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The catalytic hydro-dechlorination of 2, 4, 4' trichlorobiphenyl at mild temperatures and atmospheric pressure. 在温和的温度和大气压力下催化 2, 4, 4' 三氯联苯的加氢脱氯反应。
IF 2.7 4区 环境科学与生态学 Pub Date : 2024-05-16 DOI: 10.1080/10962247.2024.2353643
Kevin Johnson, Juan Xu, Alyssa Yerkeson, Mingming Lu
IMPLICATION STATEMENTThe remediation need for polychlorinated biphenyls (PCBs) still remains long after their production ban around the world. The development of low cost methods is highly desirable, especially for developing countries, in response to the Stockholm Convention. In this study, the dechorination of a ubiquitously present PCB congener was studied using a catalytic hydro-dechlorination (HDC) method in low temperatures up to ~ 77°C and was able to achieve near 100% dechlorination in six hours. Results indicated that the HDC process can be performed under mild temperatures and atmospheric conditions and can be a potential solution to real world PCB contamination issues.
意义说明多氯联苯(PCBs)在全世界被禁止生产后很长时间内,仍然需要采取补救措施。为响应《斯德哥尔摩公约》,开发低成本方法是非常可取的,尤其是对发展中国家而言。本研究采用催化加氢脱氯(HDC)方法,在低温(约 77 摄氏度)条件下对一种普遍存在的多氯联苯同系物进行了脱氯研究,结果表明,该方法可在 6 小时内实现接近 100% 的脱氯。结果表明,加氢脱氯过程可在温和的温度和大气条件下进行,是解决现实世界中多氯联苯污染问题的潜在办法。
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引用次数: 0
Decision-making in biogas production projects: Paradigms and prospection 沼气生产项目的决策:范例与展望
IF 2.7 4区 环境科学与生态学 Pub Date : 2024-04-09 DOI: 10.1080/10962247.2024.2338747
Daniela M. Yamaji, Saulo F. Amâncio-Vieira, Reginaldo Fidelis, Eduardo A. Do R. Contani
The decision to implement a biogas production project involves the evaluation of multiple variables, such as the problem to be solved, the biodigester, business model, investment, and final product...
实施沼气生产项目的决定涉及对多种变量的评估,如要解决的问题、生物发酵罐、商业模式、投资和最终产品......
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引用次数: 0
Cloning and characterization of FMN dependent azoreductases from textile industry effluent identified through metagenomic sequencing 通过元基因组测序从纺织工业污水中发现的 FMN 依赖性偶氮还原酶的克隆和特征描述
IF 2.7 4区 环境科学与生态学 Pub Date : 2024-02-26 DOI: 10.1080/10962247.2024.2322513
Roshani Mishra, Akhilesh Modi, Ramesh Pandit, Jyoti Sadhwani, Chaitanya Joshi, Amrutlal K Patel
Azo dyes, when released untreated in the environment, cause detrimental effects on flora and fauna. Azoreductases are enzymes capable of cleaving commercially used azo dyes, sometimes in less toxic...
偶氮染料在未经处理的情况下释放到环境中会对动植物造成有害影响。偶氮还原酶是一种能够裂解商业使用的偶氮染料的酶,有时毒性较低...
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引用次数: 0
The sulfidation behavior of zinc during microwave hydrothermal sulfidation of heavy metal-containing sludge 含重金属污泥微波水热硫化过程中锌的硫化行为
IF 2.7 4区 环境科学与生态学 Pub Date : 2024-02-01 DOI: 10.1080/10962247.2024.2312884
Junxun Jin, Jia He, Xinqi Wei, Yi Shen, Yuting Wang, Yong Gao, Qiuyue Sun
Heavy metals in sludge can react with sulfur and be converted into metal sulfides with good floatability through hydrothermal sulfidation. This is a novel method for the recovery of heavy metals fr...
污泥中的重金属可与硫发生反应,并通过水热硫化作用转化为具有良好漂浮性的金属硫化物。这是一种从污泥中回收重金属的新方法。
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引用次数: 0
Key results from the salt lake regional smoke, ozone and aerosol study (SAMOZA) 盐湖地区烟雾、臭氧和气溶胶研究(SAMOZA)的主要结果
IF 2.7 4区 环境科学与生态学 Pub Date : 2024-01-10 DOI: 10.1080/10962247.2024.2301956
Daniel A. Jaffe, Matt Ninneman, Linh Nguyen, Haebum Lee, Lu Hu, Damien Ketcherside, Lixu Jin, Emily Cope, Seth Lyman, Colleen Jones, Trevor O’Neil, Marc L. Mansfield
The Northern Wasatch Front area is one of ~ 50 metropolitan regions in the U.S. that do not meet the 2015 O3 standard. To better understand the causes of high O3 days in this region we conducted th...
北瓦萨奇前线地区是美国约 50 个未达到 2015 年臭氧浓度标准的大都市地区之一。为了更好地了解该地区臭氧浓度偏高的原因,我们在瓦萨奇前线地区开展了一项研究。
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引用次数: 0
Assessment of waste workers occupational risk to microbial agents and cytotoxic effects of mixed contaminants present in the air of waste truck cabin and ventilation filters 评估废物转运车车厢和通风过滤器空气中存在的混合污染物对微生物制剂和细胞毒性影响对废物转运工人造成的职业风险
IF 2.7 4区 环境科学与生态学 Pub Date : 2024-01-02 DOI: 10.1080/10962247.2023.2299424
Genevieve Marchand, Loïc Wingert, Carla Viegas, Liliana Caetano, Susana Viegas, Magdalena Twaruzek, Nancy Lacombe, Delphine Lanoie, Isabelle Valois, Francois Gouin, Ewelina Soszczyńska, Robert Kosicki, Marta Dias, Maximilien Debia
Workers in the waste-processing industry are potentially exposed to high concentrations of biological contaminants, leading to respiratory and digestive problems and skin irritations. However, few ...
废物处理行业的工人可能会接触到高浓度的生物污染物,从而导致呼吸道和消化系统疾病以及皮肤过敏。然而,很少有...
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引用次数: 0
An air quality data analysis system for interrelating effects, standards, and needed source reductions: Part 11. A lognormal model relating human lung function decrease to O3 exposure. 用于相互关联的影响、标准和所需源减少的空气质量数据分析系统:第11部分。人体肺功能与臭氧暴露有关的对数正态模型。
IF 2.7 4区 环境科学与生态学 Pub Date : 1991-04-01 DOI: 10.1080/10473289.1991.10466858
R I Larsen, W F McDonnell, D H Horstman, L J Folinsbee

Forced expiratory volume in 1 second (FEV1) was measured in 21 men exercising while exposed to four O3 concentrations (0.0, 0.08, 0.10, and 0.12 ppm). A lognormal multiple linear regression model was fitted to their mean FEV1 measurements to predict FEV1 percent decrease as a function of O3 concentration and exposure duration. The exercise level used was probably comparable to heavy manual labor. The longest O3 exposure studied was 6 h. Extrapolating cautiously to an 8-h workday of heavy manual labor, the model predicts that O3 concentrations of 0.08, 0.10, and 0.12 ppm would decrease FEV1 by 9, 15, and 20 percent, respectively.

研究人员测量了21名男性在暴露于四种臭氧浓度(0.0、0.08、0.10和0.12 ppm)下运动时的1秒用力呼气量(FEV1)。将对数正态多元线性回归模型拟合到他们的平均FEV1测量值中,以预测FEV1作为O3浓度和暴露时间的函数下降1%。所使用的运动水平可能与繁重的体力劳动相当。研究中最长的臭氧暴露时间为6小时。根据8小时的繁重体力劳动,该模型预测0.08、0.10和0.12 ppm的臭氧浓度将分别使FEV1减少9%、15%和20%。
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引用次数: 2
Source apportionment with site specific source profiles. 具有站点特定源配置文件的源分配。
IF 2.7 4区 环境科学与生态学 Pub Date : 1991-03-01 DOI: 10.1080/10473289.1991.10466846
D M Glover, P K Hopke, S J Vermette, S Landsberger, D R D'Auben

A receptor modeling study was performed to identify and apportion the sources of PM10 mass in Granite City, Illinois, an area of historic TSP nonattainment. Samples of the ambient aerosol were collected using a dichotomous sampler. Each sample was analyzed by x-ray fluorescence and instrumental neutron activation analysis. To begin the study, a factor analysis was performed. Two different chemical mass balance (CMB) analyses were then made. The first CMB analysis used only source profiles available from the literature while the second included twelve source profiles developed from dust samples collected in Granite City. Both CMB analyses used 20 of the 33 analyzed elements since many of the source profiles in the literature did not include the other thirteen elements. The results from both sets of CMB analyses were grouped by the predominate wind direction at the site during the time each sample was taken to identify the direction of each source relative to the sampler. It was found that regional sources were the primary contributors to the fine fraction while the coarse fraction was composed of material from local industries. These sources were generally the ones identified during the Regional Air Pollution Study previously conducted in the area. However, the emission profiles from these sources were observed to have changed between the studies. It was also found that the use of the locally generated profiles greatly improved the results of the CMB analysis.

一项受体模型研究在伊利诺伊州花岗岩市进行,以确定和分配PM10质量的来源,这是一个历史上未达到TSP的地区。使用二分采样器收集环境气溶胶样本。每个样品都通过x射线荧光和仪器中子活化分析进行分析。为了开始研究,进行了因子分析。然后进行了两种不同的化学质量平衡(CMB)分析。第一个CMB分析只使用了文献中可获得的源剖面,而第二个CMB分析包括了从花岗岩市收集的尘埃样本中开发的12个源剖面。两种CMB分析都使用了33种分析元素中的20种,因为文献中的许多源概况没有包括其他13种元素。两组CMB分析的结果按每个样本采集期间现场的主要风向分组,以确定每个源相对于采样器的方向。研究发现,区域来源是细馏分的主要来源,而粗馏分主要由地方工业原料组成。这些来源通常是先前在该地区进行的区域空气污染研究中确定的来源。然而,观察到这些源的排放分布在两次研究之间发生了变化。研究还发现,使用局部生成的剖面极大地改善了CMB分析的结果。
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引用次数: 25
Seasonal variations and trends in concentrations of filter-collected polycyclic aromatic hydrocarbons (PAH) and mutagenic activity in the San Francisco Bay area. 旧金山湾区过滤收集的多环芳烃(PAH)浓度和诱变活性的季节变化和趋势。
IF 2.7 4区 环境科学与生态学 Pub Date : 1991-03-01 DOI: 10.1080/10473289.1991.10466843
P Flessel, Y Y Wang, K I Chang, J J Wesolowski, G N Guirguis, I S Kim, D Levaggi, W Siu

Air monitoring in the San Francisco Bay Area was carried out to measure outdoor community air concentrations of polycyclic aromatic hydrocarbons (PAH) and mutagenic activity (mutagenicity) in particulate organic matter (POM). Monitoring began in 1979 and is currently conducted at six stations. PAH and mutagenicity tests were performed on organic extracts prepared from high volume (hi-vol) filters composited every four months, by meterological season. PAH were determined by high pressure liquid chromatography (HPLC) with fluorescence and ultraviolet detection. Mutagenicity was measured in the Ames Salmonella bioassay using strain TA98 with and without metabolic activation. The nine-year mean concentration of benzo(a)pyrene (BaP) was 0.4 ng/m3. The mutagenicity of this amount of BaP accounted for only about 0.2% of the observed mutagenicity in POM and other measured PAH accounted for even less. Concentrations of PAH and mutagenicity were three to nine times higher during the winter than during other seasons. Year-to-year wintertime trends in several PAH were also seen. Early in the 1980s, winter concentrations of BaP and benzo (g,h,i)perylene increased. However since the mid-1980's, their concentrations have fallen. The decrease in PAH concentrations may be the result of an increasing proportion of vehicles with relatively low organic emissions. In contrast to PAH, mutagenicity did not show significantly year-to-year time trends.

对旧金山湾区进行了空气监测,测量了社区室外空气中多环芳烃(PAH)的浓度和颗粒物有机物(POM)的致突变性。监测工作于1979年开始,目前在六个监测站进行。根据气象季节,每4个月对高容量(高容量)过滤器制备的有机提取物进行多环芳烃和致突变性试验。采用高压液相色谱法测定多环芳烃(PAH),并结合荧光和紫外检测。采用代谢激活和不代谢激活菌株TA98进行埃姆斯沙门氏菌的诱变性测定。苯并(a)芘(BaP)九年平均浓度为0.4 ng/m3。这一数量的BaP的致突变性仅占观察到的POM致突变性的0.2%左右,而其他测量到的多环芳烃的致突变性更少。冬季的多环芳烃浓度和致突变性是其他季节的3 ~ 9倍。几种多环芳烃的冬季年度变化趋势也可见一斑。20世纪80年代初,冬季BaP和苯并(g,h,i)苝的浓度增加。然而,自20世纪80年代中期以来,它们的浓度有所下降。多环芳烃浓度的下降可能是有机排放量相对较低的车辆比例增加的结果。与多环芳烃相比,致突变性没有明显的逐年趋势。
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引用次数: 24
Overview and update of the Superfund Innovative Technology Evaluation (SITE) Demonstration Program. 超级基金创新技术评估(SITE)示范项目概述和更新。
IF 2.7 4区 环境科学与生态学 Pub Date : 1991-03-01 DOI: 10.1080/10473289.1991.10466850
J F Martin

The Superfund Innovative Technology Evaluation (SITE) Program is now in its sixth year of demonstrating technologies applicable to Superfund sites. The SITE Program, conducted by the U.S. Environmental Protection Agency's Risk Reduction Engineering Laboratory, is intended to accelerate the use of new and innovative treatment processes as well as evaluate innovative measurement and monitoring techniques. Within the SITE Program, the Demonstration Program and the Emerging Technologies Program are responsible for innovative/alternative waste treatment technology development. Separate and parallel activities are progressing for development and evaluation of measuring and monitoring technologies as well as technology transfer operations.

超级基金创新技术评估(SITE)项目目前已进入第六个年头,展示适用于超级基金场址的技术。SITE项目由美国环境保护署降低风险工程实验室实施,旨在加速使用新的和创新的处理工艺,并评估创新的测量和监测技术。在SITE计划中,示范计划和新兴技术计划负责创新/替代废物处理技术的开发。发展和评价测量和监测技术以及技术转让业务方面的单独和平行活动正在取得进展。
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引用次数: 2
期刊
Journal of the Air & Waste Management Association
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