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Mild surfactant systems containing rhamnolipids for personal cleansers—Building the viscosity and studying the performance 用于个人清洁剂的含有鼠李糖脂的温和表面活性剂体系--建立粘度和研究性能
IF 1.6 4区 工程技术 Q3 CHEMISTRY, APPLIED Pub Date : 2024-05-03 DOI: 10.1002/jsde.12765
Nan Li, Hongwei Shen, Shijian Wu, Andrei Potanin, Jonghun Lee

Biosurfactants represent a promising choice for the development of environmentally friendly and gentle personal care cleansers. Building viscosity is one of the major challenges to apply biosurfactants. In this study, sodium lauroyl sarcosinate (LS) and sodium lauroamphoacetate (LA) were used as bases to build wormlike micelles, and subsequently rhamnolipids were introduced to build mild surfactant systems. The LS-LA mixture had the highest viscosity at the mass ratio of 1:5 and pH 6.0. After adding 1 wt% and less rhamnolipid, relatively high viscosity can be maintained. The viscosity of LS-LA-rhamnolipid can be increased by adding NaCl and more significantly by the addition of carrageenan due to its synergistic interactions with the surfactant mixture. In addition, the foaming properties of the systems are characterized with different amounts of rhamnolipid and carrageenan, which are correlated with the bulk viscosity and interfacial elasticity of the diluted solution used for the foaming test. Rhamnolipids have both high mildness and cleaning efficacy and adding rhamnolipids can significantly increase the mildness of the system. This study offers practical solutions for the incorporation of rhamnolipids or other biosurfactants in the formulation of personal care cleansers.

生物表面活性剂是开发环保、温和的个人护理清洁剂的理想选择。增加粘度是应用生物表面活性剂的主要挑战之一。在这项研究中,月桂酰肌氨酸钠(LS)和月桂酰两性乙酸钠(LA)被用作构建蠕虫状胶束的基质,随后鼠李糖脂被引入以构建温和的表面活性剂体系。当质量比为 1:5 和 pH 值为 6.0 时,LS-LA 混合物的粘度最高。在添加 1 wt% 或更少的鼠李糖脂后,仍能保持相对较高的粘度。加入 NaCl 可以增加 LS-LA 鼠李糖脂的粘度,而加入卡拉胶后,由于卡拉胶与表面活性剂混合物的协同作用,LS-LA 鼠李糖脂的粘度会显著增加。此外,在鼠李糖脂和卡拉胶用量不同的情况下,体系的发泡特性与用于发泡试验的稀释溶液的体积粘度和界面弹性相关。鼠李糖脂具有高温和性和清洁功效,添加鼠李糖脂可显著提高系统的温和性。这项研究为在个人护理清洁剂配方中加入鼠李糖脂或其他生物表面活性剂提供了实用的解决方案。
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引用次数: 0
Sustainable production of sophorolipid biosurfactants using renewable cellulose-derived feedstocks 利用可再生纤维素原料可持续生产槐脂类生物表面活性剂
IF 1.6 4区 工程技术 Q3 CHEMISTRY, APPLIED Pub Date : 2024-04-27 DOI: 10.1002/jsde.12762
Joseph Msanne, Richard D. Ashby, Andrew Harron, Alexis Czerhoniak

Glycolipids produced and secreted by oleaginous yeasts are renewable compounds with important physico-chemical properties, and multiple biological and industrial applications. The large-scale production of these compounds has been limited by high production costs and low yields. The sophorolipid-producing yeast Pseudohyphozyma bogoriensis may possess the ability to grow in fermentation systems using carbon substrates deriving from inexpensive lignocellulosic biomass, while simultaneously secreting high value biomaterials. In this study, comparative analyses between different cellulose-derived carbon sources including glucose, cellobiose, and sodium carboxymethyl cellulose confirmed the ability of P. bogoriensis to grow and accumulate glycolipids using these substrates. On a dry weight basis, the highest yields of about 4% (wt/wt) glycolipids were obtained when cellobiose was supplemented at 10 g/L in shake-flask fermentations. When the unconventional carbon substrate sodium carboxymethyl cellulose was supplemented, cultures exhibited a lower glycolipid yield of 0.3% (wt/wt), but the dry weight was higher compared to other substrates. Analytical analyses using various chromatography methods confirmed the chemical profiles, whereas both monoacetylated and diacetylated sophorolipid forms with 22 carbon long-chain hydroxy fatty acid were identified in all glycolipid extracts. Surface tension (ST) and critical micelle concentration (CMC) measurements showed that glycolipids produced on cellulose-derived substrates exhibited similar or even superior physical properties compared with glucose. Furthermore, availability of the yeast genome sequences facilitated the identification of putative genes that may be involved in cellulose hydrolysis (e.g., cellulase-like). Information on genomic and metabolic pathways is a prerequisite for trait improvement toward increasing the production of high value biomaterials.

由含油酵母产生和分泌的糖脂是一种可再生化合物,具有重要的物理化学特性以及多种生物和工业应用。由于生产成本高、产量低,这些化合物的大规模生产一直受到限制。生产槐脂的博哥里假酵母(Pseudohyphozyma bogoriensis)可能有能力在发酵系统中利用廉价木质纤维素生物质中的碳底物进行生长,同时分泌高价值的生物材料。在这项研究中,对不同的纤维素衍生碳源(包括葡萄糖、纤维生物糖和羧甲基纤维素钠)进行的比较分析证实,博戈瑞菌有能力利用这些底物生长和积累糖脂。按干重计算,在摇瓶发酵中添加 10 克/升的纤维生物糖时,糖脂的产量最高,约为 4%(重量/重量)。当添加非常规碳基质羧甲基纤维素钠时,培养物的糖脂产量较低,仅为 0.3%(重量/重量),但干重却高于其他基质。使用各种色谱法进行的分析证实了这些化学特征,在所有糖脂提取物中都发现了含有 22 碳长链羟基脂肪酸的单乙酰化和双乙酰化槐脂形式。表面张力(ST)和临界胶束浓度(CMC)测量结果表明,与葡萄糖相比,在纤维素衍生基质上生产的糖脂具有相似甚至更优越的物理性质。此外,酵母基因组序列的可用性有助于鉴定可能参与纤维素水解的推定基因(如纤维素酶样)。有关基因组和代谢途径的信息是改良性状以提高高价值生物材料产量的先决条件。
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引用次数: 0
Wheat protein-derived surfactants: Synthesis and properties 小麦蛋白衍生表面活性剂:合成与特性
IF 1.6 4区 工程技术 Q3 CHEMISTRY, APPLIED Pub Date : 2024-04-25 DOI: 10.1002/jsde.12753
Wanchun Li, Jie Shen, Hujun Xu

Green surfactants produced from peptides and their derivatives have excellent surface chemistry and application properties. A mild, biocompatible, and rapidly biodegradable green surfactant, potassium N-lauroyl wheat peptide (PLW), was synthesized by an acylation method in the aqueous phase with lauryl chloride and wheat oligopeptide as starting materials. Furthermore, the isoelectric point, equilibrium surface tension, dynamic surface tension, micellar aggregation behavior, foaming, and irritating properties of PLW were studied. Wheat oligopeptides were discovered to have the greatest glutamic acid content, accounting for 30.92% of the overall amino acid composition. The findings revealed that the protonation and ionization behavior of PLW was pH dependent. At pH 8.5, water's surface tension was lowered to 32.1 mN/m−1. At high concentrations and pH, PLW formed large aggregates in solution, causing the adsorption behavior of PLW molecules to shift from diffusion-controlled adsorption to mixed kinetic adsorption, with PLW exhibiting great surface activity. Furthermore, PLW has good foaming properties and is non-irritating. As a result, PLW is predicted to become widely employed in the field of household chemicals.

由多肽及其衍生物制成的绿色表面活性剂具有优异的表面化学和应用特性。本研究以月桂酰氯和小麦低聚肽为起始原料,采用酰化法在水相中合成了一种性质温和、生物相容性好且可快速生物降解的绿色表面活性剂--N-月桂酰小麦肽钾盐(PLW)。此外,还研究了 PLW 的等电点、平衡表面张力、动态表面张力、胶束聚集行为、发泡和刺激特性。研究发现,小麦低聚肽的谷氨酸含量最高,占整个氨基酸组成的 30.92%。研究结果表明,PLW 的质子化和电离行为与 pH 值有关。在 pH 值为 8.5 时,水的表面张力降低到 32.1 mN/m-1。在高浓度和高 pH 值条件下,聚乳酸在溶液中形成大量聚集体,导致聚乳酸分子的吸附行为从扩散控制吸附转变为混合动力学吸附,聚乳酸表现出极高的表面活性。此外,PLW 还具有良好的发泡特性和无刺激性。因此,预计 PLW 将在家用化学品领域得到广泛应用。
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引用次数: 0
Effects of block and random copolymerization on the properties of fatty alcohol polyoxypropylene-polyoxyethylene ether sulfates for enhanced oil recovery 嵌段聚合和无规共聚对用于提高石油采收率的脂肪醇聚氧丙烯聚氧乙烯醚硫酸盐性能的影响
IF 1.6 4区 工程技术 Q3 CHEMISTRY, APPLIED Pub Date : 2024-04-24 DOI: 10.1002/jsde.12759
Zhao Chen, Xue Lin, Qi Chen, Binglei Song, Xiaomei Pei, Zhenggang Cui

Enhanced oil recovery (EOR) by surfactant flooding has been attractive. Among the surfactants developed alcohol polyoxypropylene (PO)-polyoxyethylene (EO) ether sulfates (APES), also named extended surfactants, have been proved efficient. However, the arrangement of the PO and EO chains as well as the hydrocarbon structure in the molecules may significantly affect their performances. In this paper three APES, C18−16PO25EO10SO4Na (I), C18−16(PO/EO)25+10SO4Na (II), and C16GA(PO/EO)25+10SO4Na (III) were prepared and investigated, in which APES (I) and APES (II) were designed to have same PO and EO numbers but block and randomly copolymerized respectively with linear C18−16 fatty alcohols as starting agent, whereas the APES (III) was derived from double chain C16 Guerbet alcohol (C16GA) with PO and EO randomly copolymerized. The results show that the block copolymerized APES (I) gives much better brine solubility and counterion tolerance than the randomly copolymerized APES (II) and (III). Although all APES synthesized are highly surface-active and can reduce Daqing crude oil/simulated brine interfacial tension (IFT) to ultralow by mixing with more hydrophobic surfactants in presence or absence of alkali, the APES (III) gives the lowest IFT due to with double hydrocarbon chains. In addition, it is found that for APES (I) gelation occurs in neutralization process and the corresponding nonionic intermediate is highly viscous, whereas the randomly copolymerized two intermediates are liquid-like with low viscosity, which may be feasible to apply SO3/air falling film sulfation. This study provided useful information for arrangement of embedded nonionic moiety and hydrocarbon structure in designing extended surfactants for EOR.

通过表面活性剂浸泡来提高石油采收率(EOR)一直很有吸引力。在已开发的表面活性剂中,醇聚氧丙烯(PO)-聚氧乙烯(EO)醚硫酸盐(APES)(又称扩展表面活性剂)已被证明是高效的。然而,PO 和 EO 链的排列以及分子中的碳氢化合物结构可能会严重影响其性能。本文制备并研究了三种 APES:C18-16PO25EO10SO4Na(I)、C18-16(PO/EO)25+10SO4Na(II)和 C16GA(PO/EO)25+10SO4Na(III)、其中,APES(I)和 APES(II)以线性 C18-16 脂肪醇为起始剂,分别设计成具有相同 PO 和 EO 数但嵌段共聚和无规共聚;而 APES(III)以双链 C16 格尔伯特醇(C16GA)为起始剂,PO 和 EO 无规共聚。结果表明,嵌段共聚的 APES(I)比随机共聚的 APES(II)和(III)具有更好的盐水溶解性和耐反离子性。虽然合成的所有 APES 都具有很高的表面活性,在碱存在或不存在的情况下,通过与更疏水的表面活性剂混合,可将大庆原油/模拟盐水界面张力(IFT)降至超低,但 APES(III)由于具有双烃链,IFT 最低。此外,研究还发现,APES(I)在中和过程中会发生凝胶化,相应的非离子中间体粘度很高,而无规共聚的两种中间体则呈液态,粘度很低,这可能是应用 SO3/air 降膜硫化的可行方法。这项研究为设计用于 EOR 的扩展表面活性剂提供了嵌入式非离子分子和碳氢化合物结构排列方面的有用信息。
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引用次数: 0
Surface miscibility of Gemini surfactants and DOPE in binary mixed monolayers 双子表面活性剂和 DOPE 在二元混合单层中的表面混溶性
IF 1.6 4区 工程技术 Q3 CHEMISTRY, APPLIED Pub Date : 2024-04-24 DOI: 10.1002/jsde.12761
Scott C. Gillis, Gurmeet K. Lall, Han-Jin Philip Lu, Yilin Qiu, Shawn D. Wettig

Surface pressure (π)–molecular area (A) isotherms were gathered to characterize the packing of binary mixed Langmuir monolayers of 1,2-dioleoyl-sn-glycero-3-phosphoethanolamine (DOPE) and one of two Gemini surfactants (GS), N,N-bis(dimethyloctadecyl)-1,7-nonanediammonium dibromide (18-7-18) or 1,9-bis(octadecyl)-1,1,9,9-tetramethyl-5-amino-1,9-nonanediammonium dibromide (18-7NH-18) of varying molar fractions. Information about miscibility behavior was derived from the π–A curves by examining the excess free energy of mixing (ΔGexc) that was calculated through the surface area additivity rule. Surface compressibility modulus (Cs−1) was also used to characterize intermolecular interactions. Mutual interactions between GS and DOPE were analyzed in terms of excess Gibbs energy of mixing and the value of this parameter depended strongly on the composition of the mixed film. GS and DOPE are generally miscible as DOPE reduces intermolecular repulsion between highly charged GS molecules leading to the formation of more densely packed mixed monolayers. However, GS and DOPE are immiscible in equimolar mixtures due to tail group packing mismatch between saturated and unsaturated alkyl chains. The prevalence of attractive synergistic interactions in the monolayers studied differs from a previous finding of antagonistic mixing behavior in GS/DOPE micelles. These results contribute to the understanding of GS-lipid interactions and packing that are critical to the in vitro and in vivo stability of liposomes composed of these molecules used for non-viral gene therapy applications.

收集了表面压力(π)-分子面积(A)等温线,以描述 1,2-二油酰-sn-甘油-3-膦酰乙醇胺(DOPE)和两种 Gemini 表面活性剂(GS)之一的二元混合朗缪尔单层的堆积特征、N,N-双(二甲基十八烷基)-1,7-壬二铵二溴化物 (18-7-18) 或 1,9-双(十八烷基)-1,1,9,9-四甲基-5-氨基-1,9-壬二铵二溴化物 (18-7NH-18)。从 π-A 曲线中可以得出有关混溶行为的信息,方法是检查通过表面积加成法则计算出的混合过剩自由能(ΔGexc)。表面可压缩性模量(Cs-1)也用于表征分子间的相互作用。根据混合的过剩吉布斯能分析了 GS 和 DOPE 之间的相互影响,该参数值在很大程度上取决于混合薄膜的成分。GS 和 DOPE 通常是混溶的,因为 DOPE 可减少高电荷 GS 分子之间的分子间斥力,从而形成更密集的混合单层。然而,由于饱和烷基链和不饱和烷基链之间的尾基填料不匹配,GS 和 DOPE 在等摩尔混合物中是不相溶的。所研究的单层中普遍存在有吸引力的协同作用,这与之前在 GS/DOPE 胶束中发现的拮抗混合行为不同。这些结果有助于人们了解 GS 与脂质的相互作用和堆积,这对用于非病毒基因治疗的由这些分子组成的脂质体在体外和体内的稳定性至关重要。
{"title":"Surface miscibility of Gemini surfactants and DOPE in binary mixed monolayers","authors":"Scott C. Gillis,&nbsp;Gurmeet K. Lall,&nbsp;Han-Jin Philip Lu,&nbsp;Yilin Qiu,&nbsp;Shawn D. Wettig","doi":"10.1002/jsde.12761","DOIUrl":"10.1002/jsde.12761","url":null,"abstract":"<p>Surface pressure (π)–molecular area (A) isotherms were gathered to characterize the packing of binary mixed Langmuir monolayers of 1,2-dioleoyl-<i>sn</i>-glycero-3-phosphoethanolamine (DOPE) and one of two Gemini surfactants (GS), <i>N</i>,<i>N</i>-<i>bis</i>(dimethyloctadecyl)-1,7-nonanediammonium dibromide (18-7-18) or 1,9-<i>bis</i>(octadecyl)-1,1,9,9-tetramethyl-5-amino-1,9-nonanediammonium dibromide (18-7NH-18) of varying molar fractions. Information about miscibility behavior was derived from the π–A curves by examining the excess free energy of mixing (Δ<i>G</i><sub>exc</sub>) that was calculated through the surface area additivity rule. Surface compressibility modulus (<i>C</i><sub>s</sub><sup>−1</sup>) was also used to characterize intermolecular interactions. Mutual interactions between GS and DOPE were analyzed in terms of excess Gibbs energy of mixing and the value of this parameter depended strongly on the composition of the mixed film. GS and DOPE are generally miscible as DOPE reduces intermolecular repulsion between highly charged GS molecules leading to the formation of more densely packed mixed monolayers. However, GS and DOPE are immiscible in equimolar mixtures due to tail group packing mismatch between saturated and unsaturated alkyl chains. The prevalence of attractive synergistic interactions in the monolayers studied differs from a previous finding of antagonistic mixing behavior in GS/DOPE micelles. These results contribute to the understanding of GS-lipid interactions and packing that are critical to the in vitro and in vivo stability of liposomes composed of these molecules used for non-viral gene therapy applications.</p>","PeriodicalId":17083,"journal":{"name":"Journal of Surfactants and Detergents","volume":"27 6","pages":"863-875"},"PeriodicalIF":1.6,"publicationDate":"2024-04-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140662175","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Study on the aggregation nature of sodium cocoyl glycinate and sodium hyaluronate mixture in aqueous and NaCl solutions 椰油酰甘氨酸钠和透明质酸钠混合物在水溶液和氯化钠溶液中的聚集性质研究
IF 1.6 4区 工程技术 Q3 CHEMISTRY, APPLIED Pub Date : 2024-04-23 DOI: 10.1002/jsde.12760
Yuling Wang, Jixiang Guo, Min Zan, Songtang Xu, Xueping Guo, Bo Du, Hujun Xu

The mixed system of sodium cocoyl glycinate and sodium hyaluronate (HA) with different mass concentrations and relative molecular weights was investigated by the surface tension method. All the curves of surface tension versus logarithm of concentration (γ-lgc curves) of sodium cocoyl glycinate-HA mixed system displayed the properties of double platform. The critical micelle concentration (cmc) of sodium cocoyl glycinate was 1.690 g/L at 25°C. The two inflection points of the γ-lgc curves corresponding to the cocoyl glycine-HA mixed system were cac (the critical aggregation concentration) and cmce (the extended cmc of sodium cocoyl glycinate), and cac < cmce < cmc. With the change of the mass concentration and relative molecular weight of HA, the cac values were almost constant. However, cmce increased with the increase of the mass concentration of HA at the same HA molecular weight. For the HA of molecular weight of 800 and 260000 Da, the mass concentration of HA increased from 0.05 to 0.4 g/L, and the cmce value increased from 1.199 to 1.390 g/L and 1.102 to 1.330 g/L, respectively. When the mass concentration of HA remained the same, the change in the relative molecular weight of HA had little effect on the cmce value. For the mixed system of sodium cocoyl glycine −0.1 g/L HA, when the concentration of NaCl was 2 g/L, the salt enhancement effect was dominant. When the concentration of NaCl was 4 to 8 g/L, the salt weakening effect was dominant. It is indicated that HA can improve the chemical properties of sodium cocoyl glycinate at a certain concentration, thus improving the cleaning, foaming, and foam stability of sodium cocoyl glycinate.

采用表面张力法研究了不同质量浓度和相对分子量的椰油酰甘氨酸钠和透明质酸钠(HA)混合体系。椰油酰甘氨酸钠-HA 混合体系的表面张力与浓度对数关系曲线(γ-lgc 曲线)均显示出双平台特性。25°C 时,椰油酰甘氨酸钠的临界胶束浓度(cmc)为 1.690 克/升。椰油酰甘氨酸-HA 混合体系对应的 γ-lgc 曲线的两个拐点分别为 cac(临界聚集浓度)和 cmce(椰油酰甘氨酸钠的扩展 cmc),且 cac < cmce < cmc。随着 HA 质量浓度和相对分子量的变化,cac 值几乎保持不变。然而,在相同的 HA 分子量下,cmce 随 HA 质量浓度的增加而增加。对于分子量为 800 和 260000 Da 的 HA,HA 的质量浓度从 0.05 g/L 增加到 0.4 g/L,cmce 值分别从 1.199 g/L 增加到 1.390 g/L 和 1.102 g/L 增加到 1.330 g/L。当 HA 的质量浓度保持不变时,HA 相对分子量的变化对 cmce 值的影响很小。对于椰油酰甘氨酸钠-0.1 克/升 HA 混合体系,当 NaCl 浓度为 2 克/升时,盐增强效应占主导地位。当 NaCl 浓度为 4 至 8 克/升时,盐的减弱效应占主导地位。这表明,在一定浓度下,HA 可改善椰油酰甘氨酸钠的化学性质,从而提高椰油酰甘氨酸钠的清洁、发泡和泡沫稳定性。
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引用次数: 0
Physical chemical properties of surfactants in solution and their applications: A comprehensive account 溶液中表面活性剂的物理化学特性及其应用:全面介绍
IF 1.6 4区 工程技术 Q3 CHEMISTRY, APPLIED Pub Date : 2024-04-17 DOI: 10.1002/jsde.12757
Satya Priya Moulik, Animesh Kumar Rakshit, Bappaditya Naskar

In this brief review, we have discussed various physical chemical principles that guide the functions of surfactants in solution. The surfactants have special functions at the air/liquid and air/solid interfaces forming Gibbs and Langmuir monomolecular films by way of spreading at the interfaces. Their self-aggregation or micelle formation, a remarkable and useful phenomenon has been presented and elaborated. The application of fundamental physical chemistry principles for the understanding of the energetics of the micelle formation has been discussed. The involvement of surfactants in the formation of soft assembled (condensed) matters namely, vesicles, emulsions, foams, reverse micelles (or, microemulsions), gels, and so forth has been presented. The uniqueness of the “critical micelle concentration” (CMC), and its determination have been briefly presented. Applications of surfactants are numerous. We have briefly cited several applications namely, nano-material synthesis, detergency, agrochemical formulations, drug delivery, retardation of water evaporation, and so forth. A short account of bio-related surfactants namely, lung surfactants, bile salts, plant-and microbe-generated bio-surfactants, and their utilities have been also presented.

在这篇简短的综述中,我们讨论了指导表面活性剂在溶液中发挥作用的各种物理化学原理。表面活性剂在空气/液体和空气/固体界面上具有特殊功能,通过在界面上的扩散形成吉布斯和兰缪尔单分子膜。对表面活性剂的自聚集或胶束形成这一显著而有用的现象进行了介绍和阐述。讨论了如何应用基本物理化学原理来理解胶束形成的能量学。介绍了表面活性剂参与形成软集合(凝聚)物质(即囊泡、乳液、泡沫、反胶束(或微乳液)、凝胶等)的情况。此外,还简要介绍了 "临界胶束浓度"(CMC)的独特性及其测定方法。表面活性剂的应用非常广泛。我们简要列举了几种应用,即纳米材料合成、去污力、农用化学品配方、药物输送、延缓水分蒸发等。我们还简要介绍了与生物有关的表面活性剂,即肺表面活性剂、胆汁盐、植物和微生物产生的生物表面活性剂及其用途。
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引用次数: 0
Processing effects on bilayer structures formation and rheological behavior of softeners using cationic di(hydrogenated tallow)dimethylammonium chloride aqueous dispersions 加工对使用阳离子二(氢化牛脂)二甲基氯化铵水分散体的双层结构形成和软化剂流变行为的影响
IF 1.6 4区 工程技术 Q3 CHEMISTRY, APPLIED Pub Date : 2024-04-15 DOI: 10.1002/jsde.12758
Nathan V. de Castro, Guilherme A. Ferreira, Watson Loh

The use of softeners is essential for enhancing laundered fabrics and hair textures after washing. For these, products based on double-tailed cationic surfactants are used to reduce friction and static electricity, resulting in softer and smoother fibers. These surfactants form lamellar phases in water, which can be turned into vesicles and other bilayer aggregates upon shearing, greatly impacting on the rheological properties of these formulations. This study aims at elucidating how some parameters of the formulation process impact bilayer structures formation and the product rheology, using di(hydrogenated tallow)dimethylammonium chloride (DHTDMAC) aqueous dispersions as model system. Small angle X-ray scattering (SAXS) analyses revealed lamellar phases starting from 3% DHTDMAC, with a bilayer thickness of 1.90 ± 0.03 nm, indicating significant carbon chain interdigitation. At this concentration (3%), bilayers exhibited a repetition distance of 69 nm, unveiling a behavior close to the one predicted for infinite swelling, in which lamellar structures persisted even at high dilution. Temperature plays a significant role in the rheological behavior, with elevated temperatures favoring vesicle formation, resulting in reduced apparent viscosity due to lower resistance of vesicles to flow. Upon heating, differential scanning calorimetry (DSC) analyses revealed a transition from Lβ (gel) to Lα (fluid) structures between 28 and 41°C, which was further confirmed by X-ray diffraction (XRD). Both structural and thermotropic features observed were discussed and compared to information reported for a high-purity grade homologue of DHTDMAC, dioctadecyldimethylammonium chloride (DODAC) mixed with water. These findings deepen the understanding of fabric softener formulation and the impact of bilayer structures formation on their properties, and should be used to optimize new formulations, enhancing their overall performance and sensorial quality.

要改善洗涤后织物和头发的质地,必须使用柔软剂。为此,我们使用基于双尾阳离子表面活性剂的产品来减少摩擦和静电,从而使纤维更加柔软光滑。这些表面活性剂在水中形成片状相,在剪切时会变成囊泡和其他双层聚集体,从而对这些配方的流变特性产生极大影响。本研究以二(氢化牛脂)二甲基氯化铵(DHTDMAC)水分散体为模型系统,旨在阐明配制过程中的一些参数如何影响双层结构的形成和产品的流变性。小角 X 射线散射(SAXS)分析表明,从 3% 的 DHTDMAC 开始出现层状相,双层厚度为 1.90 ± 0.03 nm,表明碳链之间存在明显的相互结合。在此浓度(3%)下,双分子层的重复距离为 69 nm,揭示了一种接近于无限膨胀预测的行为,在这种行为中,即使在高稀释度下,层状结构也会持续存在。温度在流变行为中起着重要作用,温度升高有利于囊泡的形成,由于囊泡的流动阻力降低,表观粘度也随之降低。加热时,差示扫描量热仪(DSC)分析显示,在 28 至 41°C 之间,Lβ(凝胶)结构向 Lα(流体)结构过渡,X 射线衍射(XRD)进一步证实了这一点。研究人员对观察到的结构和热致性特征进行了讨论,并将其与 DHTDMAC 的高纯度同系物--与水混合的双十八烷基二甲基氯化铵(DODAC)的相关信息进行了比较。这些发现加深了人们对织物柔软剂配方以及双层结构的形成对其性能影响的理解,并可用于优化新配方,提高其整体性能和感官质量。
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引用次数: 0
Effect of cationic Gemini surfactants ethonium and decamethoxin on the spectral properties, solubility and tautomerism of the curcumin 阳离子双子座表面活性剂乙基和癸甲氧羰基对姜黄素光谱特性、溶解度和同分异构体的影响
IF 1.6 4区 工程技术 Q3 CHEMISTRY, APPLIED Pub Date : 2024-04-11 DOI: 10.1002/jsde.12756
Valentyna M. Barvinchenko, Olga O. Kazakova, Natalia O. Lipkovska

The properties of natural polyphenol curcumin in water solutions of cationic Gemini surfactants decamethoxin and ethonium, which have similar positively charged nitrogen hydrophilic head groups but different spacer sizes and lengths of hydrophobic tails have been investigated in a wide range of concentrations by using UV–Vis spectroscopy and quantum-chemical calculations. It was found that curcumin dissolves in the organized micellar media of these surfactants in the enol tautomeric form and its solubility increases 400 times compared to water. The binding constants of curcumin with decamethoxin and ethonium were determined by the solubility method. Significant differences in the influence of premicellar concentrations of cationic Gemini surfactants on the solubility and tautomeric transformations of curcumin were revealed. In contrast to decamethoxin, ethonium at a concentration below the CMC promotes a significant increase in the solubility of curcumin and a shift in the tautomeric equilibrium towards the formation of its keto form.

通过紫外可见光谱和量子化学计算,研究了天然多酚姜黄素在阳离子 Gemini 表面活性剂癸甲氧基和乙基水溶液中的特性,这两种表面活性剂具有相似的带正电的氮亲水头基,但疏水尾的间隔尺寸和长度不同。研究发现,姜黄素以烯醇同分异构形式溶解在这些表面活性剂的有组织胶束介质中,其溶解度比水增加了 400 倍。通过溶解度法测定了姜黄素与癸甲氧羰基和乙基的结合常数。结果表明,阳离子 Gemini 表面活性剂的前胶束浓度对姜黄素的溶解度和同分异构体转化的影响存在显著差异。与癸甲氧基醚相比,浓度低于 CMC 的乙铵盐能显著提高姜黄素的溶解度,并使同分异构体平衡向形成其酮型转变。
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引用次数: 0
Micellization, aggregation, interaction, and solubilization behaviors of mixed solutions of cationic gemini and nonionic surfactants 阳离子双子表面活性剂和非离子表面活性剂混合溶液的胶束化、聚集、相互作用和增溶行为
IF 1.6 4区 工程技术 Q3 CHEMISTRY, APPLIED Pub Date : 2024-04-09 DOI: 10.1002/jsde.12755
İkbal Sarıkaya Yıldız, Selçuk Bilgen, Halide Akbaş

The micellization properties of mixed aqueous solutions of a cationic gemini surfactant (CGS) and Triton X-100, a conventional non-ionic surfactant, with various mole fractions, were determined by measuring the surface tension at different temperatures. Various theoretical models were used to analyze the behavior of this mixed system. The interactions between CGS and Triton X-100 were determined to be non-ideal and synergistic. The calculated interaction parameters (βM) have negative values at all temperatures and for all mole fractions, showing attractive interactions. It was found that increasing the mole fraction of Triton X-100 significantly increased the synergistic effect (more negative values). Micellar aggregation number (Nagg) values of pure surfactants and their mixtures in different ratios were obtained with the steady-state fluorescence quenching method. Furthermore, the molar solubilization ratio of Sudan III organic dye in all surfactants aqueous systems was obtained using UV–Visible spectrophotometry. At concentrations above critical micelle concentration, the solubility of Sudan III in water was substantially increased linearly for all systems and it was observed that the enhancement was even more significant for mixed surfactant systems.

通过测量不同温度下的表面张力,确定了不同摩尔分数的阳离子双子表面活性剂(CGS)和传统非离子表面活性剂 Triton X-100 混合水溶液的胶束化特性。采用各种理论模型分析了这一混合体系的行为。结果表明,CGS 和 Triton X-100 之间的相互作用是非理想和协同的。计算得出的相互作用参数 (βM)在所有温度和所有摩尔分数下均为负值,显示出有吸引力的相互作用。研究发现,增加 Triton X-100 的分子分数会显著增加协同效应(负值更大)。利用稳态荧光淬灭法获得了纯表面活性剂及其不同比例混合物的微胶囊聚集数(Nagg)值。此外,还利用紫外-可见分光光度法获得了苏丹 III 有机染料在所有表面活性剂水体系中的摩尔溶解比。当浓度高于临界胶束浓度时,所有体系中苏丹Ⅲ在水中的溶解度都呈线性大幅提高,而且据观察,混合表面活性剂体系的提高更为显著。
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引用次数: 0
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Journal of Surfactants and Detergents
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