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Artificial Latexes of Butyl Rubber and Styrene Diene Thermoplastic Elastomer, Stabilised with a Mixture of Silicone and Cationic Surface-active Substances 丁基橡胶和苯乙烯二烯热塑性弹性体合成的人造乳胶,用有机硅和阳离子表面活性物质的混合物稳定
Pub Date : 2017-10-01 DOI: 10.1177/0307174X1704401009
O. I. Yamshchikova, I. Gritskova, A. N. Stuzhuk, D. K. Gaikov, E. A. Grinfel’d, D. I. Shragin, A. Bondarev
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引用次数: 0
The Heterophase Polymerisation of Styrene in the Presence of Zinc Oxide Nanoparticles 氧化锌纳米颗粒存在下苯乙烯的异相聚合
Pub Date : 2017-10-01 DOI: 10.1177/0307174X1704401003
N. S. Serkhacheva, N. Prokopov, A. Gerval’d, N. Lobanov, I. Gritskova
Heterophase polymerisation of styrene was carried out, and nanocomposite polystyrene microspheres with a controllable content of ZnO nanoparticles were synthesised. The colloid chemical properties ...
对苯乙烯进行了异相聚合,合成了ZnO含量可控的纳米复合聚苯乙烯微球。胶体的化学性质……
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引用次数: 0
Features of the Rotational Moulding of Thermoplastics 热塑性塑料滚塑的特点
Pub Date : 2017-10-01 DOI: 10.1177/0307174X1704401008
M. S. Igumenov, N. Lavrov
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引用次数: 3
Optimising the Production of Combined Filter/Sorption Composite Materials 过滤/吸附复合材料的优化生产
Pub Date : 2017-09-01 DOI: 10.1177/0307174X1704400910
A. Genis, A. Kuznetsov, G. M. Il'yutkina, L. Polyakov
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引用次数: 0
Investigating the Phase States and Transitions in Polyazomethine Ethers Based on Aromatic Dialdehydes and 4,4′-diamino Triphenylmethane 芳香族二醛和4,4′-二氨基三苯甲烷聚亚甲基醚的相态和相变研究
Pub Date : 2017-09-01 DOI: 10.1177/0307174X1704400902
T. Borukaev, A. Orlov, R. Oshroeva, R. Shetov, N. I. Samoĭlik
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引用次数: 0
The Effect of Modifying Polybutylene Terephthalate on its Processability and Mechanical Properties 改性聚对苯二甲酸丁二酯对其加工性能和力学性能的影响
Pub Date : 2017-09-01 DOI: 10.1177/0307174X1704400904
G. N. Petrova, É. Beider
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引用次数: 0
The Gas Permeability of Polyolefin Blends Containing a Glass Flake Filler 含玻璃片填料的聚烯烃共混物的透气性
Pub Date : 2017-09-01 DOI: 10.1177/0307174X1704400909
A. Ermilova, O. Ushakova, M. Petrova, E. Kalugina
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引用次数: 0
The Use of Reactions of Metathesis Polymerisation of Cyclic Olefins for the Production of a Dicyclopentadiene Polymer 利用环烯烃的复分解聚合反应生产双环戊二烯聚合物
Pub Date : 2017-09-01 DOI: 10.1177/0307174X1704400906
I. G. Sharifullin, I. Akhmetov, K. M. Kubanov, O. Sofronova, A. P. Alekseeva
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引用次数: 1
The Development of Fireproofing Compositions Based on Chemical Industry Waste 基于化工废弃物的防火组合物的研制
Pub Date : 2017-09-01 DOI: 10.1177/0307174X1704400907
B. B. Akhrarov, B. Mukhamedgaliev
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引用次数: 0
Investigating the Influence of Different Types of Thermoplastic Elastomer on the Properties of Highly Filled Composites 研究不同类型热塑性弹性体对高填充复合材料性能的影响
Pub Date : 2017-09-01 DOI: 10.1177/0307174x1704400903
K. V. Krasnov, N. M. Chalaya, V. Osipchik, A. Kazanchyan
Thermoplastic elastomers (TPEs) are polymeric materials that combine the physicomechanical properties of vulcanised rubbers during service with processability by technology similar to that used for thermoplastic polymeric materials. The application of materials of this kind makes it possible to retain high elastic properties of the material obtained and to process it like a thermoplastic polymer. TPEs are among the new materials being most actively developed. Research in the field of creating materials with unique properties is constantly being carried out, and formulations are being developed for specific articles that meet the requirements both of those who process the plastics and those who end up using them [1]. TPEs are compatible with many polymeric materials, in particular polypropylene. Blends of polypropylene with TPEs are characterised by improved deformation properties by comparison with the initial polymers, including an increased impact strength at low temperatures. Therefore, in industry, the use of such blends has been widespread, in particular for the production of special-shape extruded items sold by length, for example seals for windows, cable sheathing, etc. [2]. An important property of special-shape extruded items sold by length is low flammability of the TPEbased composites. Among the inorganic combustion inhibitors for polyolefins, wide use has been made of aluminium hydroxide Al(OH)3 and magnesium hydroxide Mg(OH)2, which have active functional groups. The main advantages of these combustion inhibitors is their low cost and the significantly lower level of smoking during the combustion of materials containing them by comparison with materials containing organic fireproofing agents. A shortcoming is their low effectiveness by comparison with halogenand phosphorus-containing compounds, as a result of which, for the production of material that extinguishes in air, it is necessary to introduce somewhere in the order of 60% aluminium hydroxide or 57–60% magnesium hydroxide into the polyolefins, depending on the particle size and the specific surface of the fireproofing agent [3]. The application of these fireproofing agents requires control of the level of physicomechanical properties of the composites. The thermoplastic elastomers most widely used in industry for the production of special-shape items sold by length are styrene thermoplastic elastomers TPE-S (block copolymers of styrene with butadiene or isoprene, ethylene butylene, ethylene propylene, etc.), and also blends based on them, including modified blends [4]. However, a considerable shortcoming of composites containing thermoplastic elastomers based on styrene block copolymers is their flammability. The application Plasticheskie Massy, No. 7-8, 2016, pp. 6–8
热塑性弹性体(TPEs)是一种聚合物材料,它结合了硫化橡胶在使用过程中的物理机械性能和类似于热塑性聚合物材料的可加工性。这类材料的应用使所获得的材料保持高弹性特性并象热塑性聚合物一样加工成为可能。tpe是最积极开发的新材料之一。在创造具有独特性能的材料领域的研究正在不断进行,并且正在开发特定物品的配方,以满足塑料加工者和最终使用者的要求[1]。tpe与许多聚合物材料兼容,特别是聚丙烯。与最初的聚合物相比,聚丙烯与tpe的共混物的特点是变形性能得到改善,包括在低温下的冲击强度增加。因此,在工业中,这种共混物的使用已得到广泛应用,特别是用于生产按长度销售的异形挤压件,例如窗户密封件、电缆护套等[2]。按长度销售的异形挤压件的一个重要特性是tpe基复合材料的低可燃性。在无机聚烯烃燃烧抑制剂中,氢氧化铝Al(OH)3和氢氧化镁Mg(OH)2具有活性官能团,得到了广泛的应用。这些燃烧抑制剂的主要优点是成本低,与含有有机防火剂的材料相比,含有它们的材料在燃烧时的冒烟水平明显较低。与卤素和含磷化合物相比,它们的缺点是效率较低,因此,为了生产在空气中熄灭的材料,有必要在聚烯烃中引入60%的氢氧化铝或57-60%的氢氧化镁,这取决于阻燃剂的粒径和比表面[3]。这些防火剂的应用要求控制复合材料的物理力学性能水平。工业上最广泛用于生产按长度出售的异形物品的热塑性弹性体是苯乙烯热塑性弹性体TPE-S(苯乙烯与丁二烯或异戊二烯、乙烯丁烯、乙烯丙烯等的嵌段共聚物),以及基于它们的共混物,包括改性共混物[4]。然而,含有基于苯乙烯嵌段共聚物的热塑性弹性体的复合材料的一个相当大的缺点是它们的可燃性。《塑料杂志》2016年第7-8期,第6-8页
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引用次数: 0
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International polymer science and technology
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