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Sodium-Decorated SiB Monolayer for Reversible Hydrogen Storage: High-Capacity Achieved by Carbon Doping 用于可逆氢存储的钠掺杂硅砖单层:通过掺碳实现高容量
IF 4.3 3区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-09-07 DOI: 10.1155/2024/3403239
Fengyu Miao, Jie Li, Feng Zhang, Xin Bi, Xin Huang, Zhihong Yang, Yunhui Wang, Yakui Weng

Based on the first-principles calculation and grand canonical Monte Carlo (GCMC) simulation, the reversible hydrogen storage of Na-decorated silicon boron (SiB) and C-doped SiB monolayers have been investigated. For double side 4Na-decorated SiB monolayer, each Na atom can adsorb five H2 molecules with the average adsorption energy of −0.18 eV/H2, yielding an H2 gravimetric density of 9.09 wt% and desorption temperature TD of 227 K. To further improve the H2 gravimetric density and desorption temperature, doping effect was employed to enhance the internal electric field between Na atom and SiB substrate. When two Si atoms in the SiB monolayer were replaced by C atoms, the adsorption energy for H2 was significantly improved. The H2 gravimetric density reaches to 10.63 wt% with the average adsorption energy of −0.22 eV/H2. Meanwhile, the desorption temperature TD was raised from 227 to 282 K, reaching the ideal condition near room temperature. In addition, the GCMC simulations further confirm that the H2 gravimetric density can fully meet the latest hydrogen storage target (5.5 wt%) for both Na-decorated SiB monolayer and Na-decorated C-doped SiB monolayer. Our results indicate that both Na-modified SiB and C-doped SiB monolayers can be used as promising materials for reversible hydrogen storage.

基于第一性原理计算和大规范蒙特卡洛(GCMC)模拟,研究了Na装饰硅硼(SiB)和C掺杂硅硼单层的可逆储氢。对于双面 4Na 装饰的硅硼单层,每个 Na 原子可吸附 5 个 H2 分子,平均吸附能为 -0.18 eV/H2,从而得到 9.09 wt% 的 H2 重量密度和 227 K 的解吸温度 TD。当 SiB 单层中的两个 Si 原子被 C 原子取代时,H2 的吸附能显著提高。H2 的重量密度达到 10.63 wt%,平均吸附能为 -0.22 eV/H2。同时,解吸温度 TD 从 227 K 提高到 282 K,达到接近室温的理想状态。此外,GCMC 模拟进一步证实,Na 修饰的硅砖单层和 Na 修饰的掺杂 C 的硅砖单层的 H2 重量密度都能完全达到最新的储氢目标(5.5 wt%)。我们的研究结果表明,Na 修饰的 SiB 单层和 C 掺杂的 SiB 单层都可以作为很有前景的可逆储氢材料。
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引用次数: 0
Efficiency Evaluation for Regional Energy and Environment Using Two-Stage DEA Model Considering Stochastic Factors 使用考虑随机因素的两阶段 DEA 模型评估区域能源与环境效率
IF 4.3 3区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-09-05 DOI: 10.1155/2024/9376955
Yi Sun, Lu Gan, Yingchun Chen, Benjamin Lev, Ying Zhou

Energy consumption has risen much more while the economy has expanded so quickly. As a result, significant environmental contamination is created, which causes public worry. Under this background, enhancing energy efficiency and lowering pollution is particularly crucial for the fulfillment of sustainable economic development. Efficiency evaluation for energy and environment is an effective measure to achieve both energy saving and emission reduction as well as sustainable social development. In this paper, energy and environmental efficiency consists of energy utilization efficiency and pollution treatment efficiency. An improved two-stage DEA model is proposed, which takes into account how stochastic and environmental factors affect decision-making units (DMUs). Finally, the author analyses the panel data of 15 cities in Southwest China from 2010 to 2018, which proves the feasibility and effectiveness of this study. The results show Southwest China’s poor energy and environmental efficiency as well as the stark differences among its cities. The scientific value revealed by this paper is as follows: (1) for the study of energy and environmental efficiency, this paper is more targeted at the differences between cities and (2) using an improved two-stage DEA model to consider the effects of stochastic factors on DMUs.

在经济快速发展的同时,能源消耗也大幅增加。因此,造成了严重的环境污染,引起了公众的担忧。在此背景下,提高能效、降低污染对实现经济可持续发展尤为重要。能源与环境效率评价是实现节能减排和社会可持续发展的有效措施。在本文中,能源与环境效率包括能源利用效率和污染处理效率。本文提出了一个改进的两阶段 DEA 模型,该模型考虑了随机因素和环境因素对决策单元(DMU)的影响。最后,作者分析了中国西南地区 15 个城市 2010 年至 2018 年的面板数据,证明了本研究的可行性和有效性。研究结果表明,中国西南地区的能源和环境效率低下,城市之间的差异也非常明显。本文揭示的科学价值如下:(1)对于能源与环境效率的研究,本文更多针对城市间的差异;(2)采用改进的两阶段 DEA 模型,考虑随机因素对 DMU 的影响。
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引用次数: 0
Continuous Monitoring of Water Levels for Industrial Boilers Using Single-Stage Object Recognition YOLOv5 使用单级对象识别 YOLOv5 对工业锅炉水位进行连续监测
IF 4.3 3区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-09-05 DOI: 10.1155/2024/6107765
Jongwon Kim, Minjun Kwon, Byeongchan So, Sewon Kim, Hongyun So

This paper presents a measurement method that utilizes object recognition technology for continuous and quantitative real-time monitoring of water levels in industrial boilers. Real-time videos of water levels were monitored using a small camera, and the YOLO algorithm, a single-stage detector, was employed to use the bounding boxes of detected objects within the video as variables, directly measuring the length ratio for each frame. The method demonstrated a high level of accuracy in water-level measurement, with an average of 99.02%, and a stable performance, with a fluctuation of 0.13% in continuous measurements. Consequently, the proposed measurement method proves feasible for quantifying continuous water levels in industrial inspection systems even in low-resource environments. These results demonstrate a new mechanism for monitoring technology, without requiring text detection, showing the potential for improving efficiency in complex boiler systems and the feasibility of reliable water-level measurement and control.

本文介绍了一种利用物体识别技术对工业锅炉水位进行连续、定量实时监测的测量方法。利用小型摄像机实时监测水位视频,并采用单级检测器 YOLO 算法,将视频中检测到的物体的边界框作为变量,直接测量每帧的长度比。该方法的水位测量精度高,平均达到 99.02%,而且性能稳定,连续测量的波动率仅为 0.13%。因此,即使在资源匮乏的环境中,所提出的测量方法也可用于量化工业检测系统中的连续水位。这些结果展示了一种无需文本检测的新监测技术机制,显示了提高复杂锅炉系统效率的潜力以及可靠水位测量和控制的可行性。
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引用次数: 0
On the Assessment of the Chilean Solar Thermal Regulation Using a Modular Simulation Model Coupled to a Multiobjective Optimization Algorithm 利用模块化仿真模型和多目标优化算法评估智利太阳能热管理条例
IF 4.3 3区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-09-03 DOI: 10.1155/2024/7478549
Jorge Contreras, Benjamin Kadoch, Fabián Bustos

In Chile, the solar thermal regulation DS331, which utilizes a global modeling approach, governs the deployment of solar thermal systems (STSs) across highly variable climatic zones. This regulation’s one-size-fits-all approach often misrepresents the solar potential and economic feasibility in different regions. To address these limitations, we introduce a refined modular energy model that incorporates a 1D multinode stratification technique for hot water storage. This model is associated with a multiobjective optimization process using the NSGA-II algorithm, focusing on optimizing the solar collector area and storage volume to maximize solar fraction and life cycle savings (LCSs) across 20 major Chilean cities. Our results demonstrated that the optimized systems achieve solar fractions ranging from 0.92 to 1.00, significantly improving upon the current regulation’s performance, particularly in southern regions where solar radiation is lower. Notably, the optimized configurations suggested a potential reduction in collector areas by up to 20% and storage volumes by up to 15% compared to those recommended by DS331, while still exceeding the legal requirements for the solar fraction. This optimization made it possible to increase LCS by ~25%–30% across various scenarios, indicating a substantial improvement in cost-effectiveness. Based on these findings, existing solar thermal regulations should be revised to take into account local climatic and consumption data. Such adjustments would ensure more accurate sizing of STS, enhanced economic viability, and greater incentive alignment for widespread adoption. This study underlines the critical role of detailed, location-specific energy modeling in shaping effective energy policies and advancing the deployment of renewable technologies in diverse environmental contexts.

在智利,太阳能热利用法规 DS331 采用全球建模方法,对不同气候区太阳能热利用系统(STS)的部署进行管理。该法规的 "一刀切 "方法往往会误导不同地区的太阳能潜力和经济可行性。为了解决这些局限性,我们引入了一个经过改进的模块化能源模型,该模型结合了用于热水储存的一维多节点分层技术。该模型与使用 NSGA-II 算法的多目标优化过程相关联,重点是优化太阳能集热器面积和存储容量,以最大限度地提高智利 20 个主要城市的太阳能利用率和生命周期节约率(LCS)。我们的研究结果表明,优化后的系统可实现 0.92 至 1.00 的太阳辐射率,大大提高了现行法规的性能,尤其是在太阳辐射较低的南部地区。值得注意的是,与 DS331 建议的配置相比,优化后的配置建议集热器面积最多可减少 20%,存储容量最多可减少 15%,同时仍可超过法定的太阳辐射分数要求。这种优化使各种方案的 LCS 增加了约 25%-30%,表明成本效益大幅提高。基于这些发现,现有的太阳能热利用法规应结合当地的气候和消费数据进行修订。这种调整将确保更准确地确定太阳能热发电系统的规模,提高经济可行性,并为广泛采用太阳能热发电系统提供更多的激励措施。这项研究强调了详细的、针对具体地点的能源建模在制定有效的能源政策以及在不同的环境背景下推进可再生能源技术应用方面的关键作用。
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引用次数: 0
BN Promoted Heterojunction Ni─Fe─P/BN Electrocatalyst with Excellent Performance of Oxygen Evolution Reaction BN 促进的 Ni─Fe─P/BN 异质结电催化剂具有优异的氧进化反应性能
IF 4.3 3区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-08-30 DOI: 10.1155/2024/6072886
Guoqiang Han, Chunyang Wang, Shen Zhao, Haowei Bian, Guangwen Xie, Xin Liu, Luhua Jiang

In this research, we have successfully synthesized a Ni─Fe─P/h-BN catalyst through a simple one-step electrodeposition method for efficient water splitting in a KOH electrolytic cell. Our prepared Ni─Fe─P/h-BN catalyst showcased exceptional electrocatalytic activity for the oxygen evolution reaction (OER), with an overpotential of only 210 mV at a current density of 10 mA cm⁻2. Notably, this value is significantly lower compared to 248 mV observed for Ni─Fe─P/Fe without h-BN and also superior to the results reported for other catalysts. Furthermore, through the ball milling, we further enhanced the OER performance of the catalyst, achieving an impressive overpotential of 200 mV at the same density of 10 mA cm−2. The exceptional OER performance displayed by the Ni─Fe─P/h-BN composite is attributable to the synergistic effects of Ni─Fe─P and h-BN. Furthermore, the introduction of a heterojunction between h-BN and Ni─Fe─P serves to further enhance the OER capability of the catalyst. This investigation introduces a straightforward and effective approach for fabricating cost-effective and high-performance electrocatalysts intended for water electrolysis.

在这项研究中,我们通过简单的一步电沉积法成功合成了 Ni─Fe─P/h-BN 催化剂,用于 KOH 电解池中的高效水分离。我们制备的 Ni─Fe─P/h-BN 催化剂在氧进化反应(OER)中表现出卓越的电催化活性,在 10 mA cm-2 的电流密度下,过电位仅为 210 mV。值得注意的是,这一数值明显低于在不含 h-BN 的 Ni─Fe─P/Fe 催化剂中观察到的 248 mV,也优于其他催化剂的结果。此外,通过球磨,我们进一步提高了催化剂的 OER 性能,在 10 mA cm-2 的相同密度下,过电位达到了令人印象深刻的 200 mV。Ni─Fe─P/h-BN 复合材料所表现出的优异 OER 性能归功于 Ni─Fe─P 和 h-BN 的协同效应。此外,h-BN 和 Ni─Fe─P 之间异质结的引入进一步增强了催化剂的 OER 能力。这项研究为制造用于水电解的高性价比、高性能电催化剂提供了一种简单有效的方法。
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引用次数: 0
Electrification of the Thermal Load in an Industrial Hall by Replacing Conventional Energy with Solar Energy 用太阳能替代传统能源,实现工业厂房热负荷电气化
IF 4.3 3区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-08-30 DOI: 10.1155/2024/6459432
Raluca-Andreea Felseghi, Angela Pleșa, Alexandru-Silviu Popa

In the context of the European Energy Directives for the period 2020–2035 and the perspectives for 2050, the next generations of energy systems and associated technologies for the power supply of buildings will have a significant impact on pollution and greenhouse gas emissions mitigation, generating clean electricity with financial efforts in decrease. Until recently, the processes of burning conventional fossil fuels represented the main source of thermal energy, but along with technological development, new solutions have been implemented for providing thermal energy that works based on renewable energies, and the hypothesis of heating electrification based on alternative resources is feasible. The present research article addresses the topic of Electrification of the Thermal Load by Replacing Conventional Energy with Solar Energy within a case study with practical applicability to an existing industrial production hall. This study aims to assess, within a comparative analysis, the feasibility of replacing conventional energy fossil resources with solar energy resources, with the objective of decarbonization through electrification of the heating in industrial hall workspaces. In the case study, by implementing the solar generator that has the role of taking over the building thermal load, carbon dioxide emissions are reduced by 90% compared to the heat generation using conventional fossil energy, and the costs can be reduced by around of 70% compared to the current costs charged by economic operators in the domain.

在 2020-2035 年欧洲能源指令和 2050 年展望的背景下,下一代能源系统和建筑供电的相关技术将对减少污染和温室气体排放产生重大影响,并在减少资金投入的情况下产生清洁电力。直到最近,传统化石燃料的燃烧过程仍是热能的主要来源,但随着技术的发展,新的解决方案已在可再生能源的基础上提供热能,基于替代资源的供热电气化假设是可行的。本研究文章在一个案例研究中探讨了 "用太阳能替代传统能源,实现热负荷电气化 "这一主题,该案例研究对现有的工业生产车间具有实际应用价值。本研究旨在通过比较分析,评估用太阳能资源替代传统化石能源的可行性,目的是通过工业厂房工作区供热电气化实现脱碳。在案例研究中,通过使用太阳能发电机承担建筑热负荷,与使用传统化石能源供热相比,二氧化碳排放量减少了 90%,与该领域经济运营商目前收取的费用相比,成本可降低约 70%。
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引用次数: 0
RETRACTION: Economic Prospects of Replacing Distributed Generation with Biofuel 回收:用生物燃料替代分布式发电的经济前景
IF 4.3 3区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-08-28 DOI: 10.1155/2024/9895219
International Journal of Energy Research

RETRACTION: I.A. Kapitonov, N.T. Batyrova, “Economic Prospects of Replacing Distributed Generation with Biofuel,” International Journal of Energy Research 45, no. 12 (2021): 17502–17514, https://doi.org/10.1002/er.7105

The above article, published online on 27 July 2021 in Wiley Online Library (wileyonlinelibrary.com) [1], has been retracted by agreement between the Commissioning Editor, Akshay Kumar Saha, and John Wiley & Sons Ltd. UK. The retraction has been agreed following concerns raised by a third party regarding the peer review process. Further investigation by the publisher has found manipulation of the peer review process. The authors did not respond to requests for an explanation. As a result, the conclusions reported in the article are not considered reliable.

撤回:I.A. Kapitonov, N.T. Batyrova, "Economic Prospects of Replacing Distributed Generation with Biofuel," International Journal of Energy Research 45, no:17502-17514, https://doi.org/10.1002/er.7105The 上述文章于 2021 年 7 月 27 日在线发表于 Wiley Online Library(wileyonlinelibrary.com)[1],经委托编辑 Akshay Kumar Saha 和 John Wiley & Sons Ltd. 英国公司同意,已被撤回。英国。撤稿是在第三方对同行评审过程提出质疑后达成的。出版商的进一步调查发现,同行评审过程存在操纵行为。作者没有回应解释要求。因此,文章中报告的结论被认为是不可靠的。
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引用次数: 0
The Imbibition Mechanism and the Calculation Method of Maximum Imbibition Length during the Hydraulic Fracturing 水力压裂过程中的浸润机理和最大浸润长度计算方法
IF 4.3 3区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-08-27 DOI: 10.1155/2024/8371615
Zhongwei Wu, Xianhong Li, Chuanzhi Cui, Yin Qian, Yidan Wang, Japan J. Trivedi

It has been recognized that fluid imbibes into the matrix and floods the oil during hydraulic fracturing; however, the mechanism of fluid imbibing into the matrix and flooding the oil remains unclear. Additionally, there is a scarcity of methods for calculating the maximum imbibition length. In this paper, we first analyzed the imbibition mechanism during hydraulic fracturing and then developed a method for calculating the imbibition length using mercury intrusion experiments, seepage theory, and numerical calculations. By comparing the proposed method calculations with experimental results and published model calculations, we verified our proposed method. Finally, we presented the influences of the maximum imbibition length. From the work, we can know that imbibition during hydraulic fracturing involves counter-current imbibition under surrounding pressure. The influence of permeability on threshold pressure gradients was found to be greater than that on capillary pressure, resulting in an increase in the maximum imbibition length with increased permeability (ranging from 0.01 to 0.2 × 10−3μm2), while the time taken to achieve the maximum imbibition length decreased exponentially. When the reservoir permeability was 0.1 × 10−3μm2, the contact angle was 60°, and the interface tension was 50 mN/m, the maximum imbibition length was 1.8 m, and the time of achieving maximum imbibition length was 70 days. This study provided a method for evaluating the extent of imbibition.

人们已经认识到,在水力压裂过程中,流体会渗入基质并淹没油层;然而,流体渗入基质并淹没油层的机理仍不清楚。此外,也缺乏计算最大浸入长度的方法。本文首先分析了水力压裂过程中的浸润机理,然后利用汞侵入实验、渗流理论和数值计算,开发了一种计算浸润长度的方法。通过将所提出的方法计算结果与实验结果和已公布的模型计算结果进行比较,我们验证了所提出的方法。最后,我们介绍了最大浸润长度的影响因素。从工作中我们可以了解到,水力压裂过程中的浸润包括周围压力下的逆流浸润。研究发现,渗透率对阈值压力梯度的影响大于对毛细管压力的影响,从而导致最大浸润长度随渗透率的增加而增加(从 0.01 到 0.2 × 10-3 μm2),而达到最大浸润长度所需的时间则呈指数下降。当储层渗透率为 0.1 × 10-3 μm2、接触角为 60°、界面张力为 50 mN/m 时,最大浸润长度为 1.8 m,达到最大浸润长度的时间为 70 天。这项研究提供了一种评估浸润程度的方法。
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引用次数: 0
A 3D Numerical Model for Improving Methane Drainage Efficiency in Underground Coal Mines Using the Cross-Measure Borehole Method 利用交叉测量钻孔法提高煤矿井下甲烷排放效率的三维数值模型
IF 4.3 3区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-08-26 DOI: 10.1155/2024/6921566
Ali Hosseini, Mehdi Najafi, Amin Hossein Morshedy

The release of methane into the working area of coal mines can affect safety and production. Therefore, methane drainage reduces the risk of explosion and can be used as a fuel and energy source. One methane drainage method is cross-measure borehole drilling, which involves drilling boreholes from tailgate roadways to the roof or floor layers of a mined seam. In this method, determining the appropriate distance between methane drainage stations has a significant impact on increasing the efficiency of operation and reducing drilling costs and the time required for drainage operations from each station. In this paper, a new 3D numerical model is developed for methane drainage from an underground coal mine to determine the suitable distance between methane drainage stations in the cross-measure borehole method using COMSOL Multiphysics software. For this purpose, by considering the porous media flow module and the laws related to the movement of gas in the goaf, different numerical models for distances of 10, 15, 20, 25, and 30 m were simulated. The simulation results showed that by reducing the distance between methane drainage stations, the speed of gas flow in the borehole and the amount of gas removed from the boreholes in a similar period of time increase to an acceptable level. In addition, the implementation of this model in a case study showed that a distance of 10 m between drainage stations increases the efficiency of boreholes to approximately 20%. Numerical simulation in this study can provide basic support for the design of drainage boreholes and reduce the risk of gas in underground coal mines.

甲烷释放到煤矿工作区会影响安全和生产。因此,瓦斯抽放可降低爆炸风险,并可用作燃料和能源。一种甲烷排放方法是交叉测量钻孔法,即从尾部巷道到开采煤层的顶板或底板层钻孔。在这种方法中,确定瓦斯抽放站之间的适当距离对提高作业效率、降低钻井成本和减少每个站抽放作业所需的时间有重要影响。本文利用 COMSOL Multiphysics 软件,为煤矿井下瓦斯抽放建立了一个新的三维数值模型,以确定交叉测量钻孔法中瓦斯抽放站之间的合适距离。为此,考虑到多孔介质流动模块和瓦斯在煤层中运动的相关规律,模拟了 10、15、20、25 和 30 米距离的不同数值模型。模拟结果表明,通过缩短甲烷排放站之间的距离,钻孔中气体流动的速度和在类似时间内从钻孔中排除的气体量都会增加到可接受的水平。此外,该模型在案例研究中的应用表明,排水站之间的距离为 10 米,井眼的效率可提高约 20%。本研究中的数值模拟可为排水钻孔的设计提供基础支持,降低煤矿井下瓦斯风险。
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引用次数: 0
Optimizing Hydrogen Storage Pathways in Ti–Al Alloys through Controlled Oxygen Addition 通过受控加氧优化钛铝合金中的储氢途径
IF 4.3 3区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-08-26 DOI: 10.1155/2024/2216181
Vivek Shukla, Sung Ju Han, Taejun Ha, Satya Prakash Padhee, Jin-Yoo Suh, Young Whan Cho, Young-Su Lee

In the present study, we aimed to destabilize the Ti–Al system with nonmetallic oxygen. The synthesis of α-(Ti, Al)[O] starting from TiO2, Ti, and Al was carried out through the arc melting method, resulting in three different oxygen content levels, 3.4, 10, and 20 at%. The room temperature activation of α-(Ti, Al)[O] was not successful, and the activation was performed at 300°C under 5 MPa H2 pressure. The structural changes after hydrogenation (maximum absorption capacity of 3.74 wt% hydrogen) arose from the transformation of α-(Ti, Al)[O] to cubic (Ti, Al)[O]Hx (c-(Ti, Al)[O]Hx); nonetheless, they recovered their original lattice parameters, which are meaningfully larger than those of α-Ti, after dehydrogenation. The hydrogen storage capacities for various α-(Ti, Al)[O] compositions generally decreased with increasing oxygen (3.4 and 10 at%) and aluminum content in the alloy. In contrast, for the compositions with a higher oxygen content of 20 at%, the hydrogen storage capacity slightly increased as the Al concentration increased: Ti0.790Al0.010O0.200 absorbed 2.91 wt% hydrogen, whereas Ti0.767Al0.033O0.200 absorbed 3.04 wt% hydrogen. The thermogravimetric analysis showed that samples with 20 at% O released hydrogen at lower temperatures even though the major phase after hydrogenation is c-(Ti, Al)[O]Hx regardless of the oxygen content.

在本研究中,我们的目标是用非金属氧破坏 Ti-Al 系统的稳定性。我们通过电弧熔融法从 TiO2、Ti 和 Al 开始合成了 α-(Ti,Al)[O],得到了 3.4%、10% 和 20% 三种不同的氧含量水平。室温活化 α-(Ti,Al)[O]并不成功,因此需要在 300°C 温度和 5 兆帕 H2 压力下进行活化。氢化后的结构变化(最大吸氢容量为 3.74 wt%)源于 α-(Ti,Al)[O] 向立方(Ti,Al)[O]Hx(c-(Ti,Al)[O]Hx)的转化;尽管如此,它们在脱氢后恢复了原来的晶格参数,而且比 α-Ti 的晶格参数大得多。随着合金中氧(3.4% 和 10%)和铝含量的增加,各种 α-(Ti,Al)[O] 成分的储氢能力普遍下降。相反,对于氧含量较高的 20% 成分,随着铝浓度的增加,储氢能力略有提高:Ti0.790Al0.010O0.200 可吸收 2.91 wt% 的氢,而 Ti0.767Al0.033O0.200 则可吸收 3.04 wt% 的氢。热重分析表明,尽管氢化后的主要相为 c-(Ti,Al)[O]Hx,但无论氧含量多少,含 20% O 的样品在较低温度下释放氢气。
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引用次数: 0
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