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Construction of an Equivalent Digital Rock Mass Based on CT Scans of Coal and the Control of Joint Dip Angle on Its Mechanical Behavior 基于煤体CT扫描的等效数字岩体构建及节理倾角对其力学行为的控制
IF 4.3 3区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-01-16 DOI: 10.1155/er/5512310
Ding Lang, Zixin Zhang, Tuanjie Li, Hongping Yuan, Xiaolou Chi, Xiaobo Wu, Lishuai Chen

The joint dip angle has a significant influence on the mechanical behavior of coal, and revealing its influence mechanism is a scientific premise for analyzing mining-induced mechanical behavior of coal mining. However, the geometric shape of coal joints is complex, and the previous research methods of artificially prefabricated cracks are difficult to accurately reshape the initial structural characteristics of coal. Therefore, the realization of the identification of the in situ occurrence of coal joints and the characterization of the distribution law is the basis for revealing the control effect of joint dip angle on mechanical behavior. Through the combination of CT scanning, three-dimensional reconstruction, rock mechanics test and numerical simulation, the equivalent digital rock mass based on geometric probability distribution model is constructed, and on this basis, the control effect of joint dip angle on the mechanical behavior of coal body is studied. The results show that: (1) The average error of joint dip angle and bulk density between the equivalent digital rock mass and the actual coal sample is 2.26%, the error of uniaxial compressive strength is 14.17%, and the error of elastic modulus is 8.45%. The results are relatively consistent. (2) According to the sensitivity coefficient, the joints with an angle in the range of 45°–60° have the greatest influence on the uniaxial compressive strength. The joint angle in the range of 30°–45° has the greatest influence on the tensile and shear strength. (3) The influence degree of joint dip angle on the strength characteristics of digital rock mass is different. According to the sensitivity coefficient, the influence degree from strong to weak is shear strength, compressive strength, and tensile strength. (4) In terms of failure mode, different angles of joints have different control effects on different forms of fracture modes. Joints with angles of 45°–60° and 75°–90° play a major role in controlling the failure modes of model compression and tensile tests, respectively.

节理倾角对煤的力学行为有显著影响,揭示其影响机理是分析采动煤层力学行为的科学前提。然而,煤节理的几何形状复杂,以往人工预制裂缝的研究方法难以准确重塑煤的初始结构特征。因此,实现煤层节理就地产状的识别和分布规律的表征,是揭示节理倾角对力学行为控制作用的基础。通过CT扫描、三维重建、岩石力学试验和数值模拟相结合,构建了基于几何概率分布模型的等效数字岩体,并在此基础上研究了节理倾角对煤体力学行为的控制作用。结果表明:(1)等效数字岩体与实际煤样的节理倾角和容重平均误差为2.26%,单轴抗压强度误差为14.17%,弹性模量误差为8.45%。结果是相对一致的。(2)根据敏感系数,角度在45°~ 60°范围内的节理对单轴抗压强度影响最大。节理角度在30°~ 45°范围内对抗拉、抗剪强度影响最大。(3)节理倾角对数字岩体强度特性的影响程度不同。根据敏感性系数,影响程度由强到弱依次为抗剪强度、抗压强度、抗拉强度。(4)在破坏模式上,不同角度的节理对不同形式的断裂模式有不同的控制作用。角度为45°~ 60°和75°~ 90°的节理分别对模型压缩和拉伸试验的破坏模式起主要控制作用。
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引用次数: 0
Multi-Teacher Knowledge Distillation Framework for Lightweight Deep Learning-Based State-of-Health Estimation 基于轻量级深度学习的健康状态评估多教师知识精馏框架
IF 4.3 3区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-01-12 DOI: 10.1155/er/5535455
Yeonho Choi, Paul Jang, Jaejung Yun

While deep learning-based approaches for state of health (SOH) estimation in lithium-ion batteries have been actively studied, most models face deployment constraints in on-device applications due to their high complexity and large number of parameters. Although previous studies have introduced knowledge distillation (KD) for model compression, single-teacher architectures exhibit limited performance improvement due to insufficient knowledge diversity. To resolve this issue, this study proposes a multi-teacher knowledge distillation (MTKD) framework to simultaneously achieve efficient SOH estimation and model compression. From raw charging data, a total of 18 health indicators (HIs) were obtained from diverse perspectives, including temporal information, statistical features, equivalent circuit model (ECM) parameters, and incremental calculation. Key features were selected through Pearson correlation analysis and the maximal information coefficient (MIC), and were utilized as inputs for the deep learning models. Subsequently, large-scale teacher models based on deep neural network (DNN), long short-term memory (LSTM), and one-dimensional convolution neural network (1D CNN) architectures were trained to capture various degradation characteristics, including nonlinear relationships, temporal dependencies, and local patterns. The lightweight student model was then trained using soft targets obtained from the teacher models along with ground truth labels. Experimental results demonstrate that the student model trained with the proposed MTKD achieved a 45.98% reduction in root mean square error (RMSE) and a 15.72% improvement in coefficient of determination (R2) compared to single-teacher KD (STKD). This study successfully extends KD research beyond traditional computer vision and image processing domains, demonstrating practical applicability in battery data-driven applications.

虽然基于深度学习的锂离子电池健康状态(SOH)估计方法已经得到积极研究,但由于其高复杂性和大量参数,大多数模型在设备上的应用面临部署限制。虽然以前的研究已经引入了知识蒸馏(KD)来进行模型压缩,但由于知识多样性不足,单教师架构的性能提高有限。为了解决这一问题,本研究提出了一个多教师知识蒸馏(MTKD)框架,以同时实现高效的SOH估计和模型压缩。从原始充电数据中,从时间信息、统计特征、等效电路模型(ECM)参数和增量计算等多个角度获得18个健康指标。通过Pearson相关分析和最大信息系数(MIC)选择关键特征,并将其作为深度学习模型的输入。随后,基于深度神经网络(DNN)、长短期记忆(LSTM)和一维卷积神经网络(1D CNN)架构的大规模教师模型进行了训练,以捕获各种退化特征,包括非线性关系、时间依赖性和局部模式。然后使用从教师模型中获得的软目标以及地面真值标签来训练轻量级学生模型。实验结果表明,与单一教师KD (STKD)相比,使用所提出的MTKD训练的学生模型的均方根误差(RMSE)降低了45.98%,决定系数(R2)提高了15.72%。这项研究成功地将KD研究扩展到传统的计算机视觉和图像处理领域之外,展示了在电池数据驱动应用中的实际适用性。
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引用次数: 0
Integrating Copper Slag Into Thermally Active Building Foundations: A Pathway to Sustainable Underground Energy Storage Systems 将铜渣集成到热活性建筑地基中:通往可持续地下储能系统的途径
IF 4.3 3区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-01-11 DOI: 10.1155/er/5370108
Michael Enemuo, Arash Dahi Taleghani, Ngozi Enemuo, Olumide Ogunmodimu

Underground thermal energy storage (UTES) integrated with building foundations is an emerging pathway to decarbonize space conditioning by shifting low-carbon heat across seasons. This review evaluates copper slag, a high-density, thermally stable byproduct of smelting, as a dual-function medium for thermally active foundations. We synthesize evidence on physicochemical, thermal, mechanical, and environmental performance, emphasizing properties most relevant to foundation-integrated sensible heat storage. Reported specific heat capacities of approximately 0.8–1.5 kJ/kg K combined with densities >3000 kg/m3 yield volumetric energy storage that can exceed typical aquifer-based systems, while cycling studies indicate stable round-trip efficiencies (≈80% over ≥100 cycles) and structural tests show that partial slag substitution in concrete (≈50%) can satisfy strength requirements. A comparative life-cycle perspective suggests that meaningful benefits can be achieved: global warming potential (GWP) reductions of 60%–74% relative to natural-gas baseline systems and 15%–20% embodied-energy savings compared to virgin aggregates, contingent upon design and electricity mix. We also identify the principal constraints to deployment, namely, heavy-metal leaching, thermo-mechanical compatibility under cyclic loads, and the absence of explicit code pathways for foundation-integrated storage, and outline mitigation strategies that span pretreatment, mix design, and containment/barrier engineering. Valorizing an industrial residue in building foundations, copper slag UTES links circular-economy objectives with practical, scalable thermal storage. Targeted research on durability, environmental safety, and standards development is now pivotal for translating this to practice.

地下热能储存(UTES)与建筑基础相结合,是一种通过跨季节转移低碳热量来脱碳空间调节的新兴途径。本文评价了铜渣作为一种高密度、热稳定的冶炼副产物,作为热活性地基的双重功能介质。我们综合了物理化学、热、机械和环境性能方面的证据,强调了与基础集成感热储存最相关的特性。报告的比热容约为0.8-1.5 kJ/kg K,结合密度>;3000 kg/m3产生的体积蓄能可以超过典型的含水层系统,而循环研究表明稳定的循环效率(≥100次循环≈80%)和结构试验表明部分炉渣替代混凝土(≈50%)可以满足强度要求。从生命周期比较的角度来看,可以实现有意义的效益:与天然气基准系统相比,全球变暖潜能值(GWP)降低60%-74%,与原始集料相比,具体节能15%-20%,具体取决于设计和电力组合。我们还确定了部署的主要制约因素,即重金属浸出,循环载荷下的热机械相容性,以及缺乏明确的基础集成存储代码路径,并概述了跨越预处理,混合设计和遏制/屏障工程的缓解策略。利用建筑地基中的工业残留物,铜渣UTES将循环经济目标与实用的、可扩展的储热联系起来。对耐久性、环境安全和标准制定的针对性研究现在是将其转化为实践的关键。
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引用次数: 0
Data-Driven Machine Learning Model for Battery Life Prediction Across Electrode Materials 跨电极材料的电池寿命预测数据驱动的机器学习模型
IF 4.3 3区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-01-09 DOI: 10.1155/er/8083561
Gaheun Shin, Joonhee Kang

Accurately predicting the remaining lifespan of lithium-ion batteries (LIBs) is crucial for manufacturing processes and safe, reliable usage. Battery lifespan prediction continues to face major challenges due to varying degradation processes, fluctuating operating conditions, and differences in electrode materials. Here, we combine commercial battery data charged and discharged under different electrodes and temperature conditions to build a data-driven machine learning model for cycle life prediction. The datasets include three types of commercial cathodes: LiFePO4 (LFP), LiNi0.86Co0.11Al0.03O2 (NCA), and LiNi0.83Co0.11Mn0.07O2 (NCM), which were cycled under various conditions and temperatures. The charging and discharging dataset under a single cathode material, trained using the Elastic Net model, shows that the root mean square error (RMSE) reaches over 1528 cycles under different electrodes. Furthermore, our findings reveal that temperature plays a critical role in predictive accuracy, emphasizing the importance of incorporating cycling conditions into prediction models. With both cathode diversity and temperature effects considered during model training, all RMSE values dropped below 200 cycles. Notably, the mean absolute percentage error (MAPE) for NCA decreased from 64% to 27%. These outcomes highlight a promising approach for developing robust machine learning models capable of accurate battery performance prediction across varied conditions, contributing to safer and more reliable battery technology.

准确预测锂离子电池(lib)的剩余寿命对于制造过程和安全可靠的使用至关重要。由于不同的降解过程、波动的操作条件和电极材料的差异,电池寿命预测仍然面临着重大挑战。在这里,我们结合商业电池在不同电极和温度条件下的充放电数据,构建了一个数据驱动的机器学习模型,用于循环寿命预测。数据集包括三种商业阴极:LiFePO4 (LFP), lini0.86 co0.11 al0.030 o2 (NCA)和lini0.83 co0.11 mn0.070 o2 (NCM),它们在不同的条件和温度下循环。使用Elastic Net模型训练的单一阴极材料充放电数据表明,在不同电极下,均方根误差(RMSE)达到1528个循环以上。此外,我们的研究结果表明,温度在预测精度中起着关键作用,强调了将循环条件纳入预测模型的重要性。在模型训练过程中考虑阴极多样性和温度效应,所有RMSE值都降至200次循环以下。值得注意的是,NCA的平均绝对百分比误差(MAPE)从64%下降到27%。这些结果突出了一种有前途的方法,即开发强大的机器学习模型,能够在各种条件下准确预测电池性能,从而有助于实现更安全、更可靠的电池技术。
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引用次数: 0
Simulation-Based Evaluation of Solar-Wind Hybrid Systems for Clean Hydrogen Production: Insights From Hot-Humid and Cold-Dry Regions 基于模拟的太阳风混合系统用于清洁制氢的评估:来自湿热和干冷地区的见解
IF 4.3 3区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-01-09 DOI: 10.1155/er/1249017
Ali Rahimi, Amin Kardgar

In the global pursuit of clean and sustainable energy, hydrogen production from renewable sources has emerged as a promising solution. This study investigates a green hydrogen production system based on a hybrid renewable energy configuration, comprising photovoltaic panels, wind turbines, and a PEM electrolyzer. The system was simulated using Homer Pro software, based on real climatic data for two cities in Iran, Mashhad and Bandar Abbas. Three different configurations of the renewable system were evaluated to determine the optimal model. The novelty of this research lies in providing a comprehensive analytical framework for the simultaneous techno-economic and environmental assessment of green hydrogen production at a daily refueling scale of 24 vehicles. The results indicate that both cities possess significant potential for hydrogen production, while the performance in Bandar Abbas is superior, with a levelized cost of hydrogen (LCOH) of $7.14/kg and a levelized cost of electricity (LCOE) of $0.1424/kWh. Moreover, this system results in an approximate reduction of 9180 tons of CO2 over the project lifetime. The findings demonstrate that hybrid renewable systems can play a significant role in reducing greenhouse gas emissions and dependence on fossil fuels in the transportation sector.

在全球追求清洁和可持续能源的过程中,利用可再生能源生产氢气已成为一种有希望的解决方案。本研究研究了一种基于混合可再生能源配置的绿色制氢系统,包括光伏板、风力涡轮机和PEM电解槽。该系统是用Homer Pro软件模拟的,基于伊朗两座城市马什哈德和阿巴斯港的真实气候数据。对可再生能源系统的三种不同配置进行了评估,以确定最优模型。本研究的新颖之处在于提供了一个综合的分析框架,可以同时对24辆汽车每日加氢规模下的绿色制氢进行技术经济和环境评估。结果表明,这两个城市都具有显著的氢气生产潜力,而阿巴斯港的表现更为优异,氢的平准化成本(LCOH)为7.14美元/kg,平准化电力成本(LCOE)为0.1424美元/kWh。此外,该系统在整个项目生命周期内减少了大约9180吨的二氧化碳排放。研究结果表明,混合可再生能源系统在减少温室气体排放和运输部门对化石燃料的依赖方面可以发挥重要作用。
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引用次数: 0
Supply–Demand Collaborative Optimization for a Hydrogen-Driven Park’s Zero-Carbon Integrated Energy System 氢驱动园区零碳综合能源系统的供需协同优化
IF 4.3 3区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-01-09 DOI: 10.1155/er/1944201
Kun Liu, Feng Gao, Zhanbo Xu, Jiang Wu

Hydrogen-driven zero-carbon energy system is one of the effective paths to realize the construction of zero-carbon parks. However, the optimal scheduling of hydrogen-driven integrated energy system (IES) faces significant challenges, including the intermittency of renewable energy, the dynamic characteristics of hydrogen production and storage, and the complex interactions among multiple energy carriers. In this paper, we construct a hydrogen-driven park’s zero-carbon IES in which wind power, photovoltaic power, and hydrogen are considered as energy sources. To achieve the goals of economic and zero carbon, a supply–demand collaborative two-stage robust optimization model is constructed in which heterogeneous energy storage, demand response, and uncertainties are considered. The C&CG algorithm is presented to solve the supply–demand collaborative robust optimization model. The results show that the integration of multienergy storage systems can reduce energy cost by 78.95% and the collaboration between energy supply and demand can reduce energy cost by 47.07%. Moreover, multiple energy storage methods can significantly increase the flexibility to realize zero carbon emission.

氢驱动的零碳能源体系是实现零碳园区建设的有效途径之一。然而,氢驱动综合能源系统的优化调度面临着可再生能源的间歇性、制氢和储氢的动态特性以及多种能源载体之间复杂的相互作用等重大挑战。本文以风力发电、光伏发电、氢能发电为能源,构建氢驱动园区的零碳IES。为实现经济和零碳目标,构建了考虑异质储能、需求响应和不确定性的供需协同两阶段稳健优化模型。提出了求解供需协同鲁棒优化模型的C&;CG算法。结果表明,多储能系统集成可降低78.95%的能源成本,能源供需协同可降低47.07%的能源成本。此外,多种储能方式可以显著增加实现零碳排放的灵活性。
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引用次数: 0
Technoeconomic Assessment of Integrated Wind-Powered Electrolysis Systems With Compressed Hydrogen Storage for Grid Balancing and Transportation Fuel Applications 用于电网平衡和运输燃料应用的集成压缩储氢风能电解系统的技术经济评估
IF 4.3 3区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-01-08 DOI: 10.1155/er/5845186
Mohammad Rashed M. Altimania, Otabek Djurabaev, Zukhra Atamuratova, Ahmed Mohsin Alsayah, Natei Ermias Benti

Wind power’s intermittent nature presents challenges for grid integration, while hydrogen production via electrolysis offers potential solutions for both energy storage and clean transportation fuel. This study conducted a comprehensive technoeconomic assessment of integrated wind-powered electrolysis systems with compressed hydrogen storage to determine optimal configurations and economic viability. Five system configurations were modeled, combining direct wind-to-electrolysis coupling and grid-connected operation with varying storage capacities. Technical performance was simulated using actual wind data from three geographic locations, while economic analysis employed discounted cash flow methodology, examining multiple revenue streams. Direct-coupled systems achieved 62.4% average efficiency from wind to hydrogen, while grid-connected systems reached 68.7%. The hybrid configuration demonstrated superior economic performance, achieving levelized hydrogen costs as low as $3.39/kg in favorable locations. Grid balancing services reduced production costs by 13.8% for hybrid systems. Carbon abatement costs ranged from $46.3 to 142.7/ton CO2eq without incentives, decreasing to $5.8–58.2/ton with enhanced policy support. The results indicate that wind-powered electrolysis systems can achieve economic viability in specific markets when implementing revenue stacking strategies. Geographic location significantly impacts performance, with the wind capacity factor being more influential than peak wind speeds. Policy incentives remain critical for near-term deployment, though projected cost reductions suggest competitive hydrogen production without subsidies is achievable by 2030.

风能的间歇性给电网整合带来了挑战,而通过电解制氢为能源储存和清洁运输燃料提供了潜在的解决方案。本研究对集成了压缩储氢的风力电解系统进行了全面的技术经济评估,以确定最佳配置和经济可行性。模拟了五种系统配置,结合了直接的风电解耦合和不同存储容量的并网运行。技术性能使用三个地理位置的实际风力数据进行模拟,而经济分析采用贴现现金流方法,检查多种收入流。直接耦合系统从风能到氢气的平均效率为62.4%,而并网系统的平均效率为68.7%。混合动力配置显示出卓越的经济性能,在有利地区实现了低至3.39美元/公斤的氢成本。电网平衡服务使混合系统的生产成本降低了13.8%。在没有激励措施的情况下,碳减排成本为每吨二氧化碳当量46.3至142.7美元,在政策支持力度加大的情况下,碳减排成本降至每吨5.8至58.2美元。结果表明,当实施收益叠加策略时,风电电解系统可以在特定市场实现经济可行性。地理位置对性能有显著影响,风量因子的影响大于峰值风速。政策激励仍然是短期部署的关键,尽管预计成本降低表明,到2030年,在没有补贴的情况下,有竞争力的氢气生产是可以实现的。
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引用次数: 0
Impact of Vehicle to Home on System Demand Profiles and Available Flexibility 车辆到家对系统需求概况和可用灵活性的影响
IF 4.3 3区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-01-08 DOI: 10.1155/er/5529610
Shuo Zhang, Sean Byrne, Divyanshu Sood, James O’Donnell, Terence O’Donnell

Vehicle to home (V2H) uses bidirectional charging to transfer the energy stored in electric vehicle (EV) batteries for household electricity usage. The usage of energy from EV batteries can lower energy bills by tapping the EV battery during high-cost periods and recharging during low-cost periods. In this work, a V2H optimization model is used to minimize home energy costs considering household electrical and heating demand, EV usage, and generation from rooftop solar under different electricity tariff structures, namely a static three-tier (day/night/peak) and the dynamic tariff structures. The work uses the optimization model to generate 100 representative residential demand profiles assuming V2H usage, which are then used to obtain total aggregate system residential demand assuming widespread use of V2H. The impact of widespread use of V2H on system-level demand profiles under different tariff structures is thus investigated for a case study using data for Ireland. It is shown that the adoption of V2H can give rise to new peaks in residential demand by aligning all charging with hours when electricity costs are low. To mitigate these peaks and flatten the load, nighttime charging constraints can be introduced. Charging constraints that reduce the charging power to 30% of maximum and restrict the minimum EV battery state of charge (SOC) to 50% are shown to be effective in reducing the peak loads by 50%. The impact of adoption of V2H on the availability of up and down flexibility from EV charging is also investigated. It is shown that the use of V2H restricts the available flexibility with down flexibility in particular being largely restricted to nighttime hours. However, the introduction of the load flattening charging constraints results in a better distribution of flexibility over nighttime hours.

车到户(V2H)使用双向充电将储存在电动汽车(EV)电池中的能量传输给家庭用电。利用电动汽车电池的能量,可以在高成本时期利用电动汽车电池,在低成本时期充电,从而降低能源费用。本文采用了一个V2H优化模型,在不同的电价结构下,即静态三层(日/夜/高峰)和动态电价结构下,考虑家庭用电和供暖需求、电动汽车使用量和屋顶太阳能发电,以最大限度地降低家庭能源成本。该工作使用优化模型生成100个具有代表性的住宅需求概况,假设V2H的使用,然后用于获得假设广泛使用V2H的总总系统住宅需求。因此,使用爱尔兰的数据进行案例研究,调查了在不同关税结构下广泛使用V2H对系统级需求概况的影响。研究表明,通过将所有充电时间与电力成本较低的时间相一致,采用V2H可以引起住宅需求的新高峰。为了减轻这些峰值并使负载变平,可以引入夜间充电限制。将充电功率降低到最大功率的30%,并将电动汽车电池的最低充电状态(SOC)限制到50%的充电约束,可以有效地将峰值负荷降低50%。采用V2H对电动汽车充电的上下灵活性的影响也进行了研究。研究表明,V2H的使用限制了可用的灵活性,特别是在夜间的灵活性很大程度上受到限制。然而,负载平坦化充电限制的引入使夜间的灵活性分布更好。
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引用次数: 0
CVD-Engineered Ni and FeNi Catalysts on Hexagonal Boron Nitride for Efficient CO2-Methane Co-Conversion to Syngas: High-Performance Alternatives to Traditional Alumina-Supported Catalysts cvd工程镍和FeNi催化剂用于六方氮化硼的co2 -甲烷高效共转化合成气:传统氧化铝负载催化剂的高性能替代品
IF 4.3 3区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-01-08 DOI: 10.1155/er/5520777
Benyamin M. Garmejani, Samira Mehravar, Shohreh Fatemi

This study presents a sustainable approach for mitigating greenhouse gas emissions by converting methane (CH4) and carbon dioxide (CO2) into syngas using nickel-based catalysts supported on hexagonal boron nitride (hBN), synthesized through chemical vapor deposition (CVD). Characterization of the 4 wt% Ni/hBN catalyst, conducted using high-resolution techniques such as X-ray photoelectron spectroscopy (XPS) and transmission electron microscopy (TEM), revealed quasi-spherical nickel particles with an average diameter of 37 nm and a calculated dispersion of 10.5%. At 700°C, this catalyst achieved conversions of 78% for CH4 and 80% for CO2, outperforming the 12 wt% Ni/γ-Al2O3 (FCR-4) catalyst by about 20%. It also displayed excellent coke resistance, with a carbon deposition rate of 2.5 mg C/(g_cat h), half that of FCR-4, and a noteworthy 30% reduction in activation energy, from 21.4 to 15.0 kJ/mol. The hydrogen yield reached 74%, a 37% increase over FCR-4, with an H2/CO ratio of 0.96, indicating its suitability for Fischer–Tropsch processes. Furthermore, a Fe-Ni/hBN catalyst was developed through selective deposition of 1% Fe onto the Ni/hBN support by establishing a temperature window of 140–200°C, determined by gas chromatography (GC) and confirmed by high-resolution transmission electron microscopy (HRTEM). This catalyst variant demonstrated minimal coke formation at 600°C, achieving CH4 and CO2 conversions of 44% and 49%, respectively, comparable to FCR-4, while maintaining superior stability against alternative catalysts. Overall, the low acidity and high thermal stability of hBN, along with CVD control over particle size and dispersion, highlight its potential for efficient dry reforming of methane (DRM) under optimized conditions.

本研究提出了一种可持续的减少温室气体排放的方法,即利用化学气相沉积(CVD)合成的六方氮化硼(hBN)负载镍基催化剂将甲烷(CH4)和二氧化碳(CO2)转化为合成气。利用高分辨率技术(如x射线光电子能谱(XPS)和透射电子显微镜(TEM))对4 wt% Ni/hBN催化剂进行表征,发现准球形镍颗粒平均直径为37 nm,计算分散度为10.5%。在700°C时,该催化剂的CH4转化率为78%,CO2转化率为80%,比12 wt% Ni/γ-Al2O3 (FCR-4)催化剂高出约20%。它还表现出优异的抗焦性能,积碳速率为2.5 mg C/(g_cat h),是FCR-4的一半,活化能从21.4 kJ/mol降低到15.0 kJ/mol,显著降低了30%。产氢率达到74%,比FCR-4提高了37%,H2/CO比为0.96,表明其适合费托工艺。此外,通过气相色谱(GC)测定和高分辨率透射电镜(HRTEM)验证,建立了140-200°C的温度窗,将1%的Fe选择性沉积在Ni/hBN载体上,制备了Fe-Ni/hBN催化剂。该催化剂变体在600°C下表现出最小的焦炭形成,CH4和CO2的转化率分别达到44%和49%,与FCR-4相当,同时对替代催化剂保持优异的稳定性。总体而言,hBN的低酸度和高热稳定性,以及CVD对粒径和分散性的控制,突出了其在优化条件下高效干重整甲烷(DRM)的潜力。
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引用次数: 0
Comparative Analysis to Determine the State of Charge of a Lithium-Ion Cell 确定锂离子电池充电状态的比较分析
IF 4.3 3区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-01-07 DOI: 10.1155/er/6116851
Hafsa Khayrane, Spyridon Giazitzis, Mohamed Louzazni, Emanuele Ogliari, Marco Mussetta

Accurate state of charge (SOC) estimation remains a challenge in lithium-ion battery management systems (BMSs) due to the cells’ complex, nonlinear internal dynamics, and their high sensitivity to operating conditions. While most existing data-driven studies rely on a core input configuration of voltage (V), current (I), and temperature (T), these models often struggle with temperature-induced variations, which typically require complex architectures. This study addresses the challenge of thermal dependency through an innovative feature engineering approach designed to maintain a low computational cost suitable for real-time applications. Recognizing that internal resistance (R) inherently reflects both the cell’s temperature and aging state, we propose replacing T with R as the third input feature, resulting in an [I, V, R] configuration. We systematically compared the performance of four estimation models: DE-long short-term memory (LSTM), DE-gated recurrent unit (GRU), LSTM-unscented Kalman filter (UKF), and GRU-UKF, using both the traditional [I, V, T] and the proposed [I, V, R] input sets. The results validate the superiority of the R-based configuration, which led to significant reductions in mean absolute error (MAE) by 46.02%, 43.31%, 14.02%, and 35.85%, and in root mean square error (RMSE) by 48.95%, 39.87%, 21.90%, and 23.95% for the DE-LSTM, DE-GRU, LSTM-UKF, and GRU-UKF models, respectively. This confirms that substituting T with R captures nonlinear temperature and aging effects more effectively while maintaining low computational complexity.

由于锂离子电池具有复杂的非线性内部动力学特性以及对运行条件的高度敏感性,准确的荷电状态(SOC)估计仍然是锂离子电池管理系统(bms)面临的一个挑战。虽然大多数现有的数据驱动研究依赖于电压(V)、电流(I)和温度(T)的核心输入配置,但这些模型经常与温度引起的变化作斗争,这通常需要复杂的架构。本研究通过一种创新的特征工程方法解决了热依赖性的挑战,该方法旨在保持适合实时应用的低计算成本。认识到内阻(R)本质上反映了电池的温度和老化状态,我们建议用R代替T作为第三个输入特征,从而得到[I, V, R]配置。我们系统地比较了四种估计模型的性能:de -长短期记忆(LSTM), de -门控循环单元(GRU), LSTM-无气味卡尔曼滤波器(UKF)和GRU-UKF,使用传统的[I, V, T]和提出的[I, V, R]输入集。结果验证了基于r的配置的优越性,DE-LSTM、DE-GRU、LSTM-UKF和GRU-UKF模型的平均绝对误差(MAE)分别降低了46.02%、43.31%、14.02%和35.85%,均方根误差(RMSE)分别降低了48.95%、39.87%、21.90%和23.95%。这证实用R代替T可以更有效地捕获非线性温度和老化效应,同时保持较低的计算复杂度。
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引用次数: 0
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International Journal of Energy Research
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