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Journal of Coordination Chemistry最新文献

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Polymeric dichlorido-bridged copper(II) offset stacked dimer coordination compounds and molecular spin stairs 聚合物二氯桥接铜(II)偏置叠层二聚配位化合物和分子自旋阶梯
IF 1.9 4区 化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR Pub Date : 2024-07-02 DOI: 10.1080/00958972.2024.2369120
Mathew R. Graci, Diane A. Dickie, Christopher P. Landee, Mark M. Turnbull
A family of oxygen coordinated dichlorido-bridged n-X-2-pyridone (1, n = 3, X = Cl; 2, n = 3, X = Br; 3, n = 4, X = Cl; 4, n = 4, X = Br; 5, n = 5, X = Cl; 6, n = 5, X = Br) Cu(II) offset stacked d...
氧配位二氯桥接正-X-2-吡啶酮(1,n=3,X=Cl;2,n=3,X=Br;3,n=4,X=Cl;4,n=4,X=Br;5,n=5,X=Cl;6,n=5,X=Br)Cu(II)偏置堆叠二...
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引用次数: 0
Synthesis, structure, and magnetic properties of lanthanide(III) complexes incorporating a tris-chelate cobalt(III) complex as a metalloligand 含有三螯合钴(III)络合物作为金属配体的镧系元素(III)络合物的合成、结构和磁性能
IF 1.9 4区 化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR Pub Date : 2024-07-02 DOI: 10.1080/00958972.2024.2369132
Md Saddam Hossain, Ryoji Mitsuhashi, Yuya Imai, Yoshihito Hayashi
A series of CoIII–LnIII–CoIII trinuclear complexes [Ln{Co(Hmtimn)3}2](NO3)3 were prepared by following a simple one-pot synthesis method, mixing an unsymmetrical bidentate ligand 2-(2-imidazolinyl)...
通过简单的一锅合成法,将非对称的双齿配体 2-(2-咪唑啉基)和[Ln{Co(Hmtimn)3}2](NO3)3 混合,制备了一系列 CoIII-LnIII-CoIII 三核配合物[Ln{Co(Hmtimn)3}2](NO3)3。
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引用次数: 0
Salicylaldehyde salicyloyl hydrazone and its copper(II) complex: synthesis, characterization, DFT, optical band gap, antibacterial activity, and molecular docking analysis 水杨醛水杨酰腙及其铜(II)配合物:合成、表征、DFT、光带隙、抗菌活性和分子对接分析
IF 1.9 4区 化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR Pub Date : 2024-07-01 DOI: 10.1080/00958972.2024.2371430
Bharat Prasad Sharma, Naimatullah Channa, Yu Jiangnan, Pratibha Kumari Chand, Sarvesh Kumar Pandey, Bishnu Prasad Marasini, Motee Lal Sharma, Sabita Shrestha
A complex of Cu(II) with a bidentate Schiff base, salicylaldehyde salicyloyl hydrazone (SSH), was synthesized by refluxing copper(II) chloride with this ligand. The formation of the complex, the na...
通过将氯化铜(II)与双叉席夫碱水杨醛水杨酰腙(SSH)配体回流,合成了一种铜(II)与该配体的配合物。该配合物的形成、na...
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引用次数: 0
Hybridization makes the difference: [2Oxa.2Oxa.2Oxa] a sp2-Carbon dominated Lehn-type cryptand - Prediction of ion selectivity by quantum chemical calculations. XVIII 杂化带来不同:[2Oxa.2Oxa.2Oxa]一种以 sp2 碳为主的莱恩型密码子--通过量子化学计算预测离子选择性。XVIII
IF 1.9 4区 化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR Pub Date : 2024-06-30 DOI: 10.1080/00958972.2024.2367223
Thomas Capponi, Clemens Bason, Dušan Ćoćić, Ralph Puchta, Rudi van Eldik
Substituting the O-C2H4-O-moiety of [2.2.2] by the O2CCO2-core of oxalic acid leads to the new Lehn-type cryptand [M ⊂ 2Oxa.2Oxa.2Oxa]m+. We explored by quantum chemical methods (B3LYP/LANL2DZp) th...
用草酸的 O2CCO2 核取代 [2.2.2] 的 O-C2H4-O 子,可以得到新的雷恩型隐色体 [M ⊂ 2Oxa.2Oxa.2Oxa]m+。我们用量子化学方法(B3LYP/LANL2DZp)探讨了...
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引用次数: 0
Studies on the interaction of aquahydroxocobinamide with 5-aminotetrazole 研究水合羟基钴胺与 5-氨基四氮唑的相互作用
IF 1.9 4区 化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR Pub Date : 2024-06-30 DOI: 10.1080/00958972.2024.2366267
Ilia A. Dereven’kov, Sergei V. Makarov, Alla I. Makarova
Here we show that 5-aminotetrazole (ATZ) is capable of moderately strong binding with aquahydroxocobinamide ((H2O)(HO-)Cbi). At pH 7.4, 25.0 °C, the reaction of (H2O)(HO-)Cbi with a two-fold excess...
在这里,我们证明了 5-氨基四氮唑(ATZ)能够与水合羟基烟酰胺((H2O)(HO-)Cbi)发生中等强度的结合。在 pH 值为 7.4、温度为 25.0 ℃ 的条件下,(H2O)(HO-)Cbi 与过量两倍的...
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引用次数: 0
An iron-free nitrogenase? Computational estimation of the ability to bind/activate N2 in manganese and cobalt complexes 无铁氮化酶?锰和钴复合物结合/激活 N2 能力的计算估算
IF 1.9 4区 化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR Pub Date : 2024-06-28 DOI: 10.1080/00958972.2024.2372812
Rami Doukeh, Daniela Craciun, Maria Lehene, Adrian M. V. Branzanic, Alexandru Lupan, Radu Silaghi-Dumitrescu
Activation of N2 to ammonia occurs in nitrogenases at an unusual carbide-iron-sulfur active site. To deconvolute the factors that allow the nitrogenase Fe to bind N2, we have recently reported a de...
氮酶在一个不寻常的碳-铁-硫活性位点将N2活化为氨。为了解密氮酶铁与 N2 结合的因素,我们最近报告了一种脱碳-铁-硫活性位点。
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引用次数: 0
Redox behavior of unsubstituted cobalt phthalocyanine in nanostructured Langmuir-Schaefer films 纳米结构朗缪尔-谢弗薄膜中未取代酞菁钴的氧化还原行为
IF 1.9 4区 化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR Pub Date : 2024-06-26 DOI: 10.1080/00958972.2024.2367764
I. A. Dereven’kov, L. A. Maiorova, A. N. Gromov
Although the properties of unsubstituted metal tetrapyrroles in solutions have received attention in numerous work, the physico-chemistry of their thin films remains poorly investigated. In this wo...
尽管未取代的金属四吡咯在溶液中的特性受到了许多研究的关注,但对其薄膜的物理化学特性的研究仍然很少。在本研究中...
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引用次数: 0
Antibiotic Schiff base metal complexes as privileged scaffolds to overcome microbial resistance 抗生素希夫碱金属复合物作为克服微生物抗药性的特效支架
IF 1.9 4区 化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR Pub Date : 2024-06-25 DOI: 10.1080/00958972.2024.2369911
Bini Babu Sujatha, Sindhu Yesodharan, Selwin Joseyphus Raphael
The incidence of multi-resistant infections has sharply increased. One of the best strategies for developing new drugs is re-engineering existing drugs to enhance their bioavailability and antimicr...
多重耐药性感染的发病率急剧上升。开发新药物的最佳策略之一是重新设计现有药物,以提高其生物利用度和抗药性。
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引用次数: 0
Synthesis, characterization, crystal structure and anticancer study of symmetrical binuclear bis-N-heterocyclic carbene silver(I) complexes 对称双核双 N-杂环碳烯银(I)配合物的合成、表征、晶体结构和抗癌研究
IF 1.9 4区 化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR Pub Date : 2024-05-31 DOI: 10.1080/00958972.2024.2355996
Nuraddeen Abdurrahman, Farhank Saber Braim, Nobuto Yoshinari, Nik Noor Ashikin Nik Abd Razak, Mohd. R. Razali
The synthesis of binuclear silver(I)-NHC complexes from bis-benzimidazolium salts and silver(I) ions has been carried out via an in-situ deprotonation (NHC = N-heterocyclic carbene). The reaction b...
通过原位去质子化反应(NHC = N-杂环碳烯),从双苯并咪唑盐和银(I)离子合成了双核银(I)-NHC配合物。反应...
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引用次数: 0
Synthesis, characterization and theoretical studies of tris-cyclometalated rhodium(III) complexes: applications to asymmetric transfer hydrogenation of ketones 三环金属化铑(III)配合物的合成、表征和理论研究:应用于酮的不对称转移加氢反应
IF 1.9 4区 化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR Pub Date : 2024-05-31 DOI: 10.1080/00958972.2024.2355257
Faezeh Moniriyan, Seyyed Javad Sabounchei, Asieh Sedghi
This paper presents the synthesis of {Rh[PyCH=C(O)Rn]3} complexes, where R1 = 4-cyanophenyl (L1), R2 = 3-nitrophenyl (L2), and R3 = 4-fluorophenyl (L3). These complexes were derived from the reacti...
本文介绍了{Rh[PyCH=C(O)Rn]3}配合物的合成,其中 R1 = 4-氰基苯(L1),R2 = 3-硝基苯(L2),R3 = 4-氟苯基(L3)。这些络合物是由...
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引用次数: 0
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Journal of Coordination Chemistry
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