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Effect of Applied Voltage on the Electrochemical Copolymerization of Thiophene and Dithenopyrrole Derivatives 施加电压对噻吩和二噻吩衍生物电化学共聚的影响
Pub Date : 1900-01-01 DOI: 10.32508/stdj.v26i2.4063
HaTranNguyen, C. Nguyen, T. P. Nguyen, T. T. Bui, B. Doan, T. H. Luu, C. Tran, T. Truong, Tung Viet, T. Tran, H. L. Tran, Xuan Van Mai
The linear sweep voltammetry potentiostatic approach was employed to electrochemically synthesize the conjugated copolymers P(3HT-random-HPDTP) at three distinct applied voltages (1.4, 1.435, 1.6 V). In relation to their synthesis conditions, their chemical structural, optical, and electrical properties were investigated and compared using Fourier transform infrared (FTIR) spectroscopy, UV−Vis absorption spectroscopy, and cyclic voltammetry (CV). The results indicated that choosing a suitable applied voltage in the electropolymerization process significantly improved the electro-chemical stability and lowered the HOMO level of the conjugated copolymer.
采用线性扫描伏安法恒电位法在3种不同的施加电压(1.4 V、1.435 V和1.6 V)下电化学合成了共轭共聚物P(3HT-random-HPDTP),并利用傅里叶变换红外光谱(FTIR)、紫外-可见吸收光谱(UV - Vis)和循环伏安法(CV)研究了它们的化学结构、光学和电学性能。结果表明,在电聚合过程中选择合适的施加电压可显著提高共轭共聚物的电化学稳定性,降低HOMO能级。
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引用次数: 0
An ultra-flattened chromatic dispersion in circular C6H6-infiltrated photonic crystal fibers 圆形c6h6浸润光子晶体光纤中的超平坦色散
Pub Date : 1900-01-01 DOI: 10.32508/stdj.v26i2.4074
NguyenThiThuy, H. Trong, Duc
Introduction : In this study, we report a new design of a circular lattice photonic crystal fiber and investigate its optical properties numerically. Methods : Near-zero ultra-flattened chromatic dispersion is achieved by allowing benzene (C 6 H 6 ) to infiltrate the hollow core and induce a difference in the air hole size in the cladding. By solving Maxwell's wave equations using the full-vector finite-difference eigenmode, the electromagnetic field modes are analyzed. Results : The results show that the variation in dispersion over the broad wavelength range of 527 nm is (cid:6) 0.753 ps/nm.km. The nonlinearity coefficient is significantly improved with a value of several thousands W (cid:0) 1 .km (cid:0) 1 ; which is favorable for supercontinuum generation with low input power even though the confinement loss has not yet reached its desired value. Conclusion : Two PCFs with optimal lattice parameters and suitable characteristic quantities are selected for supercontinuum generation orientation compatible with application fields such as spectroscopy, temperature sensing, and telecommunication.
在本研究中,我们报道了一种新的圆形晶格光子晶体光纤的设计,并对其光学特性进行了数值研究。方法:通过允许苯(c6h6)渗入空心芯并诱导包层中气孔尺寸的差异,实现接近零的超扁平色色散。利用全矢量有限差分特征模解麦克斯韦波方程,分析了电磁场的模态。结果:在527 nm宽波长范围内,色散变化为(cid:6) 0.753 ps/nm.km。非线性系数显著提高,为几千W (cid:0) 1 .km (cid:0) 1;这有利于低输入功率的超连续统发电,即使约束损耗尚未达到理想值。结论:选择了两种具有最优晶格参数和合适特征量的PCFs作为超连续谱生成取向,适合光谱、温度传感和电信等应用领域。
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引用次数: 0
Enhancement of the crystalline phase in poly(vinylidene fluoride) by using the electrospinning technique and graphene oxide composition 利用静电纺丝技术和氧化石墨烯成分增强聚偏氟乙烯的晶相
Pub Date : 1900-01-01 DOI: 10.32508/stdj.v26i2.4048
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引用次数: 0
Bacterial pathogens causing community–acquired pneumonia in hospitalized adult patients with and without chronic obstructive pulmonary disease 有或无慢性阻塞性肺疾病的住院成人患者中引起社区获得性肺炎的细菌性病原体
Pub Date : 1900-01-01 DOI: 10.32508/stdj.v26i2.4113
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引用次数: 0
Molecular dynamics simulation of pressure effect on silicene nanoribbons 硅烯纳米带压力效应的分子动力学模拟
Pub Date : 1900-01-01 DOI: 10.32508/stdj.v26i1.4013
NguyenTruongLong, Huynh Anh Huy, T. Q. Tuan, L. Vo, H. Duy, N. Lâm, N. Phuong, Anh, T. Thi, Ngoc Gia, N. T. Long
Introduction: In 2D materials, the boundary of silicene formed as nanoribbons plays an essential role in synthesis and can be controlled to achieve different characteristics. Our study aims to investigate the structural preference depending on the pressure tolerance and boundary dependency. Methods: The main methodology used in our study is molecular dynamics simulation with Stillinger Weber potentials. Our simulation was carried out on 2D models of honeycomb silicene obtained through high and low pressurized cooling from the liquid state and then heat annealing for a decent time. The final configuration of silicene will be investigated in terms of structures and thermodynamic properties. Results: We found that the effect of the cooling process under high pressure formed a 4-fold ring structure, while at low pressure, 2D honeycomb networks were recovered but with different degrees of defects depending on the boundary condition. The main difference between several transitions of 2D silicene is discussed via the evolution of total energy and the change in coordination number and bond-ring distribution. Conclusions: This study provides insights into the dependency of the structure of silicene on the pressure and boundary, repre-sentedby the first-order transition at lowpressure and a congregationof disorderedlow-numbered rings into the ordered tetragonal formation at high pressure. Notably, our results have shown that silicene nanoribbon materials can be controlled by pressure to obtain unfamiliar structures such as pentagonal and tetragonal networks.
在二维材料中,以纳米带形式形成的硅烯边界在合成中起着至关重要的作用,并且可以通过控制来实现不同的特性。我们的研究旨在探讨结构偏好取决于压力承受能力和边界依赖。方法:本研究主要采用Stillinger Weber势的分子动力学模拟方法。我们对蜂窝硅烯的二维模型进行了模拟,该模型是通过高压和低压冷却从液态获得的,然后加热退火一段时间。硅烯的最终构型将在结构和热力学性质方面进行研究。结果:我们发现高压下的冷却过程形成了4重环结构,而低压下则恢复了二维蜂窝网络,但根据边界条件的不同存在不同程度的缺陷。通过总能量的演化、配位数和键环分布的变化,讨论了二维硅烯几种跃迁之间的主要区别。结论:本研究揭示了硅烯的结构对压力和边界的依赖性,表现为低压下的一阶转变和高压下无序低编号环向有序四边形结构的聚集。值得注意的是,我们的研究结果表明,硅烯纳米带材料可以通过压力控制获得不熟悉的结构,如五边形和四边形网络。
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引用次数: 0
Controlling nonsequential double ionization mechanisms of argon atoms by parallel two-color laser pulses 平行双色激光脉冲控制氩原子非顺序双电离机制
Pub Date : 1900-01-01 DOI: 10.32508/stdj.v26i2.4107
Thu D. H. Truong, H. Tran, Hanh H. Nguyen, V. Pham
Introduction: Recently, physicists have been interested in the nonsequential double ionization (NSDI) process since it provides information about the interaction between electrons in the atomic andmolecularshellsthroughtherecollistionprocess. Technically, thedevelopmentofnear-infrared laser pulses has made them one of the most useful tools for studying the electron correlation effect in atoms and molecules. Furthermore, the parallel two-color (PTC) laser pulse is a useful instrument for controlling the process of recollision in a strong laser field. In this paper, with the aim of investigating the role of ionization mechanisms governing the NSDI of argon atoms, we use a PTC laser pulse with wavelengths of 2400 nm and 1200 nm to control the motion of two electrons. We investigate the contribution of ionization mechanisms as well as the correlation dynamics of two electrons upon the change in relative phase between the two component lasers from 0 to 2 p . Method: The two-dimensional classical ensemble model is used to simulate the NSDI process, in which the motion of two electrons is governed by Newton's law. Results: The correlated two-electron momentum distribution, recolliding time, and energy distribution after the returning electron's recolliding moment are extraordinarily sensitive to the relative phase of the two lasers. To modulate the ionization mechanisms, the relative phase between two lasers is tuned. Conclusion: The results demonstrate that parallel two-color laser pulses are an effective method of controlling the correlated electron dynamics in nonsequential double ionization.
简介:近年来,物理学家对非顺序双电离(NSDI)过程非常感兴趣,因为它提供了原子和分子壳层中电子之间通过碰撞过程相互作用的信息。从技术上讲,近红外激光脉冲的发展使其成为研究原子和分子中电子相关效应的最有用的工具之一。此外,平行双色激光脉冲在强激光场中是一种有效的重收过程控制工具。本文利用波长分别为2400 nm和1200 nm的PTC激光脉冲来控制两个电子的运动,研究了电离机制在氩原子NSDI中的作用。我们研究了电离机制和两个电子的相关动力学对两组分激光器从0到2p的相对相位变化的贡献。方法:采用二维经典系综模型模拟两个电子运动受牛顿定律支配的NSDI过程。结果:相关的双电子动量分布、回碰撞时间和回碰撞瞬间后的能量分布对两束激光的相对相位异常敏感。为了调制电离机制,调谐两个激光器之间的相对相位。结论:平行双色激光脉冲是控制非顺序双电离中相关电子动力学的有效方法。
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引用次数: 0
Effects of single-particle overlap function on the 16O(p,2p)15N reaction 单粒子重叠函数对16O(p,2p)15N反应的影响
Pub Date : 1900-01-01 DOI: 10.32508/stdj.v26i2.4102
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引用次数: 0
Synthesis of a unique oligomer by means of the thiol-maleimide reaction of extending 1,1'-(methylenedi-4,1-phenylene) bismaleimide chains for the employment of self-healing polymers 通过延长1,1'-(亚甲二烯-4,1-苯基)双马来酰亚胺链的硫醇-马来酰亚胺反应合成一种独特的低聚物,用于自愈聚合物
Pub Date : 1900-01-01 DOI: 10.32508/stdj.v26i2.4049
Le-ThuT.Nguyen, N. Khai, H. Nguyen, Mai Ly Nguyen, Duc Anh Nguyen, H. Dang, T. Truong, Thi M Nguyen N K H, Song D A N Dang H H Truong T T L N
Introduction : The Diels-Alder reaction of maleimide and furan groups is being exploited in self-healing materials; hence, it is no wonder that with the ownership of the former, 1,1'-(methylenedi-4,1-phenylene) bismaleimide (BMI) counts as a potential candidate in this area. However, it displays certain discernible demerits arising from its inflexible structure. Furthermore, the maleimide group, in all likelihood, easily takes part in the Michael addition reaction with thiol groups under basic conditions. It is crucial that this element opens the door for this ingredient to be amended with a view to weathering its shortcomings. The goal of this research is to modify the structure of BMI to create a new oligomer with maleimides at the end of its chains. Method : The oligomer was synthesized by means of the reaction of the maleimides of BMI and the thiol groups of 2,2'-(ethylenedioxy) di-ethanethiol (dithiol) with the support of triethylamine (TEA). In addition, an investigation into the possibility of this reaction happening without the base catalyst was carried out. The application of a wide assortment of modern measurements ranging from 1 H-NMR and FT-IR to GPC provided some useful data about the molecular weight and whether the reaction occurred. Result : According to the information, the formation of the oligomer owning the maleimide and thiol terminal functions was observed with the help of TEA over the 24-hour timescale at room temperature, whereas that with a lack of this catalyst is impossible. Conclusion : The research will make a major contribution to the creation of new healable polymers reliant on the Diels-Alder mechanism in the foreseeable future.
介绍:马来酰亚胺与呋喃基团的Diels-Alder反应在自修复材料中的应用前景;因此,由于前者的所有权,1,1'-(亚甲二烯-4,1-苯基)双马来酰亚胺(BMI)被视为该领域的潜在候选者也就不足为奇了。然而,由于其结构不灵活,它显示出某些明显的缺点。此外,马来酰亚胺基团在碱性条件下很容易与巯基发生Michael加成反应。至关重要的是,这种元素打开了对这种成分进行修正的大门,以消除其缺点。本研究的目的是修改BMI的结构,以创建一个新的低聚物与马来酰亚胺在其链的末端。方法:在三乙胺(TEA)的支持下,由BMI的马来酰亚胺与2,2'-(乙烯二氧基)二乙硫醇(二硫醇)的巯基反应合成该低聚物。此外,还研究了在没有碱催化剂的情况下,该反应发生的可能性。从1h - nmr和FT-IR到GPC的各种现代测量方法的应用提供了一些关于分子量和是否发生反应的有用数据。结果:根据资料,在室温下,在24小时的时间尺度上,在TEA的帮助下,可以观察到具有马来酰亚胺和硫醇末端功能的低聚物的形成,而在缺乏这种催化剂的情况下是不可能形成的。结论:在可预见的未来,该研究将为创造依赖Diels-Alder机制的新型可愈合聚合物做出重大贡献。
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引用次数: 0
Toward Deep Transfer Learning for Realistic Activity Recognition in Videos 视频中真实活动识别的深度迁移学习研究
Pub Date : 1900-01-01 DOI: 10.32508/stdj.v26i1.4017
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引用次数: 0
A deep learning model of major consulting support 主要咨询支持的深度学习模型
Pub Date : 1900-01-01 DOI: 10.32508/stdj.v26i2.4087
Kha-Tu Huynh, Nga Tu Ly
Introduction : Major selection is always a matter of concern for students who have just graduated from high school and parents who have children to go to universities. Currently, there are many students who selected the wrong major, leading to unexpected learning results and wasting time and money. In fact, many students do not know which majors they are suitable for. The paper proposes a model of decision-making support in choosing majors for students immediately after graduating from high school using deep learning. Methods : The model applied the XGBoost al-gorithm to build a decision tree for classification, mining educational data from which the student's ability and learning propensity are predicted and the appropriate majors are suggested. Results : The data used for the system are collected from 1709 students' results at the high school, the survey results on personal interests and personality, the teacher's comments and the results on major selection after graduation. From these data, the authors have built a model to advise students choosing the right major to continue their higher education. Conclusion : The model is evaluated and verified through actual experiments with a high accuracy of 86% and proves the contribution of deep learning models to education.
专业选择一直是高中刚毕业的学生和有孩子要上大学的家长关心的问题。目前,有很多学生选择了错误的专业,导致意想不到的学习结果,浪费时间和金钱。事实上,很多学生都不知道自己适合哪个专业。本文提出了一种基于深度学习的高中毕业生专业选择决策支持模型。方法:该模型采用XGBoost算法构建决策树进行分类,挖掘教育数据,预测学生的能力和学习倾向,并提出适合的专业。结果:系统使用的数据来源于1709名高中学生的成绩、个人兴趣和个性调查结果、老师的评语以及毕业后的专业选择结果。根据这些数据,作者建立了一个模型来建议学生选择合适的专业继续他们的高等教育。结论:通过实际实验对该模型进行了评估和验证,准确率高达86%,证明了深度学习模型对教育的贡献。
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引用次数: 0
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Science & Technology Development Journal
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