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Effective Removal of Heavy Metal Using Cellulose Nanocomposite Adsorbents: Response Surface Methodology 纤维素纳米复合吸附剂对重金属的有效去除:响应面法
Pub Date : 2022-01-01 DOI: 10.5829/ijee.2022.13.03.06
A. Alipour, S. Zarrinabadi, A. Azimi, M. Mirzaei
Cellulose nanocomposites were synthesized and applied to the removal of Pb(II) from aqueous solution. The synthesized nanocomposite was characterized by FT-IR, XRD, SEM, TEM, and BET analyses. Removal experiments were carried out in laboratory scale and then evaluated by response surface methodology (RSM) with a Central-Composite Design. The effects of solution pH, contact tie, initial Pb(II) concentration, adsorbent dosage and temperature on the removal efficiency were evaluated. Analysis of variance (ANOVA) was employed to find which parameter has a significant effect on the removal efficiency. The best removal efficiency value was found to be at the initial solution pH of 6.5, temperature of 34°C, initial ion concentration of 100 mg/L and the adsorbent dosage of 0.74 g/L. At this condition, the removal efficiency of Pb(II) ions was 92.54%. The adsorption equilibrium data fitted well with Langmuir isotherm model and the adsorption process followed the pseudo-second-order and intra-particle diffusion kinetic model. Thermodynamic analysis suggests that the adsorption process is endothermic, with an increasing entropy and spontaneous in nature. Besides, the nanocomposite was reused in four successive adsorption – desorption cycles, revealing a good regeneration capacity of the adsorbent. The effects of coexist cation ions on the adsorption of Pb(II) under optimal condition was also investigated. All the results demonstrate that nanocomposite is a potential recyclable adsorbent for hazardous metal ions in wastewater system.
合成了纤维素纳米复合材料,并将其应用于水中铅(II)的去除。采用FT-IR、XRD、SEM、TEM和BET等手段对合成的纳米复合材料进行了表征。在实验室进行了去除实验,然后采用响应面法(RSM)进行了中心-复合设计评价。考察了溶液pH、接触度、初始浓度、吸附剂投加量和温度对Pb(II)去除率的影响。采用方差分析(ANOVA)找出哪些参数对去除效率有显著影响。当初始溶液pH为6.5、温度为34℃、初始离子浓度为100 mg/L、吸附剂投加量为0.74 g/L时,去除效果最佳。在此条件下,对Pb(II)离子的去除率为92.54%。吸附平衡数据符合Langmuir等温线模型,吸附过程符合准二级和颗粒内扩散动力学模型。热力学分析表明,吸附过程是吸热的,熵增加,是自发的。此外,纳米复合材料在连续4次吸附-解吸循环中重复使用,表明吸附剂具有良好的再生能力。在最佳条件下,考察了共存阳离子对Pb(II)吸附的影响。结果表明,纳米复合材料是一种有潜力的可循环利用的废水系统中有害金属离子吸附剂。
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引用次数: 1
Preparation and Characterization of Amine-functional SAPO-34 Mixed Matrix Membranes for CO2/CH4 Separation 氨基功能SAPO-34混合基质膜的制备与表征
Pub Date : 2022-01-01 DOI: 10.5829/ijee.2022.13.03.04
Y. Kiamehr, I. Naser, M. Rafizadeh, A. H. Mohammadi
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引用次数: 1
Investigation on Daylight Quality of Central Courtyard’s Adjacent Rooms in Traditional Houses in Hot Dry Region of Iran: A Case Study Yazdanpanah House 伊朗干热地区传统民居中央庭院相邻房间采光质量调查——以Yazdanpanah住宅为例
Pub Date : 2022-01-01 DOI: 10.5829/ijee.2022.13.04.01
N. Tayari, M. Nikpour
Most of the spaces in contemporary houses in Iran cannot achieve enough daylight during daytime. Daylight utilization has a significant impact on decreasing energy consumption in residential buildings. Residents are deprived of natural daylight when there is no attention to the design based on daylight. Iranian traditional architects use practical and straightforward methods in constructing courtyards houses to provide comfort conditions in unique rooms in courtyard houses in terms of daylight quality. In this research, the daylight quality of five separate rooms around the courtyard of Yazdanpanah's house was investigated through an experimental method. Average work plane illuminance and uniformity ratio were calculated in these rooms of the house in Kerman city, located in Iran's hot and dry climate. Findings of this research demonstrated that all rooms surrounding the courtyard of traditional houses have the ability to achieve work plane illuminance of more than acceptable value. Among all rooms around the central courtyard, one room facing the south direction achieves more than 500 Lux work plane illuminance. The amount of uniformity in this room is acceptable with more than 0.5 on most of the days in a year. The findings of this research could be used to design more comfortable rooms in contemporary houses in terms of daylight quality by creating central courtyards. doi: 10.5829/ijee.2022.13.04.01
伊朗当代住宅的大部分空间在白天无法获得足够的日光。日光利用对减少住宅建筑的能源消耗具有重要影响。当不注意基于日光的设计时,居民被剥夺了自然光。伊朗传统建筑师使用实用和直接的方法来建造四合院,在四合院的独特房间中提供舒适的日光质量条件。在这项研究中,通过实验方法调查了Yazdanpanah家庭院周围五个独立房间的日光质量。在伊朗炎热干燥的气候条件下,克尔曼市的这些房间计算了平均工作面照度和均匀度比。本研究结果表明,传统民居庭院周围的所有房间都有能力实现工作平面照度超过可接受值。在中央庭院周围的所有房间中,一个朝南的房间达到了500勒克斯以上的工作平面照度。这个房间的均匀度是可以接受的,一年中大部分时间都在0.5以上。这项研究的结果可以通过创建中央庭院来设计现代住宅中更舒适的房间,从而提高日光质量。doi: 10.5829 / ijee.2022.13.04.01
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引用次数: 2
Sensing Image Regions for Enhancing Accuracy in People Re-identification 提高人物再识别精度的传感图像区域
Pub Date : 2022-01-01 DOI: 10.5829/ijee.2022.13.03.09
H. Hassanpour, Z. Mortezaie, Azeddine Beghdadi
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引用次数: 0
Bubble Dynamics and Nucleate Pool Boiling of Natural Convection 自然对流的气泡动力学和核池沸腾
Pub Date : 2022-01-01 DOI: 10.5829/ijee.2022.13.04.08
S. Bagheri, S. Oloomi, S. A. A. Mirjalily, A. Zare-Shahabadi
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引用次数: 1
Acoustic Design of Buildings Using Mathematical Model Based on Sound Simulation 基于声音仿真的数学模型的建筑声学设计
Pub Date : 2022-01-01 DOI: 10.5829/ijee.2022.13.01.03
H. Esmaeil Yazdi, A. Salehi
sound intensity, and sound frequency and distance from the sound source were inversely related to the sound intensity.
声强、声频、声源距离与声强呈负相关。
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引用次数: 0
An Optimal Model for Designing and Executing Windows in Tabriz Residential Buildings to Reduce Energy Consumption 大不里士住宅楼窗户设计与执行的优化模型以降低能耗
Pub Date : 2022-01-01 DOI: 10.5829/ijee.2022.13.01.04
S. Abdoli Naser, F. Haghparast, M. Singery, H. Sattari Sarbangholi
The simulations were performed again and the results index was examined. Eventually, based on the analysis of outputs, according to fixed area, it is more suitable to replace windows with the height of 1.5 to 1.74 meters instead of windows with the height of 1 or 1.2 meters. A window should be replaced with 2, 3, 4 or 5 windows with the same fixed area. I is desired to superseded triple-glazed glazing with low-emissivity filled with argon gas with clear double-glazed glazing filled with air to reduce energy consumption. The amount of heat losses for the window height of 1 to 1.5m, from one window to five windows and for the clear double-glazed glazing filled with air were 2.04%, 11.11%,. and 45.36%, respectively.
再次进行了模拟,并对模拟结果进行了检验。最终,在对输出进行分析的基础上,根据固定面积,更换高度在1.5米至1.74米的窗户,而不是高度在1米或1.2米的窗户,更为合适。一个窗口应替换为2、3、4或5个相同固定面积的窗口。希望用充满空气的透明双层玻璃取代低发射率充满氩气的三层玻璃,以减少能源消耗。1 ~ 1.5m窗高、1 ~ 5窗高和充气双层透明玻璃的热损失量分别为2.04%、11.11%、11.11%。和45.36%。
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引用次数: 1
A Novel Proposed Improvement on Performance of a Photovoltaic/Water Pumping System: Energy and Environmental Analysis 一种改进光伏/抽水系统性能的新方法:能源与环境分析
Pub Date : 2022-01-01 DOI: 10.5829/ijee.2022.13.02.11
A. H. Shiravi, M. Firoozzadeh
using possible. Photovoltaic is one of the most alternatives. are used to supply electricity for pumping systems to irrigate the farmlands. It has been proved by many scholars that PV cell temperature is a crucial factor in cell’s efficiency. In this study, a novel arrangement of a PV/pumping system has been considered, in order to enhance the pumping performance. To make it feasible, a small part of the pumped water is directed to a box-type passage at the backside of the PV module, and then connect to the water pipe and drain to the farmland. Two various flow rates of 5 and 10 L/min were tested. The results showed two proposed cases have a bit difference in their outputs. Accordingly, the temperature of modified cases did not pass beyond 36°C while, the temperature of the conventional module reaches to 72°C. This temperature reduction leads to about 50% higher electrical efficiency. From the output power point of view, more than 45% increase was observed. Also, an environment evaluation is performed and it was found that the present improvement can reduce emission of 34.57 tons CO 2 , annually.
使用成为可能。光伏发电是一种最可行的替代方案。用来为抽水系统供电,灌溉农田。许多学者已经证明PV电池温度是影响电池效率的关键因素。在本研究中,考虑了一种新型的PV/pumping system的布置,以提高抽水性能。为了使其可行,一小部分抽水被引导到光伏组件背面的箱形通道,然后连接到水管并排入农田。测试了5和10 L/min两种不同的流量。结果表明,所提出的两种情形的输出结果略有不同。因此,修改后的机箱温度不超过36℃,而常规模块的温度达到72℃。温度降低导致电效率提高约50%。从输出功率的角度来看,增加了45%以上。并进行了环境评价,发现改进后每年可减少二氧化碳排放34.57吨。
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引用次数: 2
The Strategy of Energy Democracy and Sustainable Development: Policymakers and Instruments 能源民主与可持续发展战略:政策制定者和工具
Pub Date : 2022-01-01 DOI: 10.5829/ijee.2022.13.02.10
M. Esmaeili Shayan, M. R. Hayati, G. Najafi, S. Esmaeili Shayan
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引用次数: 2
Providing A Model for Predicting and Detecting Destructive Processes to Prevent the Production of Waste and Defective Products: A Data Mining Approach 提供一种预测和检测破坏性过程以防止废品和缺陷产品产生的模型:一种数据挖掘方法
Pub Date : 2021-09-12 DOI: 10.5829/IJEE.2021.12.03.09
N. Safaie, M. Saadatmand, S. A. Nasri
Today, most industries use statistical quality control tools to improve quality and reduce the defective products and waste, but the high volume of data requires the help of a powerful tool to control processes. One of the objectives of the present study is to predict defective products and prevent their production using data mining tools due to the high power in data analysis and its predictive nature, which is less used in the industry. In this study, the statistical population of all parts produced in 2017 by Shabrun Company. The statistical sample is 2400 pieces of radiators that were randomly selected from the production line. In the operational phases of data mining, three decision tree algorithms were used: C&R Tree, Quest Tree and Chaid Tree. Using these algorithms, the most important criteria affecting quality control and rules leading to the quality of parts were determined. Comparative results showed that despite the validity of all three algorithms, the C&R Tree algorithm had the highest accuracy. Adherence to the rules resulting from the implementation of these algorithms has led to the detection and prevention of waste generation, which has increased efficiency and prevented the loss of time and cost in this production unit.
今天,大多数行业使用统计质量控制工具来提高质量,减少有缺陷的产品和浪费,但是大量的数据需要强大的工具来帮助控制过程。本研究的目的之一是利用数据挖掘工具预测不良产品并防止其产生,因为数据挖掘工具具有高功率的数据分析和预测特性,而数据挖掘工具在工业中很少使用。在本研究中,Shabrun公司2017年生产的所有零部件的统计人口。统计样本为从生产线上随机抽取的2400件散热器。在数据挖掘的操作阶段,使用了三种决策树算法:C&R树、任务树和Chaid树。利用这些算法,确定了影响质量控制的最重要准则和导致零件质量的规则。对比结果表明,尽管三种算法都是有效的,但C&R树算法的准确率最高。遵守执行这些算法所产生的规则导致发现和防止产生废物,从而提高了效率,防止了该生产单位的时间和成本损失。
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引用次数: 1
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Iranian Journal of Energy and Environment
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