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Algorithmic synthesis of chemical reactor networks using mathematical programming 基于数学规划的化学反应器网络算法合成
Pub Date : 1986-11-01 DOI: 10.1021/I100024A024
L. Achenie, L. Biegler
Etant donne un mecanisme cinetique et des expressions de la vitesse de reaction, on doit frequemment choisir de facon appropriee les diagrammes de melange et l'addition/elimination de la chaleur au cours de la conception du reacteur. Une nouvelle formulation de programmation non lineaire permet la conception optimale de ce reseau de reacteurs. On inclut les reseaux composes de reacteurs ideaux et non ideaux et les diagrammes de melange complexes. Le modele et les equations adjointes forment un probleme de valeur limite en deux points qui cree une interface avec une strategie d'optimisation efficace
由于给出了动力学机理和反应速率表达式,在反应器设计过程中必须经常选择适当的混合图和热的添加/消除。一种新的非线性规划公式使该反应堆网络的优化设计成为可能。包括由理想和非理想反应堆组成的网络以及复杂的混合图。该模型和相关方程形成了一个两点边界问题,创建了一个具有有效优化策略的界面
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引用次数: 81
Kinetic theory of polymer melts. 7. Polydispersity effects 聚合物熔体的动力学理论。7. 多分散性的影响
Pub Date : 1986-11-01 DOI: 10.1021/I100024A003
J. Schieber, C. F. Curtiss, R. Bird
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引用次数: 16
Suggested standard method for obtaining boiling curves by quenching 建议用淬火法获得沸腾曲线的标准方法
Pub Date : 1986-11-01 DOI: 10.1021/I100024A034
J. Westwater, John J. Hwalek, M. E. Irving
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引用次数: 47
Performance evaluation of particle size classifiers 粒度分类器的性能评价
Pub Date : 1986-11-01 DOI: 10.1021/I100024A037
K. Iinoya
L'evaluation de la performance d'un classificateur de particules depend fortement des proprietes d'agglomeration des poudres et des resultats erronnes d'analyse granulometrique des particules. Exemples de calcul
颗粒分级机的性能评价在很大程度上取决于粉末的团聚特性和颗粒粒度分析的错误结果。计算示例
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引用次数: 1
Separations by liquid centrifugations 液体离心分离
Pub Date : 1986-11-01 DOI: 10.1021/I100024A020
H. Hsu
Separation utilisant une technique de gradient de densite. Equations de base decrivant cette technique. Etat actuel de la centrifugation a ecoulement liquide semi-continu et continu. Perspectives de developpement de la methode continue
采用密度梯度技术进行分离。描述这种技术的基本方程。半连续和连续液体离心的现状。连续方法的发展前景
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引用次数: 3
Isotopic assessment of fundamental catalytic mechanisms by kinetic modeling 基于动力学模型的基本催化机制同位素评估
Pub Date : 1986-11-01 DOI: 10.1021/I100024A038
J. Happel, E. Walter, Y. Lecourtier
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引用次数: 22
Hydrocracking of diphenyl ether: roles of hydrogen sulfide and sulfur 二苯醚加氢裂化:硫化氢和硫的作用
Pub Date : 1986-11-01 DOI: 10.1021/I100024A043
V. Stenberg, P. G. Sweeny
Etude du role du soufre et du sulfure d'hydrogene en tant que promoteur de la liquefaction du charbon a travers la conversion d'ether diphenyl, compose modele des liaisons ether du charbon
研究硫和硫化氢作为煤液化促进剂通过二苯醚转化的作用,建立了煤的醚键模型
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引用次数: 5
The effect of surfactants on interphase solute transport. A theory of interfacial resistance 表面活性剂对相间溶质迁移的影响。界面阻力理论
Pub Date : 1986-11-01 DOI: 10.1021/I100024A031
R. Borwankar, D. Wasan
Etude theorique de la nature de la resistance interfaciale par resolution detaillee de la region interfaciale obtenue en utilisant une echelle de longueur microscopique en plus de l'echelle macroscopique. Bien que la concentration du solute et les champs de flux soient continus, leurs developpements ne sont pas uniformement valables dans le domaine complet. On utilise alors la methode de developpement asymptotique raccorde. On donne une derivation rigoureuse asymptotiquement de la formulation du macrocontinuum elastique du transfert entre phase
对界面电阻性质的理论研究,通过使用微观长度尺度和宏观尺度获得的界面区域的详细分辨率。虽然溶质浓度和流动场是连续的,但它们的发展在整个区域并不一致。然后采用连接渐近展开法。给出了相间转移弹性宏观连续体公式的严格渐近推导。
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引用次数: 16
Adaptive compensation for large disturbances in a continuous polymerization reactor 连续聚合反应器中大扰动的自适应补偿
Pub Date : 1986-08-01 DOI: 10.1021/I100023A008
J. Farber, B. Ydstie
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引用次数: 10
Effect of external mass-transfer resistance on facilitated transport 外传质阻力对运输便利的影响
Pub Date : 1986-08-01 DOI: 10.1021/I100023A025
R. Noble, J. Way, L. Powers
On derive une expression analytique du facteur de facilitation, au cours du transport facilite dans un film liquide. Cette expression tient compte des resistances externes au transfert de matiere et de la diffusion et de la reaction a l'interieur du film liquide
给出了在液体薄膜中运输过程中促进因子的分析表达式。这个表达式考虑了物质转移的外部阻力以及液体膜内的扩散和反应。
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引用次数: 47
期刊
Industrial & Engineering Chemistry Fundamentals
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