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Progress and challenges in energy storage and utilization via ammonia 氨储能与利用的进展与挑战
Q4 Materials Science Pub Date : 2023-11-10 DOI: 10.1007/s44251-023-00013-6
Chongqi Chen, Yanliang Zhou, Huihuang Fang, Xiaobo Peng, Lilong Jiang
Abstract Ammonia is a premium energy carrier with high content of hydrogen. However, energy storage and utilization via ammonia still confront multiple challenges. Here, we review recent progress and discuss challenges for the key steps of energy storage and utilization via ammonia (including hydrogen production, ammonia synthesis and ammonia utilization). In hydrogen production, we focus on important processes and catalytic designs for conversion of carbon feedstocks and water into hydrogen. To reveal crucial challenges of ammonia synthesis, catalytic designs and mechanisms are summarized and analyzed, in thermocatalytic synthesis, electrocatalytic synthesis and photocatalytic synthesis of ammonia. Further, in ammonia utilization, important processes and catalytic designs are outlined for ammonia decomposition, ammonia fuel cells and ammonia combustion. The goal of this review is to stimulate development of low-cost and eco-friendly ways for energy storage and utilization via ammonia.
摘要氨是含氢量高的优质能量载体。然而,利用氨进行能量储存和利用仍然面临着多重挑战。在此,我们回顾了近年来的进展,并讨论了氨储能和利用的关键步骤(包括制氢、氨合成和氨利用)面临的挑战。在制氢方面,我们专注于将碳原料和水转化为氢的重要工艺和催化设计。为了揭示氨合成的关键挑战,总结和分析了热催化合成、电催化合成和光催化合成氨的催化设计和机理。此外,在氨利用方面,概述了氨分解、氨燃料电池和氨燃烧的重要工艺和催化设计。本文综述的目的是促进低成本和生态友好的氨储能和利用方法的发展。
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引用次数: 0
Revealing melt-vapor-powder interaction towards laser powder bed fusion process via DEM-CFD coupled model 通过DEM-CFD耦合模型揭示熔体-蒸汽-粉末相互作用对激光粉末床熔化过程的影响
Q4 Materials Science Pub Date : 2023-11-10 DOI: 10.1007/s44251-023-00014-5
Weihao Yuan, Hui Chen, Chong Peng, Rocco Lupoi, Shuo Yin
Abstract During the laser powder bed fusion (LPBF) process, powder spattering is a crucial phenomenon to consider. This primarily arises from the intense interaction between the laser and the material. The ensuing metal vapor, induced by the evaporation process, plays a pivotal role in instigating powder spatter, which significantly impacts the quality of the resultant part. One of the pressing challenges in the field is the capture and quantitative investigation of the interplay between the melt, vapor, and powder. Such lack of clarity impedes our path to achieving defect-minimized LPBF production. In this study, we propose a physics-based model that elucidates the integrated interaction of vapor, melt, and powder using a coupled DEM-CFD approach. Our findings indicate that the vapor flow undergoes four distinct states: initialization, continuation, transition, and interruption. These states correlate closely with the progression of vapor-induced depressions and powder spattering. As compared to the existing experimental data, our model provides a more precise and comprehensive understanding of vapor flow states and their associated velocity magnitudes. Furthermore, we identify three distinct patterns of powder spatter: inward, upward, and outward flows, where powder inward flow is mainly caused by shielding gas, while the upward and outward patterns are induced by metal vapor.
摘要在激光粉末床熔合(LPBF)过程中,粉末溅射是一个必须考虑的重要现象。这主要是由于激光与材料之间的强烈相互作用。蒸发过程中产生的金属蒸气在粉末溅落中起着关键作用,对最终零件的质量产生重大影响。该领域面临的紧迫挑战之一是对熔体、蒸汽和粉末之间相互作用的捕获和定量研究。这种缺乏明确性阻碍了我们实现缺陷最小化LPBF生产的道路。在这项研究中,我们提出了一个基于物理的模型,该模型利用耦合DEM-CFD方法阐明了蒸汽、熔体和粉末的综合相互作用。我们的研究结果表明,蒸汽流动经历了四种不同的状态:初始化、延续、过渡和中断。这些状态与蒸汽引起的凹陷和粉末飞溅的进展密切相关。与现有的实验数据相比,我们的模型提供了更精确和全面的蒸汽流动状态及其相关速度大小的理解。此外,我们确定了三种不同的粉末飞溅模式:向内、向上和向外流动,其中粉末向内流动主要是由保护气体引起的,而向上和向外流动则是由金属蒸气引起的。
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引用次数: 0
Deposition of DLC film on the inner surface of N80 pipeline by hollow cathode PECVD 空心阴极PECVD在N80管道内表面沉积DLC膜
Q4 Materials Science Pub Date : 2023-10-19 DOI: 10.1007/s44251-023-00012-7
Zhengyu Liu, Chenglong Mou, Pingmei Yin, Xueqian Cao, Guangan Zhang, Qunji Xue
Abstract The corrosion and wear of N80 pipeline in oil and gas field environment has always been an urgent problem to be solved in the field of oil and gas exploitation. DLC film is considered to be an effective material for prolonging the service life of pipeline due to its excellent properties. However, it is very difficult to deposit a uniform DLC film on the inner surface of long pipeline. In this paper, DLC film was deposited on the inner surface of a 1 m-long N80 pipeline with an inner diameter of 75 mm by hollow cathode plasma enhanced chemical vapor deposition (HC-PECVD) using the pipeline itself as the deposition chamber and cathode. The uniformity of microstructure, mechanical properties, corrosion resistance and tribological properties of DLC film were discussed. The results show that the DLC film deposited on the inner surface of N80 long pipeline by HC-PECVD equipment possesses excellent axial uniformity. The deposition of DLC film increases the corrosion potential and reduces the corrosion current density, which greatly improves the corrosion resistance of N80 pipeline. In addition, the deposition of DLC film also reduces the friction coefficient and wear rate, which greatly improves the wear resistance of N80 pipeline. Therefore, the deposition of DLC film is an effective protection method for the inner surface of N80 pipeline, which prolongs the service life of the pipeline. HC-PECVD equipment with pipeline as cavity uniformly deposits DLC film on the inner surface of long pipeline, which is a potential deposition method to prolong the service life of long pipeline in oil and gas exploitation.
油气田环境中N80管道的腐蚀磨损一直是油气开采领域亟待解决的问题。DLC膜由于其优异的性能被认为是延长管道使用寿命的有效材料。然而,在长管道内表面沉积均匀的DLC膜是非常困难的。本文采用空心阴极等离子体增强化学气相沉积(HC-PECVD)技术,以管道本身作为沉积室和阴极,在内径为75 mm的1 m长的N80管道内表面沉积DLC薄膜。讨论了DLC膜的显微组织均匀性、力学性能、耐蚀性和摩擦学性能。结果表明,HC-PECVD设备沉积在N80长管道内表面的DLC膜具有良好的轴向均匀性。DLC膜的沉积提高了腐蚀电位,降低了腐蚀电流密度,大大提高了N80管道的耐蚀性。此外,DLC膜的沉积还降低了摩擦系数和磨损率,大大提高了N80管道的耐磨性。因此,DLC膜的沉积是N80管道内表面的有效保护方法,延长了管道的使用寿命。以管道为腔体的HC-PECVD设备在长管道内表面均匀沉积DLC膜,是油气开采中延长长管道使用寿命的一种极具潜力的沉积方法。
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引用次数: 0
Improving activity and barrier properties of epoxy modified polyurethane coating with in-situ polymerized polypyrrole functionalized graphene oxide 原位聚合聚吡咯功能化氧化石墨烯改善环氧改性聚氨酯涂料的活性和阻隔性能
Q4 Materials Science Pub Date : 2023-10-18 DOI: 10.1007/s44251-023-00010-9
Yue Sun, Dalei Song, Jing Yu, Jiahui Zhu, Jingyuan Liu, Rongrong Chen, Qi Liu, Peili Liu, Jun Wang
Abstract The limited dispersibility and lack of active anti-corrosion properties of graphene oxide (GO) have hindered its application in corrosion resistance. In this study, we graft the corrosion inhibitor benzotriazole (BTA) on the surface of GO to achieve pH response release, providing active corrosion protection for epoxy modified polyurethane (EP-PU) coating. An environmentally friendly composite material with a sandwich-like structure was synthesized by in-situ polymerization of pyrrole to improve GO dispersion and prevent rapid release of BTA. The electrochemical impedance spectroscopy (EIS) shows that adding 0.15% GBP enhances the coating's anti-corrosion performance. The dual functions of passive and active corrosion enable the GBP/EP-PU coating to provide long-term corrosion protection for metal substrates.
摘要氧化石墨烯(GO)的分散性有限,缺乏有效的抗腐蚀性能,阻碍了其在耐腐蚀领域的应用。在本研究中,我们将缓蚀剂苯并三唑(BTA)接枝到氧化石墨烯表面,实现pH响应释放,为环氧改性聚氨酯(EP-PU)涂层提供有效的防腐保护。通过原位聚合吡咯,合成了一种具有三明治状结构的环保型复合材料,以改善氧化石墨烯的分散性,防止BTA的快速释放。电化学阻抗谱(EIS)分析表明,添加0.15% GBP能提高涂层的防腐性能。被动和主动腐蚀的双重功能使GBP/EP-PU涂层能够为金属基材提供长期的防腐保护。
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引用次数: 0
Machined surface formation and integrity control technology of SiCp/Al composites: a review SiCp/Al复合材料加工表面形成及完整性控制技术综述
Q4 Materials Science Pub Date : 2023-10-13 DOI: 10.1007/s44251-023-00011-8
Biao Zhao, Jianhao Peng, Wenfeng Ding
Abstract SiC particle reinforced Al matrix composites (SiC p /Al MMCs) have been widely used in aerospace and other fields due to their excellent mechanical properties, and their machined surface integrity is crucial for the use of new generation high-tech equipment. In order to enhance the understanding and regulation of machined surface integrity in Al matrix composites, this article provides a comprehensive review of the research advancements regarding influential factors, damage characteristics, creation techniques for machined surfaces, as well as technologies for controlling machined surface integrity both domestically and internationally. The present study discusses the key issues and solutions in the processing of aluminum matrix composite materials, along with examining the extent and mechanism of various energy field assistance influence on the surface integrity of mechanically processed aluminum matrix composites. Ultimately, this article proposes future research prospects for achieving high surface integrity machining of aluminum matrix composites.
SiC颗粒增强Al基复合材料(SiC p /Al MMCs)由于其优异的力学性能在航空航天等领域得到了广泛的应用,其加工表面的完整性对新一代高科技装备的使用至关重要。为了提高对铝基复合材料加工表面完整性的认识和调控,本文综述了国内外在影响因素、损伤特征、加工表面形成技术以及加工表面完整性控制技术等方面的研究进展。探讨了铝基复合材料机械加工过程中存在的关键问题及解决方法,探讨了各种能量场辅助对机械加工铝基复合材料表面完整性的影响程度及机理。最后,提出了今后实现铝基复合材料高表面完整性加工的研究前景。
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引用次数: 0
Interfacial catalysis of metal-oxide nanocatalysts in CO2 hydrogenation to value-added C1 chemicals 金属氧化物纳米催化剂在CO2加氢过程中的界面催化作用
Q4 Materials Science Pub Date : 2023-10-12 DOI: 10.1007/s44251-023-00009-2
Ziwei Wang, Zhenhua Zhang
Abstract Catalytic CO 2 hydrogenation to valuable chemicals is an excellent approach to address the increasingly serious “greenhouse effect” caused by CO 2 emission generated from the utilizations of nonrenewable fossil energies, while such a process is limited by chemical inertia and thermal stability of the CO 2 molecule and complex hydrogenation routes. In this review, we first summarized the recent progresses of metal-oxide nanocatalysts considered as a category of the most promising catalysts in CO 2 hydrogenation to value-added C1 chemicals including CH 4 /CO, formic acid/formate, and methanol. These studies involve with different structural factors affecting the metal-oxide interfacial catalysis including the structures of both the metals (type, particle size, morphology/crystal plane, and bimetal alloy) and the supports (type, particle size, crystal phase, morphology/crystal plane, and composite) and their (strong) metal-support interactions so as to identify the key factor determining the reaction activity, product selectivity, and catalytic stability in CO 2 hydrogenation. Finally, we further discuss challenging coupling with future research opportunities for tunable interfacial catalysis of metal-oxide nanocatalysts in CO 2 conversion.
摘要催化co2加氢制有价化学品是解决不可再生化石能源利用过程中co2排放所造成的日益严重的“温室效应”的一种极好的途径,但该过程受到co2分子的化学惯性和热稳定性以及复杂加氢途径的限制。本文首先综述了纳米金属氧化物催化剂的研究进展,认为纳米金属氧化物催化剂是co2加氢制备高附加值C1化学品最有前途的催化剂,包括ch4 /CO、甲酸/甲酸和甲醇。这些研究涉及影响金属-氧化物界面催化的不同结构因素,包括金属的结构(类型、粒度、形貌/晶面和双金属合金)和载体的结构(类型、粒度、晶相、形貌/晶面和复合材料)及其(强)金属-载体相互作用,以确定决定CO 2加氢反应活性、产物选择性和催化稳定性的关键因素。最后,我们进一步讨论了金属氧化物纳米催化剂在CO 2转化中的可调界面催化的挑战耦合和未来的研究机会。
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引用次数: 0
Announcement for a new journal: Surface Science and Technology 新期刊:表面科学与技术
Q4 Materials Science Pub Date : 2023-09-27 DOI: 10.1007/s44251-023-00008-3
Shengkai Gong
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引用次数: 0
Progress on high-temperature protective coatings for aero-engines 航空发动机高温防护涂层研究进展
Q4 Materials Science Pub Date : 2023-09-27 DOI: 10.1007/s44251-023-00005-6
Lei Guo, Wenting He, Wenbo Chen, Zhaolu Xue, Jian He, Yiqian Guo, Yang Wu, Lihua Gao, Dongqing Li, Zhao Zhang, Liangliang Wei, Yuyi Gao, Tiehao Zhang, Jiao Qiao, Qianhui Li, Hongbo Guo
Abstract Aero-engine is a key part of aircraft, the operating temperature of which is being pushed to unprecedented levels for higher engine efficiency and performance. To accomplish higher gas-inlet temperature of aero-engines, applying thermal barrier coatings (TBCs) on hot-section metallic components, or even replacing some of the metallic components in aero-engines with ceramic-matrix composites (CMCs) and applying environmental-barrier coatings (EBCs) on them, are effective methods and have been widely accepted. On the other hand, increasing aero-engines operating temperature causes the aircraft more easily be detected, thus stealth coatings are necessary for engines. Except the hottest part in aero-engines, other parts may not need TBCs or EBCs due to the relatively low operating temperature, but they still need protection from oxidation and corrosion. Hence, corrosion-resistant coatings are essential. In this paper, the latest progress of the above high-temperature protective coatings, i.e., TBCs, EBCs, stealth coatings and corrosion-resistant coatings is reviewed, mainly including their materials, fabrication technologies and performance. In addition, due to the harsh operating environment, these protective coatings face many threats such as calcia-magnesia-aluminosilicates (CMAS) attack, causing premature failure of the coatings, which is also concerned in this paper. The work would provide a comprehensive understanding on the high-temperature protective coatings in aero-engines and guidance for developing advanced protective coatings for next-generation aero-engines.
摘要航空发动机是飞机的关键部件,为提高发动机的效率和性能,其工作温度正被推向前所未有的高度。为实现航空发动机较高的进气温度,在热截面金属部件上应用热障涂层,甚至用陶瓷基复合材料(CMCs)代替航空发动机的部分金属部件并在其上应用环境障涂层是一种有效的方法,已被广泛接受。另一方面,航空发动机工作温度的升高使飞机更容易被发现,因此隐身涂层对发动机是必要的。除了航空发动机中温度最高的部件外,其他部件由于工作温度相对较低,可能不需要tbc或ebc,但仍需要防止氧化和腐蚀。因此,耐腐蚀涂层是必不可少的。本文综述了上述高温防护涂料的最新进展,主要包括tbc、ebc、隐身涂层和耐腐蚀涂层的材料、制备工艺和性能。此外,由于使用环境恶劣,这些防护涂层面临着钙镁铝硅酸盐(CMAS)侵蚀等诸多威胁,导致涂层过早失效,这也是本文所关注的问题。这项工作将为全面了解航空发动机高温防护涂层提供依据,并为下一代航空发动机先进防护涂层的开发提供指导。
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引用次数: 0
Surface engineering design on alleviating fretting wear: a review 减轻微动磨损的表面工程设计综述
Q4 Materials Science Pub Date : 2023-09-27 DOI: 10.1007/s44251-023-00003-8
Min-Hao Zhu, Xiao-Qiang Fan, Zhen-bing Cai, Jin-Fang Peng, Qi Sun
Abstract This paper introduces the definition, classification, and running modes of fretting damage, as well as industrial phenomena of fretting damage cases. It is detail reviewed the progress of two-types fretting map theory (running condition fretting map-RCFM and material response fretting map-MRFM), and outlines the protection strategy of fretting wear according to the fretting map theory, i.e. eliminating the mixed fretting regime and slip regime, increasing the strength of the contact surface, reducing the coefficient of friction, and selecting and matching of materials. Several surface engineering techniques (such as PVD, laser surface modification technology, bonded solid lubricant coating, thermal spraying coating, and micro-arc oxidation coating) against fretting wear are reviewed, several mechanisms to alleviating fretting wear are proposed as well as a collection of practical examples of surface engineering designs to anti-fretting wear. Base on the review of previous studies, mechanisms of surface engineering technologies for alleviating fretting wear have been proposed. In addition, the content and process of surface engineering design are introduced in this paper. A quantitative evaluation method using polar coordinate diagram is applied to choose appropriate surface engineering technology. Finally, taking the locking pin of variable gauge train as an example, the process of surface engineering design is further expounded.
摘要介绍了微动损伤的定义、分类、运行方式以及微动损伤案例的工业现象。详细综述了两类微动图理论(运行工况微动图- rcfm和材料响应微动图- mrfm)的研究进展,提出了基于微动图理论的微动磨损保护策略,即消除微动和滑移混合状态、提高接触面强度、降低摩擦系数、材料选择与匹配等。综述了几种抗微动磨损的表面工程技术(如PVD、激光表面改性技术、结合固体润滑剂涂层、热喷涂涂层和微弧氧化涂层),提出了几种缓解微动磨损的机制,并收集了抗微动磨损的表面工程设计实例。在回顾前人研究的基础上,提出了表面工程技术缓解微动磨损的机理。此外,本文还介绍了表面工程设计的内容和过程。采用极坐标图定量评价方法,选择合适的表面工程技术。最后,以变轨距列车的锁紧销为例,进一步阐述了表面工程设计的过程。
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引用次数: 0
Progress in infrared transparencies under opto electro thermo and mechanical environments 光电、热、机械环境下红外透性研究进展
Q4 Materials Science Pub Date : 2023-09-27 DOI: 10.1007/s44251-023-00002-9
Liangge Xu, Shuai Guo, Victor Ralchenko, Gang Gao, Sam Zhang, Jiaqi Zhu
Abstract In recent years, there has been a growing interest and research focus on infrared optical thin films as essential components in infrared optical systems. In practical applications, extreme environmental factors such as aerodynamic heating and mechanical stresses, electromagnetic interferences, laser interferences, sand erosions, and rain erosions all lead to issues including cracking, wrinkling, and delaminations of infrared thin films. Extreme application environment imposes stringent requirements on functional films, necessitating high surface hardness, stability, and adhesion. Additionally, for multispectral optical transmissions, infrared optical thin films are expected to exhibit high transmittance in the visible and far-infrared wavelength bands while possessing tunability and optical anti-reflection properties in specific wavelength ranges. Electromagnetic shielding requires superior electrical performance, while resisting laser interference demands rapid phase change capabilities. This paper focuses on current research progresses in infrared optical thin films under extreme conditions such as opto, electro, thermos and mechanical environments. Table of Contents Graphic gives detailed outline. Future opportunities and challenges are also highlighted. Graphical Abstract
红外光学薄膜作为红外光学系统的重要组成部分,近年来受到越来越多的关注和研究。在实际应用中,空气动力学加热和机械应力、电磁干扰、激光干扰、砂石侵蚀和雨水侵蚀等极端环境因素都会导致红外薄膜开裂、起皱和分层等问题。极端的应用环境对功能性薄膜提出了严格的要求,需要高表面硬度、稳定性和附着力。此外,对于多光谱光传输,红外光学薄膜有望在可见光和远红外波段具有高透射率,同时在特定波长范围内具有可调性和光学抗反射特性。电磁屏蔽需要卓越的电气性能,而抵抗激光干扰则需要快速相变能力。重点介绍了红外光学薄膜在光、电、热、机械等极端环境下的研究进展。目录图给出了详细的大纲。同时也强调了未来的机遇和挑战。图形抽象
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引用次数: 0
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Journal of Surface Science and Technology
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