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Destruction of the lithosphere beneath the SW margin of the São Francisco Craton evidenced by refertilized and deformed mantle xenoliths 由再肥化和变形地幔异岩石证明的圣弗朗西斯科克拉通西南缘下岩石圈的破坏情况
IF 3.9 2区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-08-12 DOI: 10.1093/petrology/egae087
Luisa Gomes Braga, Tiago Jalowitzki, Fernanda Gervasoni, Rodrigo Antonio Freitas Rodrigues, Maurizio Mazzucchelli, Tommaso Giovanardi, Marina Marques Dalla Costa, Roberto Ventura Santos, Marcelo Peres Rocha, Reinhardt Adolfo Fuck, Georgina Rubiano Lorenzoni, Gustavo Walter Bertotto
The destruction of the cratonic root has been documented for multiple cratons worldwide and is characterized by severe lithospheric thinning, extensive extensional deformation, and intense thermal activity. Here, we present detailed petrography accompanied by comprehensive geochemical and isotopic data for peridotites, pyroxenites, and eclogites from the SW margin of the São Francisco Craton that has also been severely thinned. The diamond-bearing Canastra-1 kimberlite represents a Cretaceous intrusion from the Alto Paranaíba Igneous Province and hosts garnet-bearing mantle xenoliths from different mantle sources, revealing a complex history of metasomatism/refertilization related to superimposed tectonic events since the cratonic consolidation. Eclogites (T = 978–982°C; P ~ 4.0 GPa) and pargasite-bearing websterites (T = 875–926°C; P = 2.0–3.0 GPa) represent the shallower and colder cratonic lithosphere. Mantle-derived high-MgO eclogitic clinopyroxenes show a light rare earth element (LREE)-enriched pattern (Ce/YbN = 60.90–93.63) while both clinopyroxene and garnet present high 87Sr/86Sr ratios (0.70842–0.70912) and negative εNd values (−5.6 to −7.3). These features, supported by the reconstructed whole-rock composition, suggest a mafic protolith probably metasomatized by fluid/melt derived from the overlying sedimentary rocks. The pargasite websterites are cumulates from an evolved (SiO2-rich) and hydrated basaltic andesitic magma. These xenoliths are characterized by high concentration of LREE relative to heavy-REE (HREE) in clinopyroxenes (Ce/YbN = 10.52–50.61) and pargasite (Ce/YbN = 10.26–57.06), and by the presence of Al-rich orthopyroxene. As observed in eclogites, clinopyroxene and garnet from pargasite websterites display high 87Sr/86Sr ratios (0.70894–0.71094) and strong negative εNd values (−7.2 to −13.3). Trace elements (i.e. Zr, Ti, and Y) in garnets of both rock types indicate the role of a depleted component affected by a metasomatic agent. Although we were unable to date the formation of these rocks or the metasomatic events, we suggest a possible relationship with the consolidation of Gondwana during the Neoproterozoic. Sheared lherzolites, clinopyroxenites, anhydrous websterites, and dunite are deeper fragments from the lithosphere-asthenosphere boundary (LAB: 1191–1290°C; 5.3–5.6 GPa). They have abundant kelyphitic rims around garnet grains, which indicate metasomatism promoted by the percolation of a high-temperature proto-kimberlite melt enriched in Ti, Zr, and Y. The presence of kelyphitic phlogopite with high-Ti-Cr contents reinforces this assumption. LREE-enriched clinopyroxenes (Ce/YbN = 12.06–48.02) confirm the enriched character of the silicate melt responsible for the refertilization process within the cratonic root. The proto-kimberlite metasomatism is further supported by the preferential enrichment of 87Sr/86Sr ratios (0.70560–0.70869) accompanied by positive εNd values (+1.8 to +10.10). The two-point clinopyroxene
全球已有多个克拉通根部遭到破坏的记录,其特征是岩石圈严重变薄、广泛的伸展变形和强烈的热活动。在这里,我们展示了来自圣弗朗西斯科克拉通西南边缘的橄榄岩、辉绿岩和蚀变岩的详细岩相图以及全面的地球化学和同位素数据。含钻石的卡纳斯特拉-1金伯利岩是来自上帕拉纳伊巴火成岩省的白垩纪侵入体,并包含来自不同地幔源的含石榴石的地幔异长岩,揭示了自克拉通整合以来与叠加构造事件相关的变质/再肥化的复杂历史。斜长岩(T = 978-982°C;P ~ 4.0 GPa)和含副长石的网状岩(T = 875-926°C;P = 2.0-3.0 GPa)代表了较浅和较冷的板块岩石圈。来自地幔的高氧化镁蜕皮挛辉石显示了轻稀土元素(LREE)富集模式(Ce/YbN = 60.90-93.63),同时挛辉石和石榴石都显示了较高的 87Sr/86Sr 比值(0.70842-0.70912)和负εNd 值(-5.6 至 -7.3)。这些特征以及重建的全岩成分表明,该岩体可能是由上覆沉积岩中的流体/熔体变质而成的黑云母原岩。副基性网状岩是由演化的(富含 SiO2)水合玄武安山岩岩浆累积而成的。这些闪长岩的特点是,相对于鳞辉石(Ce/YbN = 10.52-50.61)和副辉石(Ce/YbN = 10.26-57.06)中的重稀有元素(HREE),LREE 的浓度较高,并且存在富 Al 的正辉石。与在蚀变岩中观察到的一样,辉绿辉石和钠榴石显示出较高的 87Sr/86Sr 比值(0.70894-0.71094)和较强的负εNd 值(-7.2 至-13.3)。两种岩石类型的石榴石中的痕量元素(即 Zr、Ti 和 Y)都显示出受元成因影响的贫化成分的作用。虽然我们无法确定这些岩石或变质事件的形成年代,但我们认为可能与新近纪冈瓦纳大陆的整合有关。剪切岩、clinopyroxenites、无水websterites和云英岩是岩石圈-热液层边界(LAB:1191-1290°C;5.3-5.6 GPa)的较深碎片。它们在石榴石颗粒周围有丰富的鳞片状边缘,这表明富含Ti、Zr和Y的高温原金伯利岩熔体的渗流促进了变质作用。富含 LREE 的倩辉石(Ce/YbN = 12.06-48.02)证实了硅酸盐熔体的富集特征,该熔体负责板根内部的再肥化过程。87Sr/86Sr 比值(0.70560-0.70869)的优先富集以及正εNd 值(+1.8 至 +10.10)进一步证实了原金伯利岩的变质作用。两点辉石-榴辉岩 Sm-Nd 等时线得出的平均年龄为 120 ± 5 Ma,代表了寄主金伯利岩的喷发/置换年龄。这些较深的 LAB 异岩石揭示了自白垩纪冈瓦纳断裂早期,即金伯利岩喷发前不久(120 Ma),高温原金伯利岩熔体渗流引发的岩石圈强烈变薄。因此,它们为圣弗朗西斯科克拉通因热力-机械侵蚀而遭到破坏并引发其复兴提供了重要证据。
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引用次数: 0
Metamorphic origin of large nuggets of platinum-group metals: evidence from multiphase inclusions in Os-Ir-Ru alloys from the adamsfield placer, tasmania 大块铂族金属的变质起源:来自塔斯马尼亚州亚当斯菲尔德矿床的奥-铁-鲁合金中多相夹杂物的证据
IF 3.9 2区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-08-03 DOI: 10.1093/petrology/egae086
Anton Kutyrev, Vadim S Kamenetsky, Ivan F Chayka, Nikolai A Nekrylov, Lyudmila Kryuchkova, Vladimir V Shilovskikh, Alkiviadis Kontonikas-Charos, Stepan P Krasheninnikov, Anna Sapegina, Alexei L Perchuk
Platinum-group elements (PGE) are most effectively concentrated via sulfide-silicate melt immiscibility; however, under sulfide-undersaturated conditions, PGE may exhibit highly-siderophile behaviour and occur as native metals and alloys. In this case, they can form μm-size inclusions within Cr-spinel, but also large nuggets (up to several kilograms), found in chromitites and related placer deposits. The exact formation mechanism of such large nuggets and accumulations of PGE unrelated to sulfide melts remains controversial due to mass balance issues. In this study of multiphase inclusions in Os-Ir-Ru nuggets from the Adamsfield placer district (Tasmania, Australia), we constrain their crystallization environment. Multiphase inclusions comprise variable proportions of hornblende, enstatite, quartz, anthophyllite, anorthite, chlorite and native iridium and coexist with single-phase olivine and Cr-spinel inclusions. The heterogeneity in phase and chemical composition of the inclusions indicates a complex origin from an inhomogeneous source media. This is corroborated by grain scale disequilibrium mineral assemblages, where forsterite and quartz are both included within a single osmium grain. Our proposed multi-stage origin of Adamsfield Os-Ir-Ru nuggets involved magmatic olivine-Cr-spinel-Os-Ir-Ru cumulates in peridotite bodies that were subsequently overprinted by various hydrothermal and metamorphic processes, including serpentinization or growth of Os-Ir-Ru from supercritical fluids. The final metamorphic stage resulted in the obliteration of Os-Ir-Ru zonation, culminating in the current assemblage of inclusions.
铂族元素(PGE)通过硫化物-硅酸盐熔体的不溶性得到最有效的富集;然而,在硫化物不饱和的条件下,铂族元素可能会表现出高度亲硒的行为,并以原生金属和合金的形式出现。在这种情况下,它们可以在铬尖晶石中形成微米大小的包裹体,也可以在铬铁矿和相关的块状矿床中形成大型金块(重达几公斤)。由于质量平衡问题,这种与硫化物熔体无关的大型金块和 PGE 聚集的确切形成机制仍存在争议。在这项对亚当斯菲尔德(澳大利亚塔斯马尼亚州)块矿区的 Os-Ir-Ru 金块中多相包裹体的研究中,我们对其结晶环境进行了分析。多相包裹体由不同比例的角闪石、英安岩、石英、直闪石、阳起石、绿泥石和原生铱组成,并与单相橄榄石和铬尖晶石包裹体共存。包裹体在相位和化学成分上的异质性表明其来源复杂,来自不均匀的源介质。晶粒尺度的不平衡矿物组合也证实了这一点,在一个锇晶粒中同时包含了紫锂辉石和石英。我们提出的亚当斯菲尔德 Os-Ir-Ru 金块的多阶段成因涉及橄榄岩体中的岩浆橄榄石-Cr-尖晶石-Os-Ir-Ru 堆积物,这些堆积物随后被各种热液和变质过程覆盖,包括蛇纹石化或超临界流体中 Os-Ir-Ru 的生长。最后的变质阶段导致了Os-Ir-Ru分带的消失,最终形成了目前的包裹体组合。
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引用次数: 0
Tracing Lower Crustal Contamination in Continental Arc Magmas Using Sr-Nd-Hf Isotopes: a Combined in-Situ and Bulk Rock Approach Applied to the Adamello Batholith 利用 Sr-Nd-Hf 同位素追踪大陆弧岩浆中的下地壳污染:应用于阿达梅洛岩浆岩的原位与块岩相结合的方法
IF 3.9 2区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-07-30 DOI: 10.1093/petrology/egae084
Manuel Pimenta Silva, Andrea Giuliani, Urs Schaltegger, Massimo Chiaradia, Alexandra Nowak, Blair Schoene, Peter Ulmer, Othmar Müntener
The incremental construction of plutons characterises magmatic activity in arc settings, where new continental crust is produced. This polyphasic growth entails interactions with one or more crustal components, which modulate the geochemical and isotopic compositions of the newly formed crust. However, the early stages of magmatism are not always preserved due to obliteration by later magmatic pulses. Spatial migration of magmatism during the construction of the Adamello batholith (Northern Italy) enables the examination of the early pulses of pluton formation, thus allowing a time-integrated study of the relative importance of crystallisation-differentiation and contamination in a continental arc setting. We conducted a detailed textural, major and trace element, and Sr isotopic study of plagioclase from the first intrusive pulses of the Adamello batholith, combined with new major, trace element and Sr-Nd isotopic analyses of bulk rock samples across the entire Adamello batholith. We selected well-characterised samples with published CA-ID-TIMS 206Pb-238U ages and Hf isotopic composition for zircons. Strontium isotopes in plagioclase from the same samples were determined by laser ablation multi-collector ICP-MS. The tonalitic samples in the early magmatic stages show elevated but constant Sr isotopic compositions despite large variations in anorthite contents (An90 to An13), indicating that crustal contamination occurred before significant differentiation. Invariant bulk-rock 87Sr/86Sr with variable SiO2 in all superunits of the Adamello batholith further supports contamination preceding significant melt differentiation. Contamination by lower crustal basement lithologies is due to the increasing thermal anomaly triggered by consecutive magmatic injections coupled with the heterogeneous and less restitic nature of the basement in the early stage of the magmatic system (i.e. before consumption of fusible components). In addition, we observe significant variability in crustal contamination proxies (e.g. 87Sr/86Srplag, 87Sr/86Srbulk, εNdbulk, εHfzircon) during the initial phases of magmatism. This variability likely reflects the uneven distribution of positive thermal anomalies in the lower crust during early magmatic stages as well as the diverse lithological and isotopic makeup of the lower crust. The processes identified in our case study are pertinent to continental arc magmatism, particularly where magmas interact with a metapelitic lower crust.
在产生新大陆地壳的弧形环境中,岩浆活动的特点是柱状构造的递增。这种多相生长需要与一个或多个地壳成分相互作用,从而改变新形成地壳的地球化学和同位素组成。然而,由于后期岩浆脉冲的湮没,岩浆活动的早期阶段并不总能保存下来。在阿达梅洛浴成岩(意大利北部)的构造过程中,岩浆活动的空间迁移使我们能够对岩浆形成的早期脉冲进行研究,从而能够对大陆弧环境中结晶-分异和污染的相对重要性进行时间整合研究。我们对来自阿达梅洛岩床第一批侵入脉冲的斜长石进行了详细的纹理、主要元素、痕量元素和锶同位素研究,并对整个阿达梅洛岩床的大块岩石样本进行了新的主要元素、痕量元素和锶钕同位素分析。我们选择了具有已公布的 CA-ID-TIMS 206Pb-238U 年龄和锆石 Hf 同位素组成的特征良好的样本。通过激光烧蚀多收集器 ICP-MS 测定了相同样品中斜长石的锶同位素。尽管阳起石含量(An90 至 An13)变化很大,但早期岩浆阶段的黑云母样品却显示出较高但恒定的锶同位素组成,这表明在显著分化之前发生了地壳污染。在阿达梅洛浴成岩的所有超单元中,块岩87Sr/86Sr不变,SiO2可变,这进一步证明了在熔体显著分化之前的污染。下地壳基底岩性的污染是由于连续的岩浆注入引发的热异常不断增加,以及岩浆系统早期(即可熔成分消耗之前)基底的异质性和较少的重岩性造成的。此外,我们还观察到岩浆活动初期地壳污染代用指标(如 87Sr/86Srplag、87Sr/86Srbulk、εNdbulk、εHfzircon)的显著变化。这种变化很可能反映了岩浆早期阶段下地壳正热异常的不均匀分布,以及下地壳岩性和同位素构成的多样性。我们的案例研究确定的过程与大陆弧岩浆活动有关,特别是岩浆与偏闪长岩下地壳相互作用的情况。
{"title":"Tracing Lower Crustal Contamination in Continental Arc Magmas Using Sr-Nd-Hf Isotopes: a Combined in-Situ and Bulk Rock Approach Applied to the Adamello Batholith","authors":"Manuel Pimenta Silva, Andrea Giuliani, Urs Schaltegger, Massimo Chiaradia, Alexandra Nowak, Blair Schoene, Peter Ulmer, Othmar Müntener","doi":"10.1093/petrology/egae084","DOIUrl":"https://doi.org/10.1093/petrology/egae084","url":null,"abstract":"The incremental construction of plutons characterises magmatic activity in arc settings, where new continental crust is produced. This polyphasic growth entails interactions with one or more crustal components, which modulate the geochemical and isotopic compositions of the newly formed crust. However, the early stages of magmatism are not always preserved due to obliteration by later magmatic pulses. Spatial migration of magmatism during the construction of the Adamello batholith (Northern Italy) enables the examination of the early pulses of pluton formation, thus allowing a time-integrated study of the relative importance of crystallisation-differentiation and contamination in a continental arc setting. We conducted a detailed textural, major and trace element, and Sr isotopic study of plagioclase from the first intrusive pulses of the Adamello batholith, combined with new major, trace element and Sr-Nd isotopic analyses of bulk rock samples across the entire Adamello batholith. We selected well-characterised samples with published CA-ID-TIMS 206Pb-238U ages and Hf isotopic composition for zircons. Strontium isotopes in plagioclase from the same samples were determined by laser ablation multi-collector ICP-MS. The tonalitic samples in the early magmatic stages show elevated but constant Sr isotopic compositions despite large variations in anorthite contents (An90 to An13), indicating that crustal contamination occurred before significant differentiation. Invariant bulk-rock 87Sr/86Sr with variable SiO2 in all superunits of the Adamello batholith further supports contamination preceding significant melt differentiation. Contamination by lower crustal basement lithologies is due to the increasing thermal anomaly triggered by consecutive magmatic injections coupled with the heterogeneous and less restitic nature of the basement in the early stage of the magmatic system (i.e. before consumption of fusible components). In addition, we observe significant variability in crustal contamination proxies (e.g. 87Sr/86Srplag, 87Sr/86Srbulk, εNdbulk, εHfzircon) during the initial phases of magmatism. This variability likely reflects the uneven distribution of positive thermal anomalies in the lower crust during early magmatic stages as well as the diverse lithological and isotopic makeup of the lower crust. The processes identified in our case study are pertinent to continental arc magmatism, particularly where magmas interact with a metapelitic lower crust.","PeriodicalId":16751,"journal":{"name":"Journal of Petrology","volume":"49 1","pages":""},"PeriodicalIF":3.9,"publicationDate":"2024-07-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141885302","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The Age of Granulite-Facies Metamorphism in the Ivrea-Verbano Zone (NW Italy) Determined through in-Situ U–Pb Dating of Garnet 通过石榴石的原位 U-Pb 定年测定伊夫雷亚-维尔巴诺区(意大利西北部)花岗岩-成因变质作用的年龄
IF 3.9 2区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-07-30 DOI: 10.1093/petrology/egae083
Omar Bartoli, Leo J Millonig, Bruna B Carvalho, Horst R Marschall, Axel Gerdes
Rates of melt production, extraction and crystallization, as well as scales of melt transfer and interaction with their residuum change continuously in migmatite and granulite, affecting the behavior of monazite and zircon as time capsules. Therefore, accessory mineral chronometers may be ambiguous and incomplete in providing an overview of the temperature–time evolution of high-grade metamorphic rocks. In this study, we applied the novel technique of in-situ U–Pb dating of garnet to the archetypal lower continental crust of the Ivrea-Verbano Zone (IVZ), NW Italy. In the IVZ, the temporal relationship between granulite-facies metamorphism and mafic underplating has long been debated, because of the interplay between tectonic, magmatic, metamorphic and metasomatic processes over a period of more than a hundred million years. Garnet from mafic and pelitic granulites yielded U–Pb ages between 287.4 ± 4.9 Ma and 280.1 ± 12.4 Ma, overlapping within uncertainty the time proposed for the emplacement of the Mafic Complex (286–282 Ma). These results indicate that the thermal climax in granulitic rocks was caused by mafic underplating and concomitant asthenospheric upwelling, rather than being inherited from the post-Variscan Carboniferous evolution. Providing robust dating of garnet with as low as 4 ng/g U, this study demonstrates the strength of garnet petrochronology in resolving complex tectono-metamorphic histories of high-grade terranes. It also represents a further step forward towards establishing garnet as part of the in-situ U–Pb geochronology repertoire.
在辉绿岩和花岗岩中,熔体产生、萃取和结晶的速率,以及熔体转移和与其残余物相互作用的规模都在不断变化,影响着作为时间胶囊的独居石和锆石的行为。因此,附属矿物计时仪在概述高品位变质岩的温度-时间演化方面可能是模糊和不完整的。在这项研究中,我们将石榴石原位 U-Pb 定年的新技术应用于意大利西北部伊夫雷亚-韦尔巴诺区(IVZ)的典型下大陆地壳。在伊夫雷亚-维尔巴诺区(IVZ),由于构造、岩浆、变质和变质过程在一亿多年的时间里相互作用,花岗岩成因变质作用与黑云母底侵之间的时间关系一直存在争议。从黑云母和辉绿岩花岗岩中提取的石榴石的 U-Pb 年龄介于 287.4 ± 4.9 Ma 和 280.1 ± 12.4 Ma 之间,与所提出的黑云母复合体的形成时间(286-282 Ma)在不确定的范围内重叠。这些结果表明,花岗岩的热高潮是由黑云母下伏和随之而来的星体层上涌造成的,而不是从后石炭纪演化中继承而来。这项研究提供了低至 4 ng/g U 的石榴石可靠年代测定,证明了石榴石岩石年代学在解析高品位陆相复杂构造-变质历史方面的优势。它还标志着在将石榴石确定为原位 U-Pb 地质年代的一部分方面又向前迈进了一步。
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引用次数: 0
PROGRESSIVE STRAIN LOCALIZATION AND FLUID FOCUSING IN MANTLE SHEAR ZONES DURING RIFTING: PETROSTRUCTURAL CONSTRAINTS FROM THE ZABARGAD PERIDOTITES, RED SEA 断裂过程中地幔剪切带中的渐进应变定位和流体聚焦:来自红海扎巴尔加德橄榄岩的岩石结构制约因素
IF 3.9 2区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-07-24 DOI: 10.1093/petrology/egae081
M Chardelin, A Tommasi, J A Padrón-Navarta
This article documents the evolution of pressure and temperature conditions and the successive influence of hydrous melts and aqueous fluids on the operation of extensional shear zones, which exhumed mantle slivers from deep lithospheric or asthenospheric depths, in a rift-to-drift setting. These results are based on a re-analysis of 40 samples from three peridotite massifs of Zabargad island in the northern Red Sea. By integrating high-resolution mapping of the microstructure by electron backscattered diffraction with recent developments in barometry for plagioclase-bearing peridotites and thermodynamic modelling of peridotitic compositions, this study: (1) constrains the temporal and spatial evolution of petrological and tectonic processes in the shallow mantle during rifting and (2) documents the presence of melts or aqueous fluids throughout the activity of the shear zones, unravelling substantial feedback between petrological and tectonic processes. Thermobarometry and thermodynamic modelling, constrained by the microstructural observations, document progressive strain localization associated with shearing under decreasing pressure and temperature, from near solidus conditions at >1 GPa (in the north and central peridotite massifs) or ~0.7 GPa (in the southern massif) to < 600°C and <0.3 GPa in all three massifs. The data substantiate local aqueous fluid saturation in the shear zones. This together with higher contents of hydrous minerals in ultramylonites indicate fluid focusing in the shear zones, with seawater ingress extending to >10 km depth. The presence of melts or fluids enabled concurrent dislocation and dissolution-precipitation creep, resulting in weakening of the shear zones. However, fluid supply was spatially heterogeneous and likely intermittent, with equilibrium achieved only locally in the ultramylonites. The present study documents therefore how the feedback between progressive strain localization and fluid-focusing in extensional shear zones contributes to thinning and exhumation of the mantle during continental rifting and the rift-to-drift transition.
这篇文章记录了压力和温度条件的演变,以及含水熔体和含水流体对延伸剪切带运行的连续影响,这些剪切带在断裂到漂移的环境中,从岩石圈或天体层深处吐出地幔碎片。这些结果基于对来自红海北部扎巴尔加德岛三个橄榄岩岩块的 40 个样本的重新分析。这项研究通过电子反向散射衍射对微观结构进行高分辨率测绘,并结合含斜长石橄榄岩的气压测定法和橄榄岩成分热力学模型的最新进展,得出了以下结果:(1) 制约了断裂期间浅地幔岩石学和构造过程的时空演变;(2) 记录了整个剪切带活动过程中熔体或水液的存在,揭示了岩石学和构造过程之间的实质性反馈。在微结构观测的制约下,热压计和热力学模型记录了在压力和温度不断降低的情况下,与剪切有关的应变逐渐局部化,从北部和中部橄榄岩岩块的近固结条件(1 GPa)或南部岩块的约 0.7 GPa,到所有三个岩块的 600°C 和 0.3 GPa。这些数据证实了剪切带的局部水液饱和。这一点以及超基性岩中较高的含水矿物含量表明,流体集中在剪切带,海水进入的深度可达10千米。熔体或流体的存在使位错和溶解-沉淀蠕变同时发生,导致剪切带减弱。然而,流体供应在空间上是异质的,而且很可能是间歇性的,只有在超基性岩的局部地区才能达到平衡。因此,本研究记录了延伸剪切带中的渐进应变局部化与流体集中之间的反馈如何在大陆裂陷和裂陷向裂陷过渡期间促进地幔的减薄和排挤。
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引用次数: 0
In-situ Lu-Hf garnet dating of Archean deep crust granulites from the polymetamorphic Grenville Front Tectonic Zone 对来自多变质格伦维尔前沿构造带的阿尔歇斯山深壳花岗岩进行原位卢-铪石榴石测年
IF 3.9 2区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-07-19 DOI: 10.1093/petrology/egae080
Antoine Godet, Marine Jouvent, Christiaan Laureijs, Carl Guilmette, Kyle Larson, Mark Coleman, Jérémie Darveau, Myriam Côté-Roberge
Recent advances in geochronological techniques now allow the ability to efficiently decipher the timing and duration of geological processes in complex high-grade polymetamorphosed orogenic terranes. This is the case of the Grenville Front Tectonic Zone, which truncates the Superior Craton to the southeast. The zone exposes parautochtonous Archean rocks that underwent mid- to high-pressure granulite facies metamorphism of uncertain age. The metamorphic assemblages have been either interpreted as Archean and associated with the final stages of the Superior craton assembly, or as the result of Mesoproterozoic Grenvillian metamorphism, based on cross-cutting relationships and traditional geochronology methods such as U-Pb zircon and 40Ar-39Ar mica dating. Herein, we revisit the extent of the Grenvillian metamorphic overprint in the parautochtonous domain and provide new age constraints for granulite-facies metamorphic assemblages through in-situ garnet dating within migmatitic paragneiss, migmatitic orthogneiss, and mafic granulites, combined with in-situ trace element mapping. Six samples, which show bell-shaped and occasionally sharp and oscillatory lutetium growth zoning in garnet, yield garnet Lu-Hf isochrons with identical Archean dates of c. 2.6 Ga. Sparce analyses of material trend toward Grenvillian ages (c. 1 Ga) in one sample from which garnet shows lutetium zoning consistent with post-growth fluid-assisted disturbance. Overall, our results indicate that the widespread granulite-facies metamorphism within the Grenville Front Tectonic Zone is dominantly late Neoarchean in age, unveiling a rare exposure of Archean lower crust in the southeastern Superior Craton. Our results also point towards a limited Grenvillian metamorphic overprint though the spatial extent and precise thermal conditions of this metamorphism are still unknown. The results presented herein demonstrate the potential of in-situ isotopic geochronology on rock-forming minerals like garnet in polymetamorphic terranes.
地质年代学技术的最新进展使我们现在能够有效地解读复杂的高品位多变质造山地层地质过程的时间和持续时间。格勒尼维尔前沿构造带就属于这种情况,它将苏必利尔克拉通向东南方向截断。该构造带揭露了经历了年龄不确定的中高压花岗岩变质作用的准奥陶纪岩石。根据横切关系和传统的地质年代学方法(如 U-Pb 锆石和 40Ar-39Ar 云母测年法),这些变质组合要么被解释为 Archean 时代,与 Superior 克拉顿组装的最后阶段有关,要么被解释为中新生代 Grenvillian 变质作用的结果。在这里,我们通过对偏闪长岩、偏闪长岩正长岩和黑云母花岗岩进行原位石榴石定年,并结合原位痕量元素测绘,重新审视了格勒维里安变质作用在副奥陶系的覆盖范围,并为花岗岩层变质组合提供了新的年龄约束。六个样品的石榴石呈现钟形,偶尔也有尖锐和振荡的镥生长分带,这些样品的石榴石lu-Hf等时线与约2.6 Ga的Archean年代完全相同。在一个样品中,对材料进行的斯帕斯分析趋向于格伦维里安时代(约 1 Ga),该样品中的石榴石显示出与生长后流体辅助扰动一致的镥分带。总之,我们的研究结果表明,格伦维尔前构造带内广泛存在的花岗岩成因变质作用在年龄上主要是新奥陶纪晚期,揭示了东南部苏必利尔克拉通罕见的奥陶纪下地壳露头。我们的研究结果还表明,虽然变质作用的空间范围和精确热条件尚不清楚,但格林维利变质作用的覆盖范围是有限的。本文介绍的结果证明了对多变质地层中石榴石等成岩矿物进行原位同位素地质年代研究的潜力。
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引用次数: 0
The crystallization of continental flood basalt (CFB) lavas: insights from textural studies 大陆洪积玄武岩(CFB)熔岩的结晶:纹理研究的启示
IF 3.9 2区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-07-18 DOI: 10.1093/petrology/egae082
Aristle Monteiro, Tushar Mittal, Raymond Duraiswami, Stephen Self
Continental flood basalts provinces are the product of the largest known volumetric eruptions on Earth (~104 km3), with individual flow fields commonly covering well over 10 000 km2 with a mean lava thickness of over 5 m. Studies focusing on the emplacement style of such lava flows have relied extensively on morphological observations and comparisons with modern lava flows and experimental analogs. In the present study, we compare the textures of flood basalt lavas with those from different eruption settings all over the world using data collected from pre-existing literature to gain detailed insights into the style of eruption. Comparison of crystal size distribution (CSD) data indicates that the eruption style of CFBs is similar to those of modern-day fissure eruptions (e.g. Iceland). This matches inferences based on observations of morphology. We also use a 1D thermal model to estimate the depth dependent cooling rates within a single lava lobe and test the validity of assumptions built into the formulation of these models. The results reveal that, on average, flood basalt lavas need to conductively cool much faster than we would expect (up to order of ~102 times faster) to match the textural observations. The model is also frequently unable to replicate the observed depth-wise relative variations in length with depth for CFB lavas. Furthermore, the calculated cooling rates from crystal shapes also do not match those calculated from crystal lengths, indicating the assumptions in cooling flow models need to be modified for large CFB flow fields. Given the large areas of CFB flow-fields and the relatively long eruption times inferred for the emplacement of individual flow fields, we hypothesize that inflation of lobes and formation of new lobes via breakouts combined with variable eruption rates are key processes that are missing when modeling the cooling of these flow fields. Accounting for these processes is essential to derive accurate cooling rates, which is important to better understand the environmental impact CFBs have at the time of emplacement.
大陆洪积玄武岩群是地球上已知体积最大的喷发(约104立方公里)的产物,单个流场的面积通常远远超过1万平方公里,平均熔岩厚度超过5米。对这类熔岩流的喷发方式的研究广泛依赖于形态观察以及与现代熔岩流和实验类似物的比较。在本研究中,我们利用从已有文献中收集到的数据,将洪积玄武岩熔岩的质地与世界各地不同喷发环境下的熔岩进行比较,以详细了解喷发的风格。晶体尺寸分布(CSD)数据的比较表明,CFB 的喷发方式与现代裂隙喷发(如冰岛)的喷发方式相似。这与基于形态观测的推断相吻合。我们还使用一维热模型来估算单个熔岩裂隙内随深度变化的冷却率,并检验这些模型的假设是否有效。结果显示,平均而言,洪积玄武岩熔岩的传导冷却速度要比我们预期的快得多(快达约102倍),才能与纹理观测结果相吻合。该模型还经常无法复制观测到的 CFB 熔岩长度随深度的相对变化。此外,根据晶体形状计算出的冷却速度与根据晶体长度计算出的冷却速度也不一致,这表明对于大面积的CFB流场,冷却流模型的假设条件需要修改。鉴于 CFB 流场的面积很大,而且推断单个流场的喷发时间相对较长,我们推测,裂片的膨胀和通过断裂形成新裂片以及喷发速率的变化是这些流场冷却模型中缺少的关键过程。考虑到这些过程对于得出准确的冷却率至关重要,而准确的冷却率对于更好地了解 CFB 在喷发时对环境的影响非常重要。
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引用次数: 0
Experimental Constraints on the Storage Conditions and Differentiation of High-Ti Basalts from the Panzhihua and Hongge Layered Intrusions, SW China 中国西南攀枝花和红格层状侵入体高钛玄武岩储集条件和分异的实验约束
IF 3.9 2区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-07-10 DOI: 10.1093/petrology/egae078
Dachuan Wang, Tong Hou, Roman Botcharnikov, Sarah Haselbach, Florian Pohl, Renat R Almeev, Andreas Klügel, Meng Wang, Jingyi Qin, Zhaochong Zhang, Francois Holtz
High-Ti basalts are commonly believed to represent parental magmas leading to the formation of mafic-ultramafic layered intrusions, such as Late Permian Panzhihua and Hongge in the Emeishan Large Igneous Province (SW China). Consequently, elucidation of the crystallisation and crustal differentiation of high-Ti basalts is critical for our understanding of the petrogenesis of these layered intrusions and the associated oxide ore mineralisation. Here, we present the results of crystallisation experiments carried out in internally heated pressure vessels using a primitive high-Ti basaltic composition. The experiments were conducted at 100 and 300 MPa, in the temperature interval of 950-1200 °C and with water activities (aH2O) from 0 to 1. The oxygen fugacity (fO2) was controlled and varied from FMQ - 1 to FMQ + 3.3 log units (FMQ corresponds to fayalite-quartz-magnetite buffer). The main mineral phases are olivine, clinopyroxene and plagioclase, accompanied by Cr-Fe-Ti-oxides, orthopyroxene, apatite and amphibole, depending on the conditions. Redox conditions primarily influence the stability fields of Cr-Fe-Ti oxides. Clinopyroxene, orthopyroxene and amphibole are pressure-dependent and have larger stability fields under high pressure conditions. The olivine→orthopyroxene and olivine→amphibole peritectic reactions are observed. Comparisons of phase equilibria between this study and experiments conducted with parental magma of Skaergaard layered intrusion demonstrate the effect of bulk system composition. For instance, ilmenite crystallisation is determined by intrinsic parameters such as fO2 but also by additional compositional parameters (e.g., melt Ti, Fe, Al and Mg content). Although COMAGMAT and MELTS modelling results generally reproduce the crystallisation sequence, only the stability field of clinopyroxene and its composition are perfectly modelled. The comparison of experimental results with the rocks from the lowest units of Panzhihua and Hongge layered intrusions are applied to constrain storage conditions in the magma reservoirs. Compared to Hongge, we conclude that the Panzhihua magma chamber was probably located at a shallower depth (~3-6 km), that magma crystallisation started at lower temperatures (~1125-1100 °C), higher fO2 (~FMQ + 1 to FMQ + 2), and that its initial melt H2O content was lower (~0.5-1 wt.%).
高钛玄武岩通常被认为是导致岩浆-超岩浆层状侵入体形成的母岩,如中国西南部峨眉山大火成岩省的晚二叠世攀枝花和红格。因此,阐明高钛玄武岩的结晶和地壳分异对于我们了解这些层状侵入体的成岩过程以及相关的氧化矿成矿过程至关重要。在此,我们介绍使用原始高钛玄武岩成分在内部加热的压力容器中进行的结晶实验结果。实验在 100 和 300 兆帕,950-1200 °C的温度区间内进行,水活度(aH2O)从 0 到 1。氧富集度(fO2)在 FMQ - 1 到 FMQ + 3.3 对数单位(FMQ 相当于辉绿岩-石英-磁铁矿缓冲)之间变化。主要矿物相为橄榄石、倩辉石和斜长石,根据条件不同,还有铬-铁-钛-氧化物、正长石、磷灰石和闪石。氧化还原条件主要影响铬-铁-钛氧化物的稳定性。霞石、正长石和闪石与压力有关,在高压条件下稳定场较大。观察到橄榄石→正辉石和橄榄石→闪石的包晶反应。这项研究与斯卡尔加德层状侵入体母岩浆实验之间的相平衡比较表明了体系成分的影响。例如,钛铁矿的结晶是由 fO2 等固有参数决定的,但也受其他成分参数(如熔体中的钛、铁、铝和镁含量)的影响。虽然 COMAGMAT 和 MELTS 建模结果总体上再现了结晶顺序,但只有霞石的稳定场及其成分是完美建模的。将实验结果与攀枝花和红格层状侵入体最低单元的岩石进行对比,用于约束岩浆储层的储集条件。与红格相比,我们得出结论:攀枝花岩浆腔可能位于较浅的深度(约3-6千米),岩浆结晶开始于较低的温度(约1125-1100 °C)、较高的fO2(约FMQ + 1至FMQ + 2),其初始熔体H2O含量较低(约0.5-1 wt.%)。
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引用次数: 0
The role of latent heat buffering in the generation of high-silica rhyolites 潜热缓冲在高硅流纹岩生成过程中的作用
IF 3.9 2区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-06-25 DOI: 10.1093/petrology/egae072
L Tavazzani, R C Economos, S Peres, G Demarchi, S Sinigoi, O Bachmann
The physical process of crystal-melt separation is responsible for the accumulation of small to very large volumes (>100 km3) of eruptible rhyolitic melt in the shallow crust. Granitic intrusions, although providing a terminal, time-integrated image of melt segregation processes, host an unmatched record of the physical properties controlling mechanisms and rates of interstitial melt extraction from a crystal-rich source. We applied mass balance calculations and thermodynamic modeling simulations to an extensive bulk rock geochemistry dataset (>150 samples) collected in a Permian upper-crustal granitoid intrusion of the Italian Southern Alps. Textural and geochemical evidence indicate that this intrusion constituted a single, zoned magma body, with a crystal-rich base and a thick (~2 km), high-silica cap (75-77 wt% SiO₂). The large compositional variability of the crystal-rich materials (cumulate) suggests variable degrees of melt extraction efficiency and corresponding terminal porosities. Specifically, the loosely bimodal distribution of porosity values (φ) indicates that at least two distinct melt segregation mechanisms were operating in this system, which produced both high (0.65-0.45) and low terminal porosities (0.45-0.25) in the cumulate materials. Modeling of latent heat budget shows that coexistence of cumulate products with differing terminal porosity signature can be explained by melt segregation processes taking place at different depths across a thick, interconnected magmatic reservoir with an initial homogenous water content (~4 wt% H2O). Deep in the mush column, low water activities (aH₂O<0.5) promoted thermal buffering of cooling magma at high crystallinities, enabling residual melt extraction by percolation through a crystalline framework accompanied by compaction. Instead, at shallower depths, high water activities (aH₂O>0.5) ensured prolonged magma residence at porosities that promoted crystal melt separation via hindered settling. Distinct melt extraction processes, acting synchronously but at different depths in vertically extensive silicic mush columns, can account for the large volumes of residual, haplogranitic melt mobilized during the relatively short lifespan of upper crustal magma reservoirs (~105 years).
晶体-熔体分离的物理过程是在浅地壳中积累少量到大量(>100 km3)可喷发流纹岩熔体的原因。花岗岩侵入体虽然提供了熔体分离过程的终端、时间整合图像,但对于控制从富含晶体的源头提取间隙熔体的机制和速率的物理特性,却有着无与伦比的记录。我们将质量平衡计算和热力学模型模拟应用于在意大利南阿尔卑斯山二叠纪上地壳花岗岩侵入体中采集的大量岩石地球化学数据集(150 个样本)。纹理和地球化学证据表明,该侵入体是一个单一的带状岩浆体,具有富含晶体的底部和厚(约 2 千米)的高硅帽(75-77 wt% SiO₂)。富晶体物质(积聚物)的成分变化很大,表明熔体萃取效率和相应的末端孔隙度程度各不相同。具体来说,孔隙度值(φ)的松散双峰分布表明,在该系统中至少有两种不同的熔体偏析机制在起作用,从而在堆积物中产生了高孔隙度(0.65-0.45)和低孔隙度(0.45-0.25)。潜热预算模型显示,具有不同末端孔隙度特征的堆积产物的共存,可以解释为熔体偏析过程发生在一个厚的、相互连接的岩浆储层的不同深度,其初始含水量相同(约4 wt% H2O)。在钙钛矿柱深处,低水活度(aH₂O<0.5)促进了高结晶度冷却岩浆的热缓冲,使残余熔体通过结晶框架渗流萃取,并伴随着压实。相反,在较浅的深度,高水活度(aH₂O>0.5)确保了岩浆在孔隙中长时间停留,通过受阻沉降促进了晶体熔体分离。在垂直分布的硅质岩浆柱中,不同的熔体萃取过程在不同深度同步发生作用,这可以解释为什么在上地壳岩浆储层相对较短的生命周期(约105年)内,会有大量的残余杂岩熔体被动员起来。
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引用次数: 0
Bulk rock and olivine chemistry and isotopes of 106-58 Ma basalts from Liaodong Peninsula and its adjacent areas: Implications for secular evolution of the big mantle wedge in eastern China 辽东半岛及其邻近地区106-58 Ma玄武岩的块岩和橄榄石化学及同位素:中国东部大地幔楔世代演化的意义
IF 3.9 2区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-06-21 DOI: 10.1093/petrology/egae071
Chao Zhang, Qiang Ma, Lu-Bing Hong, Hong-Kun Dai, Liang Ma, Yi-Gang Xu, Jian-Ping Zheng, Hui-Ying Cao
The subducting Pacific slab stagnates in the mantle transition zone and creates a big mantle wedge (BMW) system in East Asia. A similar BMW structure may have already existed since the Early Cretaceous (>120 Ma), but how such a structure evolved from Early Cretaceous to the present day remains unclear. We address this issue by comparing compositions and source heterogeneity of the 106-58 Ma basalts from Liaodong Peninsula and its adjacent areas (LPAA) in eastern China, with those formed in the modern BMW setting. The LPAA basalts display oceanic island basalts-like trace element patterns. Elemental and isotopic compositions of these basalts and their olivine phenocrysts point to peridotite and two recycled components in their source. One recycled component is altered lower oceanic crust given the low δ18Oolivine (2.8-5.2‰) of the ~99 Ma Liaoyuan alkali basalts. The second component consists of altered upper oceanic crust and pelagic sediments indicated by high δ18Oolivine (>6.0‰), represented by the ~58 Ma Luanshishanzi alkali basalts. The depleted mantle-like isotopes of these two components suggests derivation from a young HIMU source with characteristics of the Izanagi plate (e.g., Indian Ocean-type Sr-Nd-Pb-Hf isotopes), which may have resided in the mantle transition zone at that time. Our results reveal strong similarities between chemical and source characteristics of the mantle sampled by the 106-58 Ma LPAA basalts and those derived from the modern BMW. This implies that the BMW structure has been present since the Early Cretaceous, probably having lasted more than 120 Myr, and modulating the chemical properties of the upper mantle and influencing a variety of geological processes.
俯冲的太平洋板块停滞在地幔过渡带,在东亚形成了一个大地幔楔(BMW)系统。类似的大地幔楔结构可能早在早白垩世(120 Ma)就已存在,但这种结构如何从早白垩世演化至今仍不清楚。我们通过比较中国东部辽东半岛及其邻近地区(LPAA)106-58 Ma玄武岩与现代BMW环境中形成的玄武岩的成分和来源异质性来解决这个问题。辽东半岛及其邻近地区的玄武岩显示出类似大洋岛屿玄武岩的微量元素模式。这些玄武岩及其橄榄石表晶的元素和同位素组成表明,它们的来源是橄榄岩和两种再循环成分。其中一种再循环成分是经过改造的下洋壳,因为辽源碱性玄武岩的δ18O橄榄石含量较低(2.8-5.2‰)。第二部分由δ18Oolivine较高(>6.0‰)的蚀变上洋地壳和远洋沉积物组成,以〜58 Ma琅石山子碱性玄武岩为代表。这两种成分的贫地幔类同位素表明,它们来自年轻的HIMU源,具有伊邪那岐板块的特征(如印度洋型Sr-Nd-Pb-Hf同位素),当时可能居住在地幔过渡带。我们的研究结果表明,106-58 Ma LPAA玄武岩所采样的地幔化学特征和来源特征与现代BMW的地幔特征非常相似。这意味着 BMW 结构自早白垩世以来就一直存在,持续时间可能超过 120 Myr,并调节着上地幔的化学特性,影响着各种地质过程。
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引用次数: 0
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Journal of Petrology
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