Pub Date : 2023-11-04DOI: 10.1142/s2010135x23500236
E. V. Glazunova, L. A. Shilkina, A. S. Chekhova, A. V. Nazarenko, I. A. Verbenko, L. A. Reznichenko
The solid solutions of the (1-x)Na[Formula: see text]Bi[Formula: see text]TiO 3 -xNa[Formula: see text]K[Formula: see text]NbO 3 system were produced by the conventional ceramic technology using mechanical activation of the synthesized product. It was found that in the (1-x)Na[Formula: see text]Bi[Formula: see text]TiO 3 -xNa[Formula: see text]K[Formula: see text]NbO 3 system at room temperature, a number of morphotropic phase transitions occur: rhombohedral → cubic → tetragonal → monoclinic phases. The introduction of a small amount of Na[Formula: see text]K[Formula: see text]NbO 3 leads to an increase in the temperature stability of the dielectric properties of ceramics. A change in the relaxor properties of the solid solutions of the (1-x)Na[Formula: see text]Bi[Formula: see text]TiO 3 -xNa[Formula: see text]K[Formula: see text]NbO 3 system was shown. The increase in energy density and energy efficiency was found at additive 10[Formula: see text]mol.% of Na[Formula: see text]K[Formula: see text]NbO 3 .
{"title":"Structure and dielectric properties of (1-<i>x</i>)Na<sub>0.5</sub>Bi<sub>0.5</sub>TiO<sub>3-<i>x</i></sub>Na<sub>0.5</sub>K<sub>0.5</sub>NbO<sub>3</sub> ceramics","authors":"E. V. Glazunova, L. A. Shilkina, A. S. Chekhova, A. V. Nazarenko, I. A. Verbenko, L. A. Reznichenko","doi":"10.1142/s2010135x23500236","DOIUrl":"https://doi.org/10.1142/s2010135x23500236","url":null,"abstract":"The solid solutions of the (1-x)Na[Formula: see text]Bi[Formula: see text]TiO 3 -xNa[Formula: see text]K[Formula: see text]NbO 3 system were produced by the conventional ceramic technology using mechanical activation of the synthesized product. It was found that in the (1-x)Na[Formula: see text]Bi[Formula: see text]TiO 3 -xNa[Formula: see text]K[Formula: see text]NbO 3 system at room temperature, a number of morphotropic phase transitions occur: rhombohedral → cubic → tetragonal → monoclinic phases. The introduction of a small amount of Na[Formula: see text]K[Formula: see text]NbO 3 leads to an increase in the temperature stability of the dielectric properties of ceramics. A change in the relaxor properties of the solid solutions of the (1-x)Na[Formula: see text]Bi[Formula: see text]TiO 3 -xNa[Formula: see text]K[Formula: see text]NbO 3 system was shown. The increase in energy density and energy efficiency was found at additive 10[Formula: see text]mol.% of Na[Formula: see text]K[Formula: see text]NbO 3 .","PeriodicalId":14871,"journal":{"name":"Journal of Advanced Dielectrics","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-11-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135728105","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-11-03DOI: 10.1142/s2010135x23500248
Elena Pashnina, Dmitry Chezganov, Alla Slautina, Anton Turygin, Andrei Ushakov, Qingyuan Hu, Xin Liu, Zhuo Xu, Xiaoyong Wei, Vladimir Shur
{"title":"Domain patterning in nonpolar cut PMN–PT by focused ion beam","authors":"Elena Pashnina, Dmitry Chezganov, Alla Slautina, Anton Turygin, Andrei Ushakov, Qingyuan Hu, Xin Liu, Zhuo Xu, Xiaoyong Wei, Vladimir Shur","doi":"10.1142/s2010135x23500248","DOIUrl":"https://doi.org/10.1142/s2010135x23500248","url":null,"abstract":"","PeriodicalId":14871,"journal":{"name":"Journal of Advanced Dielectrics","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-11-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135868270","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"A Series of Formic Acid MOFs/Polylactic Acid Blending Composites with the Improved Dielectric Performance in Co(II) Systems","authors":"Zhuting Hao, Danhong Yang, Zhicheng Zhang, Qin-Xiang Jia, Wen Zhang","doi":"10.1142/s2010135x23400040","DOIUrl":"https://doi.org/10.1142/s2010135x23400040","url":null,"abstract":"","PeriodicalId":14871,"journal":{"name":"Journal of Advanced Dielectrics","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135222033","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-10-17DOI: 10.1142/s2010135x23500200
Evgeniy Savelyev, Andrey Akhmatkhanov, Boris Slautin, Herve Tronche, Florent Doutre, Tommaso Lunghi, Pascal Baldi, Vladimir Shur
The paper presents the results of an experimental study of the local polarization reversal and creation of domains by a biased tip of scanning probe microscope (SPM) in lithium niobate single crystals of congruent composition with a surface layer modified by soft proton exchange (SPE). The depth dependence of H[Formula: see text] ions concentration in the SPE-modified layer measured by confocal Raman microscopy demonstrates a sufficient composition gradient. The creation of isolated domains and stripe domain structures has been done by two switching modes: (1) point switching by field application in separated points and (2) line scanning switching by motion of the biased tip being in contact with the sample surface. For point switching for pulse durations less than 10[Formula: see text]s, the logarithmic dependence of the domain diameter on the pulse duration was observed. The change of the dependence to a linear one for pulse duration above 10[Formula: see text]s has been attributed to the transition from the stochastic step generation at the domain wall to the deterministic one at the domain vertexes. The periodical structure of stripe domains was created in SPE CLN planar waveguides by scanning at elevated temperature. The revealed switching regime suppresses electrostatic interaction of neighboring domains and leads to a significant improvement of the domain structure regularity. The creation of the stable periodical domain structure with submicron periods in SPE CLN planar waveguides was demonstrated.
{"title":"Creation of periodical domain structure by local polarization reversal in planar waveguide produced by soft proton exchange in LiNbO<sub>3</sub>","authors":"Evgeniy Savelyev, Andrey Akhmatkhanov, Boris Slautin, Herve Tronche, Florent Doutre, Tommaso Lunghi, Pascal Baldi, Vladimir Shur","doi":"10.1142/s2010135x23500200","DOIUrl":"https://doi.org/10.1142/s2010135x23500200","url":null,"abstract":"The paper presents the results of an experimental study of the local polarization reversal and creation of domains by a biased tip of scanning probe microscope (SPM) in lithium niobate single crystals of congruent composition with a surface layer modified by soft proton exchange (SPE). The depth dependence of H[Formula: see text] ions concentration in the SPE-modified layer measured by confocal Raman microscopy demonstrates a sufficient composition gradient. The creation of isolated domains and stripe domain structures has been done by two switching modes: (1) point switching by field application in separated points and (2) line scanning switching by motion of the biased tip being in contact with the sample surface. For point switching for pulse durations less than 10[Formula: see text]s, the logarithmic dependence of the domain diameter on the pulse duration was observed. The change of the dependence to a linear one for pulse duration above 10[Formula: see text]s has been attributed to the transition from the stochastic step generation at the domain wall to the deterministic one at the domain vertexes. The periodical structure of stripe domains was created in SPE CLN planar waveguides by scanning at elevated temperature. The revealed switching regime suppresses electrostatic interaction of neighboring domains and leads to a significant improvement of the domain structure regularity. The creation of the stable periodical domain structure with submicron periods in SPE CLN planar waveguides was demonstrated.","PeriodicalId":14871,"journal":{"name":"Journal of Advanced Dielectrics","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-10-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135944967","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-10-17DOI: 10.1142/s2010135x23400027
Yu Song, Xiaoming Shi, Dan Li, Jing Wang, Houbing Huang
Ferroelectric materials possessing exceptional piezoelectric attributes have garnered widespread utilization in various applications. Solid solution systems improve piezoelectric properties through multiphase mixing, but the methodologies for effective design remain wanting. Based on the Landau–Devonshire theory, we propose a theoretical design method. Binary materials with morphotropic phase boundary (MPB) compositions are added with new elements to increase the free energy of the original stabilized phase and lower the energy barrier (EB). Flatter EBsand higher piezoelectric coefficients are found at the phase boundaries of the ternary system. By calculating the phase diagram, piezoelectric coefficient, dielectric constant, polarization, and EBs, we reveal the origin of the highest piezoelectric coefficient at the phase boundaries. This study underscores the importance of the EBs for polarization rotation in characterizing piezoelectric properties and proposes a theoretical design method for exploring materials with high piezoelectric coefficients.
{"title":"Designing high piezoelectric properties at the BaTiO<sub>3</sub>-PbZrO<sub>3</sub>-PbTiO<sub>3</sub> phase boundary by Landau-Devonshire theory","authors":"Yu Song, Xiaoming Shi, Dan Li, Jing Wang, Houbing Huang","doi":"10.1142/s2010135x23400027","DOIUrl":"https://doi.org/10.1142/s2010135x23400027","url":null,"abstract":"Ferroelectric materials possessing exceptional piezoelectric attributes have garnered widespread utilization in various applications. Solid solution systems improve piezoelectric properties through multiphase mixing, but the methodologies for effective design remain wanting. Based on the Landau–Devonshire theory, we propose a theoretical design method. Binary materials with morphotropic phase boundary (MPB) compositions are added with new elements to increase the free energy of the original stabilized phase and lower the energy barrier (EB). Flatter EBsand higher piezoelectric coefficients are found at the phase boundaries of the ternary system. By calculating the phase diagram, piezoelectric coefficient, dielectric constant, polarization, and EBs, we reveal the origin of the highest piezoelectric coefficient at the phase boundaries. This study underscores the importance of the EBs for polarization rotation in characterizing piezoelectric properties and proposes a theoretical design method for exploring materials with high piezoelectric coefficients.","PeriodicalId":14871,"journal":{"name":"Journal of Advanced Dielectrics","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-10-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135944964","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-10-13DOI: 10.1142/s2010135x23500224
Binzhi Liu, Anand P. S. Gaur, Jun Cui, Xiaoli Tan
{"title":"Substitution of Pb with (Li<sub>1/2</sub>Bi<sub>1/2</sub>) in PbZrO<sub>3</sub>-Based Antiferroelectric Ceramics","authors":"Binzhi Liu, Anand P. S. Gaur, Jun Cui, Xiaoli Tan","doi":"10.1142/s2010135x23500224","DOIUrl":"https://doi.org/10.1142/s2010135x23500224","url":null,"abstract":"","PeriodicalId":14871,"journal":{"name":"Journal of Advanced Dielectrics","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-10-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135918753","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-09-30DOI: 10.1142/s2010135x23500194
A. Pelaiz-Barranco, Y. Perez-Martin, O. Garcia-Zaldivar, Y. Gagou
(Pb[Formula: see text]Ba[Formula: see text])[(Zn[Formula: see text]Nb[Formula: see text])[Formula: see text]Ti[Formula: see text]]O 3 relaxor-type ferroelectric ceramics was obtained via classical solid-state reaction. The hysteresis loop results were discussed in the frame of ergodicity criterium around the characteristic ferroelectric relaxor freezing temperature. Slimer hysteresis loops were observed below the freezing temperature reflecting an ergodic relaxor behavior. Above this temperature, estimated around 223[Formula: see text]K for the studied system, larger and unsaturated like ferroelectric hysteresis loops were observed. This temperature also coincides with the slope change on maximum polarization and inflection point of remnant polarization curves. Energy storage, energy loss and efficiency values were determined in a wide temperature range. While the recoverable energy density shows relatively low values (0.23[Formula: see text]J/cm 3 ), there are interesting behaviors for this parameter and for the efficiency, since the two physical quantities increase versus temperature and the efficiency even reaches the value of 97%.
{"title":"Energy storage and relaxor behavior in (Pb<sub>0.8</sub>Ba<sub>0.2</sub>)[(Zn<sub>1/3</sub>Nb<sub>2/3</sub>)<sub>0.7</sub>Ti<sub>0.3</sub>]O<sub>3</sub> ferroelectric ceramic","authors":"A. Pelaiz-Barranco, Y. Perez-Martin, O. Garcia-Zaldivar, Y. Gagou","doi":"10.1142/s2010135x23500194","DOIUrl":"https://doi.org/10.1142/s2010135x23500194","url":null,"abstract":"(Pb[Formula: see text]Ba[Formula: see text])[(Zn[Formula: see text]Nb[Formula: see text])[Formula: see text]Ti[Formula: see text]]O 3 relaxor-type ferroelectric ceramics was obtained via classical solid-state reaction. The hysteresis loop results were discussed in the frame of ergodicity criterium around the characteristic ferroelectric relaxor freezing temperature. Slimer hysteresis loops were observed below the freezing temperature reflecting an ergodic relaxor behavior. Above this temperature, estimated around 223[Formula: see text]K for the studied system, larger and unsaturated like ferroelectric hysteresis loops were observed. This temperature also coincides with the slope change on maximum polarization and inflection point of remnant polarization curves. Energy storage, energy loss and efficiency values were determined in a wide temperature range. While the recoverable energy density shows relatively low values (0.23[Formula: see text]J/cm 3 ), there are interesting behaviors for this parameter and for the efficiency, since the two physical quantities increase versus temperature and the efficiency even reaches the value of 97%.","PeriodicalId":14871,"journal":{"name":"Journal of Advanced Dielectrics","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136271675","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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