Pub Date : 2017-11-01DOI: 10.1177/0307174X1704401106
V. Yulovskaya, T. Monakhova, V. Petrova, S. Karpova
We studied the influence of the composition of rubber mixes based on nitrile butadiene rubbers of different polarity (BNKS-18, BNKS-28, BNKS-40) on the physicomechanical and relaxation properties of vulcanisates produced using sulphur and peroxide vulcanising systems under conditions of oxidation in an oxygen atmosphere and heat ageing. By electron spin resonance (ESR) spectroscopy it was established that the values of the correlation time before and after the oxidation of vulcanisates based on BNK-28 nitrile butadiene rubber hardly differ from one another, which is indirect evidence of the absence of degradation. The introduction of a vulcanising system and the process of vulcanisation itself activate the oxidation of specimens, increasing the oxidation rate and the amount of bound oxygen. The replacement of the sulphur-containing vulcanising system with a peroxide system increases the induction period of oxidation by a factor of 6–7. The introduction of nanosized titanium dioxide (NTD) (Degussa) into the rubber mix leads to a certain reduction in tensile strength and elongation at break. The addition of 1% NTD into the pure rubber hardly affects the kinetics of oxidation. The introduction of 3% NTD leads to a reduction in the correlation time after oxidation (from 19 × 10−10 to 16 × 10−10 s).
{"title":"The Influence of the Rubber Mix Composition on the Ageing Resistance of Vulcanisates Based on Nitrile Butadiene Rubbers of Different Polarity","authors":"V. Yulovskaya, T. Monakhova, V. Petrova, S. Karpova","doi":"10.1177/0307174X1704401106","DOIUrl":"https://doi.org/10.1177/0307174X1704401106","url":null,"abstract":"We studied the influence of the composition of rubber mixes based on nitrile butadiene rubbers of different polarity (BNKS-18, BNKS-28, BNKS-40) on the physicomechanical and relaxation properties of vulcanisates produced using sulphur and peroxide vulcanising systems under conditions of oxidation in an oxygen atmosphere and heat ageing. By electron spin resonance (ESR) spectroscopy it was established that the values of the correlation time before and after the oxidation of vulcanisates based on BNK-28 nitrile butadiene rubber hardly differ from one another, which is indirect evidence of the absence of degradation. The introduction of a vulcanising system and the process of vulcanisation itself activate the oxidation of specimens, increasing the oxidation rate and the amount of bound oxygen. The replacement of the sulphur-containing vulcanising system with a peroxide system increases the induction period of oxidation by a factor of 6–7. The introduction of nanosized titanium dioxide (NTD) (Degussa) into the rubber mix leads to a certain reduction in tensile strength and elongation at break. The addition of 1% NTD into the pure rubber hardly affects the kinetics of oxidation. The introduction of 3% NTD leads to a reduction in the correlation time after oxidation (from 19 × 10−10 to 16 × 10−10 s).","PeriodicalId":14443,"journal":{"name":"International polymer science and technology","volume":"16 1","pages":"25-28"},"PeriodicalIF":0.0,"publicationDate":"2017-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87788469","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2017-11-01DOI: 10.1177/0307174X1704401103
A. P. Voznyakovskiĭ, A. Smirnov, B. Fedorov, A. V. Esina, N. P. Boreiko
{"title":"The Effect of Nanocarbons on the Structural and Thermophysical Characteristics of a Polymer Matrix","authors":"A. P. Voznyakovskiĭ, A. Smirnov, B. Fedorov, A. V. Esina, N. P. Boreiko","doi":"10.1177/0307174X1704401103","DOIUrl":"https://doi.org/10.1177/0307174X1704401103","url":null,"abstract":"","PeriodicalId":14443,"journal":{"name":"International polymer science and technology","volume":"28 1","pages":"9-14"},"PeriodicalIF":0.0,"publicationDate":"2017-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74525290","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2017-11-01DOI: 10.1177/0307174X1704401108
A. F. Puchkov, N. A. Tret’yakova, S. Khodakova, I. I. Abol’skaya, S. Bobrov
{"title":"The Effect of Molecular Complexes of Lactam-Containing and Proton-Donor Substances on the Adhesion Properties of Adhesive Composites","authors":"A. F. Puchkov, N. A. Tret’yakova, S. Khodakova, I. I. Abol’skaya, S. Bobrov","doi":"10.1177/0307174X1704401108","DOIUrl":"https://doi.org/10.1177/0307174X1704401108","url":null,"abstract":"","PeriodicalId":14443,"journal":{"name":"International polymer science and technology","volume":"54 1","pages":"37-40"},"PeriodicalIF":0.0,"publicationDate":"2017-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"72809993","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2017-11-01DOI: 10.1177/0307174x1704401101
Heinz C. Rost
{"title":"Biofuel Compatibility of Sealing Materials at Low Temperatures","authors":"Heinz C. Rost","doi":"10.1177/0307174x1704401101","DOIUrl":"https://doi.org/10.1177/0307174x1704401101","url":null,"abstract":"","PeriodicalId":14443,"journal":{"name":"International polymer science and technology","volume":"2021 1","pages":"1-4"},"PeriodicalIF":0.0,"publicationDate":"2017-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74300182","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2017-10-01DOI: 10.1177/0307174X1704401005
T. Matseevich, O. V. Kovriga, A. Askadskii
{"title":"The Influence of the Chemical Composition and Concentration of Components of a Polymer/Nanoparticle Mixture on their Flow Temperature","authors":"T. Matseevich, O. V. Kovriga, A. Askadskii","doi":"10.1177/0307174X1704401005","DOIUrl":"https://doi.org/10.1177/0307174X1704401005","url":null,"abstract":"","PeriodicalId":14443,"journal":{"name":"International polymer science and technology","volume":"51 1","pages":"23-26"},"PeriodicalIF":0.0,"publicationDate":"2017-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"76380154","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2017-10-01DOI: 10.1177/0307174X1704401001
Y. Kazakov, A. M. Volkov, I. G. Ryzhikova, N. Bauman, S. Volfson
{"title":"Binary Blends of Ethylene-α-olefin Elastomers for Improving the Balance between the Impact Strength and Individual Deformation and Strength Properties of Polypropylene Composites Produced by Reactive Extrusion","authors":"Y. Kazakov, A. M. Volkov, I. G. Ryzhikova, N. Bauman, S. Volfson","doi":"10.1177/0307174X1704401001","DOIUrl":"https://doi.org/10.1177/0307174X1704401001","url":null,"abstract":"","PeriodicalId":14443,"journal":{"name":"International polymer science and technology","volume":"8 1","pages":"1-6"},"PeriodicalIF":0.0,"publicationDate":"2017-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83485119","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2017-10-01DOI: 10.1177/0307174X1704401007
V. Korchagin, A. V. Protasov, N. Erofeeva
{"title":"The Rheological Behaviour of Prooxidants Based on Iron Stearate","authors":"V. Korchagin, A. V. Protasov, N. Erofeeva","doi":"10.1177/0307174X1704401007","DOIUrl":"https://doi.org/10.1177/0307174X1704401007","url":null,"abstract":"","PeriodicalId":14443,"journal":{"name":"International polymer science and technology","volume":"39 1","pages":"33-38"},"PeriodicalIF":0.0,"publicationDate":"2017-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"72934598","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2017-10-01DOI: 10.1177/0307174X1704401004
B. Izmailov, L. G. Komarova, E. Rodlovskaya, G. Markova, V. Vasnev, T. Rudakova, A. A. Amelichev, N. Novikova
{"title":"Heterorganic Fire-resistant Coatings for Artificial Fibres","authors":"B. Izmailov, L. G. Komarova, E. Rodlovskaya, G. Markova, V. Vasnev, T. Rudakova, A. A. Amelichev, N. Novikova","doi":"10.1177/0307174X1704401004","DOIUrl":"https://doi.org/10.1177/0307174X1704401004","url":null,"abstract":"","PeriodicalId":14443,"journal":{"name":"International polymer science and technology","volume":"32 1","pages":"19-22"},"PeriodicalIF":0.0,"publicationDate":"2017-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90448972","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2017-10-01DOI: 10.1177/0307174X1704401002
D. V. Kramarev, V. Azarov, V. Osipchik, N. M. Chalaya, A. B. Berezina
{"title":"A Study of the Processes of Imidisation and Modification of Polyimide Materials for Multilayer Structures","authors":"D. V. Kramarev, V. Azarov, V. Osipchik, N. M. Chalaya, A. B. Berezina","doi":"10.1177/0307174X1704401002","DOIUrl":"https://doi.org/10.1177/0307174X1704401002","url":null,"abstract":"","PeriodicalId":14443,"journal":{"name":"International polymer science and technology","volume":"106 1","pages":"7-12"},"PeriodicalIF":0.0,"publicationDate":"2017-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"72785804","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2017-10-01DOI: 10.1177/0307174X1704401006
G. A. Lushcheĭkin
{"title":"Modelling the Impact Strength of Polymeric Materials","authors":"G. A. Lushcheĭkin","doi":"10.1177/0307174X1704401006","DOIUrl":"https://doi.org/10.1177/0307174X1704401006","url":null,"abstract":"","PeriodicalId":14443,"journal":{"name":"International polymer science and technology","volume":"26 1","pages":"27-32"},"PeriodicalIF":0.0,"publicationDate":"2017-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90631877","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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