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Energy analysis of mechanical alloying of molybdenum disilicide in a new-type high energy vibrating ball mill 新型高能振动球磨机机械合金化二硅化钼的能量分析
Pub Date : 2008-09-01 Epub Date: 2008-09-17 DOI: 10.1016/S1006-1266(08)60093-0
FENG Pei-zhong , WANG Xiao-hong , QIANG Ying-huai , QU Xuan-hui

In order to understand the fundamentals of a high energy vibrating type milling process, the energy transfer during mechanical alloying of molybdenum disilicide is investigated based on the Magini-Iasonna energy transfer method, amended by Murty. The efficiency factor and total energy of milling are calculated. MoSi2 synthesized by a mechanically induced self-propagating reaction has also been studied according to different milling parameters, such as the number of balls and the ball to powder weight ratio. The results indicate that the efficiency factor is between 1.944 and 8.507 J/(g·s). A total milling energy of about 19.38-26.47 kJ/g is found to be necessary for the mechanically induced self-propagating reaction of a Mo:2Si powder mixture. The efficiency of milling energy transfer is about 3.3%-4.5%. The experiment and modeling show that the optimum condition for mechanical alloying is a half full vial of balls.

为了了解高能振动型铣削过程的基本原理,基于Murty修正的Magini-Iasonna能量传递方法,研究了二硅化钼机械合金化过程中的能量传递。计算了铣削效率系数和铣削总能量。对机械诱导自扩散反应合成的MoSi2进行了研究,并根据不同的研磨参数,如球数和球粉重量比进行了研究。结果表明,效率因子在1.944 ~ 8.507 J/(g·s)之间。Mo:2Si粉末混合物的机械诱导自扩散反应所需的总磨矿能量约为19.38 ~ 26.47 kJ/g。铣削能量传递效率约为3.3% ~ 4.5%。实验和模拟表明,机械合金化的最佳条件是半满瓶的球。
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引用次数: 7
Kinetics and mechanism of the adsorption of methylene blue onto ACFs ACFs吸附亚甲基蓝的动力学及机理
Pub Date : 2008-09-01 Epub Date: 2008-09-17 DOI: 10.1016/S1006-1266(08)60090-5
YANG Zhi-yuan

The kinetics and mechanism of methylene blue (MB) adsorption onto activated carbon fibers (ACFs) have been studied. The effects of various experimental parameters, such as the initial MB concentration and the ACF mass, on the adsorption rate were investigated. Equilibrium data were fit well by a Freundlich isotherm equation. Adsorption measurements show that the process is very fast. The adsorption data were modeled using first- and second-order kinetic equations and intra-particle diffusion models. It was found that the first-order kinetic equation could best describe the adsorption kinetics. The adsorption process was found to be complex and controlled by both surface and pore diffusion with surface diffusion at the earlier stages, followed by pore diffusion at the later stages. The thermodynamic parameters ΔG0, ΔS0 and ΔH0, have been calculated. The thermodynamics of the MB-ACF system indicate that the adsorption process is spontaneous.

研究了活性炭纤维(ACFs)吸附亚甲基蓝(MB)的动力学和机理。考察了初始MB浓度和ACF质量等实验参数对吸附速率的影响。平衡数据用Freundlich等温线方程拟合得很好。吸附测量表明,该过程非常快。采用一、二级动力学方程和颗粒内扩散模型对吸附数据进行建模。发现一级动力学方程最能描述吸附动力学。吸附过程复杂,受表面扩散和孔扩散共同控制,前期为表面扩散,后期为孔扩散。计算了热力学参数ΔG0, ΔS0和ΔH0。MB-ACF体系的热力学分析表明,吸附过程是自发的。
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引用次数: 24
Characteristics of the main polluting trace elements in the water environment of mining subsidence pools 开采沉陷池水环境中主要污染微量元素特征
Pub Date : 2008-09-01 Epub Date: 2008-09-17 DOI: 10.1016/S1006-1266(08)60076-0
YAO En-qin , GUI He-rong

Mining subsidence pools are water bodies formed by soil subsidence near mines. We studied the impact the surrounding coal production activities and power plants have on these waters by measuring the concentrations of harmful trace elements in these waters. The concentration of the four elements F, Hg, Se and As increased by 0.92%, 0.78%, 0.70% and 0.81%, respectively, in the Datong mining subsidence pool from November 2004 to November 2006. The four elements increased by 1.58%, 1.23%, 1.08% and 0.92%, respectively, in the Xie'er mining subsidence pool and 1.16%, 1.06%, 1.02% and 1.01%, respectively, in the Pansan mining subsidence pool over the same time period. The absolute levels of F, Hg, Se and As in the pool are related to the background levels of the elements. A close relationship between nearby coal mines and power plants and increasing levels of the measured elements is noted.

采矿沉陷池是矿山附近土壤沉陷形成的水体。我们通过测量这些水域中有害微量元素的浓度,研究了周围煤炭生产活动和发电厂对这些水域的影响。2004年11月至2006年11月,大同矿区沉陷池中F、Hg、Se和As四种元素的浓度分别上升了0.92%、0.78%、0.70%和0.81%。谢二矿沉陷池4个要素同期分别增长1.58%、1.23%、1.08%和0.92%,盘三矿沉陷池4个要素同期分别增长1.16%、1.06%、1.02%和1.01%。池中F、Hg、Se和As的绝对含量与背景含量有关。报告指出,附近的煤矿和发电厂与所测元素水平的增加有密切关系。
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引用次数: 4
Analysis of underground fires in Polish hard coal mines 波兰坚硬煤矿地下火灾分析
Pub Date : 2008-09-01 Epub Date: 2008-09-17 DOI: 10.1016/S1006-1266(08)60070-X
WACHOWICZ Jan

In the period of the first twenty years after World War II the number of fires in Polish hard coal mines reached annually the value of several thousands of cases. About 80% of fires constituted spontaneous fires. Investigations into the development of new methods of fire hazard prediction and implementation of new methods and means of fire prevention as well as the introduction of prohibition concerning the use of products manufactured of combustible organic materials in underground mine workings reduced considerably the hazard of underground fire rise. The worked out at the Central Mining Institute (GIG) new method of underground fire prediction allows the correct selection of fire prevention means. The introduction into common use of fire-resistant conveyor belts, the main factor giving rise to spontaneous fires, and methods of assessment of their fire resistance eliminated practically the fire hazard. These activities contributed in an efficient way to the reduction of the number of underground fires to a satisfactory level.

在第二次世界大战后的头二十年里,波兰硬煤矿的火灾数量每年达到数千起。约80%的火灾为自燃。研究开发火灾危险预测新方法,实施新的防火方法和手段,以及禁止在地下矿山作业中使用可燃性有机材料制造的产品,大大减少了地下火灾的危险。中央矿业研究所(GIG)制定的地下火灾预测新方法可以正确选择防火手段。防火传送带的普遍使用,引起自燃火灾的主要因素,以及评估其防火性的方法,实际上消除了火灾危险。这些活动有效地将地下火灾的次数减少到令人满意的程度。
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引用次数: 35
An OGC standard-oriented architecture for distributed coal mine map services 面向OGC标准的分布式煤矿地图服务体系结构
Pub Date : 2008-09-01 Epub Date: 2008-09-17 DOI: 10.1016/S1006-1266(08)60080-2
SONG Xian-feng , RUI Xiao-ping , HOU Wei , TAN Hai-qiao

GIS- or CAD-based technology has been widely used for cartographic maps in coal mines, but structural gaps between such maps make it difficult to provide an integrated map service, for any specific purpose, at higher levels. There is no uniform platform that can be used to manage all involved maps. The main reason for this is that datasets are submitted by individual coal mines using their individual, diverse software. No consistent model is used within the software for data abstraction and symbolization. This paper first reviews all the essential specifications concerning OGC (Open Geospatial Consortium) interoperability. Then an OGC standard-oriented architecture is proposed to provide distributed coal mine map services. Within this new architecture the management of spatial data archives, and the integration of coal mine maps, are achieved through the interfaces of geospatial services. Finally an open source geospatial approach is suggested to implement the proposed scheme. A case study of the Huaibei Coal Group is used to demonstrate the proposal.

以地理信息系统或计算机辅助设计为基础的技术已广泛用于煤矿的制图,但这些地图之间的结构性差距使得难以在更高层次上为任何具体目的提供综合地图服务。没有一个统一的平台可以用来管理所有相关的地图。造成这种情况的主要原因是,数据集是由各个煤矿使用各自不同的软件提交的。软件中没有使用一致的模型进行数据抽象和符号化。本文首先回顾了有关OGC(开放地理空间联盟)互操作性的所有基本规范。然后提出了一种面向OGC标准的分布式煤矿地图服务体系结构。在该体系结构中,通过地理空间服务接口实现了空间数据档案管理和煤矿地图集成。最后,提出了一种开源的地理空间方法来实现所提出的方案。以淮北煤业集团为例进行了实证分析。
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引用次数: 12
Comparison between open phase fault of arc suppression coil and single phase to earth fault in coal mine distribution network 煤矿配电网消弧线圈断相故障与单相接地故障的比较
Pub Date : 2008-09-01 Epub Date: 2008-09-17 DOI: 10.1016/S1006-1266(08)60077-2
LI Xiao-bo, WANG Chong-lin

When, in a coal mine distribution network whose neutral point is grounded by an arc suppression coil (ASC), a fault occurs in the ASC, compensation cannot be properly realized. Furthermore, it can damage the safe and reliable run of the network. We first introduce a three-phase five-column arc suppression coil (TPFCASC) and discuss its autotracking compensation theory. Then we compare the single phase to ground fault of the coal mine distribution network with an open phase fault at the TPFCASC using the Thévenin theory, the symmetrical-component method and the complex sequence network respectively. The results show that, in both types of faults, zero-sequence voltage of the network will appear and the maximum magnitude of this zero-sequence voltage is different in both faults. Based on this situation, a protection for the open phase fault at the TPFCASC should be established.

当煤矿配电网中性点由消弧线圈接地时,消弧线圈发生故障,无法正常实现补偿。此外,它还会破坏网络的安全可靠运行。首先介绍了一种三相五柱消弧线圈(TPFCASC),并讨论了其自跟踪补偿原理。然后分别运用thamesin理论、对称分量法和复杂序列网络对煤矿配电网单相接地故障和TPFCASC断相故障进行了比较。结果表明,两种故障均会出现电网零序电压,且该零序电压最大值在两种故障中不同。基于这种情况,应该建立对TPFCASC断相故障的保护。
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引用次数: 7
Hot-corrosion mechanism of Ni-Cr coatings at 650°C under different simulated corrosion conditions 650℃不同模拟腐蚀条件下Ni-Cr涂层的热腐蚀机理
Pub Date : 2008-09-01 Epub Date: 2008-09-17 DOI: 10.1016/S1006-1266(08)60092-9
OU Xue-mei, SUN Zhi, SUN Min, ZOU Duan-lian

The oxidation and lower temperature hot corrosion (LTHC) processes occurring on the surface of Ni-Cr coatings produced by high velocity arc spray (HVAS) were studied. Several different conditions were studied under simulated boiler conditions at 650°C. The protection effect of an Al coating deposited by HVAS onto the Ni-Cr coating was also investigated. Microscope, X-ray diffraction and corrosion rate curves have been used to analyze corrosion mechanisms. The experimental results show that: 1) The oxidation rates are almost superposed in both air (no SO3) and in simulated coal-fired gas (containing SO3) as long as no salt was present on the surface. These rate curves show a logarithmic relationship. 2) When the surface is coated with salt (75%K2SO3 + 25%Na2SO3) the rate curve for LTHC of the Ni-Cr coated surface shows a parabolic shape in the simulated coal-fire flue gas. In air only the oxidation reaction takes place, the second type of LTHC was not seen. And 3) the Al over coating on the Ni-Cr enhances resistance to LTHC because an inter-metallic compound, Al3Ni2, forms at the Al/Ni-Cr interface and because of the increase in coating thickness.

研究了高速电弧喷涂(HVAS)制备的镍铬涂层表面的氧化和低温热腐蚀(LTHC)过程。在650℃的模拟锅炉工况下,研究了几种不同的工况。研究了HVAS沉积的Al涂层对Ni-Cr涂层的保护作用。利用显微镜、x射线衍射和腐蚀速率曲线分析了腐蚀机理。实验结果表明:1)在空气(无SO3)和模拟燃煤气体(含SO3)中,只要表面不存在盐,氧化速率几乎重合。这些速率曲线呈对数关系。2)在模拟燃煤烟气中,表面涂覆盐(75%K2SO3 + 25%Na2SO3)后,Ni-Cr表面的LTHC速率曲线呈抛物线状。在空气中只发生氧化反应,第二类LTHC未见。3)由于Al/Ni-Cr界面上形成了金属间化合物Al3Ni2,并且涂层厚度增加,从而增强了Ni-Cr的抗LTHC性能。
{"title":"Hot-corrosion mechanism of Ni-Cr coatings at 650°C under different simulated corrosion conditions","authors":"OU Xue-mei,&nbsp;SUN Zhi,&nbsp;SUN Min,&nbsp;ZOU Duan-lian","doi":"10.1016/S1006-1266(08)60092-9","DOIUrl":"10.1016/S1006-1266(08)60092-9","url":null,"abstract":"<div><p>The oxidation and lower temperature hot corrosion (LTHC) processes occurring on the surface of Ni-Cr coatings produced by high velocity arc spray (HVAS) were studied. Several different conditions were studied under simulated boiler conditions at 650°C. The protection effect of an Al coating deposited by HVAS onto the Ni-Cr coating was also investigated. Microscope, X-ray diffraction and corrosion rate curves have been used to analyze corrosion mechanisms. The experimental results show that: 1) The oxidation rates are almost superposed in both air (no SO<sub>3</sub>) and in simulated coal-fired gas (containing SO<sub>3</sub>) as long as no salt was present on the surface. These rate curves show a logarithmic relationship. 2) When the surface is coated with salt (75%K<sub>2</sub>SO<sub>3</sub> + 25%Na<sub>2</sub>SO<sub>3</sub>) the rate curve for LTHC of the Ni-Cr coated surface shows a parabolic shape in the simulated coal-fire flue gas. In air only the oxidation reaction takes place, the second type of LTHC was not seen. And 3) the Al over coating on the Ni-Cr enhances resistance to LTHC because an inter-metallic compound, Al<sub>3</sub>Ni<sub>2</sub>, forms at the Al/Ni-Cr interface and because of the increase in coating thickness.</p></div>","PeriodicalId":15315,"journal":{"name":"Journal of China University of Mining and Technology","volume":"18 3","pages":"Pages 444-448"},"PeriodicalIF":0.0,"publicationDate":"2008-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S1006-1266(08)60092-9","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80284851","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 19
Mechanism of CO2 enhanced CBM recovery in China: a review 中国CO2促进煤层气开采的机理研究进展
Pub Date : 2008-09-01 Epub Date: 2008-09-17 DOI: 10.1016/S1006-1266(08)60085-1
QIN Yong

Permeability of coal reservoirs in China is in general low. Injection of CO2 into coal seams is one of the potential approaches for enhancing coalbed methane (CBM) production. The feasibility of this technology has been investigated in China since the 1990s. Advances in mechanism of CO2 enhanced CBM recovery (CO2-ECBM) in China are reviewed in light of certain aspects, such as the competitive multi-component gas adsorption, sorption-induced coal swelling/shrinkage and its potential effect on CBM production and numerical simulation for CO2-ECBM recovery. Newer investigations for improving the technology are discussed. It is suggested that a comprehensive feasibility demonstration in terms of geology, technology, economics and environment-carrying capacity is necessary for a successful application of the technology for CBM recovery in China. The demonstration should be carried out after more investigations into such facets as the control of coal components and structure to a competitive multi-component-gas adsorption, the behavior and essence of supercritical adsorption by coal of gas, environmental and safe feasibility of coal mining after CO2 injection and more extensive pilot tests for CO2-ECBM recovery.

中国煤储层渗透率普遍较低。煤层注二氧化碳是提高煤层气产量的潜在途径之一。自20世纪90年代以来,中国已对该技术的可行性进行了研究。从多组分气体的竞争性吸附、煤的溶胀收缩及其对煤层气产量的潜在影响、CO2- ecbm开采的数值模拟等方面综述了国内CO2- ecbm开采机理的研究进展。讨论了改进工艺的新研究。建议从地质、技术、经济和环境承载能力等方面进行综合可行性论证,使煤层气开采技术在中国成功应用。在对煤的组分和结构对多组分气体竞争性吸附的控制、煤对气体的超临界吸附行为和本质、注入CO2后采煤的环境和安全可行性以及更广泛的CO2- ecbm回收中试试验等方面进行更多的研究之后,才能进行论证。
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引用次数: 25
Fault diagnosis of a mine hoist using PCA and SVM techniques 基于主成分分析和支持向量机的矿井提升机故障诊断
Pub Date : 2008-09-01 Epub Date: 2008-09-17 DOI: 10.1016/S1006-1266(08)60069-3
CHANG Yan-wei , WANG Yao-cai , LIU Tao , WANG Zhi-jie

A new method based on principal component analysis (PCA) and support vector machines (SVMs) is proposed for fault diagnosis of mine hoists. PCA is used to extract the principal features associated with the gearbox. Then, with the irrelevant gearbox variables removed, the remaining gearbox, the hydraulic system and the wire rope parameters were used as input to a multi-class SVM. The SVM is first trained by using the one class-based multi-class optimization algorithm and it is then applied to fault identification. Comparison of various methods showed the PCA-SVM method successfully removed redundancy to solve the dimensionality curse. These results show that the algorithm using the RBF kernel function for the SVM had the best classification properties.

提出一种基于主成分分析(PCA)和支持向量机(svm)的矿井提升机故障诊断方法。主成分分析用于提取与齿轮箱相关的主要特征。然后,剔除不相关的齿轮箱变量,将剩余的齿轮箱、液压系统和钢丝绳参数作为多类支持向量机的输入。首先使用基于一类的多类优化算法对支持向量机进行训练,然后将其应用于故障识别。各种方法的比较表明,PCA-SVM方法成功地消除了冗余,解决了维数诅咒问题。结果表明,采用RBF核函数作为支持向量机的算法具有最好的分类性能。
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引用次数: 45
Numerical simulation analysis by solid-liquid coupling with 3DEC of dynamic water crannies in overlying strata 上覆岩层动水裂隙固液耦合3DEC数值模拟分析
Pub Date : 2008-09-01 Epub Date: 2008-09-17 DOI: 10.1016/S1006-1266(08)60073-5
MA Li-qiang , ZHANG Dong-sheng , JING Sheng-guo , ZHANG Wei , FAN Gang-wei

To solve the problem of water loss during mining of shallow, buried coal seams, we have first analyzed the mechanism and suitability of solid-liquid coupling, i.e., we used the FLUID-MECHANICS system of 3-Dimensional Distinct Element Code (3DEC) in simulating dynamic water crannies in overlying strata, under mining conditions of a large longwall coalface. Next the dynamic initiation of a water cranny, its propagation and close phases were studied with 3DEC, along with the overlying strata breakage and recombination as the mining space of the shallow, buried coal seam increased. Combined with the change in the stress and displacement fields, the distribution features of the mining cranny were systematically studied. The effect of regularities and their effective measures of local filling and mine slicing technology in controlling mine crannies were investigated and the potential danger areas of water loss identified. Our results can be applied to decrease water loss during the exploitation of shallow, buried coal seams with a thin bedrock. The results also prove that 3DEC is a credible numerical analytical method to predict initiations of dynamic water crannies, their propagation, their closure phases and other concomitant hazards.

为了解决浅埋煤层开采过程中的失水问题,首先分析了固液耦合的机理及其适用性,即利用三维离散元程序(3DEC)流体力学系统模拟了大型长壁工作面开采条件下上覆岩层的动态水裂隙。利用3DEC研究了随着浅埋煤层开采空间的增大,水裂隙的动态起裂、扩展和闭合阶段以及上覆岩层的破碎和重组过程。结合应力场和位移场的变化,系统地研究了采动裂隙的分布特征。研究了局部充填和分层开采技术在控制矿山裂隙中的规律作用及其有效措施,确定了矿区失水的潜在危险区。研究结果可应用于薄基岩浅埋煤层开采过程中减少水分损失。结果也证明了3DEC是一种可靠的数值分析方法,可用于预测动态水裂隙的起裂、扩展、闭合阶段及其他伴生危害。
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引用次数: 13
期刊
Journal of China University of Mining and Technology
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