n-heptane cracking REHY沸石的结构和裂解性能。正庚烷裂化的活性、选择性和催化衰变优化
Pub Date : 1986-06-01 DOI: 10.1021/I300022A018
A. Corma, V. Fornés, J. B. Montón, A. Orchillés
Etude de la selectivite et de l'activite de zeolites de types Terres rares-HY, au cours du craquage du n-heptane. Les catalyseurs etudies presentent differents rapports (Terres rares) 3+ /NH 4 + . Leurs caracteristiques sont mesurees avant et apres desactivation en phase vapeur, par spectroscopie IR, chimisorption et diffraction X
稀土- hy型沸石在正庚烷裂解过程中的选择性和活性研究。所研究的催化剂具有不同的稀土比3+ / nh4 +。采用红外光谱、化学吸附和X射线衍射对其气相失活前后的特性进行了测量。
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引用次数: 25
Model of temperature dependence of a vanadia-alumina catalyst for nitric oxide reduction by ammonia: fresh catalyst 氨还原一氧化氮的钒-氧化铝催化剂温度依赖性模型:新鲜催化剂
Pub Date : 1986-06-01 DOI: 10.1021/I300022A011
I. Nam, J. Eldridge, J. Kittrell
On etudie la competition entre les reactions d'oxydation de NH 3 par NO et de reduction de NO par O 2
研究了nh3与NO氧化反应与o2还原反应之间的竞争。
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引用次数: 29
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Industrial & Engineering Chemistry Product Research and Development
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