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Lotus Seed Protein Hydrolysate Enhances the Mechanical, Barrier, and Thermal Properties of Propylene Glycol Alginate Bio-Composite Films 莲子蛋白水解物增强海藻酸丙二醇生物复合膜的机械、屏障和热性能
IF 2.9 3区 农林科学 Q3 ENGINEERING, CHEMICAL Pub Date : 2026-02-13 DOI: 10.1111/jfpe.70361
Hanzhi Jing, Linjing He, Mengjiao Zhang, Yuhan Chen, Yuan Huang, Pengkai Wang, Hongying Du

As petroleum-based plastics contribute significantly to environmental pollution, the development of novel biodegradable and even edible packaging materials has become a research hotspot. In this study, lotus seed protein hydrolysate (LSPH) was extracted and used to fabricate a propylene glycol alginate (PGA)/LSPH composite film. The antioxidant activity of LSPH was predicted through structural analysis and bioinformatics tools, complemented by peptide sequencing and amino acid composition analysis. The composite film with 0.2% LSPH/PGA exhibited the highest tensile strength (35 MPa) along with improved elongation at break. Moreover, this film demonstrated the lowest water vapor permeability (WVP), enhanced surface hydrophobicity, and increased thermal stability. Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM) analyses indicated that the addition of LSPH led to the formation of non-covalent bonds—including hydrogen bonds, hydrophobic interactions, and electrostatic interactions—with other components in the composite film, contributing to a homogeneous and smooth microstructure.

由于石油基塑料严重污染环境,开发新型可生物降解甚至可食用的包装材料已成为研究热点。本研究以莲子蛋白水解物(LSPH)为原料,制备海藻酸丙二醇酯(PGA)/LSPH复合膜。通过结构分析和生物信息学工具预测LSPH的抗氧化活性,并辅以肽段测序和氨基酸组成分析。添加0.2% LSPH/PGA的复合膜抗拉强度最高(35 MPa),断裂伸长率也有所提高。此外,该膜表现出最低的水蒸气渗透性(WVP),增强的表面疏水性和提高的热稳定性。傅里叶变换红外光谱(FTIR)和扫描电镜(SEM)分析表明,LSPH的加入导致复合膜中其他组分形成非共价键,包括氢键、疏水相互作用和静电相互作用,有助于形成均匀光滑的微观结构。
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引用次数: 0
Validation of Sanitizer Concentration to Reduce Cross-Contamination Risk During Washing of Apples 降低苹果清洗过程中交叉污染风险的杀菌剂浓度验证
IF 2.9 3区 农林科学 Q3 ENGINEERING, CHEMICAL Pub Date : 2026-02-13 DOI: 10.1111/jfpe.70377
Kevin Tarwa, Alexandra Chiu, Iris Elisa Cuadra, Zhujun Gao, Rohan V. Tikekar

The presence of elevated chemical oxygen demand (COD) during apple washing can negatively affect the effectiveness of sanitizers. Here, we evaluated the effectiveness of 80 ppm sodium hypochlorite (NaOCl) and 80 ppm peracetic acid (PAA) to control and prevent cross-contamination of Escherichia coli TVS353 on freshly harvested Pink Lady apples (Malus domestica “Cripps Pink”). One inoculated apple was washed for 2 min in a simulated dump tank wash (SDTW) with 14 uninoculated apples under low (500 mg/L) or high (3000 mg/L) COD conditions. Bacterial enumeration was performed on uninoculated washed apples, inoculated washed apples, and the wash water using a modified most probable number (MPN) method. Results showed significantly higher levels of E. coli TVS353 detected at both low and high COD in the absence of sanitizer (2.3 ± 0.3 and 1.2 ± 0.6 log MPN/apple) compared to NaOCl (0.2 ± 0.0 and 0.3 ± 0.0 log MPN/apple) and PAA treatments (0.2 ± 0.0 and 0.2 ± 0.0 log MPN/apple). PAA was more effective than NaOCl in reducing E. coli on apples, achieving a 5.3–6.0 log reduction compared to NaOCl's 2.9–3.7 log reduction (p < 0.05). NaOCl's efficacy was negatively impacted by high COD levels, while PAA remained effective. In the absence of sanitizer, substantial cross-contamination and E. coli persistence in wash water were observed. These findings suggest that applying sanitizer treatment during apple washing is more effective in reducing and preventing the spread of microbes to clean apples and wash water compared to washing with water alone.

苹果洗涤过程中化学需氧量(COD)的升高会对杀菌剂的效果产生负面影响。本研究评价了80 ppm次氯酸钠(NaOCl)和80 ppm过氧乙酸(PAA)对新鲜收获的粉红女士苹果(Malus domestica“Cripps Pink”)大肠杆菌TVS353交叉污染的控制和预防效果。将1个接种后的苹果与14个未接种的苹果在低(500 mg/L)或高(3000 mg/L) COD条件下,在模拟倒灌槽洗涤(SDTW)中洗涤2 min。采用改进的最可能数(MPN)法对未接种的洗净苹果、接种过的洗净苹果和洗净水进行细菌计数。结果表明,低COD和高COD处理(2.3±0.3和1.2±0.6 log MPN/苹果)的大肠杆菌TVS353含量显著高于无消毒剂处理(0.2±0.0和0.3±0.0 log MPN/苹果)和PAA处理(0.2±0.0和0.2±0.0 log MPN/苹果)。PAA在减少苹果上大肠杆菌方面比NaOCl更有效,达到5.3-6.0的对数减少,而NaOCl的对数减少为2.9-3.7 (p < 0.05)。NaOCl的疗效受到高COD水平的负面影响,而PAA仍然有效。在没有消毒剂的情况下,观察到大量的交叉污染和大肠杆菌在洗涤水中的持久性。这些研究结果表明,在洗苹果过程中使用消毒剂处理比单独用水洗苹果更有效地减少和防止微生物在清洁苹果和洗水中的传播。
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引用次数: 0
Continuous Isomerization of Galactose to Rare Isomers in Arginine Solution Using Microwave Heating 半乳糖在精氨酸溶液中连续异构为稀有异构体的微波加热研究
IF 2.9 3区 农林科学 Q3 ENGINEERING, CHEMICAL Pub Date : 2026-02-13 DOI: 10.1111/jfpe.70375
Khwanjai Klinchongkon, Kulisara Ampairat, Thanika Sodok, Kantnapat Chiropasworrapong, Neeranuch Milasing, Takashi Kobayashi, Yoshiyuki Watanabe, Shuji Adachi, Pramote Khuwijitjaru

Tagatose is a low-calorie alternative sweetener with several health benefits. This study is the first demonstration of continuous-flow microwave-assisted isomerization of galactose using arginine as an alkaline catalyst, which enabled precise residence time control under pressurized conditions. With a microwave power of 800 W and a residence time of 3.18 min (flow rate of 0.5 mL/min), a tagatose yield of 10.9% was obtained using 0.2 M galactose and 10 mol% arginine, together with a small amount of talose and sorbose. Increasing arginine concentration from 2.5 to 15 mol% significantly increased the yield to the highest value of 14.9%, but the yield decreased at 20 mol%. Initial galactose concentration from 0.1 to 0.6 M with 15 mol% arginine did not enhance tagatose yield, but productivity increased to the highest value of 254.4 g/L h. Acid formation and browning increased with the galactose concentration. Lower galactose concentration (0.2 M) provided lower productivity (101.4 g/L h), but also much lower browning, which is an advantage for further downstream purification. Overall, this study shows the potential of this novel continuous process using microwave heating, which is more energy-efficient than the conventional batch method and provides a novel and sustainable rare sugar production approach.

塔格糖是一种低热量的甜味剂,对健康有益。这项研究首次证明了半乳糖的连续流微波辅助异构化,使用精氨酸作为碱性催化剂,可以在加压条件下精确控制停留时间。在微波功率为800 W、停留时间为3.18 min(流速为0.5 mL/min)的条件下,以0.2 M半乳糖和10 mol%精氨酸为原料,加入少量的塔格糖和山梨糖,得到了10.9%的塔格糖收率。当精氨酸浓度从2.5 mol%增加到15 mol%时,产率显著提高,达到最大值14.9%,但在20 mol%时产率下降。初始半乳糖浓度为0.1 ~ 0.6 M,精氨酸浓度为15 mol%,对塔格糖产量无显著影响,但产量最高可达254.4 g/L h。随着半乳糖浓度的增加,酸生成和褐变增加。较低的半乳糖浓度(0.2 M)提供了较低的生产率(101.4 g/L h),但也大大降低了褐变,这是进一步下游纯化的优势。总的来说,本研究显示了这种使用微波加热的新型连续工艺的潜力,它比传统的间歇式方法更节能,并提供了一种新的可持续的稀有糖生产方法。
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引用次数: 0
Combined Effects of Ultra-High-Pressure Homogenization and Enzyme Treatments on the Quality Properties of Juice From Apple Industrial By-Products 超高压均质和酶处理对苹果工业副产物果汁品质的影响
IF 2.9 3区 农林科学 Q3 ENGINEERING, CHEMICAL Pub Date : 2026-02-11 DOI: 10.1111/jfpe.70385
Muhammet İrfan Aksu, Sıla Satı Şimşek, Emre Turan, Nevzat Konar, İlyas Atalar

The objective of this study was to investigate the influence of ultra-high pressure homogenization [UHPH, 0 MPa (Control without UHPH), 100, and 150 MPa] and different enzyme treatments (non-enzyme, pectinase and cellulase) on some quality and color changes of fruit juices produced from dried apple pomace powder (DAPP). DAPP was a valuable waste product due to its high total phenolic content (198.42 ± 2.60 mg GAE/100 g dw) as well as low moisture (2.78 ± 0.17%) and pH (3.20 ± 0.03). The pH, total soluble solids (TSS), color, total color difference (ΔE), and National Bureau of Standards (NBS) parameters of fruit juices (DAPPJ) produced from DAPP were affected by both enzyme (p < 0.01) and UHPH treatments (p < 0.01). Enzyme and UHPH treatments increased the TSS value (p < 0.05). Pectinase treatment of DAPPJ resulted in lower pH values and color coordinates (L*, a*, and b*) compared to cellulase and non-enzyme groups (p < 0.05). Regardless of enzyme treatment, UHPH processing increased lightness and yellowness, while decreasing redness in DAPPJ. The combination of pectinase enzyme and 100 MPa UHPH offered a ‘distinct’ color difference with the lowest ΔE, while ΔE was ‘very distinct’ in all treatment groups processed with 150 MPa UHPH (p < 0.05). The color difference based on NBS classification was “noticeable” for enzyme treatments and “appreciable” for UHPH processing. Considering a lighter yellowish and less reddish fruit juice for consumer acceptance, the combination of cellulase enzyme and 150 MPa UHPH can be recommended for industrial applications of DAPPJ. On the other hand, to minimize the visible color difference, a combination of pectinase enzyme and 100 MPa UHPH is a more suitable option for DAPPJ production.

研究了超高压均质[UHPH、0 MPa(无超高压对照)、100 MPa和150 MPa]和不同酶处理(无酶、果胶酶和纤维素酶)对苹果干渣粉(DAPP)果汁品质和颜色变化的影响。DAPP总酚含量高(198.42±2.60 mg GAE/100 g dw),水分低(2.78±0.17%),pH值低(3.20±0.03),是一种有价值的废弃物。酶处理(p < 0.01)和UHPH处理(p < 0.01)对DAPP果汁(DAPPJ)的pH、总可溶性固形物(TSS)、颜色、总色差(ΔE)和国家标准局(NBS)参数均有影响。酶和超高压ph处理提高了TSS值(p < 0.05)。与纤维素酶和非酶组相比,果胶酶处理DAPPJ的pH值和颜色坐标(L*、a*和b*)较低(p < 0.05)。在不考虑酶处理的情况下,UHPH处理增加了DAPPJ的亮度和黄度,同时降低了DAPPJ的红度。果胶酶和100 MPa UHPH的组合提供了“明显”的颜色差异,最低的ΔE,而在150 MPa UHPH处理的所有处理组中ΔE“非常明显”(p < 0.05)。根据NBS分类,酶处理的色差“明显”,超高压处理的色差“可观”。考虑到消费者接受的淡黄色和少红的果汁,纤维素酶和150 MPa UHPH的组合可以推荐用于DAPPJ的工业应用。另一方面,为了最大限度地减少可见色差,果胶酶与100 MPa UHPH的组合是生产DAPPJ的更合适的选择。
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引用次数: 0
Mathematical Modeling and Experimental Evaluation of Heat and Mass Transfer During Pork Loin Roasting 猪里脊烤过程传热传质数学建模及实验评价
IF 2.9 3区 农林科学 Q3 ENGINEERING, CHEMICAL Pub Date : 2026-02-11 DOI: 10.1111/jfpe.70370
Jhony T. Teleken, Mariane Wolf, João P. Ferreira, João B. Laurindo, Bruno A. M. Carciofi

Meat is an important source of nutrients in the human diet, and proper cooking is essential to enhance food safety, digestibility, and sensory quality. This study aimed to develop a mathematical model based on heat and mass transfer equations to simulate pork loin roasting in an electric oven. The model treats meat as a saturated porous medium, incorporating anisotropy due to muscle fiber orientation and the effects of thermal protein denaturation on moisture transfer. It accounts for thermal radiation and convective heat and mass transfer at the surface, along with conduction, moisture diffusion, and pressure-driven water flow within the meat, described by Darcy's law. The Finite Element Method (FEM) was used to solve the model, and predictions of meat temperature and moisture content were validated against roasting experiments at 180°C, 200°C, and 220°C. Experimental methods determined meat emissivity via thermal imaging and convective heat transfer coefficients using the lumped thermal capacity approach. Water permeability and effective moisture diffusion coefficients were obtained through optimization. The model accurately predicts transient temperature, moisture content, and pressure distributions. Results show that moisture loss is primarily due to dripping (~70%), and thermal radiation accounts for 60%–80% of total heat transfer. Sensitivity analysis identified relative humidity inside the oven as a critical factor influencing moisture loss and cooking time, while anisotropy had a limited effect under the conditions studied. The developed model combines accurate predictions with fewer parameters than previous multiphase transport models, while remaining adaptable to various processing conditions, making it suitable for process design and control.

肉类是人类饮食中重要的营养来源,适当的烹饪对提高食品安全性、消化率和感官质量至关重要。本研究旨在建立一个基于传热传质方程的数学模型来模拟猪腰肉在电烤箱中的烘烤。该模型将肉类作为一种饱和多孔介质,考虑了肌肉纤维取向的各向异性和热蛋白变性对水分传递的影响。它解释了肉表面的热辐射、对流传热和传质,以及肉内的传导、水分扩散和压力驱动的水流,这些都是达西定律所描述的。采用有限元法(FEM)对模型进行求解,并在180°C、200°C和220°C的烘烤实验中验证了肉类温度和水分含量的预测结果。实验方法通过热成像和采用集中热容量法的对流传热系数来确定肉的发射率。通过优化得到了透水性和有效水分扩散系数。该模型准确地预测瞬态温度、水分含量和压力分布。结果表明:湿损主要是由滴落造成的(~70%),热辐射占总传热的60% ~ 80%。灵敏度分析表明,烘箱内相对湿度是影响水分损失和烹饪时间的关键因素,而各向异性在研究条件下的影响有限。所开发的模型结合了准确的预测和比以前的多相输运模型更少的参数,同时保持对各种加工条件的适应性,使其适合工艺设计和控制。
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引用次数: 0
A Numerically Stable Sequential Model for Estimating Shear Rheological Parameters of Food Fluids 一种估计食品流体剪切流变参数的数值稳定序列模型
IF 2.9 3区 农林科学 Q3 ENGINEERING, CHEMICAL Pub Date : 2026-02-11 DOI: 10.1111/jfpe.70350
Nobuaki Ikeda, Ayuri Kimoto, Satoko Fujioka, Koichi Terasaka

This study aims to improve the numerical stability of rheological parameter estimation for non-Newtonian food fluids by proposing a Sequential Herschel–Bulkley (SHB) model, which sequentially estimates yield stress (τ0), consistency index (K), and flow behavior index (n) using pressure drop and flow rate data obtained from tube flow. In contrast to the conventional Herschel–Bulkley (HB) model, which fits all three parameters simultaneously and is susceptible to numerical instability, the SHB model first determines τ0 using the Casson equation and then fits K and n with τ0 fixed. The method was validated using tamarind seed gum (TG) solution, xanthan gum (XG) solution, and ketchup. Flow curves derived from SHB-based tube-flow measurements showed improved agreement with rotational viscometer data, particularly for ketchup, where the mean absolute percentage error (MAPE) decreased from 4.49% for the HB model to 2.10% for the SHB model. In addition, repeated nonlinear fitting demonstrated that the SHB model consistently reduced the coefficients of variation and parameter variances relative to the HB model, indicating enhanced robustness. These findings demonstrate that the SHB model provides a concise, reliable, and numerically stable approach for estimating shear rheological parameters of yield-stress food fluids using practical in-line measurement signals.

为了提高非牛顿食品流体流变参数估计的数值稳定性,本研究提出了一个序贯Herschel-Bulkley (SHB)模型,该模型利用从管流中获得的压降和流速数据,序贯地估计屈服应力(τ0)、一致性指数(K)和流动行为指数(n)。传统的Herschel-Bulkley (HB)模型同时拟合所有三个参数,容易受到数值不稳定性的影响,与之相反,SHB模型首先使用Casson方程确定τ0,然后在τ0固定的情况下拟合K和n。用罗望子胶(TG)溶液、黄原胶(XG)溶液和番茄酱对该方法进行验证。基于SHB的管流测量得到的流动曲线与旋转粘度计数据的一致性得到了改善,特别是对于番茄酱,其中平均绝对百分比误差(MAPE)从HB模型的4.49%下降到SHB模型的2.10%。此外,反复非线性拟合表明,相对于HB模型,SHB模型的变异系数和参数方差一致减小,表明鲁棒性增强。这些发现表明,SHB模型提供了一种简洁、可靠和数值稳定的方法,可以使用实际的在线测量信号来估计屈服应力食品流体的剪切流变参数。
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引用次数: 0
Hyperspectral Imaging for Identification of Early Freeze Damage in Oranges 高光谱成像技术在柑桔早期冻害鉴定中的应用
IF 2.9 3区 农林科学 Q3 ENGINEERING, CHEMICAL Pub Date : 2026-02-09 DOI: 10.1111/jfpe.70378
Lei Shi, Jun Sun, Bing Zhang, Xiaojiao Du, Zhiyan Shi, Xin Zhou, Xiaohong Wu

The orange affected by freeze damage will experience the loss of partial nutrients, decline in taste quality, and acceleration of deterioration. According to the early signs of freeze damage, it becomes challenging for the naked eye to differentiate between oranges with freeze damage and those that are intact. This study aimed to investigate the feasibility of using hyperspectral imaging for identification of oranges with different degrees of early freeze damage. Firstly, the fundamental mechanism of hyperspectral imaging for identifying early freeze damage of orange was investigated by weight change before and after freeze damage, soluble solids content, and fluorescence images of the oranges with different degrees of early freeze damage. Subsequently, a variance inflation factor modified competitive adaptive reweighted sampling (VIF-CARS) algorithm and a reptile search algorithm optimized support vector machine (RSA-SVM) were proposed to extract effective wavelengths associated with freeze damage information of oranges and identify oranges with different degrees of early freeze damage. The results demonstrated that VIF-CARS exhibited promising outcomes in dimensionality reduction, effective information extraction, and wavelength interpretability compared with traditional methods. Moreover, when combined with the RSA-SVM model, this combination showcased reliable discrimination capabilities for identifying oranges with different degrees of early freeze damage, achieving the optimal classification accuracy of 94.44% and the F1-score of 0.9484. Therefore, hyperspectral imaging offers a feasible approach for identification of oranges with different degrees of early freeze damage, which is a crucial step toward improving the detection system for the fruit supply chains.

受冻害影响的橙子会失去部分营养,口感下降,加速变质。根据冻伤的早期迹象,肉眼很难区分有冻伤的橙子和完好无损的橙子。本研究旨在探讨利用高光谱成像技术鉴别不同程度早期冻害的柑橘的可行性。首先,通过对不同冻害程度的柑桔进行冻害前后的重量变化、可溶性固形物含量和荧光图像分析,探讨了高光谱成像识别柑桔早期冻害的基本机理。随后,提出了方差膨胀因子修正的竞争自适应重加权采样(VIF-CARS)算法和爬行动物搜索算法优化的支持向量机(RSA-SVM)算法,提取与橙子冻害信息相关的有效波长,识别不同程度的早期冻害橙子。结果表明,与传统方法相比,VIF-CARS在降维、有效信息提取和波长可解释性方面表现出良好的效果。结合RSA-SVM模型,对不同程度的早期冻害橙子表现出可靠的识别能力,最优分类准确率为94.44%,f1得分为0.9484。因此,高光谱成像技术为识别不同程度的早期冻害橙子提供了一种可行的方法,是完善水果供应链检测系统的关键一步。
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引用次数: 0
Research on Rice Safety Risk Prediction Model Under High Temperature and Humidity Environments 高温高湿环境下大米安全风险预测模型研究
IF 2.9 3区 农林科学 Q3 ENGINEERING, CHEMICAL Pub Date : 2026-02-09 DOI: 10.1111/jfpe.70348
Huawei Jiang, Ruomeng Hu, Jinyou Jiang, Wanbao Sheng, Wenqiang Pi, Zhen Yang, Like Zhao

Under high temperature and humidity environments, the pollution characteristics of rice exhibit instability and high complexity, which makes traditional prediction models face challenges of insufficient stability and robustness in feature screening and outlier processing. Therefore, this paper proposes a rice safety risk prediction model of OREDRVFL (Outlier-robust Ensemble Deep Random Vector Functional Link Network) improved by the FAOA (Fitness-Distance-Balance-Arithmetic Optimization Algorithm). First, the MI (Mutual Information) method is employed to screen a series of key risk factors. Second, the AOA (Arithmetic Optimization Algorithm) is improved by the FDB (Fitness-Distance-Balance) strategy. Then, regularization constraints and sparsity modeling are used to construct the OREDRVFL network, and FAOA is employed to optimize its number of hidden layers and regularization parameters. Finally, experimental verification is carried out using the detection data of a major rice-producing province from 2022 to 2023. The results show that the improved MI-FAOA-OREDRVFL model significantly outperforms traditional models in terms of indicators such as root mean square error (RMSE = 0.4300), mean absolute error (MAE = 0.2900), and correlation coefficient (R2 = 0.8800). Under noise interference, its RMSE remains stable at 0.1700, verifying the high precision and strong robustness of the model, and providing technical support for the prediction of rice safety risks under high temperature and humidity environments.

在高温高湿环境下,水稻污染特征表现出不稳定性和高复杂性,使得传统的预测模型在特征筛选和离群值处理方面面临稳定性和鲁棒性不足的挑战。为此,本文提出了一种采用FAOA (Fitness-Distance-Balance-Arithmetic Optimization Algorithm)改进的OREDRVFL (Outlier-robust Ensemble Deep Random Vector Functional Link Network)大米安全风险预测模型。首先,采用互信息(MI)方法筛选一系列关键风险因素。其次,采用适应度-距离-平衡(Fitness-Distance-Balance)策略对AOA算法进行改进。然后,利用正则化约束和稀疏化建模构建OREDRVFL网络,并利用FAOA优化其隐藏层数和正则化参数。最后,利用某水稻大省2022 - 2023年的检测数据进行实验验证。结果表明,改进后的MI-FAOA-OREDRVFL模型在均方根误差(RMSE = 0.4300)、平均绝对误差(MAE = 0.2900)、相关系数(R2 = 0.8800)等指标上均显著优于传统模型。在噪声干扰下,其RMSE稳定在0.1700,验证了模型的高精度和较强的鲁棒性,为高温高湿环境下大米安全风险预测提供了技术支持。
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引用次数: 0
Reinforcement Materials and Processing of Starch-Based Composites for Rigid and Semi-Rigid Food Packaging 硬质和半硬质食品包装用淀粉基复合材料的增强材料及加工
IF 2.9 3区 农林科学 Q3 ENGINEERING, CHEMICAL Pub Date : 2026-02-08 DOI: 10.1111/jfpe.70381
Néstor C. Posada, Clara P. Peña-Venegas, Diego A. Castellanos

Starch is a natural, renewable, and low-cost biopolymer with promising potential to replace petrochemical plastics in food packaging applications. Starch as a polymeric matrix offers a wide range of possibilities for improvement, making it more attractive to use in various applications in rigid/semi-rigid packaging than other biodegradable materials such as cellulose-based paper/cardboard or polylactic acid (PLA). Thermoplastic starch (TPS) processing under optimized plasticization conditions allows suitable mechanical properties (tensile strength: 2–15 MPa; elongation at break: 10%–150%). However, native starch exhibits high hydrophilicity and poor thermal stability. This review critically evaluates TPS performance for rigid/semi-rigid food packaging applications, such as mechanical strength, moisture barrier, thermal stability, and structural integrity, and discusses advanced reinforcement strategies. These include nanofillers (starch/nanocellulose composites achieving Young's modulus > 3 GPa), natural fibers (e.g., 20% hemp fiber increasing tensile strength by ~200%; thermal stability improvement up to 50°C with lignocellulosic fibers), nano clays (WVTR reduction by 30%–70%) and polymer blending (e.g., TPS/PLA mixtures with 10% lower moisture absorption). Processing techniques (extrusion, injection, compression molding) and interfacial compatibility (e.g., silane coupling agents that improve adhesion between filler and matrix) are also analyzed. Finally, the main challenges of industrial adaptation to advance starch-based packaging toward high-performance biodegradable applications are addressed.

淀粉是一种天然的、可再生的、低成本的生物聚合物,在食品包装方面具有替代石化塑料的潜力。淀粉作为一种聚合物基质提供了广泛的改进可能性,使其在刚性/半刚性包装的各种应用中比其他可生物降解材料(如纤维素基纸/纸板或聚乳酸(PLA))更具吸引力。热塑性淀粉(TPS)在优化的塑化条件下加工,具有合适的力学性能(抗拉强度:2 - 15mpa;断裂伸长率:10%-150%)。然而,天然淀粉具有较高的亲水性和较差的热稳定性。这篇综述批判性地评估了TPS在刚性/半刚性食品包装应用中的性能,如机械强度、防潮性、热稳定性和结构完整性,并讨论了先进的加固策略。这些材料包括纳米填充物(淀粉/纳米纤维素复合材料达到杨氏模量>; 3gpa)、天然纤维(例如,20%的大麻纤维可将抗拉强度提高约200%;使用木质纤维素纤维可将热稳定性提高至50°C)、纳米粘土(WVTR降低30%-70%)和聚合物共混物(例如,TPS/PLA混合物,吸湿率降低10%)。还分析了加工技术(挤出、注射、模压)和界面相容性(例如,硅烷偶联剂提高填料和基体之间的附着力)。最后,解决了工业适应的主要挑战,以推进淀粉基包装向高性能可生物降解的应用。
{"title":"Reinforcement Materials and Processing of Starch-Based Composites for Rigid and Semi-Rigid Food Packaging","authors":"Néstor C. Posada,&nbsp;Clara P. Peña-Venegas,&nbsp;Diego A. Castellanos","doi":"10.1111/jfpe.70381","DOIUrl":"10.1111/jfpe.70381","url":null,"abstract":"<div>\u0000 \u0000 <p>Starch is a natural, renewable, and low-cost biopolymer with promising potential to replace petrochemical plastics in food packaging applications. Starch as a polymeric matrix offers a wide range of possibilities for improvement, making it more attractive to use in various applications in rigid/semi-rigid packaging than other biodegradable materials such as cellulose-based paper/cardboard or polylactic acid (PLA). Thermoplastic starch (TPS) processing under optimized plasticization conditions allows suitable mechanical properties (tensile strength: 2–15 MPa; elongation at break: 10%–150%). However, native starch exhibits high hydrophilicity and poor thermal stability. This review critically evaluates TPS performance for rigid/semi-rigid food packaging applications, such as mechanical strength, moisture barrier, thermal stability, and structural integrity, and discusses advanced reinforcement strategies. These include nanofillers (starch/nanocellulose composites achieving Young's modulus &gt; 3 GPa), natural fibers (e.g., 20% hemp fiber increasing tensile strength by ~200%; thermal stability improvement up to 50°C with lignocellulosic fibers), nano clays (WVTR reduction by 30%–70%) and polymer blending (e.g., TPS/PLA mixtures with 10% lower moisture absorption). Processing techniques (extrusion, injection, compression molding) and interfacial compatibility (e.g., silane coupling agents that improve adhesion between filler and matrix) are also analyzed. Finally, the main challenges of industrial adaptation to advance starch-based packaging toward high-performance biodegradable applications are addressed.</p>\u0000 </div>","PeriodicalId":15932,"journal":{"name":"Journal of Food Process Engineering","volume":"49 2","pages":""},"PeriodicalIF":2.9,"publicationDate":"2026-02-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146256244","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Development of Bigels Using Citrus Fiber and Beeswax: Application in Cocoa Spread Formulation as Palm Oil Alternative 利用柑橘纤维和蜂蜡制备凝胶剂:作为棕榈油替代品在可可酱配方中的应用
IF 2.9 3区 农林科学 Q3 ENGINEERING, CHEMICAL Pub Date : 2026-02-08 DOI: 10.1111/jfpe.70372
Ezgi Genc Yılmaz, Alican Akcicek, Taylan Kablan, Muhammed Özgölet, Salih Karasu

In this study, bigel systems were developed as potential alternatives to palm oil in cocoa spreads. This study developed citrus fiber (CF)-based bigel systems as alternatives to palm oil in cocoa spreads. Bigels were formulated by combining hydrogels (HG) containing CF (5% and 7.5%) with olive oil oleogels (OG) structured using 10% beeswax at different HG:OG ratios (80:20, 50:50, and 20:80). All bigels exhibited higher storage (G′) and loss (G″) moduli than palm oil, indicating enhanced viscoelastic behavior. Increasing the oleogel fraction improved the structural integrity of the bigel network. Bigels containing 7.5% CF were incorporated into cocoa spreads, where higher oleogel ratios increased the solid character (G′). All bigel-enriched cocoa spreads showed thixotropic behavior with lower deformation and higher structural recovery compared to palm oil-based spreads. Additionally, bigel addition improved temperature-dependent stability. These results demonstrate that CF-based bigels provide a compact, viscoelastic, and stable fat system, highlighting their potential as palm oil replacers in cocoa spread formulations.

在这项研究中,bigel系统被开发为可可酱中棕榈油的潜在替代品。本研究开发了以柑橘纤维(CF)为基础的bigel系统,作为可可酱中棕榈油的替代品。将含有CF(5%和7.5%)的水凝胶(HG)与含有10%蜂蜡的橄榄油油凝胶(OG)以不同的HG:OG比例(80:20,50:50和20:80)混合配制成凝胶。比棕榈油具有更高的储存(G′)和损失(G″)模量,表明粘弹性增强。增加油凝胶分数提高了bigel网络的结构完整性。含有7.5% CF的Bigels被加入到可可酱中,其中较高的油凝胶比例增加了固体特性(G ')。与棕榈油为基础的涂抹剂相比,所有富含高糖的可可涂抹剂都表现出触变行为,具有更低的变形和更高的结构恢复。此外,bigel的加入改善了温度依赖性的稳定性。这些结果表明,基于cf的bigels提供了一种致密、粘弹性和稳定的脂肪系统,突出了它们作为可可酱配方中棕榈油替代品的潜力。
{"title":"Development of Bigels Using Citrus Fiber and Beeswax: Application in Cocoa Spread Formulation as Palm Oil Alternative","authors":"Ezgi Genc Yılmaz,&nbsp;Alican Akcicek,&nbsp;Taylan Kablan,&nbsp;Muhammed Özgölet,&nbsp;Salih Karasu","doi":"10.1111/jfpe.70372","DOIUrl":"10.1111/jfpe.70372","url":null,"abstract":"<div>\u0000 \u0000 <p>In this study, bigel systems were developed as potential alternatives to palm oil in cocoa spreads. This study developed citrus fiber (CF)-based bigel systems as alternatives to palm oil in cocoa spreads. Bigels were formulated by combining hydrogels (HG) containing CF (5% and 7.5%) with olive oil oleogels (OG) structured using 10% beeswax at different HG:OG ratios (80:20, 50:50, and 20:80). All bigels exhibited higher storage (<i>G</i>′) and loss (<i>G</i>″) moduli than palm oil, indicating enhanced viscoelastic behavior. Increasing the oleogel fraction improved the structural integrity of the bigel network. Bigels containing 7.5% CF were incorporated into cocoa spreads, where higher oleogel ratios increased the solid character (<i>G</i>′). All bigel-enriched cocoa spreads showed thixotropic behavior with lower deformation and higher structural recovery compared to palm oil-based spreads. Additionally, bigel addition improved temperature-dependent stability. These results demonstrate that CF-based bigels provide a compact, viscoelastic, and stable fat system, highlighting their potential as palm oil replacers in cocoa spread formulations.</p>\u0000 </div>","PeriodicalId":15932,"journal":{"name":"Journal of Food Process Engineering","volume":"49 2","pages":""},"PeriodicalIF":2.9,"publicationDate":"2026-02-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146216742","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Journal of Food Process Engineering
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