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Effects of Anthropomorphism of Environmental Mascots on Acceptance of Photovoltaic Power Generation 环境吉祥物的拟人化对接受光伏发电的影响
IF 0.2 Q4 Energy Pub Date : 2023-11-20 DOI: 10.3775/jie.102.120
Satoshi Arai, Takahiro Matsunaga, Hiroki Hondo
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引用次数: 0
英文目次 英文目次
IF 0.2 Q4 Energy Pub Date : 2023-11-20 DOI: 10.3775/jie.102.tce11_1
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引用次数: 0
和文目次 和文目次
IF 0.2 Q4 Energy Pub Date : 2023-11-20 DOI: 10.3775/jie.102.tcj11_1
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引用次数: 0
Dehydrocyclization-cracking of Soybean Oil Using Pt/NiMo Sulfide Catalysts Supported on Hierarchical ZSM-5-Al<sub>2</sub>O<sub>3</sub>-TiO<sub>2</sub>-composite Prepared by Sol-gel Method 溶胶-凝胶法制备ZSM-5-Al&lt;sub&gt;2&lt;/sub&gt; o&gt;3&lt;/sub&gt;-TiO&lt;sub&gt;2&lt;/sub&gt;-复合材料负载Pt/NiMo硫化物催化剂对大豆油的脱氢环裂解
Q4 Energy Pub Date : 2023-10-20 DOI: 10.3775/jie.102.110
Yuuya HAYASHI, Tadanori HASHIMOTO, Atsushi ISHIHARA
Hierarchical ZSM-5-Al2O3-TiO2-composite supported Pt, Ni and Mo sulfides catalysts were used for the dehydrocyclization-cracking of soybean oil at 1.0 MPa of hydrogen in the range 420-580 °C. Pt/NM/Z(24)75Ti(500sg) (N=Ni, M=Mo, Z=ZSM-5, 24=SiO2/Al2O3, 75=weight ratio, Ti=TiO2, 500=cal-cination temp. °C, sg=sol-gel method) and Pt/NM/Z(24)75Ti(600sg) prepared by the sol-gel method exhibited the higher activity in this reaction and the higher aromatics yields than the catalysts with single use of Al2O3 and TiO2 prepared by the kneading method. Further, Pt/NM/Z(24)30Al30Ti prepared by the kneading method and Pt/NM/Z(24)75Al(600sg) prepared by the sol-gel method exhibited the highest aromatics yield of 15% among the catalysts tested. The result indicated that the addition of TiO2 to the composite support would promote the interaction between molybdenum sulfide and TiO2, activate hydrogen and lead to enhanced cracking of ester group of triglyceride and cyclization of hydrocarbon fragments. When the sol-gel method was used, the catalysts with not only TiO2 but also Al2O3 exhibited the higher aromatics yields. Pt/NM/Z(24)75Ti(500sg) and Pt/NM/Z(24)75Ti(600sg) inhibited the formation of gaseous products while Pt/NM/Z(24)30Al30Ti and Pt/NM/Z(24)75Al(600sg) increased gaseous products, suggesting that the mechanism of aromatics formation might be different, and that the former would produce aromatics through the direct cyclization of longer-chained hydrocarbon fragments while the latter would produce them through gasification to C2-C4 olefins and the successive cyclization by the Diels-Alder reaction of olefins.
采用zsm -5- al2o3 - tio2 -复合负载Pt、Ni、Mo硫化物催化剂,在1.0 MPa氢气条件下,在420 ~ 580℃范围内对大豆油进行脱氢环裂解反应。Pt/NM/Z(24)75Ti(500sg) (N=Ni, M=Mo, Z=ZSM-5, 24=SiO2/Al2O3, 75=重量比,Ti=TiO2, 500=煅烧温度,sg=溶胶-凝胶法)和Pt/NM/Z(24)75Ti(600sg)在该反应中表现出比单一使用Al2O3和TiO2的捏合法制备的催化剂更高的活性和更高的芳香收率。其中,捏合法制备的Pt/NM/Z(24)30Al30Ti和溶胶-凝胶法制备的Pt/NM/Z(24)75Al(600sg)的芳烃产率最高,达到15%。结果表明,TiO2在复合载体上的加入会促进硫化钼与TiO2的相互作用,激活氢,导致甘油三酯酯基的裂解和烃碎片的环化。采用溶胶-凝胶法制备时,不仅含有TiO2,而且含有Al2O3的催化剂均表现出较高的芳烃产率。Pt/NM/Z(24)75Ti(500sg)和Pt/NM/Z(24)75Ti(600sg)抑制了气态产物的生成,而Pt/NM/Z(24)30Al30Ti和Pt/NM/Z(24)75Al(600sg)增加了气态产物的生成,说明芳烃的生成机理可能不同。前者通过长链烃片段的直接环化生成芳烃,而后者通过气化生成C2-C4烯烃并由烯烃的Diels-Alder反应连续环化生成芳烃。
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引用次数: 0
和文目次 和文目次
Q4 Energy Pub Date : 2023-10-20 DOI: 10.3775/jie.102.tcj10_1
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引用次数: 0
英文目次 英文目次
Q4 Energy Pub Date : 2023-10-20 DOI: 10.3775/jie.102.tce10_1
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引用次数: 0
英文目次 英文目次
Q4 Energy Pub Date : 2023-09-20 DOI: 10.3775/jie.102.tce9_1
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引用次数: 0
和文目次 和文目次
Q4 Energy Pub Date : 2023-09-20 DOI: 10.3775/jie.102.tcj9_1
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引用次数: 0
Microalgae Cultivation in Electrochemically Oxidized Anaerobic Digestate from Coffee Waste Biomass 咖啡废弃物电化学氧化厌氧消化液中微藻的培养
Q4 Energy Pub Date : 2023-09-20 DOI: 10.3775/jie.102.96
Haibo CHEN, Gen YOSHIDA, Fetra J. ANDRIAMANOHIARISOAMANANA, Ikko IHARA
Anaerobic digestate contains rich nutrients, such as nitrogen and phosphorus, which could be reused in microalgae cultivation. However, a clear growth medium is required for the cultivation to facilitate light permeable condition. The aim of this work was to investigate microalgae cultivation in electrochemically oxidized liquid digestate from coffee waste biomass. After removing the solid fraction of the digestate through microfiltration, the liquid digestate was treated by electrochemical oxidation using a boron-doped diamond anode. The liquid digestate (LD) and electrochemically oxidized liquid digestate (ELD) were used as media for microalgae cultivation.The effects of dilution from 5 to 20 times of the LD and reaction time from 1 to 5 h of the ELD on microalgae growth were also investigated. The results showed that the electrochemical oxidation had little influence on ammonium concentration in the digestate, whereas a color removal of up to 85% was observed. The ELD showed better microalgal growth performances than diluted LD, based on the data from optical density at 680 nm and cell density. The 10 times diluted, 2 h ELD achieved the best growth performance (additional optical density of 1.5 (-)) in all conditions. Our experiments proved that the ELD as a highly light permeable medium, better improved the growth performance of C. sorokiniana cultivation when compared with the LD medium.
厌氧消化液中含有丰富的氮、磷等营养物质,可在微藻培养中重复利用。然而,需要一种透明的生长介质,以促进光透条件的培养。本研究的目的是研究咖啡废生物质电解氧化液体消化液中微藻的培养。通过微滤去除消化液中的固体部分后,采用掺硼金刚石阳极对液体消化液进行电化学氧化处理。以液体消化液(LD)和电化学氧化消化液(ELD)为培养基培养微藻。研究了5 ~ 20倍的LD稀释和1 ~ 5 h的LD反应时间对微藻生长的影响。结果表明,电化学氧化对消化液中铵的浓度影响不大,但脱色率高达85%。基于680 nm光密度和细胞密度数据,ELD的微藻生长性能优于稀释后的LD。10倍稀释,2 h的ELD在所有条件下都获得了最佳的生长性能(附加光密度为1.5(-))。我们的实验证明,与LD培养基相比,ELD作为一种高度透光的培养基,能更好地提高sorokiniana的生长性能。
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引用次数: 0
Facile Preparation of Fe Mo Impregnated Catalyst for Carbon Nanotube Synthesis from Eucalyptus Oil 桉叶油制备铁钼浸渍碳纳米管催化剂的研究
Q4 Energy Pub Date : 2023-09-20 DOI: 10.3775/jie.102.104
Giang T. T. LE, BoA KYUNG, Emma ROUYRE, Sakhon RATCHAHAT, Weerawut CHAIWAT, Tawatchai CHARINPANITKUL
Carbon nanotubes were produced via co-pyrolysis of a carbon source and catalytic metal nanoparticles. Utilization of molybdenum to iron impregnated catalyst was found to provide carbon nanotubes with superior graphitic carbon content at rather low pyrolysis temperature and higher CNT yield. In this work, a facile method to obtain Fe Mo impregnated catalyst was introduced, and eucalyptus oil was employed as main carbon source with an aim of utilizing bio-based and renewable feedstock. After impregnation and drying steps, ferrocene impregnated with molybdenum was employed for CNT synthesis without any further treatment. Repeated experimental results using Fe Mo impregnated catalyst revealed that CNT yield could be increased from 0.269 to 0.404 kg/kg when pyrolysis temperature was increased from 800 to 900 °C. Based on SEM, XRD, and Raman spectroscopic analyses, CNTs obtained from Fe Mo impregnated catalyst possessed higher graphitic content when compared to those obtained from pure ferrocene only. These results reveal a promising way to utilize FeMo impregnated catalyst for effective valorization of eucalyptus oil to produce CNTs.
碳纳米管是通过碳源和催化金属纳米颗粒共热解制备的。利用钼作为铁浸渍催化剂,可以在较低的热解温度下获得优异的石墨碳含量和较高的碳纳米管收率。介绍了一种以桉树油为主要碳源制备铁钼浸渍催化剂的简便方法,目的是利用生物基和可再生原料。经过浸渍和干燥步骤后,用钼浸渍二茂铁合成碳纳米管,无需进一步处理。采用Fe - Mo浸渍催化剂的重复实验结果表明,当热解温度从800℃提高到900℃时,碳纳米管产率可从0.269 kg/kg提高到0.404 kg/kg。SEM、XRD和拉曼光谱分析表明,与纯二茂铁相比,Fe - Mo浸渍催化剂得到的碳纳米管具有更高的石墨含量。这些结果揭示了利用FeMo浸渍催化剂对桉树油进行有效增值以产生碳纳米管的有希望的方法。
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引用次数: 0
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Journal of The Japan Institute of Energy
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