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Magnetovolume effect in ferromagnetic metals 铁磁性金属中的磁体积效应
Pub Date : 1988-09-01 DOI: 10.1088/0305-4608/18/9/025
I. Takahashi, M. Shimizu
It is shown that the magnetovolume effect in ferromagnetic metals can be estimated by using two functions, b(M,V)= delta F(M,V)/ delta M and p(M,V)=- delta F(M,V)/ delta V, where F(M,V) is the free energy of the system with magnetic moment M and volume V. The magnetovolume effect in ferromagnetic BCC iron at zero temperature is estimated numerically by using the spin density functional formalism. The band structure used in the numerical calculation is obtained by the linear muffin-tin orbital method. The calculated results of the magnetovolume effect indicate the necessity to improve the local spin density approximation in the ferromagnetic state.
结果表明,铁磁性金属中的磁体积效应可以用b(M,V)= F(M,V)/ M和p(M,V)=- F(M,V)/ V两个函数来估计,其中F(M,V)是磁矩为M、体积为V的系统的自由能。数值计算中所用的能带结构采用线性松饼-锡轨道法得到。磁体积效应的计算结果表明,有必要改进铁磁状态下的局部自旋密度近似。
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引用次数: 5
Theoretical strain-induced elastic anomalies in metals and alloys 金属和合金中理论应变引起的弹性异常
Pub Date : 1988-09-01 DOI: 10.1088/0305-4608/18/9/012
J. Marschall, F. Milstein
The theoretical large-strain elastic response of crystals has long been a subject of interest. Although various atomic models have been used in a variety of theoretical computations, considerations that have largely been neglected are the anomalous stress and elastic moduli variations that occur when a Brillouin zone boundary is brought into contact with the Fermi surface as a result of deformation. The present work rationalises these occurrences for axial loadings of BCC and FCC crystals. Various pseudopotential model computations are carried out for the specific case of (100) uniaxial loading. With q a reciprocal lattice vector, kf the Fermi wavenumber, lambda 1 the axial stretch in (100) loading and z the valence, the results are summarised as plots of the 'critical value' of lambda 1 (i.e. lambda 1 at q=2kf) against z. Examples of pseudopotential model computations of the elastic moduli Cij of Al as q to 2kf are also presented.
晶体的理论大应变弹性响应一直是人们感兴趣的课题。尽管在各种理论计算中使用了各种原子模型,但在很大程度上被忽略的考虑因素是当布里渊区边界由于变形而与费米表面接触时发生的异常应力和弹性模量变化。目前的工作合理化了BCC和FCC晶体轴向载荷的这些现象。针对(100)单轴加载的具体情况,进行了各种伪势模型的计算。其中q为倒易晶格向量,kf为费米波数,lambda 1为(100)载荷中的轴向拉伸,z为价态,结果总结为lambda 1(即λ 1在q=2kf处)对z的“临界值”图。还给出了Al在q至2kf时弹性模量Cij的伪势模型计算示例。
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引用次数: 4
Magnetic transitions in dysprosium: a calorimetric study 镝中的磁跃迁:一项量热研究
Pub Date : 1988-09-01 DOI: 10.1088/0305-4608/18/9/028
H. Astrom, G. Benediktsson
The nature of the magnetic transitions in high-purity dysprosium has been investigated with a high-resolution microcalorimeter. Single crystals of two purities corresponding to RRR values of 88 (Dy(A)) and 15 (Dy(B)) have been studied. At Tn the authors have observed an energy peak for both materials of 7 J mol-1 extending over a few tenths of a degree. The transition temperatures were 180.6+or-0.1 K for Dy(A) and 178.7+or-0.1 K for Dy(B). A small thermal hysteresis in TN was observed for both materials. The data suggest a weak first-order transition at TN. The first-order nature of the ferromagnetic transition has been confirmed. The latent heat measured was 35+or-2 J mol-1 and 17+or-3 J mol-1 and the transition temperature 91.1+or-0.2 and 90.3+or-0.2 K for Dy(A) and Dy(B) respectively. The latent heats are in fair agreement with calculated values. Commensurate turn-angle effects have been sought in the helical regime. For Dy(A) small energy peaks of 0.2+or-0.1 J mol-1 were observed at 166+or-2 K and 173+or-1 K. The temperatures for the energy changes are close to two of the temperatures of commensurability obtained from neutron diffraction data.
用高分辨率微量热计研究了高纯度镝的磁跃迁性质。研究了RRR值分别为88 (Dy(A))和15 (Dy(B))的两种纯度的单晶。在Tn,作者观察到两种材料的能量峰值都为7j mol-1,延伸了零点几度。Dy(A)的转变温度为180.6±0.1 K, Dy(B)的转变温度为178.7±0.1 K。两种材料在TN中都观察到小的热滞后。数据表明在TN处存在弱的一阶跃迁。铁磁跃迁的一阶性质已被证实。Dy(A)和Dy(B)的潜热分别为35+或2 J mol-1和17+或3 J mol-1,转变温度分别为91.1+或0.2和90.3+或0.2 K。潜热与计算值基本一致。在螺旋状态下已寻求相应的转角效应。对于Dy(A),在166+或2 K和173+或1 K下观察到0.2+或0.1 jmol -1的小能量峰。能量变化的温度接近中子衍射数据中可公度的两个温度。
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引用次数: 8
Interplay of the Boltzmann-type ordinary transport and quantum corrections in Ag-Cu-Ge amorphous alloy system. I. Temperature dependence of electrical resistivity Ag-Cu-Ge非晶合金体系中玻尔兹曼型普通输运与量子修正的相互作用。电阻率的温度依赖性
Pub Date : 1988-09-01 DOI: 10.1088/0305-4608/18/9/018
U. Mizutani, K. Sato, I. Sakamoto, K. Yonemitsu
The electrical resistivity has been measured in the temperature range 2-300 K for (Ag0.5Cu0.5)1-xGex amorphous alloys over a wide composition range 0
在2-300 K的温度范围内测量了(Ag0.5Cu0.5)1-xGex非晶合金在0<或=x<或=0.95的宽成分范围内的电阻率。分析了金属区的散射机制,假设散射持续至60 at。% Ge合金或电阻率低于约1000 μ ω cm。在约200 μ ω cm以下的低电阻率区,rho -T特性可以用基于玻尔兹曼方程或广义费伯-齐曼理论的普通散射机制一致地解释。在200 μ ω cm以上的高电阻率区,量子修正发挥了重要作用:15k以下和30k以上的rho -T特性主要是由电子-电子和电子-声子相互作用引起的。通过研究维数对rho -T特性的影响,也证实了量子修正的主导作用。
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引用次数: 16
Electrical and optical properties of discontinuous Al films near the percolation threshold 在渗透阈值附近不连续Al膜的电学和光学性质
Pub Date : 1988-09-01 DOI: 10.1088/0305-4608/18/9/023
E. Dobierzewska-Mozrzymas, P. Bieganski
The electrical and optical properties of discontinuous Al films on NaCl substrates have been investigated. The temperature dependence of the resistance and the TCR were determined in situ under vacuum conditions for films with various volume fractions q. The reflectivity was measured in the spectral range from 220 to 700 nm. It has been found that the electrical and optical properties of the film are subject to significant changes near the percolation threshold, which is characterised by the critical range of the volume fraction ( Delta qc). This behaviour is to be attributed to the change in the type of conduction and in the character of optical properties. Films having volume fractions q Delta qc the optical anomalies disappear and the TCR is greater than zero.
研究了NaCl衬底上不连续Al薄膜的电学和光学性质。在真空条件下原位测定了不同体积分数q薄膜的电阻和TCR与温度的关系,并在220 ~ 700 nm光谱范围内测量了反射率。研究发现,薄膜的电学和光学性质在渗透阈值附近会发生显著变化,渗透阈值的特征是体积分数的临界范围(Delta qc)。这种行为可归因于传导类型和光学性质的变化。体积分数为q δ qc的薄膜,光学异常消失,TCR大于零。
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引用次数: 13
An icosahedral phase formed during annealing of ion-irradiated Fe-Mo amorphous films 离子辐照Fe-Mo非晶薄膜退火过程中形成二十面体相
Pub Date : 1988-09-01 DOI: 10.1088/0305-4608/18/9/001
C. Shang, Jiahao Li, H. D. Li, B. Liu
An icosahedral phase has been observed in the Fe-Mo system for the first time. The new icosahedral phase was formed during thermal annealing of ion-irradiated Fe-Mo amorphous films, which were prepared by sputtering from an Fe50Mo50 alloy ingot. The atomic concentration of this phase was determined by in situ energy-dispersive spectra (EDS) to be around Fe40Mo60 which has been proved to be a favourable composition for ion-induced amorphisation in this system.
首次在Fe-Mo体系中观察到二十面体相。用Fe50Mo50合金锭溅射法制备的Fe-Mo非晶态薄膜在离子辐照后的热退火过程中形成了新的二十面体相。原位能谱(EDS)测定了该相的原子浓度在Fe40Mo60左右,证明了Fe40Mo60是该体系中离子诱导非晶化的有利成分。
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引用次数: 6
Thermal expansion and ultrasonic velocity and attenuation at the continuous Neel transition in Cr+0.2 at.% V Cr+0.2 at连续Neel转变时的热膨胀、超声速度和衰减。% V
Pub Date : 1988-09-01 DOI: 10.1088/0305-4608/18/9/009
P. C. D. Carmargo, E. P. Castro, E. Fawcett
The thermal expansion of a high quality Cr+0.2 at.% V single crystal shows a well defined continuous Neel transition in contrast with the weak first-order transition in Cr. The change in the nature of the ultrasonic velocity and attenuation anomalies at the phase transition also supports the idea that a tricritical point occurs at some concentration less than 0.2 at.% V in Cr.
高质量Cr+0.2 at的热膨胀。与Cr的弱一阶转变相比,% V单晶表现出明确的连续尼尔转变。超声速度性质的变化和相变中的衰减异常也支持了三临界点在小于0.2 at的浓度下出现的观点。% V in Cr。
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引用次数: 5
Comparative investigation of structural and transport properties of L10 NiPt and Copt phases; the role of magnetism L10 NiPt和Copt相结构和输运性质的比较研究磁性的作用
Pub Date : 1988-09-01 DOI: 10.1088/0305-4608/18/9/021
C. Leroux, M. Cadeville, V. Pierron-Bohnes, G. Inden, F. Hinz
The retilt 01 :I compar;itivc investigation of strueturiil and transport properties of equiatomic NiPt and C'oPt ph;ies. in their ordered and disordered states. iire presented and dicusetl. The tho compounds displa) the same hind ol order-disorder transforma- tion LI,,-h, in rhcir pir;imagnetic tate. In thi stud!. atrcntion viis paid to make iiieiiiiremcnts on ampies in well detined thermod~n,imie state. U hich can he either equilihriuin statcs or quenched one. Thi in~estig;ition hi)& that the atomic disorder gencr;ited hy the thermal effect or h) contitution:il deleet (o('C-toichiometr! ) hiis jimilur consequences on the structure (tetragon;ility ratio) irnd on the reidual rcistivit) in the tho compounds. A grcat ditt'erence occur in the high-Tmistivity. he lo^ and iit the 0-1) translormation temperature (T,),)). Whcre;i NiPt displa)s ;I hehakiour typical of this kind of transforina- tion. Copt how unexpected rcults. in particular ii decrease in its resistibity ;it To,,. Such ;I dil'lerence can he e.;pl;iincd by taking into account the pin-disorder cattcring contribu- tion to the resistiity. which I larger in Copt than in NiPt. A process hased on the existence ol Huctu;iting Ioc,il magnetic moment and magnetic short-range order in the p;iramagnetic state of C'oPt i propowd to expl;iin the ohserved hehaviour qualitatiely.
[1]等原子NiPt和C'oPt的结构和输运性质的比较研究。处于有序和无序状态。我提出了一个建议,并提出了一个建议。这两种化合物显示出相同的后序-无序转换- LI,,-h,在rhcirr pir;在这个stud里!在定义良好的热电偶联状态下,对电流进行三阶电流补偿是有吸引力的。它既可以是平衡态,也可以是淬灭态。这一研究表明,原子的无序产生了热效应或构词:将删除(0)(C- 0)。这对这两种化合物的结构(四边形;率比)和单体活性都有类似的影响。在高辐射率下,会发生较大的差异。(0-1)变换温度(T,),)这就是这种转换的典型特征。没想到会有这样的结果。特别是它的电阻率降低;它为,,。考虑到引脚无序性对电阻的影响,我们可以得出这样的结论。它在Copt中比在NiPt中大。基于C'oPt ' i '的p磁性态中存在ol hutu;iting Ioc、il磁矩和磁短程序的过程,拟定性地推导出C'oPt ' i '的观测行为。
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引用次数: 134
Calculation of diffraction patterns of the icosahedral phase 二十面体相衍射图样的计算
Pub Date : 1988-09-01 DOI: 10.1088/0305-4608/18/9/010
Dongshan Zhao, Renhui Wang, Yifan Cheng, Zhouguang Wang
The method of calculating electron diffraction patterns of the simple quasilattice developed by Elser (1985, 1986) has been generalised to the case where the icosahedral phase is stacked with 20 prolate and oblate rhombohedra and each rhombohedron has the same atomic decoration. The electron diffraction patterns and the powder X-ray and neutron diffraction patterns for four atomic models have been calculated and compared with experimental ones.
Elser(1985,1986)提出的计算简单准晶格电子衍射图的方法已推广到二十面体相由20个长形和扁形菱形体堆叠而成,每个菱形体具有相同的原子装饰的情况。计算了四种原子模型的电子衍射图、粉末x射线衍射图和中子衍射图,并与实验结果进行了比较。
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引用次数: 4
A laboratory EXAFS facility adapted to thin-film studies 适用于薄膜研究的实验室EXAFS设备
Pub Date : 1988-09-01 DOI: 10.1088/0305-4608/18/9/029
J. Mimault, T. Girardeau, M. Jaouen
The authors describe an experimental set-up which offers laboratory EXAFS facilities for thin-film characterisation. To be close to the usual transmission-mode EXAFS, they use the specular reflectivity properties of X-rays on solid surfaces. An application to the ion beam mixing of an Fe-Al multilayered sample is reported.
作者描述了一个实验装置,为薄膜表征提供了实验室EXAFS设施。为了接近通常的传输模式EXAFS,他们利用了固体表面上x射线的镜面反射特性。报道了一种应用于Fe-Al多层样品离子束混合的方法。
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引用次数: 0
期刊
Journal of Physics F: Metal Physics
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