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Investigating the impact of sample desiccation on Itrax XRF core scanner signal reproducibility 研究样品干燥对 Itrax XRF 核心扫描仪信号再现性的影响
IF 1.5 4区 地球科学 Q2 Earth and Planetary Sciences Pub Date : 2024-02-20 DOI: 10.1111/iar.12517
Naveed Hassan, Ludvig Löwemark, Alice Chien-Yi Liao

Sediment samples tend to dry out during storage and are, therefore, stored refrigerated at about 4°C after wrapping in plastic foil. During XRF core scanning however, the samples must be taken out of their cover, increasing the risk of drying and formation of desiccation cracks on the surface. Because scan times can often amount to several hours and at highest resolution may take over a day to complete, the core will progressively dry out during scanning. With this study we aim to increase our understanding of how this slow drying of the samples during scanning and storage influences the XRF signal because of changes in water content, sediment surface topography, and the development of small, but slowly expanding cracks in the sediment core. Results show that the desiccation of samples during scanning and storage influence the XRF measurements in several ways. Most importantly, slow desiccation of the cores results in both a general lowering of the sample surface, and a shortening of the core due to shrinkage. Larger distance between sediment surface and detector leads to increased noise levels and poor reproducibility for many elements, while the shrinking of cores may shift individual data points between runs, resulting in poor reproducibility and offsets between datasets obtained at different times. Moreover, the loss of light elements, such as hydrogen and oxygen, can influence the matrix effect, especially for organic-rich sediment. Because the XRF signals of individual elements are affected to different degrees, these changes may induce artificial shifts and biases in many elemental ratios commonly used for paleoenvironmental reconstruction.

沉积物样本在储存过程中容易变干,因此用塑料薄膜包裹后冷藏储存,温度约为 4°C。然而,在 XRF 岩心扫描过程中,必须将样品从覆盖物中取出,这就增加了表面干燥和形成干燥裂缝的风险。由于扫描时间通常长达数小时,最高分辨率的扫描可能需要一天以上才能完成,因此岩芯会在扫描过程中逐渐变干。通过这项研究,我们希望进一步了解样品在扫描和储存过程中的缓慢干燥是如何影响 XRF 信号的,这是因为含水量、沉积物表面地形发生了变化,沉积物岩芯中出现了细小但缓慢扩展的裂缝。结果表明,样品在扫描和储存过程中的干燥会在多个方面影响 XRF 测量结果。最重要的是,岩心的缓慢干燥会导致样品表面普遍降低,以及岩心收缩变短。沉积物表面与检测器之间的距离增大会导致噪声水平升高,许多元素的重现性变差,而岩心的收缩可能会在运行之间移动个别数据点,导致重现性变差,不同时间获得的数据集之间也会出现偏差。此外,轻元素(如氢和氧)的损失会影响基质效应,尤其是富含有机质的沉积物。由于单个元素的 XRF 信号会受到不同程度的影响,这些变化可能会导致许多常用于古环境重建的元素比率出现人为偏移和偏差。
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引用次数: 0
Apatite U–Pb geochronology and whole rock, Sr–Nd–Pb isotopic geochemistry of XV mafic-ultramafic intrusion, Bafq, Central Iran: Implications for petrogenesis and tectonic setting 伊朗中部巴夫克 XV 黑云母-超黑云母侵入体的磷灰石 U-Pb 地质年代和全岩 Sr-Nd-Pb 同位素地球化学:对岩石成因和构造背景的影响
IF 1.5 4区 地球科学 Q2 Earth and Planetary Sciences Pub Date : 2024-02-17 DOI: 10.1111/iar.12514
Sakine Amraei, Mohammad Yazdi, Liang Qiu, Chang-Zhi Wu, Lei Chen, Bertrand Moine, Majid Ghasemi Siani, Qihui Zhang, Shahrokh Rajabpour

The XV mafic-ultramafic intrusion is located in the western part of the Posht-e-Badam Block (PBB) within the Central Iranian Micro-Continent (CIMC). Petrographically, the intrusion is composed of gabbro and pyroxenite. Apatite U–Pb dating has established the crystallization age of this intrusion to be 363 ± 67 Ma. The XV intrusive rocks are tholeiitic to slightly calc-alkaline in nature and are characterized by an enrichment of large ion lithophile elements (LILE) and light rare earth elements (LREE) relative to high field strength elements (HFSE) and Heavy Rare Earth Elements (HREE), respectively. The major oxide elements display continuous trends relative to SiO2. The 87Sr/86Sr(i) ratios range from 0.7045 to 0.7056, and the εNd(i) values range from 2.63 to 3.30. In addition, the 206Pb/204Pb, 207Pb/204Pb, and 208Pb/204Pb ratios exhibit a narrow range, varying from 18.68 to 18.70, 15.67 to 15.71, and 38.84 to 38.99, respectively. The geochemical and isotopic characteristics suggest that the parental magma was derived from a Sub- Continental Lithospheric Mantle (SCLM) that was modified by oceanic slab-derived components. The locations of the XV intrusive rocks in εNd(i) versus TDM (Ga) and Nb/La versus discrimination diagrams further support this conclusion. Fractional crystallization is identified as the dominant process influencing the formation of distinct lithological units within the XV intrusive rocks. Our newly presented isotopic and geochronological data, when considered in the regional context, suggest that the XV intrusive rocks were formed in an extensional tectonic setting. In this scenario, upwelling from the asthenospheric mantle induced heating, leading to the melting of previously subduction-modified SCLM. Comparative analysis with previously published ages indicates that extensional magmatism in the PBB continued into the Middle Paleozoic.

十五号黑云母-超黑云母侵入体位于伊朗中部微大陆(CIMC)的波什特-巴达姆区块(Posht-e-Badam Block)西部。从岩石学角度看,该侵入体由辉长岩和辉绿岩组成。根据磷灰石 U-Pb 测定法,该侵入体的结晶年龄为 363 ± 67 Ma。十五号侵入岩为透辉石质至轻微钙碱性,其特征是大离子亲岩元素(LILE)和轻稀土元素(LREE)分别富集于高场强元素(HFSE)和重稀土元素(HREE)。主要氧化物元素相对于二氧化硅显示出连续的趋势。87Sr/86Sr(i) 比值范围为 0.7045 至 0.7056,εNd(i) 值范围为 2.63 至 3.30。此外,206Pb/204Pb、207Pb/204Pb 和 208Pb/204Pb 的比值范围较窄,分别为 18.68 至 18.70、15.67 至 15.71 和 38.84 至 38.99。地球化学和同位素特征表明,母体岩浆来源于次大陆岩石圈地幔(SCLM),并经过大洋板块衍生成分的改造。XV侵入岩在εNd(i)与TDM(Ga)和Nb/La与判别图中的位置进一步支持了这一结论。碎裂结晶被认为是影响 XV 侵入岩内部不同岩性单元形成的主要过程。我们新提供的同位素和地质年代数据,结合区域背景来看,表明 XV 侵入岩是在伸展构造环境中形成的。在这种情况下,来自天体层地幔的上涌诱导了加热,导致了先前经俯冲改造的 SCLM 的熔化。与以前公布的年龄进行的比较分析表明,PBB地区的伸展岩浆活动一直持续到中古生代。
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引用次数: 0
Delineation of an exhumed intermediate-depth crustal fault in a collisional setting: An example from the Himalaya 在碰撞环境中划分出一条隆起的中深层地壳断层:喜马拉雅山脉的一个例子
IF 1.5 4区 地球科学 Q2 Earth and Planetary Sciences Pub Date : 2024-02-16 DOI: 10.1111/iar.12515
Dyuti Prakash Sarkar, Jun-ichi Ando, Kaushik Das, Gautam Ghosh

The regionally prominent main boundary thrust (MBT) of the Himalayan fold-thrust belt in northwest India is typically defined by the presence of Proterozoic rocks in the hanging wall and Cenozoic rocks in the footwall. The present study focuses on identifying the MBT contact across Gambar River section in Himachal Pradesh, India, using alternative methodologies, such as the meter-scale litho-structural mapping, followed by detrital zircon U–Pb geochronology to precisely identify the thrust contact and provide insights on the deformation history of the MBT zone. We have identified a sharp change in the age (from ~600 to ~61 Ma) of the sedimentary units along a narrow zone in the study area by detrital zircon U–Pb geochronology using LA-ICP-MS. The sharp change in the detrital zircon U–Pb age data thus delineate the MBT occurring in the area along a < ~1 m thickness. The lithological assemblage and the age data indicate the unified maximum depositional age from ~700 to ~600 Ma for the hanging wall rocks, which have been equated with the Krol Group of the Lesser Himalayan Sequence (LHS). In comparison, the footwall rocks exhibit the maximum depositional age of ~61 Ma and have been equated with the Cenozoic Subathu Formation of the Sub-Himalayan Sequence (SHS).

印度西北部喜马拉雅褶皱-推力带的区域性突出主边界推力(MBT)通常由悬壁中的新生代岩石和底壁中的新生代岩石所界定。本研究的重点是确定印度喜马偕尔邦甘巴尔河段的MBT接触点,研究采用了其他方法,如米级岩石结构测绘法,然后采用非铁质锆石U-Pb地质年代学,以精确确定推力接触点,并深入了解MBT带的变形历史。我们通过使用 LA-ICP-MS 进行的碎屑锆石 U-Pb 地质年代学研究,确定了研究区域狭窄地带沉积单元年龄的急剧变化(从 ~600 Ma 到 ~61 Ma)。因此,碎屑锆石 U-Pb 年龄数据的急剧变化划定了该地区发生的厚度为 1 米的 MBT。岩性组合和年龄数据表明,悬壁岩的统一最大沉积年龄为 ~700 Ma 至 ~600 Ma,与小喜马拉雅序列(LHS)的 Krol 组相等。相比之下,脚墙岩的最大沉积年龄为 ~61 Ma,被等同于新生代次喜马拉雅山系(SHS)的 Subathu 组。
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引用次数: 0
Field-based description of near-surface crustal deformation in a high-strain shear zone: A case study in southern Kyushu, Japan 基于实地的高应变剪切带近地表地壳变形描述:日本九州南部案例研究
IF 1.5 4区 地球科学 Q2 Earth and Planetary Sciences Pub Date : 2024-02-13 DOI: 10.1111/iar.12516
Masakazu Niwa, Koji Shimada, Shuji Terusawa, Akira Goto, Nariaki Nishiyama, Toru Nakajima, Takanori Ishihara, Hiroaki Hakoiwa

This study investigated geological evidence for near-surface crustal deformation in a high-strain shear zone that has been geodetically identified but which is not associated with obvious tectonic landforms. Fieldwork was conducted in the east–west-trending southern Kyushu high-strain shear zone (SKHZ), Japan, focusing mainly on occurrences of fracture zones, which are defined by a visible fracture density of >1 per 10 cm2 and are commonly associated with cataclasite, fault breccia, and gouge. The area in which east–west-trending fracture zones are dominant is restricted to the east–west-trending, ~2-km-wide aftershock area of the 1997 Northwestern Kagoshima Earthquakes. Analysis of slip data from minor faults using the multiple inverse method, irrespective of whether the faults are in fracture zones, reveals that the area where the calculated main stress field is consistent with the current stress field estimated from focal-mechanism solutions of microearthquakes is restricted to the east–west-trending aftershock area. This finding for the SKHZ contrasts with the case of the Niigata–Kobe Tectonic Zone, which is a major strain-concentration zone with many exposed active faults in central Japan and for which the stress field estimated using fault-slip data is considered to be uniform and coincides with the current stress field. The cumulative amount of displacement estimated from the areal density of fracture zones in the SKHZ study area is smaller than that estimated from geodetically measured strain rates. Investigations based on slip data from minor faults and fracture-zone occurrence could help to identify concealed faults that are too small to generate tectonic landforms but which are sufficiently large to trigger major earthquakes.

这项研究调查了一个高应变剪切带近地表地壳变形的地质证据,该剪切带已被大地测量确定,但与明显的构造地貌无关。实地考察在日本东西走向的南九州高应变剪切带(SKHZ)进行,主要侧重于断裂带的出现,断裂带的定义是可见断裂密度为每 10 平方厘米 1 条,通常与白云岩、断层角砾岩和冲沟有关。东西走向断裂带占主导地位的区域仅限于东西走向、约 2 公里宽的 1997 年鹿儿岛西北部地震余震区。使用多重反演法分析小断层的滑移数据(无论断层是否位于断裂带中)发现,计算出的主应力场与微地震的焦点机制解法估算出的当前应力场一致的区域仅限于东西走向的余震区。新泻-神户构造带是一个主要的应变集中区,在日本中部有许多裸露的活动断层,利用断层滑动数据估算的应力场被认为是均匀的,并与当前应力场相吻合。根据 SKHZ 研究区断裂带的面积密度估算出的累计位移量小于根据地质测量应变率估算出的位移量。根据小断层的滑动数据和断裂带的出现情况进行调查,有助于确定哪些隐蔽的断层太小,不足以产生构造地貌,但其规模足以引发大地震。
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引用次数: 0
Magnetostratigraphic dating of Early Miocene deep-sea fossils from the Morozaki Group in central Japan 日本中部盛崎组早中新世深海化石的磁层年代测定
IF 1.5 4区 地球科学 Q2 Earth and Planetary Sciences Pub Date : 2024-01-29 DOI: 10.1111/iar.12513
Hiroyuki Hoshi, Akari Matsunaga

Early Miocene sediments of the Morozaki Group in central Japan contain deep-sea fossils that have been dated using biostratigraphic and radiometric data. In this study, we utilize magnetostratigraphy to provide a more precise age for mudstones from just below the layer containing the fossils. Rock magnetic experiments suggest that both magnetic iron sulfide and Ti-poor titanomagnetite carry the remanent magnetization of the mudstones. Two different stratigraphic sites have normal polarity directions with a northeastern declination, which can be correlated with Chronozone C5Dn. Given their magnetostratigraphic position near the C5Dn/C5Dr chronozone boundary (17.466 Ma) and a high sedimentation rate, the estimated age for both the sites and the deep-sea fossils is ~17.4 Ma. The northeasterly-directed site-mean directions suggest clockwise tectonic rotation, most likely due to the Early Miocene clockwise rotation of Southwest Japan associated with the back-arc opening of the Japan Sea. The deep-sea fossils, dated at ~17.4 Ma, represent organisms deposited within a submarine structural depression formed by crustal extension during the back-arc opening stage.

日本中部的盛崎组早中新世沉积物中含有深海化石,这些化石的年代是通过生物地层学和辐射测量数据确定的。在这项研究中,我们利用磁地层学为含化石层下的泥岩提供了更精确的年代。岩石磁性实验表明,磁性硫化铁和贫钛磁铁矿都携带着泥岩的剩磁。两个不同的地层点具有东北偏角的正极性方向,可与时空带 C5Dn 相关联。鉴于它们的磁地层位置靠近 C5Dn/C5Dr 时带边界(17.466Ma),且沉积速率较高,这两个地点和深海化石的估计年龄约为 17.4Ma。东北向的遗址平均方向表明顺时针构造旋转,这很可能是由于早中新世日本西南部顺时针旋转与日本海的后弧开口有关。深海化石的年代约为 17.4 Ma,代表了沉积在弧后开裂阶段地壳延伸形成的海底构造凹陷中的生物。
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引用次数: 0
Rhuddanian to Aeronian (Llandovery, early Silurian) carbon isotope stratigraphy throughout carbonate sequences in the upper Yangtze region, South China block 华南区块长江上游地区整个碳酸盐岩层序的红垩纪至阿龙纪(兰德发现期,志留纪早期)碳同位素地层学
IF 1.5 4区 地球科学 Q2 Earth and Planetary Sciences Pub Date : 2024-01-23 DOI: 10.1111/iar.12512
Shenyang Yu, Qijian Li, Stephen Kershaw, Axel Munnecke, Yingyan Mao, Yue Li

The Xiangshuyuan Formation (middle Rhuddanian to middle Aeronian stages of the Llandovery Series, lower Silurian) records a shelly fauna representing recovery after the end-Ordovician mass extinction in a well-oxygenated shallow carbonate platform of the Upper Yangtze region, South China Block. Carbon isotope stratigraphy is documented from limestone sequences of the formation at the Qiankou section, northeast Guizhou. The early Aeronian carbon isotope excursion (EACIE, with an amplitude of about 2 ‰ and peak value of 2.44 ‰) is identified in the middle and upper parts of the formation (Ozarkodina obesa conodont Biozone). The EACIE recorded herein correlates well with those in Baltica, Canada, and the United States; together with its records from organic material (δ13Corg) the data verify that the EACIE is a global event. The beginning of the EACIE can be used as a chemostratigraphic marker defining the Rhuddanian/Aeronian boundary in strata that lack high-resolution biostratigraphic constraints.

湘水源地层(兰德发现系中段至阿龙纪中段,志留系下统)记录了华南地块上长江地区一个含氧良好的浅层碳酸盐岩平台中代表奥陶纪末大灭绝后复苏的搁浅动物群。碳同位素地层学资料来自贵州东北部黔口段的石灰岩层序。在该地层的中上部(Ozarkodina obesa conodont Biozone)发现了早阿隆纪碳同位素偏移(EACIE,振幅约为2‰,峰值为2.44‰)。这里记录的 EACIE 与波罗的海、加拿大和美国的 EACIE 有很好的相关性;加上有机物质(δ13Corg)的记录,这些数据验证了 EACIE 是一个全球性事件。在缺乏高分辨率生物地层学约束的地层中,EACIE 的开端可作为界定 Rhuddanian/Aeronian 边界的化合地层学标志。
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引用次数: 0
Indosinian anatexis of Paleoproterozoic granites in the east Cathaysia Block, South China 华南东国泰区块古新生代花岗岩的印支期无性生殖现象
IF 1.5 4区 地球科学 Q2 Earth and Planetary Sciences Pub Date : 2024-01-19 DOI: 10.1111/iar.12510
Wei Zhang, Hanwen Zhou, Xiaohua Zhou, Xilin Zhao, Huan Liu, Yang Jiang, Chunzhong Li

Granulite facies metamorphism and crustal anatexis exist in the East Cathaysia Block, the exact timing of granulite facies partial melting and its link with orogenesis have not been well constrained. In this study, we carried out petrography, whole rock geochemistry, and zircon U–Pb dating, trace elements and Hf isotopes analyses on Dazhe gneissic granite and banded migmatite from the Badu Group in southwest Zhejiang province in the East Cathaysia Block. The melts were produced through the dehydration of biotite, such as biotite + quartz + plagioclase = orthopyroxene + K-feldspar + melt and biotite + quartz + plagioclase + sillimanite = garnet + K-feldspar + melt. Zircons from these rocks show clear core-rim structure and yield rim and core concordant ages at 233 Ma and 1.83 Ga, respectively. The zircon rims suggesting the melts and the cores are suggesting the protolith of Dazhe gneissic granite and banded migmatite were crystallized from an evolving magma. The zircon cores and rims have negative εHf(t) = −2.2 ~ −6.3 and εHf(t) = −22.8 ~ −32.4, and they give suggestion of the presence of Neoarchean components. Although the major-element compositions of the gneissic granite and banded migmatite are slightly different, the trace-element spider diagram and REE pattern show they are similar, and then we find that the protoliths are A-type granodiorite/diorite. Combined with the published data, we suggested that the Dazhe gneissic granite and banded migmatite were formed through granulite facies partial melting at 233 Ma, which was promoted by crustal shortening and thickening of the collision orogeny between East Cathaysia Block and an unknown terrane with a NNE trend structure line. The protoliths (granite or granodiorite) of Dazhe gneissic granite and banded migmatite crystallized at 1.83 Ga by reworking of the Neoarchean components of East Cathaysia Block. The Paleoproterozoic (1912–1819 Ma) collisional orogeny and the later intraplate rifting stage are corresponding to the aggregation and breakup of the Columbia supercontinent.

东中国地块存在花岗岩变质作用和地壳异常,但花岗岩面部分熔融的确切时间及其与造山运动的联系尚未得到很好的解释。在本研究中,我们对东中国海地块浙江西南部八都组的大浙片麻岩和带状伟晶岩进行了岩石学、全岩石地球化学、锆石U-Pb定年、微量元素和Hf同位素分析。这些熔体是由生物岩脱水产生的,如生物岩+石英+斜长石=正长石+K长石+熔体和生物岩+石英+斜长石+矽线石=石榴石+K长石+熔体。这些岩石中的锆石显示出清晰的岩心-岩缘结构,其岩缘和岩心的一致年龄分别为 233 Ma 和 1.83 Ga。锆石边缘表明熔体,而锆石核心则表明大泽片麻状花岗岩和带状辉长岩的原岩是从演化岩浆中结晶出来的。锆石岩心和岩缘的εHf(t)=-2.2 ~ -6.3和εHf(t)=-22.8 ~ -32.4分别为负值,表明存在新元古代成分。虽然片麻状花岗岩和带状闪长岩的主要元素组成略有不同,但痕量元素蛛网图和REE模式显示两者相似,进而发现原岩为A型花岗闪长岩/闪长岩。结合已发表的资料,我们认为大柘片麻状花岗岩和带状闪长岩是在233Ma时由花岗岩面局部熔融形成的,它是在东国泰地块与一个未知陆块之间的碰撞造山运动的地壳缩短和增厚的作用下形成的,其构造线呈NNE走向。大泽片麻岩和带状辉长岩的原岩(花岗或花岗闪长岩)在1.83 Ga时由东长春地块的新元古代成分再加工结晶而成。早新生代(1912-1819Ma)的碰撞造山运动和后期的板块内断裂阶段与哥伦比亚超大陆的聚集和分裂相对应。
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引用次数: 0
Eocene extensional tectonics in the Amakusa region, northern Ryukyu arc 琉球弧北部天草地区始新世伸展构造运动
IF 1.5 4区 地球科学 Q2 Earth and Planetary Sciences Pub Date : 2024-01-11 DOI: 10.1111/iar.12511
Kentaro Ushimaru, Atsushi Yamaji

Paleogene surface tectonics in Japan is not well understood because of the paucity of onshore Paleogene stratigraphic records except for those from accretionary complexes. Paralic Paleogene formations remaining in SW Japan are usually so thin that it is difficult to decipher the tectonics from them. However, the Eocene paralic sedimentary package with a thickness of kilometers indicates syn-depositional tectonic subsidence by a few kilometers in the Amakusa archipelago, west of Kyushu Island. Thus, we made a detailed geological map of the Eocene formations in an area of ~50 square kilometers in the northwestern part of the archipelago. We identified NE-SW and NW-SE trending normal faults, most of which were recognized by previous researchers, and also discovered low-angle faults. NW-SE trending ones are known to be of the Miocene. NE-SW trending and low-angle normal faults are the oldest map-scale structures in the Eocene ones. It is not obvious within the above-mentioned area whether those normal faults are accompanied by growth strata. However, the significant southeastward thickening of the Eocene formations across the Amakusa archipelago suggests that they filled a large half graben with the basin margin fault along the eastern side of the archipelago. This basin model is consistent with the N-S to NW-SE transport directions of the low-angle and NE-SW trending normal faults. Since many NE-SW to EW trending Eocene grabens were formed in the offshore regions west of Kyushu Island and in the East China Sea, the Amakusa region was probably a northeastern branch of the rift system. The geologic structures and depositional ages of the Eocene formations indicate that the Eocene extensional tectonics removed the overlying strata to some extent for the high-P/T Takahama Metamorphic Rocks which crops out to the south of our study area.

日本的古近纪地表构造还不太清楚,因为除了来自增生复合体的地层记录外,陆上古近纪地层记录很少。日本西南部残留的古新世副层地层通常很薄,很难从中解读构造。然而,在九州岛以西的天草群岛,厚度达数公里的始新世副沉积岩包显示出同步沉积构造下沉了数公里。因此,我们绘制了该群岛西北部约 50 平方公里范围内始新世地层的详细地质图。我们确定了 NE-SW 和 NW-SE 走向的正断层,其中大部分已被之前的研究人员确认,同时还发现了低角度断层。已知西北-东南走向的断层属于中新世时期。东北-西南走向的正断层和低角度断层是始新世断层中最古老的图层结构。在上述区域内,这些正断层是否伴有生长地层并不明显。不过,整个天草群岛的始新世地层向东南方向明显增厚,这表明它们沿群岛东侧与盆地边缘断层一起填充了一个大的半地堑。这一盆地模型与低角度和东北-西南走向的正断层的 N-S 至 NW-SE 走向一致。由于在九州岛以西的近海地区和中国东海形成了许多东北-西南-东南走向的始新世地堑,因此天草地区很可能是裂谷系统的东北分支。始新世地层的地质构造和沉积年龄表明,始新世的伸展构造在一定程度上移除了上覆地层,从而在我们研究区域南部形成了高P/T高滨变质岩。
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引用次数: 0
Magmatic processes forming replacement textures with fluorite alignments in feldspars in an evolved trachyte from Oki-Dogo Island, Sea of Japan 岩浆作用过程在日本海冲东乡岛的长石中形成萤石排列的置换纹理
IF 1.5 4区 地球科学 Q2 Earth and Planetary Sciences Pub Date : 2024-01-08 DOI: 10.1111/iar.12509
Satoshi Nakano, Kuniaki Makino

Internal microtextures of ternary alkali feldspars in sanidine trachyte from Oki-Dogo Island were examined using an electron microprobe analyzer, a scanning electron microscope, a transmission electron microscope and cathodoluminescence instruments, to develop the understanding of volcanic processes of alkaline magmas related to feldspar crystallization. The examined trachyte is an evolved rock of the Oki-Dogo Pliocene trachyte group. Its phenocryst feldspars are commonly associated with lamellar-wavy-domain textures with scales approximately from 100 nm up to several hundreds of μm that show complex and gradual variations in composition: however, anti-rapakivi zoning textures common in other Oki-Dogo alkaline rocks are almost completely absent in the trachyte. These textures are produced by extensive magmatic ion-exchange replacement reactions progressively advanced in the evolved magma. Characteristic braided fluorite alignments are developed consistently with lamellar-wavy-domain textures in phenocryst feldspars, and similar braided alignments are also present in groundmass feldspars with complicated microtextures. Most of fluorite grains are <100 nm in diameter, and the patterns of braided fluorite alignments vary greatly in individual feldspars. The whole occurrence of the feldspar microtextures represents an extreme example of diffusion-controlled replacement reactions, progressively advanced in the dry (relatively anhydrous) trachyte magma. The genetic processes forming fluorite alignments in feldspars are related to magma compositions, especially F and P contents, and the crystallization of F-bearing minerals, especially of fluorapatite.

使用电子微探针分析仪、扫描电子显微镜、透射电子显微镜和阴极发光仪器,对冲古岛砂岩中三元碱性长石的内部微观结构进行了研究,以加深对与长石结晶有关的碱性岩浆的火山过程的了解。所考察的砂岩是冲古-多哥上新世砂岩群的一种演化岩。它的表晶长石通常伴有尺度约为 100 纳米到数百微米的片状波浪域纹理,这些纹理显示出复杂而渐进的成分变化:然而,在其他冲古谷碱性岩中常见的反拉帕基维分带纹理在该砂岩中几乎完全不存在。这些纹理是由演化岩浆中逐渐推进的广泛岩浆离子交换置换反应产生的。特征性的编织萤石排列与表晶长石中的片状波浪域纹理一致,类似的编织排列也出现在具有复杂微观纹理的基质长石中。大多数萤石晶粒的直径为 100 nm,个别长石的萤石编织排列模式差异很大。长石微观结构的整体出现代表了在干燥(相对无水)的岩浆中逐步推进的扩散控制置换反应的一个极端例子。形成长石中萤石排列的遗传过程与岩浆成分(尤其是 F 和 P 含量)以及含 F 矿物(尤其是氟磷灰石)的结晶有关。
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引用次数: 0
Rock magnetic analyses as a tool to investigate diversity of drift pumice clasts: An example from Japan's 2021 Fukutoku-Oka-no-Ba (FOB) eruption 将岩石磁性分析作为研究漂移浮石碎屑多样性的工具:以 2021 年日本福德大阪火山(FOB)喷发为例
IF 1.5 4区 地球科学 Q2 Earth and Planetary Sciences Pub Date : 2023-12-28 DOI: 10.1111/iar.12507
Julie Carlut, Aude Isambert, Claire Carvallo, Geoffrey Garcia da Fonseca, Nelly-Wangue Moussissa, Arthur Bouis, Kenta Yoshida

The crystallization of nanolites within magma chambers has recently raised a strong interest due to their impact on increasing melt viscosity and triggering magmatic eruptions. In 2021, the Fukutoku-Oka-no-Ba (FOB) underwater eruption produced large quantities of pumices that eventually formed rafts drifting at the surface of the ocean to the East coasts of Japan. Pumices collected along the shore shortly after grounding show various colors, microscopic and Raman analyses made by Yoshida et al. (Island Arc, 31, 1, 2022) revealed the presence of magnetite nanolites in some of them. In this study, we explore the magnetic properties of a batch of pumices of different colors from the FOB eruption, aiming to refine characterization of iron oxide nanolites. We used various analytical techniques such as SEM and FEG-SEM observations, EDS-X analyses, and rock magnetic experiments, including thermomagnetic analyses, hysteresis curves, coercivity analyses and FORC measurements. Our findings reveal that the iron oxides present in the FOB samples are Ti-magnetite, with minor amounts of Mg and Al. The magnetic crystals show a wide range of sizes, from extra small iron oxide nanolites (ESION) in the pumices with the lighter colors, to more bulky grains reaching the micrometer size in some of the dark color samples, significant diffusion is inferred in that case. Consequently, the magnetic characterization of iron oxide crystals within the Fukutoku-Oka-no-Ba pumices reveals varying stages of nucleation, dissolution, growth, and diffusion processes, providing evidences for the heterogeneous state of the magma during the eruption.

由于纳米石对增加熔体粘度和引发岩浆喷发的影响,岩浆腔内的纳米石结晶最近引起了人们的强烈兴趣。2021 年,Fukutoku-Oka-no-Ba(FOB)水下喷发产生了大量浮石,这些浮石最终在海面上形成浮筏漂流到日本东海岸。Yoshida 等人(Island Arc, 31, 1, 2022)通过显微镜和拉曼分析(Island Arc, 31, 1, 2022)发现其中一些浮石中存在磁铁矿纳米石。在本研究中,我们探索了一批来自 FOB 火山喷发的不同颜色浮石的磁特性,旨在完善纳米氧化铁的表征。我们使用了各种分析技术,如扫描电镜和 FEG-SEM 观察、EDS-X 分析以及岩石磁性实验,包括热磁分析、磁滞曲线、矫顽力分析和 FORC 测量。我们的研究结果表明,FOB 样品中的铁氧化物是钛磁铁矿,并含有少量的镁和铝。磁性晶体的尺寸范围很广,从浅色浮石中的超小型氧化铁纳米石(ESION)到一些深色样品中达到微米大小的大颗粒,在这种情况下可以推断出明显的扩散。因此,Fukutoku-Oka-no-Ba 浮灰中氧化铁晶体的磁性特征揭示了成核、溶解、生长和扩散过程的不同阶段,为岩浆在喷发过程中的异质状态提供了证据。
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