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Late Cretaceous–Paleogene terrestrial sequence in the northern Kitakami Mountains, Northeast Japan: Depositional ages, clay mineral contents, and vitrinite reflectance 日本东北部北上山脉北部晚白垩世-古近纪陆地序列:沉积年龄、粘土矿物含量和镜质组反射率
IF 1.5 4区 地球科学 Q4 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2023-09-22 DOI: 10.1111/iar.12500
Atsushi Noda, Kazuya Morimoto, Koji U. Takahashi, Tohru Danhara, Hideki Iwano, Takafumi Hirata

Forearc basin deposits on continental margins contain important information that can be used to reconstruct the tectonic setting, volcanism, and climate at the time of their deposition. Coal-bearing terrestrial to shallow marine strata in Northeast Japan were deposited in a forearc basin along the Eurasian continental margin during the Cretaceous–Paleogene. The rocks exposed in the Kado district, Iwate Prefecture, in the northern Kitakami Mountains include the Upper Cretaceous Yokomichi Formation and the Paleogene Kogawa Group; the latter is known for high-quality refractory clay (kaolin clay). However, their stratigraphy and sedimentological characteristics are not yet fully understood. To reconstruct the formation and filling of the basin, we investigated field observations, U–Pb dating of tuff samples, XRD analysis of tuff and mudstone samples, and vitrinite reflectance of coal samples in this sequence. The U–Pb ages of the Yokomichi Formation and the Kogawa Group are ∼86 Ma and 58–52 Ma, respectively. The U–Pb age of the kaolin-dominated tuffaceous rock (“red rocks”) is 56.1 ± 0.2 Ma. The mean random vitrinite reflectance (VRr) ranges from 0.37% to 0.53% through the sequence. We propose the following sequence for the formation and filling of the basin. (1) The basin initially formed during the Coniacian–Santonian (Late Cretaceous) and was filled by fluvial–lacustrine sediment. (2) These sediments kept the shallow burial depths during a ∼28 Myr and made a hiatus (86–58 Ma). (3) The basin was reactivated and covered by tuffs during the Thanetian, and the tuffs were altered to kaolin clay during the Paleocene–Eocene Thermal Maximum. (4) The basin was filled rapidly by alluvial fan deposits and subsided <2300 m (assuming a geothermal gradient of >30 K/km). (5) The basin was uplifted and exhumed at a rate of >50 m/Myr faster than the mean exhumation rate of the Kitakami Mountains since the Paleogene.

大陆边缘的弧前盆地沉积物包含重要信息,可用于重建其沉积时的构造环境、火山活动和气候。日本东北部的含煤陆地至浅海地层在白垩纪-古近纪沉积在欧亚大陆边缘的弧前盆地中。岩手县加都区北越山脉北部出露的岩石包括上白垩统横道组和古近系小川组;后者以高质量耐火粘土(高岭土)而闻名。然而,它们的地层学和沉积学特征尚不完全清楚。为了重建盆地的形成和填充,我们调查了野外观测、凝灰岩样品的U–Pb测年、凝灰岩和泥岩样品的XRD分析以及煤样品的镜质组反射率。横道组和Kogawa群的U-Pb年龄为~86 马和58–52 马。高岭土为主的凝灰质岩石(“红色岩石”)的U–Pb年龄为56.1 ± 0.2 Ma。整个序列的平均随机镜质组反射率(VRr)在0.37%-0.53%之间。我们建议按照以下顺序形成和填充盆地。(1) 该盆地最初形成于科尼亚阶-桑托阶(晚白垩世),由河流-湖泊沉积物填充。(2) 这些沉积物保持了浅埋深度 Myr和中断(86–58 马)。(3) 在Thanetian期间,盆地被凝灰岩重新激活和覆盖,在古新世-始新世热盛期,凝灰岩变为高岭土。(4) 该盆地被冲积扇沉积物迅速填充,并沉降<;2300 m(假设地热梯度>30 K/km)。(5) 盆地以>;50 m/Myr比古近纪以来北上山脉的平均挖掘速度快。
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引用次数: 0
Simulation of methane hydrate formation in coarse- to fine-grained sediments in the Nankai Trough, Japan 日本南开海槽粗粒沉积物中甲烷水合物形成的模拟
IF 1.5 4区 地球科学 Q4 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2023-09-19 DOI: 10.1111/iar.12502
Chao Xu, Hitoshi Tomaru

The properties of host sediments and pore water considerably affect both the occurrence and formation processes of methane hydrate. In coarse-grained layers, hydrates are generally concentrated preferentially in the pore space, and their formation is influenced by pore water salinity. To understand how geophysical and geochemical factors control the distribution of methane hydrates, we conducted numerical simulations using a one-dimensional flow model under different reservoir and fluid conditions in the Kumano Forearc Basin, Nankai Trough, Japan. Assuming an estimated range of methane flux between 0.002 and 1.9 kg m−2 year−1, three flow scenarios were considered. When the methane flux was relatively small, the results coincided with the observed hydrate distribution. In general, a low-methane flux decreases the hydrate saturation upward from the bottom of the methane hydrate stability, whereas a high-methane flux increases the saturation downward. These results also suggest that the sediment structure, such as the fracture distribution, influences the sediment stress conditions and constrains the flow regime. We further examined the effects of permeability changes in the heterogeneous lithological units on the simulation results using typical permeabilities of 10−13 m2 for sand and 10−15 m2 for mud. The results showed that hydrate saturation sharply increased and decreased in adjacent high- and low-permeability units, respectively. The consideration of complex stratigraphic conditions and variable fluid configurations provides an understanding of the environmental factors controlling hydrate generation and distribution, which is important for hydrate resource extraction and geohazard prevention.

宿主沉积物和孔隙水的性质在很大程度上影响甲烷水合物的产生和形成过程。在粗粒层中,水合物通常优先集中在孔隙空间中,其形成受到孔隙水盐度的影响。为了了解地球物理和地球化学因素如何控制甲烷水合物的分布,我们在日本南开海槽熊野前陆盆地的不同储层和流体条件下,使用一维流动模型进行了数值模拟。假设甲烷流量的估计范围在0.002和1.9之间 公斤 m−2 −1年,考虑了三种流量情景。当甲烷流量相对较小时,结果与观测到的水合物分布一致。通常,低甲烷通量从甲烷水合物稳定性的底部向上降低水合物饱和度,而高甲烷通量向下增加饱和度。这些结果还表明,泥沙结构,如裂缝分布,影响了泥沙应力条件,并限制了流态。我们使用10−13的典型渗透率进一步研究了非均质岩性单元渗透率变化对模拟结果的影响 m2用于沙子和10−15 m2用于泥浆。结果表明,相邻的高渗透单元和低渗透单元的水合物饱和度分别急剧上升和下降。考虑复杂的地层条件和可变的流体配置,可以了解控制水合物生成和分布的环境因素,这对水合物资源开采和地质灾害预防很重要。
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引用次数: 0
Role of mantle carbonation in trench outer-rise region in the global carbon cycle 海沟外隆起区地幔碳酸化在全球碳循环中的作用
IF 1.5 4区 地球科学 Q4 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2023-09-04 DOI: 10.1111/iar.12499
Ikuo Katayama, Keishi Okazaki, Atsushi Okamoto

A nearly balanced carbon budget between subduction input and degassing output has likely controlled the long-term surface environment and habitability of Earth throughout geological history. However, the ongoing extensive hydration and carbonation of the mantle in trench outer-rise regions may affect the global carbon budget. In this study, we show that the carbon content of the lithospheric mantle can be inferred from geophysical data and thermodynamic modeling. Based on the seismic velocity anomaly in trench outer-rise regions, we estimated that the total carbon flux due to mantle carbonation is 7–31 Mt C/year, with possible fluid-to-rock mass ratios of 250–1000. These values are similar to the carbon uptake by altered oceanic crust, indicating that mantle carbonation has a significant effect on the subduction carbon budget. Although there are large uncertainties on the estimates of the subduction and degassing carbon fluxes, secular cooling of the mantle leads to the development of outer-rise faults associated with bending of the oceanic lithosphere and increased mantle carbonation, which may disrupt the self-regulating system of the global carbon cycle on geological timescales.

在整个地质史上,俯冲输入和脱气输出之间几乎平衡的碳预算可能控制了地球的长期表面环境和宜居性。然而,海沟外隆起区地幔持续的广泛水合和碳酸化可能会影响全球碳预算。在这项研究中,我们表明岩石圈地幔的碳含量可以从地球物理数据和热力学模型中推断出来。根据海沟外隆起区的地震速度异常,我们估计地幔碳酸化导致的总碳通量为7–31 Mt C/年,可能的流体与岩石质量比为250–1000。这些数值与蚀变海洋地壳的碳吸收相似,表明地幔碳酸化对俯冲碳收支有显著影响。尽管俯冲和脱气碳通量的估计存在很大的不确定性,但地幔的长期冷却导致了与海洋岩石圈弯曲和地幔碳酸化增加相关的外升断层的发展,这可能会破坏地质时间尺度上全球碳循环的自调节系统。
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引用次数: 1
The proximal volcaniclastic materials of Fukutoku-Oka-no-Ba in the Izu-Bonin arc show contrasting characteristics to the drift pumice of the 2021 eruption Izu‐Bonin弧中Fukutoku‐Oka‐no‐Ba的近端火山碎屑物质显示出与2021年火山喷发的浮石形成对比的特征
IF 1.5 4区 地球科学 Q4 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2023-08-24 DOI: 10.1111/iar.12498
Kenta Yoshida, Yoshihiko Tamura, Tomoki Sato, Erika Tanaka, Noriko Tada, Morihisa Hamada, Takeshi Hanyu, Qing Chang, Shigeaki Ono

Fukutoku-Oka-no-Ba is a submarine volcano located at 24°17.1′ N/141°28.9′ E in the Izu–Bonin arc, and is one of the most active volcanoes in Japan. This volcano produced an explosive eruption in August 2021 that generated a large amount of volcaniclastic material, some of which drifted westward to Japan and the coastal area of East Asia as a pumice raft. The pumice clasts that drifted for >1000 km were mostly homogeneous and identical to those produced by past historical eruptions. The clasts have trachytic compositions (SiO2 = 61–63 mass% and Na2O + K2O = 8.6–10.0 mass%) and contain augite, plagioclase, olivine (Mg# ~65), and magnetite, along with a small number of mafic enclaves containing diopside and high-Mg olivine (Mg# ~ 92). We undertook a research cruise to investigate the proximal volcaniclastic materials by dredging. The proximal materials include pumice, weakly vesiculated lapilli, and volcanic blocks, which have trachytic composition (SiO2 contents up to 64.5 mass%). The main minerals in the proximal material are similar to those in the drift pumice, although remnants of mafic magma do not occur in the SiO2-rich samples. The petrographic and geochemical characteristics of the proximal and drift ejecta from Fukutoku-Oka-no-Ba suggest the magma reservoir was stratified into two parts. The major part experienced magma mixing with a limited volume of mafic magma, whereas the other part was more differentiated. The differentiated high-SiO2 magma accumulated in the upper part of the magma reservoir and avoided the mixing with and feed of volatile from the mafic magma, then were pushed out from the volcanic vent without extensive bubbling to sunk in the proximal area.

Fukutoku‐Oka‐no‐Ba是一座海底火山,位于24°17.1′ N/141°28.9′ 伊豆-薄宁弧中的E火山,是日本最活跃的火山之一。这座火山在2021年8月爆发,产生了大量火山碎屑物质,其中一些物质作为浮石筏向西漂移到日本和东亚沿海地区。浮石碎屑漂移超过1000 km大部分是同质的,与过去历史喷发产生的km完全相同。碎屑具有粗管成分(SiO2 = 61–63质量%和Na2O+K2O = 8.6–10.0质量%),含有辉石、斜长石、橄榄石(Mg#~65)和磁铁矿,以及少量含有透辉石和高镁橄榄石(Mg# ~ 92)。我们进行了一次研究巡航,通过疏浚来调查近端火山碎屑物质。近端材料包括浮石、弱泡状火山岩和火山岩块,其具有管胞成分(SiO2含量高达64.5质量%)。近端物质中的主要矿物与漂移浮石中的矿物相似,尽管富含SiO2的样品中没有镁铁质岩浆的残余物。Fukutoku‐Oka‐no‐Ba近端和漂移喷出物的岩相和地球化学特征表明,岩浆储层分为两部分。主要部分经历了岩浆与有限体积的镁铁质岩浆的混合,而另一部分则更加分化。分化的高SiO2岩浆聚集在岩浆储层的上部,避免了与镁铁质岩浆的挥发性物质混合和补给,然后在没有大量起泡的情况下从火山口被推出,沉入近端区域。
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引用次数: 0
Metamorphic history of mafic granulite and garnet-bearing amphibolite from the Oki-Dogo Island, Japan 日本御木道吾岛镁铁质麻粒岩和含石榴石角闪岩的变质史
IF 1.5 4区 地球科学 Q4 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2023-08-24 DOI: 10.1111/iar.12497
Mizuki Takahashi, Shunsuke Endo, Atsushi Kamei

Oki metamorphic rocks have long been considered as a constituent of the Hida Belt based on their geographic proximity, lithology, and Permo-Triassic metamorphism. However, recent geochronological studies have demonstrated that both para- and ortho-gneisses in the Oki-Dogo Island display Paleoproterozoic protolith formation and two separate phases of metamorphism at 1.85 Ga and 250–230 Ma. Consequently, the Oki metamorphic rocks are closely connected to the Paleoproterozoic massifs in the Korean Peninsula, although little is known about their pressure (P)–temperature (T) history. Here, we provide petrological data on mafic metamorphic rocks in the Oki-Dogo Island. The mafic lithologies are classified into mafic granulite, amphibolitized granulite and amphibolite. In addition, we first discover a garnet-bearing variety of amphibolite from the Oki-Dogo Island. The texture and composition of Ca amphibole suggest these rock types share a common P–T history but the dominant mineral assemblage in each rock type records different stages of metamorphism. The inferred P–T history includes two distinct events. The first event includes a low-P granulite facies stage (~900°C, 0.7–0.8 GPa) and subsequent amphibolite facies retrogression. This event is linked to the continuous compositional change of Ca amphibole from Ti-rich pargasite to hornblende/actinolite. The second event is prograde amphibolite facies metamorphism, which is associated with the formation of tschermakitic hornblende and calcic plagioclase. In high Fe/(Mg + Fe) rocks, garnet was formed at ~550–580°C, 0.45–0.50 GPa in this stage. Depending on the age of the first event, the low-P granulite facies metamorphism is likely to have occurred in a similar tectonic setting as the Paleoproterozoic crustal metamorphism in the Yeongnam Massif or the Permo-Triassic ultrahigh-T metamorphism in the northern Gyeonggi Massif.

Oki变质岩长期以来被认为是Hida带的一个组成部分,基于它们的地理邻近性、岩性和二叠纪-三叠纪变质作用。然而,最近的地质年代学研究表明,Oki - Dogo岛的准片麻岩和正片麻岩均显示古元古代的原岩形成,并在1.85 Ga和250-230 Ma两个不同的变质阶段。因此,Oki变质岩与朝鲜半岛的古元古代地块有着密切的联系,尽管对它们的压力(P) -温度(T)历史知之甚少。在此,我们提供了Oki - Dogo岛基性变质岩的岩石学数据。基性岩岩性分为基性麻粒岩、角闪岩化麻粒岩和角闪岩。此外,我们首次在Oki - Dogo岛发现了一种含石榴石的角闪岩。Ca角闪洞的结构和组成表明这些岩石类型具有共同的P-T历史,但每种岩石类型的主要矿物组合记录了不同的变质阶段。推断的P-T历史包括两个不同的事件。第一个事件包括低磷麻粒岩相阶段(~900°C, 0.7-0.8 GPa)和随后的角闪岩相退退。这一事件与Ca角闪洞从富钛寄生石到角闪石/放光石的连续组成变化有关。第二个事件为进阶角闪岩相变质作用,与闪质角闪石和钙质斜长石的形成有关。在高Fe/(Mg + Fe)岩石中,石榴石形成于~550 ~ 580℃,0.45 ~ 0.50 GPa。根据第一次事件的年龄,低磷麻粒岩相变质作用可能发生在与岭南地块古元古代地壳变质作用或京畿地块北部二叠纪-三叠纪超高铁变质作用相似的构造环境中。
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引用次数: 0
Complex factors contribute to the chemical composition of clastic sediments traveling from rivers to the ocean along island arcs: A case study of the Otsuchi area, Northeast Japan 复杂因素影响碎屑沉积物沿岛弧从河流流向海洋的化学成分:以日本东北部大口地区为例
IF 1.5 4区 地球科学 Q4 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2023-08-24 DOI: 10.1111/iar.12496
Kei Sugiura, Hikaru Sawada, Mutsumi Iizuka, Mana Yasui, Qing Chang, Takafumi Kasaya

The chemical composition of coastal sediments and river sediments is influenced by the geological constitution of provenance and fractionation of clastic particles during sedimentary processes. The intricate nature of the geology in active subduction zones has complicated the comprehension of detrital sediments. More geochemical case studies in such areas are necessary to enhance the understanding of the coastal detrital sediments. This study presents the results of a geochemical and particle size analysis of sediment samples from the Sanriku coastal area of Northeast Japan, including inside and outside of Otsuchi Bay and the three rivers that flow into the bay. Otsuchi Bay area is known to have been severely affected by the 2011 off the Pacific coast of the Tohoku Earthquake and tsunami, and tsunami deposits on its seabed have been reported. The present geochemical analysis indicates that the sediments along those three rivers are well explained by the mixing of rocks occurring in their respective provenance. The chemical composition and particle size distribution of the sediments within Otsuchi Bay suggested the removal of coarse-grained quartz. They increased the abundance of fine-grained mafic minerals from Unosumai River having the largest catchment area among the three rivers. During shell debris in the seabed sediment outside of the bay made interpretation of the results was difficult; the sediments collected closer to the bay mouth contained more coarse-grained material with a composition closer to granitoid and sandstone in the provenance. In contrast, offshore sediments consisted of finer grains with a composition closer to mudstone. Notably, the sediments within Otsuchi Bay did not exhibit the characteristic compositional fractionation or particle size distribution associated with tsunami deposits. These findings underscore the importance of considering the geological diversity of provenances and the particle size distribution of minerals in understanding coastal sediments in subduction zones, including tsunami deposits.

海岸沉积物和河流沉积物的化学成分受物源地质构造和沉积过程中碎屑颗粒分馏作用的影响。活动俯冲带复杂的地质性质使得对碎屑沉积物的认识复杂化。需要在这些地区进行更多的地球化学案例研究,以提高对海岸碎屑沉积物的认识。本研究介绍了日本东北部三陆沿海地区沉积物样本的地球化学和粒度分析结果,包括大槌湾内外以及流入海湾的三条河流。众所周知,2011年太平洋沿岸的东北地震和海啸对大槌湾地区造成了严重影响,据报道,大槌湾的海床上有海啸沉积物。目前的地球化学分析表明,这三条河流沿岸的沉积物很好地解释了在各自的物源区发生的岩石混合。大槌湾沉积物的化学成分和粒度分布表明粗粒石英被去除。他们增加了三河中集水区最大的宇苏迈河中细粒基性矿物的丰度。期间贝壳碎屑在海湾外的海底沉积物中造成了解释结果的困难;靠近海湾口的沉积物含有更多粗粒物质,物源成分更接近花岗岩和砂岩。相比之下,近海沉积物由更细的颗粒组成,其成分更接近泥岩。值得注意的是,大池湾内的沉积物没有表现出海啸沉积物特有的成分分异和粒度分布特征。这些发现强调了考虑物源的地质多样性和矿物粒度分布对理解俯冲带海岸沉积物(包括海啸沉积物)的重要性。
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引用次数: 0
Soft body reconstruction of a reptile fossil by the nondestructive elemental mapping with a newly designed XRF 用新设计的XRF进行非破坏性元素映射的爬行动物化石软体重建
IF 1.5 4区 地球科学 Q4 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2023-08-16 DOI: 10.1111/iar.12495
Wei Wang, Ling Shu, Deqi Wang

Vertebrate fossils usually consist only of mineralized skeletons and rarely preserve soft body parts. However, the buried soft body releases the degraded material into the surrounding sediments. The degraded material can be preserved as invisible signals of some chemicals or authigenic minerals, which can be revealed by the elemental distribution of the fossils' surface and their surrounding rock. As a method for surface elemental mapping, X-ray fluorescence (XRF) measurement requires the samples to be ground and polished as a mirror-like plane that keeps a stable distance of X-ray source-sample-detector. This destructive pretreatment is undesirable for precious fossils. To rectify this problem, a nondestructive XRF for element mapping of the fossils' 3D surface is newly invented. The new equipment can follow the 3D shape model to keep the distance for every XRF scanned point. We performed the element mapping of Ca and Fe on the surface of a marine sauropterygian fossil (Keichousaurus hui) and its surrounding sediments, and found that the soft tissue around the thoracic cage is thicker than the abdomen. The abnormal elemental distribution on the area of the angular and surangular of the skull can be explained as unprofessionally prepared. In addition, this research found that elemental mapping revealed the invisible signals of the paleoenvironment around fossils and information for the reconstruction of soft-tissue anatomy. We also give an example that based on the wide application of the “Internet of Things” and “Industrial Network,” the design and development of specialized equipment for paleontologists' requirements are going simple.

脊椎动物化石通常只由矿化的骨骼组成,很少保存柔软的身体部分。然而,被埋的软体将降解物质释放到周围的沉积物中。降解物质可以作为一些化学物质或自生矿物的不可见信号保存下来,这些化学物质或自生矿物可以通过化石表面及其周围岩石的元素分布来揭示。作为表面元素映射的一种方法,X射线荧光(XRF)测量需要将样品研磨和抛光为镜面状平面,以保持X射线源-样品-探测器之间的稳定距离。这种破坏性的预处理对于珍贵的化石是不可取的。为了解决这个问题,新发明了一种用于化石三维表面元素映射的无损XRF。新设备可以按照三维形状模型来保持每个XRF扫描点的距离。我们对一具海生龙化石(Keichousaurus hui)及其周围沉积物表面进行了钙、铁元素作图,发现其胸廓周围的软组织比腹部厚。颅骨角、角区元素分布异常可解释为非专业制作。此外,本研究还发现元素映射揭示了化石周围古环境的隐形信号和软组织解剖重建的信息。我们还举了一个例子,基于“物联网”和“工业网络”的广泛应用,满足古生物学家需求的专用设备的设计和开发正在变得简单。
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引用次数: 0
Geochronology and geochemistry of early Palaeozoic ultramafic rocks along Jiangshan-Shaoxing Fault and their tectonic significance 江山—绍兴断裂早古生代超铁质岩年代学、地球化学特征及其构造意义
IF 1.5 4区 地球科学 Q4 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2023-07-13 DOI: 10.1111/iar.12493
Cunzhi Wang, Zhizhong Huang, Qingbo Zhu, Guangfu Xing, Guodong Jin, Pingli Chu

The origins of early Paleozoic orogen in South China have two different models: subduction model and intra-continental model. Here we report two new identification of ~440 Ma arc-related ultramafic intrusions in Tingzifan (TZF) and Fomuting (FMT) along Jiangshan-Shaoxing fault (JSF) in South China, respectively. The Silurian ultramafic intrusions are composed of olivine pyroxenite, the SiO2, MgO and TiO2 contents of olivine pyroxenites are 39.67–41.25 wt%, 28.98–31.38 wt% and 0.23–0.51 wt%, respectively. The geochemical compositions of the olivines, clinopyroxenes and hornblendes suggest an arc-related environment for these intrusions. As for the whole-rock trace elements, the ultramafic intrusions contain low total rare earth element (REE) contents (27.59–34.26 μg/g) and high field strength elements (HFSEs), such as Nb, Zr, Hf, Ti, and are systematically enriched in large ion lithophile elements and light rare earth elements (LREEs). Trace element compositions share most features of Alaskan-type ultramafic-mafic intrusions. Isotopically, the TZF and FMT ultramafic intrusions are characterized by negative Zircons εHf(t) values (0.38–7.54). Combined with their whole-rock and mineral chemistry as well as zircon Hf isotope, we suggest that the Alaskan-type TZF and FMT pyroxenite were formed at the root of the continental arc by underplating and fractional crystallization of mafic magma which derived from subduction metasomatized mantle source. Thus, we proposed that the early Paleozoic ultramafic–mafic along Jiangshan-Shaoxing fault were most likely related to early Paleozoic subduction of the Paleo-South China Ocean between Cathaysia and Yangtze blocks, arguing that the origins of early Paleozoic orogen in the South China Block is a typical subduction-accretionary collisional-type orogenic belt rather than an intraplate belt.

华南早古生代造山带的成因有两种不同的模式:俯冲模式和陆内模式。本文报道了沿江山-绍兴断裂(JSF)在汀子湾(TZF)和富亭(FMT)分别发现的~440 Ma与弧相关的超镁铁质侵入岩。志留系超镁铁性侵入体主要由橄榄石辉石岩组成,橄榄石辉石岩的SiO2、MgO和TiO2含量分别为39.67 ~ 41.25 wt%、28.98 ~ 31.38 wt%和0.23 ~ 0.51 wt%。橄榄石、斜辉石和角闪石的地球化学组成表明,这些侵入物的环境与弧有关。在全岩微量元素方面,超镁铁质侵入体中稀土元素总含量较低(27.59 ~ 34.26 μg/g), Nb、Zr、Hf、Ti等强场强元素较为富集,大离子亲石元素和轻稀土元素较为富集。微量元素组成具有阿拉斯加型超镁基性侵入岩的大部分特征。锆石εHf(t)值为负(0.38 ~ 7.54)。结合它们的全岩和矿物化学特征以及锆石Hf同位素特征,认为阿拉斯加型TZF型和FMT型辉石岩是由俯冲交代地幔源基性岩浆的底作用和分结晶作用形成于大陆弧根部。因此,我们认为沿江山-绍兴断裂的早古生代超基性铁质极有可能与华夏和扬子地块之间的古华南洋早古生代俯冲有关,认为华南地块早古生代造山带的成因是典型的俯冲-增生碰撞型造山带,而非板内造山带。
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引用次数: 0
U–Pb and fission-track dating of Miocene hydrocarbon source rocks in the Akita Basin, Northeast Japan, and implications for the timing of paleoceanographic changes in the sea of Japan 日本秋田盆地中新世烃源岩的U-Pb和裂变径迹测年及其对日本海古海洋学变化的意义
IF 1.5 4区 地球科学 Q4 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2023-07-13 DOI: 10.1111/iar.12490
Takeshi Nakajima, Hideki Iwano, Tohru Danhara, Takafumi Hirata, Kenta Asahina, Koji U. Takahashi, Yasuaki Hanamura

Middle to Late Miocene organic-rich siliceous mudstones (Onnagawa Formation) in the Akita Basin, Northeast Japan have been an important target for both paleoceanographic studies and hydrocarbon exploration in Japan. However, the reliable age of their formation has remained poorly constrained. Here, we report new zircon U–Pb and fission-track ages of the Onnagawa Formation from a previously well-studied outcrop route in the Yashima area, central Akita Basin. The thin tuff bed in the lower Onnagawa Formation was dated at around 11.6 Ma, whereas thin tuff beds in the upper Onnagawa Formation was dated at 10.4–9.6 Ma. The new age model constrains the base of the succession as older than 15.6–13.8 Ma and the top of the succession as 8.7–8.2 Ma. The results suggest that the lowest part of the succession was deposited before the Onnagawa Stage. The new age model indicates a rapid deposition in the lower Onnagawa Stage. The new age model also clarifies a temporary decrease in the sedimentation rate during 10.9–9.4 Ma, which coincided with a hiatus or slow deposition reported from other areas along the Sea of Japan coast. The new age model also revises the timing of paleoceanographic changes, of the best hydrocarbon source horizon, and of hydrothermal activity responsible for seafloor chemoautotrophic communities in the Akita Basin. This revised timing reveals that the onset of paleoceanographic changes from oxidizing to anoxic bottom environments favorable for hydrocarbon source rock formation was closely related to the tectonic uplift of the Northeast Japan Arc at ~12 Ma, whereas the timing of hydrothermal activity was related to the following extensional tectonics at ~9 Ma. The results of this study thus shed light on hitherto unclarified relationships between tectonics, volcanism, and paleoceanographic changes in the Sea of Japan.

日本秋田盆地中-晚中新世富有机硅质泥岩(女川组)是日本古海洋学研究和油气勘探的重要对象。然而,它们形成的可靠年龄仍然没有得到很好的限制。在此,我们报告了在秋田盆地中部八岛地区一个先前研究得很好的露头路线上的新的Onnagawa组锆石U-Pb和裂变径迹年龄。下女川组薄凝灰岩层的年龄约为11.6 Ma,上女川组薄凝灰岩层的年龄约为10.4 ~ 9.6 Ma。新年龄模型约束演替的基底年龄大于15.6 ~ 13.8 Ma,演替的顶端年龄大于8.7 ~ 8.2 Ma。结果表明,演替的最低部分沉积于女川期之前。新时代模式表明女川期下部沉积迅速。新时代模型还澄清了10.9-9.4 Ma期间沉积速率的暂时下降,这与日本海沿岸其他地区报道的沉积中断或缓慢相吻合。新时代模型还修正了秋田盆地古海洋学变化、最佳烃源层和海底化学自养群落形成的热液活动的时间。修正后的时间表明,有利于烃源岩形成的氧化性底环境向缺氧性底环境转变的开始时间与~12 Ma日本东北弧的构造隆升密切相关,而热液活动的开始时间与~9 Ma以后的伸展构造活动有关。因此,这项研究的结果阐明了迄今为止尚未阐明的日本海构造、火山作用和古海洋学变化之间的关系。
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引用次数: 0
Late Cretaceous tectono-magmatism of southeast China: Evidence from Qushandao Granite in the eastern Zhejiang province 中国东南晚白垩世构造岩浆作用——来自浙东曲山岛花岗岩的证据
IF 1.5 4区 地球科学 Q4 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2023-07-10 DOI: 10.1111/iar.12494
Pingli Chu, Lang Bao, Zheng Duan, Minggang Yu, Yanhui Zhu

The Qushandao Granite, mainly composed of alkali-feldspar granite, is situated in the eastern Zhejiang province of coastal southeast China. In this paper, we present whole-rock geochemistry, zircon U–Pb geochronology, and Hf isotopes to constrain the age, magma sources, and geodynamic setting of the Qushandao Granite. LA-ICP-MS zircon U–Pb dating results revealed that the Qushandao Granite was emplaced in the Late Cretaceous (101–98 Ma). Geochemically, the Qushandao Granite exhibits relatively high silica and alkali contents, metaluminous to weakly peraluminous (A/CNK = 0.98–1.02), and low abundances of phosphorus, titanium, magnesium, and calcium. It is also characterized by enrichment in Rb, K, Th, and depletion in Nb, Ta, P, Ti, and Sr with moderately to weakly negative europium anomalies (Eu/Eu* = 0.71–0.87). Furthermore, the Qushandao Granite displays lower FeOT/MgO, 104 × Ga/Al, and Zr + Nb + Ce + Y values relative to typical A-type granites. Therefore, we classify the Qushandao Granite as calc-alkaline I-type granite based on a synthesis of geological and geochemical characteristics. The Qushandao Granite shows variable zircon Hf isotopic compositions (εHf(t) = −7.6 to +2.3) and TDM2 model ages of 1.40–0.83 Ga with a mean value of 1.17 Ga. We argue that the Qushandao Granite was most likely generated by mixing of mantle-derived mafic magma and crust-derived felsic magma in the lower crust, and that it was formed during post-collisional extension in the Late Cretaceous, related to the gradually increasing subduction angle of the Paleo-Pacific plate.

曲山岛花岗岩位于中国东南沿海浙江省东部,主要由碱长石花岗岩组成。本文利用全岩地球化学、锆石U-Pb年代学和Hf同位素对曲山岛花岗岩的年龄、岩浆来源和地球动力学背景进行了研究。LA-ICP-MS锆石U-Pb测年结果表明,曲山岛花岗岩形成于晚白垩世(101 ~ 98 Ma)。地球化学特征表明,曲山岛花岗岩硅、碱含量较高,含铝质至弱过铝质(A/CNK = 0.98 ~ 1.02),磷、钛、镁、钙丰度较低。Rb、K、Th富集,Nb、Ta、P、Ti、Sr亏缺,铕呈中至弱负异常(Eu/Eu* = 0.71-0.87)。此外,曲山岛花岗岩的FeOT/MgO、104 × Ga/Al和Zr + Nb + Ce + Y值均低于典型a型花岗岩。综合地质地球化学特征,将曲山岛花岗岩划分为钙碱性ⅰ型花岗岩。曲山岛花岗岩的锆石Hf同位素组成变化较大(εHf(t) =−7.6 ~ +2.3),TDM2模式年龄为1.40 ~ 0.83 Ga,平均值为1.17 Ga。本文认为,曲山岛花岗岩极有可能是下地壳幔源基性岩浆与壳源长英质岩浆混合形成的,形成于晚白垩世后碰撞伸展时期,与古太平洋板块俯冲角度逐渐增大有关。
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