Pub Date : 2025-08-05DOI: 10.1080/00958972.2025.2539945
Isaac S Schomberg-Sanchez, Wilmar A Janusz, Christopher M Lemon
Dipyrrin has proven to be a versatile ligand platform for metals across the periodic table. Since much of the coordination chemistry has focused on transition metals, main-group dipyrrin chemistry has been underexplored, particularly in the case of heavy p-block elements. Boron dipyrrin complexes (also known as BODIPY) were initially reported in 1968, yet the first well-characterized example of a heavy p-block dipyrrin complex was in 2006. This nascent area of research has undergone a significant surge, where nearly half of the reports in this field have been published since 2019. Given this renewed interest and rapid development, we provide a focused review on heavy p-block dipyrrin complexes, describing the synthesis, structure, and spectroscopy of these molecules. One significant aspect of these complexes is their optical properties, which access red and near-infrared wavelengths with high quantum yields. While these main-group dipyrrins have been used as catalysts, they have also been leveraged for a variety of biological applications including photodynamic therapy, tumor imaging, and cytotoxic drugs. With the advent of synthetic methods for these novel p-block complexes, dipyrrins can begin to interface with recent advances and applications of main-group chemistry, potentially offering advantages over other ligand platforms.
{"title":"Beyond BODIPY: dipyrrin complexes of P-block elements.","authors":"Isaac S Schomberg-Sanchez, Wilmar A Janusz, Christopher M Lemon","doi":"10.1080/00958972.2025.2539945","DOIUrl":"10.1080/00958972.2025.2539945","url":null,"abstract":"<p><p>Dipyrrin has proven to be a versatile ligand platform for metals across the periodic table. Since much of the coordination chemistry has focused on transition metals, main-group dipyrrin chemistry has been underexplored, particularly in the case of heavy p-block elements. Boron dipyrrin complexes (also known as BODIPY) were initially reported in 1968, yet the first well-characterized example of a heavy p-block dipyrrin complex was in 2006. This nascent area of research has undergone a significant surge, where nearly half of the reports in this field have been published since 2019. Given this renewed interest and rapid development, we provide a focused review on heavy p-block dipyrrin complexes, describing the synthesis, structure, and spectroscopy of these molecules. One significant aspect of these complexes is their optical properties, which access red and near-infrared wavelengths with high quantum yields. While these main-group dipyrrins have been used as catalysts, they have also been leveraged for a variety of biological applications including photodynamic therapy, tumor imaging, and cytotoxic drugs. With the advent of synthetic methods for these novel p-block complexes, dipyrrins can begin to interface with recent advances and applications of main-group chemistry, potentially offering advantages over other ligand platforms.</p>","PeriodicalId":15421,"journal":{"name":"Journal of Coordination Chemistry","volume":" ","pages":""},"PeriodicalIF":2.1,"publicationDate":"2025-08-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12396737/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144955852","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-01-10eCollection Date: 2025-01-01DOI: 10.1080/00958972.2024.2448520
Zaskia Bezuidenhout, Andreas Roodt
Bis-rhodium-mu-chlorido dinuclear complexes with natural occurring limonene-type enantiomeric diene nucleophiles, (S)- and (R)-carvone [SCar and RCar], are presented and their single crystal structures reported. Utilizing the diolefinic bonds of the carvones, mu-[RhI(SCar)Cl]2 (IA/B) and mu-[RhI(RCar)Cl]2 (IIA/B) were obtained in ca. 80% yields in clean reactions with reactant RhCl3(H2O)x. The "structured" chiral nanomaterials (IA/B and IIA/B>1.1 nm) crystallize as two independent, dinuclear chiral molecules Syn-mu-[RhI(SCar)Cl]2 (IA), Anti-mu-[RhI(SCar)Cl]2 (IB), and Syn-mu-[RhI(RCar)Cl]2 (IIA, Anti-mu-[RhI(RCar)Cl]2 (IIB), respectively (based on the relative orientation of the carvone ring, oxo and methyl groups). Principal differences between the IA/IIAvsIB/IIB complexes in the solid state include the relative orientation of the two carvones, inducing a significant distortion in the µ2-Rh2Cl2 core, with the dihedral angles of 49.7(1)°/49.73(6)° in IA/IIA (Syn-mu geometry), versus 23.8(1)°/24.00(6)° in IB/IIB (Anti-mu geometry), respectively. The presence of the two structurally independent complexes in the solid state is also inferred from 1H NMR spectra.
{"title":"In pursuit of natural occurring chiral dienes {(R/S)-carvone} as bidentate ligands for coordination to rhodium(I).","authors":"Zaskia Bezuidenhout, Andreas Roodt","doi":"10.1080/00958972.2024.2448520","DOIUrl":"10.1080/00958972.2024.2448520","url":null,"abstract":"<p><p>Bis-rhodium-<i>mu</i>-chlorido dinuclear complexes with natural occurring limonene-type enantiomeric diene nucleophiles, (S)- and (R)-carvone [<b>S</b>Car and <b>R</b>Car], are presented and their single crystal structures reported. Utilizing the diolefinic bonds of the carvones, <i>mu</i>-[Rh<sup>I</sup>(<b>S</b>Car)Cl]<sub>2</sub> (<b>IA/B</b>) and <i>mu</i>-[Rh<sup>I</sup>(<b>R</b>Car)Cl]<sub>2</sub> (<b>IIA/B</b>) were obtained in ca. 80% yields in clean reactions with reactant RhCl<sub>3</sub>(H<sub>2</sub>O)<sub>x</sub>. The \"structured\" chiral nanomaterials (<b>IA/B</b> and <b>IIA/<i>B</i> </b>><b> </b>1.1 nm) crystallize as two independent, dinuclear chiral molecules <i>Syn-mu</i>-[Rh<sup>I</sup>(<b>S</b>Car)Cl]<sub>2</sub> (<b>IA</b>), <i>Anti-mu</i>-[Rh<sup>I</sup>(<b>S</b>Car)Cl]<sub>2</sub> (<b>IB</b>), and <i>Syn-mu</i>-[Rh<sup>I</sup>(<b>R</b>Car)Cl]<sub>2</sub> (<b>IIA</b>, <i>Anti-mu</i>-[Rh<sup>I</sup>(<b>R</b>Car)Cl]<sub>2</sub> (<b>IIB</b>), respectively (based on the relative orientation of the carvone ring, oxo and methyl groups). Principal differences between the <b>IA/IIA</b> <i>vs</i> <b>IB/IIB</b> complexes in the solid state include the relative orientation of the two carvones, inducing a significant distortion in the <i>µ</i> <sup>2</sup>-Rh<sub>2</sub>Cl<sub>2</sub> core, with the dihedral angles of 49.7(1)°/49.73(6)° in <b>IA/IIA</b> (<i>Syn-mu</i> geometry), versus 23.8(1)°/24.00(6)° in <b>IB/IIB</b> (<i>Anti-mu</i> geometry), respectively. The presence of the two structurally independent complexes in the solid state is also inferred from <sup>1</sup>H NMR spectra.</p>","PeriodicalId":15421,"journal":{"name":"Journal of Coordination Chemistry","volume":"78 1-3","pages":"208-224"},"PeriodicalIF":2.2,"publicationDate":"2025-01-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11854040/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143515779","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-01-01Epub Date: 2025-02-03DOI: 10.1080/00958972.2025.2453062
Katherine J Smith, Timothy M Schwartz, Hannah M Johnston, David M Freire, Kristóf Póta, Kayla N Green
The metal binding properties of macrocyclic small molecules is a key property that drives what applications for which these ligands can be used. Pyridine modified Py2N2 pyridinophane small molecules are a new class of macrocyclic small molecules, whose properties have not been explored. As a result, Zn(II) metal binding of a library of six pyridine modified Py2N2 complexes are reported here. These results include 1H NMR, log βZn(II), and X-ray diffraction, which are compared to PyN3 congeners to show that the differences in each scaffold yield markedly different metal binding properties that can be exploited in future applications.
{"title":"Effect of 4-Position Pyridine Ring Substitution on Zn(II) Complexes of 4-substituted Py<sub>2</sub>N<sub>2</sub> Pyridinophane Macrocycles.","authors":"Katherine J Smith, Timothy M Schwartz, Hannah M Johnston, David M Freire, Kristóf Póta, Kayla N Green","doi":"10.1080/00958972.2025.2453062","DOIUrl":"10.1080/00958972.2025.2453062","url":null,"abstract":"<p><p>The metal binding properties of macrocyclic small molecules is a key property that drives what applications for which these ligands can be used. Pyridine modified Py<sub>2</sub>N<sub>2</sub> pyridinophane small molecules are a new class of macrocyclic small molecules, whose properties have not been explored. As a result, Zn(II) metal binding of a library of six pyridine modified Py<sub>2</sub>N<sub>2</sub> complexes are reported here. These results include <sup>1</sup>H NMR, log β<sub>Zn(II)</sub>, and X-ray diffraction, which are compared to PyN<sub>3</sub> congeners to show that the differences in each scaffold yield markedly different metal binding properties that can be exploited in future applications.</p>","PeriodicalId":15421,"journal":{"name":"Journal of Coordination Chemistry","volume":"78 1-3","pages":"225-232"},"PeriodicalIF":2.1,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12492988/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145232785","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-17DOI: 10.1080/00958972.2024.2404071
Yajing Zhang
The development of efficient, and environmentally friendly catalytic systems for synthesis of 5-substituted 1H-tetrazoles is an important challenge in organic synthesis because tetrazole derivative...
{"title":"Construction and characterization of Fe3O4@SiO2-Dop/Amide-BTA-pd(0) nanocomposite as a novel and efficient nanomagnetic recoverable catalyst for synthesis of 5-substituted 1h-tetrazoles in water","authors":"Yajing Zhang","doi":"10.1080/00958972.2024.2404071","DOIUrl":"https://doi.org/10.1080/00958972.2024.2404071","url":null,"abstract":"The development of efficient, and environmentally friendly catalytic systems for synthesis of 5-substituted 1H-tetrazoles is an important challenge in organic synthesis because tetrazole derivative...","PeriodicalId":15421,"journal":{"name":"Journal of Coordination Chemistry","volume":"34 1","pages":""},"PeriodicalIF":1.9,"publicationDate":"2024-09-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142267447","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Dye-sensitized solar cells offer a promising alternative to conventional photovoltaics due to their low production costs and high power conversion efficiencies. A crucial component in DSSCs is the ...
{"title":"A review on advanced counter electrode materials for high-efficiency dye sensitized solar cells","authors":"Kirandeep Kaur Dhillon, Meenakshi Patyal, Shikha Bhogal, Nidhi Gupta","doi":"10.1080/00958972.2024.2404070","DOIUrl":"https://doi.org/10.1080/00958972.2024.2404070","url":null,"abstract":"Dye-sensitized solar cells offer a promising alternative to conventional photovoltaics due to their low production costs and high power conversion efficiencies. A crucial component in DSSCs is the ...","PeriodicalId":15421,"journal":{"name":"Journal of Coordination Chemistry","volume":"11 1","pages":""},"PeriodicalIF":1.9,"publicationDate":"2024-09-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142267642","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-10DOI: 10.1080/00958972.2024.2400713
Christopher P. Landee, Mark M. Turnbull, Diane A. Dickie, Brendan Twamley, Jan L. Wikaira
Five new copper(II) complexes of substituted quinoxaline ligands have been prepared and characterized via single crystal X-ray diffraction, including [Cu(5-Mequinox)2(NO3)2] (2), [Cu(5-Mequinox)(NO...
通过单晶 X 射线衍射，制备并表征了五种新的取代喹喔啉配体的铜（II）配合物，包括 [Cu(5-Mequinox)2(NO3)2] (2)、[Cu(5-Mequinox)(NO...
{"title":"Copper(II) complexes of hindered diazines: methylquinoxalines","authors":"Christopher P. Landee, Mark M. Turnbull, Diane A. Dickie, Brendan Twamley, Jan L. Wikaira","doi":"10.1080/00958972.2024.2400713","DOIUrl":"https://doi.org/10.1080/00958972.2024.2400713","url":null,"abstract":"Five new copper(II) complexes of substituted quinoxaline ligands have been prepared and characterized via single crystal X-ray diffraction, including [Cu(5-Mequinox)2(NO3)2] (2), [Cu(5-Mequinox)(NO...","PeriodicalId":15421,"journal":{"name":"Journal of Coordination Chemistry","volume":"3 1","pages":""},"PeriodicalIF":1.9,"publicationDate":"2024-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142204947","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
We have synthesized and characterized five copper(II) complexes, [Cu(L1)(alanine)(NO3)]·2H2O (1), [Cu(L1)(methionine)(H2O)]NO3·4H2O (2), [Cu(L2)(glycine)] NO3·3H2O (3), [Cu(L2)(alanine)Cl]·2H2O (4)...
Pub Date : 2024-09-10DOI: 10.1080/00958972.2024.2400573
Ece Tugba Saka, Ahmet Senocak, Cagla Akkol
Photocatalytic oxidation is an advanced oxidation technique widely preferred for the removal of pollutants in wastewater. In this work, paramagnetic metallo-phthalocyanines EB2 and EB3 (Co(II)phtha...
{"title":"Synthesis of phthalocyanine/C3N4 structures and investigation of photocatalytic activities in the oxidation reaction of 4-nitrophenol","authors":"Ece Tugba Saka, Ahmet Senocak, Cagla Akkol","doi":"10.1080/00958972.2024.2400573","DOIUrl":"https://doi.org/10.1080/00958972.2024.2400573","url":null,"abstract":"Photocatalytic oxidation is an advanced oxidation technique widely preferred for the removal of pollutants in wastewater. In this work, paramagnetic metallo-phthalocyanines EB2 and EB3 (Co(II)phtha...","PeriodicalId":15421,"journal":{"name":"Journal of Coordination Chemistry","volume":"37 1","pages":""},"PeriodicalIF":1.9,"publicationDate":"2024-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142267448","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-31DOI: 10.1080/00958972.2024.2398216
Simranjeet Singh, Mukesh Choudhary
The reaction of sodium thiocyanate with CuCl2·2H2O salt using 1,10-phenanthtroline as a co-ligand led to chloridobis(1,10-phenanthroline)-(thiocyanato) copper(II), [Cu(Phen)2(Cl)(NCS)] (1). The str...
{"title":"Design, structure and antivirus molecular docking of chloridobis(1,10-phenanthroline)-(thiocyanato)-copper(II)","authors":"Simranjeet Singh, Mukesh Choudhary","doi":"10.1080/00958972.2024.2398216","DOIUrl":"https://doi.org/10.1080/00958972.2024.2398216","url":null,"abstract":"The reaction of sodium thiocyanate with CuCl2·2H2O salt using 1,10-phenanthtroline as a co-ligand led to chloridobis(1,10-phenanthroline)-(thiocyanato) copper(II), [Cu(Phen)2(Cl)(NCS)] (1). The str...","PeriodicalId":15421,"journal":{"name":"Journal of Coordination Chemistry","volume":"2 1","pages":""},"PeriodicalIF":1.9,"publicationDate":"2024-08-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142204951","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-28DOI: 10.1080/00958972.2024.2395894
Mukesh Kawad, Sagar R. Sangani, Jigneshkumar Parmar, Ranjitsinh C. Dabhi, Rishita Chauhan, Sarfaraz Ahmed, Rakesh Kumar Ameta
Herein, we report 2-propyl-1H-imidazole-4,5-dicarboxylate complexes of Cu/Co/Fe/Ni metal ions. The complexes have been characterized using powder X-ray diffraction, FTIR, and mass spectrometry. The...
在此，我们报告了铜/钴/铁/镍金属离子的 2-丙基-1H-咪唑-4,5-二羧酸盐配合物。我们使用粉末 X 射线衍射、傅立叶变换红外光谱和质谱对这些配合物进行了表征。这些...
{"title":"2-Propyl-1H-imidazole-4,5-dicarboxylate acid supported cu/ni/fe/co complexes: synthesis, biological and catalytic evaluation","authors":"Mukesh Kawad, Sagar R. Sangani, Jigneshkumar Parmar, Ranjitsinh C. Dabhi, Rishita Chauhan, Sarfaraz Ahmed, Rakesh Kumar Ameta","doi":"10.1080/00958972.2024.2395894","DOIUrl":"https://doi.org/10.1080/00958972.2024.2395894","url":null,"abstract":"Herein, we report 2-propyl-1H-imidazole-4,5-dicarboxylate complexes of Cu/Co/Fe/Ni metal ions. The complexes have been characterized using powder X-ray diffraction, FTIR, and mass spectrometry. The...","PeriodicalId":15421,"journal":{"name":"Journal of Coordination Chemistry","volume":"98 1","pages":""},"PeriodicalIF":1.9,"publicationDate":"2024-08-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142204950","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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