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U-Pb ages and Hf isotopic composition of detrital zircon in western Algarve Triassic sandstone (SW Iberia): Implications for crustal evolution, provenance, and paleogeography 阿尔加维西部三叠纪砂岩(伊比利亚西南部)中锆石碎片的 U-Pb 年龄和 Hf 同位素组成:对地壳演化、产地和古地理的影响
IF 2.9 2区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-11-15 DOI: 10.1016/j.lithos.2024.107871
Manuel Francisco Pereira, Cristina Gama
The Triassic paleogeographic configuration before the Central Atlantic Ocean's opening and the Pangea's breakup establishes that Iberia was close to North America and North Africa. We present UPb and Hf isotope data of Triassic siliciclastic rocks of the Western Algarve basin (Southwest Iberia, Portugal) to draw inferences on their provenance to define the crustal evolution of the potential sources. Detrital zircon age populations of five samples of Triassic sandstones (68–80 % Neoproterozoic; 5–23 % Paleoproterozoic; 5–14 % Mesoproterozoic; <5 % Archaen and < 4 % Paleozoic) differ significantly from those of the underlying Carboniferous turbidites of the South Portuguese Zone suggesting provenance from outside present-day SW Iberia. Hf isotope signatures of the zircon grains from the western Algarve Triassic sandstones unravel a complex crustal evolution characterized by successive cycles of input of juvenile magmas and magmas derived from the reworking of older crust. Archean detrital zircon grains with positive εHf(t) values and model ages of 3.1–3 Ga indicate juvenile crust formation (Leonian event), while a grain dated at ca. 2.6 Ga showing negative εHf(t) values and model ages of 3.1 Ga suggests that the Archean crust became reworked later (Liberian event). Zircon grains dated between 2.4 and 2.5 Ga having positive to slightly negative εHf(t) values and model ages of 3.3–2.6 Ga model ages correspond to magmatism older than the Eburnean event known in the Reguibat shield, involving a juvenile component mixed with variable proportions of reworked Archean crust. Younger Paleoproterozoic grains (ca. 2.10 to 2.05 Ga; Eburnean-Birimian event) having positive εHf(t) values and model ages of 2.3–2.1 Ga and negative εHf(t) values and model ages of 3.6–2.6 Ga, also indicate interaction of juvenile sources with mixing of old crust. Mesoproterozoic grains show positive εHf(t) values and model ages of 2.3–2.1 Ga, suggesting juvenile crust formation and reworking of the Eburnean crust. Neoproterozoic (ca. 695–555 Ma) detrital zircon with positive εHf(t) values and model ages of 0.76–0.58 Ga point to juvenile crust formation (i.e. Cadomian/Pan-African and Avalonian arcs). They also have negative εHf(t) values in the range − 21.6 to −11.7 and model ages of 3.2–2.1 Ga, suggesting reworking of older crust. In summary, the εHf(t) values and UPb age pattern of the zircon grains from the Triassic siliciclastic rocks are similar to NW Africa and North America potential sources. Still, there is a notable gap in juvenile crust production during the Siderian in the peri-Eastern Laurentia, Avalonia, and Ganderia potential sources unknown in NW Africa. The lack of ca. 525–380 Ma and ca. 380–330 Ma detrital zircon in the western Algarve Triassic sandstones makes it challenging to admit an Atlantic margin of North America and SW Iberia provenance.
中大西洋开辟和泛大陆解体之前的三叠纪古地理格局确定了伊比利亚靠近北美洲和北非。我们提供了西阿尔加维盆地(葡萄牙伊比利亚西南部)三叠纪硅质碎屑岩的 UPb 和 Hf 同位素数据,以推断其来源,从而确定潜在来源的地壳演化。五个三叠纪砂岩样本的锆英石年龄群(68-80 % 新新生代;5-23 % 古新生代;5-14 % 中新生代;<5 % 古生代和<4 % 古生代)与南葡萄牙区石炭纪浊积岩下层的锆英石年龄群差异显著,表明其来源于当今伊比利亚西南部以外的地区。阿尔加维西部三叠纪砂岩中锆石颗粒的 Hf 同位素特征揭示了复杂的地壳演化过程,其特点是幼年岩浆和旧地壳再加工产生的岩浆的连续循环输入。具有正εHf(t)值和3.1-3 Ga模型年龄的Archean岩屑锆石颗粒表明地壳是由幼年岩浆形成的(Leonian事件),而一个年代为约2.6 Ga的锆石颗粒显示出负εHf(t)值和3.1 Ga模型年龄,这表明Archean岩壳在后来经过了再加工(Liberian事件)。年代在2.4-2.5 Ga之间的锆石颗粒,其εHf(t)值为正值到轻微的负值,模型年龄为3.3-2.6 Ga,对应于比雷吉巴特盾状区已知的埃伯恩事件更早的岩浆活动,包括混合了幼年成分和不同比例的再造阿切安地壳。较年轻的古近纪岩粒(约 2.10 至 2.05 Ga;埃伯恩-比里曼事件)具有正的εHf(t)值和 2.3 至 2.1 Ga 的模型年龄,以及负的εHf(t)值和 3.6 至 2.6 Ga 的模型年龄,也表明幼生源与旧地壳混合的相互作用。中新生代晶粒显示正的εHf(t)值和2.3-2.1 Ga的模型年龄,表明幼生代地壳的形成和埃伯恩地壳的再加工。新元古代(约695-555Ma)锆英石的εHf(t)值为正,模型年龄为0.76-0.58Ga,表明是幼壳形成(即Cadomian/泛非弧和Avalonian弧)。它们的εHf(t)值在-21.6到-11.7之间,模型年龄为3.2-2.1 Ga,表明是老地壳的再加工。总之,三叠纪硅质碎屑岩锆石晶粒的εHf(t)值和UPb年龄模式与非洲西北部和北美洲的潜在来源相似。然而,在西北非未知的近东劳伦西亚、阿瓦隆尼亚和甘德利亚潜在来源地区,西德纪的幼生地壳生成仍存在明显的差距。阿尔加维西部三叠纪砂岩中缺乏约 525-380 Ma 和约 380-330 Ma 的锆英石,这使得承认北美大西洋边缘和伊比利亚西南部的来源具有挑战性。
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引用次数: 0
Magmatic differentiation of peralkaline granites: Constraints from iron isotope fractionation between Fe-bearing minerals 碱性花岗岩的岩浆分异:含铁矿物间铁同位素分馏的制约因素
IF 2.9 2区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-11-12 DOI: 10.1016/j.lithos.2024.107863
De-Hong Du , Xiao-Lei Wang , Hang Xu , Shuo Wang , Ying-Ze Zhang , Weiqiang Li
Iron isotopes have been found useful in tracing magmatic processes of calc-alkaline granitic magmas, but its application in peralkaline granitic systems is hampered by the lack of information regarding the Fe isotope fractionation factors between alkali-rich ferromagnesian silicate minerals and FeTi oxides. To better understand the behavior of Fe isotopes during peralkaline magma differentiation, we carried out high-precision Fe isotope analyses on peralkaline and associated metaluminous high-silica granite rocks and Fe-bearing minerals separated from the rocks in Zhoushan archipelago, southeast China. The Fe-bearing mineral show a large dispersion in Fe isotope compositions, with δ56Fe ranging from 0.03 ‰ to 0.70 ‰, following the sequence of K-feldspar ≥ magnetite > aegirine > arfvedsonite > ilmenite. The δ56Fe differences between the mineral pairs are relatively consistent. Based on the magmatic temperatures defined by quartz-zircon oxygen isotopic geothermometer, the temperature-dependent equilibrium Fe isotope fractionation functions between following mineral pairs are obtained: Δ56Feaegirine-arfvedsonite = 0.20 (± 0.07) × 106/T2, Δ56Femagnetite-arfvedsonite = 0.38 (± 0.06) × 106/T2, and Δ56Femagnetite-aegirine = 0.16 (± 0.04) × 106/T2. The bulk peralkaline granites have variable but generally high δ56Fe values ranging from 0.28 ± 0.03 ‰ to 0.62 ± 0.04 ‰, with a mean of 0.42 ± 0.09 ‰ (1SD), which are higher than those of the associated metaluminous granitic samples (δ56Fe = 0.22 ± 0.05 ‰, 1SD). Furthermore, δ56Fe values of the peralkaline granites are negatively correlated with Sm/Yb and MnO, consistent with removal of isotopically light Fe-enriched arfvedsonite, implying that peralkaline granites experienced extensive magma differentiation regardless whether they were derived from differentiation of mantle-derived basaltic melts or partial melting of curst sources. Our results highlight a large Fe isotope fractionation between alkali ferromagnesian silicates and oxides, confirming Fe isotopes as a potential tool in tracking the differentiation processes of peralkaline magmas.
铁同位素被认为有助于追踪钙碱性花岗岩岩浆的岩浆过程,但由于缺乏有关富碱铁镁硅酸盐矿物与铁钛氧化物之间铁同位素分馏因子的信息,铁同位素在围岩花岗岩体系中的应用受到了阻碍。为了更好地了解围岩岩浆分异过程中铁同位素的行为,我们对中国东南部舟山群岛的围岩和伴生金属铝高硅花岗岩岩石以及从岩石中分离出来的含铁矿物进行了高精度的铁同位素分析。含铁矿物的铁同位素组成呈现出较大的分散性,δ56Fe从0.03‰到0.70‰不等,按照K长石≥磁铁矿>egirine>arfvedsonite>钛铁矿的顺序排列。矿物对之间的δ56Fe差异相对一致。根据石英-锆石氧同位素地温计确定的岩浆温度,可以得到以下矿物对之间与温度相关的平衡铁同位素分馏函数:Δ56Feaegirine-arfvedsonite = 0.20 (± 0.07) × 106/T2,Δ56Femagnetite-arfvedsonite = 0.38 (± 0.06) × 106/T2,Δ56Femagnetite-aegirine = 0.16 (± 0.04) × 106/T2。大块围岩花岗岩的δ56Fe值从0.28±0.03‰到0.62±0.04‰不等,平均值为0.42±0.09‰(1SD),但普遍较高,高于相关的金属铝质花岗岩样品(δ56Fe = 0.22 ± 0.05 ‰,1SD)。此外,碱性花岗岩的δ56Fe值与Sm/Yb和MnO呈负相关,这与富含同位素轻Fe的阿费维德松石被移除是一致的,这意味着碱性花岗岩经历了广泛的岩浆分异,无论它们是来自地幔玄武岩熔体的分异,还是来自凝灰岩源的部分熔融。我们的研究结果突显了碱性铁镁硅酸盐和氧化物之间存在着巨大的铁同位素分馏,证实了铁同位素是追踪围岩岩浆分异过程的潜在工具。
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引用次数: 0
Pressure-Temperature-time paths from metapelites reveal Neoproterozoic continental crust underthrusting related to the West Gondwana amalgamation 来自元古岩的压力-温度-时间路径揭示了与西冈瓦纳混杂有关的新近纪大陆地壳下推作用
IF 2.9 2区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-11-12 DOI: 10.1016/j.lithos.2024.107865
Alice Westin , Mahyra Tedeschi , Mario C. Campos Neto , George L. Luvizotto , Rafael G. Motta , Augusto G. Nobre , Rômulo A. Ando
In this contribution, we employed a petrochronological approach to investigate the tectonometamorphic evolution of Al-rich garnet-staurolite and garnet-staurolite-kyanite (biotite- and plagioclase-free) metapelites of the southernmost portion of the Neoproterozoic Brasília orogen. We have reconstructed the first prograde to peak pressure-temperature-time (P-T-t) paths reported for metamorphic units of the area, by combining petrographic analyses, quantitative compositional mapping of major elements, phase equilibrium modeling, and EPMA Th–U–Pb monazite chemical dating. The metamorphic reactions involved in the prograde metamorphic evolution are discussed, including the effects of garnet fractionation, exhaustion of reactants, and re-equilibration reactions on the major-element composition of garnet porphyroblasts, and their influence on P-T condition estimates. Raman spectroscopy on carbonaceous material (RSCM) thermometry provided insights into the synkinematic retrograde path. A steep prograde path marked by two stages is recorded by the garnet porphyroblasts of garnet-staurolite-muscovite (±kyanite) schists: (i) 555–585 °C and 0.60–0.90 GPa; (ii) 590–635 °C and 1.0–1.4 GPa. Monazite crystals record the prograde to peak path from ca. 630–625 Ma to ca. 605–595 Ma. Matrix graphite crystals suggest post-peak cooling to 400–500 °C concurrent with the late stages of development of the main foliation. The reconstructed P-T-t paths indicate an intermediate dT/dP metamorphism, and a burial rate of ∼0.55 km/Ma, with garnet compositional zoning suggesting that the high-pressure P-T-t path resulted from a single metamorphic event. The corresponding geothermal gradients, and in-situ ages, combined with regional evidence, suggest that peak metamorphic conditions were attained during collisional underthrusting of the continental crust related to the West Gondwana amalgamation.
在这篇论文中,我们采用岩石年代学方法研究了新新生代巴西利亚造山带最南端富铝石榴石-陶粒岩和石榴石-陶粒岩-榍石(不含生物岩和斜长石)变质岩的构造-变质演化。我们结合岩相分析、主要元素定量成分制图、相平衡建模和 EPMA Th-U-Pb monazite 化学年代测定,重建了该地区变质岩单位的首个从顺行到峰值的压力-温度-时间(P-T-t)路径。讨论了级变质演化过程中涉及的变质反应,包括石榴石分馏、反应物耗竭和再平衡反应对石榴石斑岩主要元素组成的影响,及其对 P-T 条件估算的影响。碳质材料上的拉曼光谱(RSCM)测温法提供了对同步逆行路径的深入了解。石榴石-白云石-莫斯卡维石(±斜长石)片岩的石榴石斑晶记录了两个阶段的陡峭逆行路径:(i) 555-585 °C,0.60-0.90 GPa;(ii) 590-635 °C,1.0-1.4 GPa。独居石晶体记录了从约 630-625 Ma 到约 605-595 Ma 的顺行至峰值路径。基质石墨晶体表明,峰后冷却至 400-500 °C,与主褶皱的后期发展阶段同时发生。重建的P-T-t路径显示了中间的dT/dP变质作用,埋藏率为∼0.55 km/Ma,石榴石成分分带表明高压P-T-t路径来自单一变质事件。相应的地热梯度和原位年龄,结合区域证据,表明变质峰值条件是在与西冈瓦纳混杂有关的大陆地壳碰撞下推过程中达到的。
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引用次数: 0
Tracking HFSE associated with high salinity fluid during HP metamorphism in the Zavkhan Terrane, Western Mongolia 追踪蒙古西部扎布汗地层在高压变质过程中与高盐度流体相关的高频震荡(HFSE
IF 2.9 2区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-11-10 DOI: 10.1016/j.lithos.2024.107853
Manzshir Bayarbold , Atsushi Okamoto , Masaoki Uno , Otgonbayar Dandar , Mayuko Fukuyama , Geri Agroli , Noriyoshi Tsuchiya
Garnets often exhibit high concentrations of heavy rare-earth elements, which provide crucial insights into element mobility and fluid dynamics during metamorphism. This research reports on the distributions of trace and major elements in garnets from the Khungui eclogite of the Zavkhan Terrane in Western Mongolia. Within the eclogite sample, two types of garnets were identified, featuring dissimilar microstructures and compositional zoning: aggregate-type garnet with asymmetric zoning (Grt1) and euhedral garnet with concentric zoning (Grt2). Previous studies determined that Grt2 formation occurred in the pre-eclogite stage to eclogite facies (2.1–2.2 GPa and 580–610 °C), associated with the infiltration of high-saline fluids. The hexagonal-shaped pseudomorphs of Ti-bearing minerals associated with Grt1 suggest that the nucleation of titanite and garnet was simultaneously accelerated by the destabilization of Ti-augite during pre-eclogite metamorphism. This process could have contributed to the formation of aggregation textures, where Ti-bearing minerals are closely associated with Grt1 in the Khungui eclogite. Based on major divalent elemental composition zoning and trace element characteristics, both Grt1 and Grt2 in the Khungui eclogite are formed simultaneously from the pre-eclogite to eclogite stages. The cores (high Fe + Mg + Mn; Y + REE) of Grt1 and Grt2 are attributed to Rayleigh fractionation or a diffusion-limited uptake process. In contrast, the growth mechanisms of the Grt1 rim and Grt2 rim are distinct during the eclogite stage. The Grt1 rim is explained by a dissolution–reprecipitation, which resulted in the atoll texture observed in Grt1. The Grt2 rim (high Ca; low Y + REE) grew through a mechanism consistent with that of the Grt2 core. The major and trace element zonings of these garnets provide insights into element mobility related to Ti-bearing minerals and infiltration of high salinity fluids at different stages: (1) the mobilization of Ti and V increased under eclogite facies conditions (growth stage of garnet) compared to the pre-eclogite stage, with the mobility of Ti, Nb, Ta elements being pronounced under the exhumation stage (Rt–Ilm–Ttn2), possibly because of the infiltration of high-saline fluids and an increase in temperature, and (2) post-growth compositional modification of Grt1 was induced by a localized transport of Fe, Mg, Mn, and Ca elements in response to the replacement of ilmenite by titanite during decompression (0.1–0.5 GPa and 421–534 °C). The contrasting zoning of garnet in Khungui eclogite indicates dissimilar scales of element mobility under eclogite facies conditions (over a thin-section scale) and during decompression (up to several centimeters or beyond).
石榴石通常含有高浓度的重稀土元素,这为了解变质过程中元素的流动性和流体动力学提供了重要信息。本研究报告介绍了蒙古西部扎夫汗地层 Khungui 蚀变岩中石榴石的微量元素和主要元素的分布情况。在该斜长岩样本中,发现了两种类型的石榴石,它们具有不同的微观结构和成分分带:具有非对称分带的集合型石榴石(Grt1)和具有同心分带的八面体石榴石(Grt2)。之前的研究确定,Grt2 的形成是在夕闪岩前阶段到夕闪岩面(2.1-2.2 GPa 和 580-610 °C),与高碱性流体的渗入有关。与 Grt1 相关的六方形含钛矿物假象表明,在前沸石变质过程中,钛橄榄石和石榴石的成核同时被钛橄榄石的不稳定所加速。这一过程可能促成了聚集纹理的形成,在坤贵闪长岩中,含钛矿物与 Grt1 紧密相连。根据主要二价元素组成分带和微量元素特征,坤贵斜长岩中的Grt1和Grt2是在前斜长岩到斜长岩阶段同时形成的。Grt1和Grt2的核心(高铁+镁+锰;Y+稀土元素)归因于雷利分馏或扩散受限的吸收过程。相比之下,在辉绿岩阶段,Grt1 边缘和 Grt2 边缘的生长机制则截然不同。Grt1 边缘可解释为溶解再沉淀,这导致了在 Grt1 中观察到的环状纹理。Grt2 边缘(高 Ca;低 Y + REE)的生长机制与 Grt2 内核的生长机制一致。这些石榴石的主要元素和痕量元素分带提供了与含钛矿物和高盐度流体在不同阶段的渗透有关的元素流动性的见解:(1) 与前夕长岩阶段相比,在夕长岩面条件下(石榴石的生长阶段),Ti 和 V 元素的移动性增加,而在(Rt-Ilm-Ttn2)辉绿岩阶段,Ti、Nb、Ta 元素的移动性明显增加、(2) 在减压过程中,由于钛铁矿取代了钛铁矿,Fe、Mg、Mn 和 Ca 元素发生了局部迁移,从而引起了 Grt1 生长后成分的改变(0.1-0.5 GPa 和 421-534 °C)。坤贵斜长辉石中石榴石的对比分带表明,在斜长辉石面条件下(薄切片范围内)和减压过程中(长达几厘米或更远),元素移动的规模各不相同。
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引用次数: 0
Triassic–Jurassic alkaline magmatism in the Ivrea-Verbano Zone, Southern Alps: A zircon perspective on mantle sources and geodynamic significance 南阿尔卑斯山伊夫雷亚-韦尔巴诺区三叠纪-侏罗纪碱性岩浆活动:从锆石角度看地幔来源和地球动力学意义
IF 2.9 2区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-11-08 DOI: 10.1016/j.lithos.2024.107854
Mattia Bonazzi , Abimbola C. Ogunyele , Tommaso Giovanardi , Maurizio Mazzucchelli , Alessandro Decarlis , Alessio Sanfilippo , Alberto Zanetti
The Ivrea-Verbano Zone (IVZ; western Southern Alps) consists of a distinctive sequence of the lower continental crust of the Adriatic plate, extending down to the subcontinental lithospheric mantle. It is characterized by a large variety of intrusive bodies of variable geochemical composition and age, offering a unique insight into the evolution of mantle-derived magmatism in post-collisional and extensional geodynamic settings. In this study, we characterize a suite of alkaline dykes intruding a mantle massif – the Finero Phlogopite Peridotite in northern IVZ. These dykes include zircon-bearing diorites and anorthosites, mainly composed by HFSE-rich amphibole and phlogopite, albite (>90 vol% in anorthosites) and apatite. Zircon, monazite, ilmenite, titanite, Nb-rich oxides, and carbonates are common accessory minerals. Additionally, a “composite” diorite dyke containing both HFSE-rich and HFSE-poor amphiboles was investigated. The study is aimed at providing new trace element, U-Pb geochronological and Lu-Hf isotopes dataset on zircon from these alkaline dykes, to refine the understanding of their mantle source characteristics, emplacement age and geodynamic implications. The trace element composition of zircons from the studied dykes points to segregation from melts with alkaline to ultra-alkaline affinity. Concordia U-Pb ages of zircon from the alkaline diorite dykes span from 221 to 191 Ma, which are interpreted as the result of multiple crystallization/recrystallization stages related to different magmatic pulses. Conversely, zircon from anorthosite and composite diorite dykes yield a narrow time range of 198–202 Ma, highlighting the occurrence of a magmatic pulse around ca. 200 Ma. The εHf(t) values (+13.4 to +5.7) of zircon from the alkaline diorite dykes are significantly more positive compared to the values in those from anorthosite and composite diorite dykes (+4.2 to −0.4), suggesting that the parental melts were derived from heterogeneous asthenospheric mantle sources with low to moderate amount of recycled continental crust components. Our data and reappraisal of the literature indicate that the IVZ experienced a protracted period of alkaline magmatism from ca. 235 Ma to 185 Ma. The melts migrated along mantle shear zones during the Triassic-Jurassic lithospheric extension. Different pulses of alkaline magmatism were associated with relevant extensional tectonic stages recorded by the continental crust, presumably triggering a passive uplift of heterogenous asthenospheric reservoirs over a front of at least 500 km. This tectono-magmatic cycle is a precursor to the focused rifting stage which caused the opening of the Jurassic Alpine Tethys, enhancing Pangea fragmentation.
伊夫雷亚-韦尔巴诺区(Ivrea-Verbano Zone,南阿尔卑斯山西部)由亚得里亚海板块下部大陆地壳的一个独特序列组成,一直延伸到次大陆岩石圈地幔。其特点是有大量不同地球化学成分和年龄的侵入体,为了解碰撞后和伸展地球动力环境中地幔岩浆的演变提供了独特的视角。在这项研究中,我们描述了一套侵入地幔块体--位于IVZ北部的Finero辉绿岩橄榄岩--的碱性岩体的特征。这些岩体包括含锆石的闪长岩和正长岩,主要由富含HFSE的闪长岩和辉长岩、白云石(在正长岩中占90%)和磷灰石组成。锆石、独居石、钛铁矿、榍石、富铌氧化物和碳酸盐是常见的附属矿物。此外,还研究了一个 "复合 "闪长岩斜长岩,其中包含富含高频闪长岩和贫含高频闪长岩的闪长岩。该研究旨在为这些碱性岩堤中的锆石提供新的痕量元素、U-Pb地质年代和Lu-Hf同位素数据集,以完善对其地幔源特征、成岩年龄和地球动力学影响的认识。所研究堤坝中锆石的微量元素组成表明,这些锆石是从具有碱性至超碱性亲和力的熔体中分离出来的。来自碱性闪长岩堤的锆石的康科迪亚 U-Pb 年龄跨度为 221 至 191 Ma,可解释为与不同岩浆脉冲有关的多个结晶/再结晶阶段的结果。相反,从正长岩和复合闪长岩岩体中提取的锆石的时间范围很窄,为198-202 Ma,突显了大约200 Ma的岩浆脉冲。碱性闪长岩岩体锆石的εHf(t)值(+13.4至+5.7)与正长岩和复合闪长岩岩体锆石的εHf(t)值(+4.2至-0.4)相比明显偏正,表明母体熔体来自异质天体层地幔源,含有少量至中等量的再循环大陆地壳成分。我们的数据和对文献的重新评估表明,IVZ经历了从约235Ma到185Ma的漫长碱性岩浆活动期。在三叠纪-侏罗纪岩石圈延伸期间,熔融物沿着地幔剪切带迁移。不同的碱性岩浆活动脉冲与大陆地壳记录的相关延伸构造阶段相关联,可能引发了异质星震层储层在至少 500 公里的前沿被动隆升。这一构造-岩浆循环是造成侏罗纪阿尔卑斯特提斯开裂的集中裂解阶段的前兆,加剧了泛大陆的分裂。
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引用次数: 0
Paleoproterozoic sediment-derived magmas reveal a late orogenic stage in the southern São Francisco Craton, Brazil: Evidence from petrogenesis of the 2.0 Ga Cupim Pluton leucogranites 古近纪沉积物衍生岩浆揭示了巴西圣弗朗西斯科克拉通南部的晚期造山阶段:来自 2.0 Ga Cupim Pluton 白岩浆岩岩石成因的证据
IF 2.9 2区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-11-07 DOI: 10.1016/j.lithos.2024.107852
Syro Lacerda , Martin Guitreau , Leonardo Gonçalves , Hugo Moreira , Cristiane C. Gonçalves , Marco Aurélio Pinheiro , Cassiano Costa e Castro , Régis Doucelance
Sediment-derived granites (S-type) can provide detailed information about continental crust reworking processes and tectonic regimes through time. Their compositions reflect the nature of sedimentary rocks that melted to form them. Inherited accessory minerals in these granites can provide information regarding the age and nature of the crustal rocks that contributed to the formation of their sedimentary source rock. In addition, S-type granites typically form during collisional stages in modern orogens, and their Precambrian records can provide clues about ancient tectonics. In this contribution, we present a detailed petrogenesis of the Cupim Pluton, located in the Paleoproterozoic Mineiro Belt (Brazil). The Cupim pluton is composed of two-mica and garnet-bearing leucogranites that are strongly peraluminous (ASI > 1.1), high-K (K2O/Na2O > 1), low MgO + FeO + TiO2 (<2 wt%). Its composition is similar to that of melts experimentally produced by muscovite/biotite dehydration melting reactions. Rb/Sr and Rb/Ba ratios suggest that these leucogranites are formed by the melting of heterogeneous sedimentary source(s). Zircon crystals from the Cupim Pluton unveil a protracted crustal melting period (2.01–1.98 Ga) hitherto unknown in the Mineiro Belt, which itself discloses a late collisional orogenic stage in southern São Francisco Craton. Igneous zircon crystals exhibit εHf(t) between −16.4 and − 0.6, and δ30Si between −1.16 and − 0.26 ‰, which is typical for zircon from sediment-derived granites. Hafnium isotope variations reflect mixing between at least two crustal sources, which is in line with inherited zircon cores that evidence major Archean and minor Paleoproterozoic sediment contributions. The emplacement of the Cupim Pluton leucogranites ends a subduction-collision cycle, following a long period of TTG-sanukitoid magma production, and promoted the stabilization of the southern São Francisco Craton.
沉积衍生花岗岩(S 型)可提供有关大陆地壳再加工过程和构造体系的详细信息。它们的成分反映了熔化形成它们的沉积岩的性质。这些花岗岩中继承的附属矿物可提供有关沉积源岩形成过程中地壳岩石的年龄和性质的信息。此外,S 型花岗岩通常形成于现代造山运动的碰撞阶段,它们的前寒武纪记录可以提供有关古代构造的线索。在这篇论文中,我们详细介绍了位于巴西古生代米涅罗带的 Cupim 板块的岩石成因。Cupim岩体由双云母和含石榴石的白榴石组成,具有强过铝性(ASI >1.1)、高K(K2O/Na2O >1)、低MgO + FeO + TiO2(<2 wt%)。其成分与麝香石/橄榄石脱水熔化反应实验产生的熔体成分相似。Rb/Sr和Rb/Ba比率表明,这些白榴石是由异质沉积源熔化形成的。丘比姆岩块的锆石晶体揭示了米内罗带迄今未知的漫长地壳熔化期(2.01-1.98 Ga),而米内罗带本身则揭示了圣弗朗西斯科克拉通南部晚期的碰撞造山阶段。火成岩锆石晶体的εHf(t)介于-16.4和-0.6之间,δ30Si介于-1.16和-0.26 ‰之间,这是沉积花岗岩锆石的典型特征。铪同位素的变化反映了至少两种地壳来源之间的混合,这与继承的锆石岩心相吻合,这些锆石岩心证明了主要的奥陶纪沉积物和次要的古近纪沉积物的贡献。Cupim Pluton白花岗岩的置换结束了一个俯冲-碰撞周期,并经历了一个漫长的TTG-Sanukitoid岩浆生成期,促进了圣弗朗西斯科克拉通南部的稳定。
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引用次数: 0
Mesozoic lithospheric mantle evolution in South China: Evidence from Ar-Ar dating, geochemistry and Sr-Nd-Pb isotopes of lamprophyres 华南中生代岩石圈地幔演化:从Ar-Ar测年、地球化学和灯石的Sr-Nd-Pb同位素得出的证据
IF 2.9 2区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-11-06 DOI: 10.1016/j.lithos.2024.107851
Lei Wang , Hua Huang , Xinbiao Jin , Xiujuan Bai , Xinyu Wang , Xiangke Wu
Understanding the Mesozoic lithospheric mantle beneath South China is challenging, primarily because mantle-derived magmatic rocks are rare, whereas granitic magmatism is far more abundant. In this study, we present new 40Ar/39Ar geochronology, major and trace elemental composition, and Sr-Nd-Pb isotopic data for lamprophyres from northern and central Guangxi Province, South China. Our results reveal two intrusion phases: an earlier phase at 207.7 ± 1.2 Ma, and a later phase between 95.6 ± 0.6 Ma and 102.3 ± 0.7 Ma. The earlier phase, represented by the Danyang lamprophyres, is marked by low Cr (330–355 ppm) and Ni (241–258 ppm) contents and strongly fractionated REE patterns with (La/Yb)n ratios of 57.5 to 62.8. The later phase, represented by the Leidong, Nongchang, and Longchang lamprophyres, shows higher Cr (490–781 ppm) and Ni (237–377 ppm) contents, with less fractionated REE patterns and (La/Yb)n ratios of 20.2 to 27.8. Despite their temporal differences, the lamprophyres share similar isotopic characteristics, including high initial 87Sr/86Sr (0.707940–0.721310), negative εNd(t) (−9.19 to −5.31), and radiogenic Pb isotopic compositions (206Pb/204Pb: 18.200–18.331, 207Pb/204Pb: 15.62–15.72, 208Pb/204Pb: 38.53–38.84). These features suggest derivation from low-degree partial melting of a phlogopite-bearing, refractory peridotite lithospheric mantle, modified by olivine and clinopyroxene fractionation. This refractory mantle was metasomatically enriched by Proterozoic subduction processes beneath the Yangtze Craton. By synthesizing published Sr-Nd-Pb isotopic data, we propose that the lithospheric mantle beneath South China shifted from enriched to depleted mantle between ∼220 Ma and ∼ 100 Ma, possibly due to extension associated with the subduction and rollback of the Paleo-Pacific Plate.
了解华南地下中生代岩石圈地幔具有挑战性,这主要是因为地幔衍生岩浆岩非常罕见,而花岗岩岩浆岩则丰富得多。在本研究中,我们展示了华南广西省北部和中部灯盏花岩的新 40Ar/39Ar 地质年代、主要元素和微量元素组成以及 Sr-Nd-Pb 同位素数据。我们的研究结果揭示了两个侵入阶段:207.7 ± 1.2 Ma的早期阶段和95.6 ± 0.6 Ma至102.3 ± 0.7 Ma的晚期阶段。早期阶段以丹阳灯盏花岩为代表,铬(330-355 ppm)和镍(241-258 ppm)含量较低,REE形态分馏强烈,(La/Yb)n比值为57.5至62.8。以雷洞、弄场和龙场灯体为代表的晚期灯体显示出较高的铬(490-781 ppm)和镍(237-377 ppm)含量,较少的分馏REE模式和(La/Yb)n比值为20.2至27.8。尽管在时间上存在差异,但这些灯泡岩具有相似的同位素特征,包括较高的初始 87Sr/86Sr (0.707940-0.721310)、负εNd(t) (-9.19 至 -5.31)和放射性铅同位素组成(206Pb/204Pb:18.200-18.331;207Pb/204Pb:15.62-15.72;208Pb/204Pb:38.53-38.84)。这些特征表明,这些岩石是由含辉绿岩的难熔橄榄岩岩石圈地幔经橄榄石和挛辉石分馏后的低度局部熔融衍化而成的。这种难熔地幔在长江克拉通下的新生代俯冲过程中发生了变质富集。通过综合已发表的Sr-Nd-Pb同位素数据,我们提出华南地下岩石圈地幔在220Ma∼100Ma之间从富集地幔转变为贫化地幔,这可能是与古太平洋板块的俯冲和回滚有关的延伸所致。
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引用次数: 0
Restite entrainment in S-type granites: A systematic review S 型花岗岩中的息石夹带:系统回顾
IF 2.9 2区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-11-05 DOI: 10.1016/j.lithos.2024.107850
M. García-Arias
S-type granites show linear correlations for major elements and some trace elements in bivariate diagrams against maficity (FeOt + MgO), with negative trends for major incompatible elements and positive trends for major compatible elements, extending beyond the usual composition of experimental and anatectic melts. Although several petrogenetic processes have been suggested, restite entrainment has been prominently proposed to explain that compositional feature. Restite entrainment implies that melt leaves the partially melted source rocks containing variable amounts of the solid phases present in the melting volume, which are generally Ca-Fe-Mg-Ti-richer and Si-Na-K-poorer than the melt. The entrainment of these phases will consequently produce the described compositional trends. In this manuscript I provide a review of this process based on my personal experience with thermodynamic modelling of the partial melting of metasedimentary sources and on conclusions published by other authors. In particular, I review what constitutes restite, the factors that control the entrainment of minerals, the proposed types of restite entrainment, the evidence in favor of (or against) this process, and other related aspects.
在双变量图中,S 型花岗岩的主要元素和一些微量元素与岩浆度(FeOt + MgO)呈线性相关,主要不相容元素呈负趋势,而主要相容元素呈正趋势,超出了实验熔体和无极熔体的通常成分。虽然提出了几种成岩过程,但主要提出了休止符夹带来解释这种成分特征。休止岩夹带意味着熔体离开部分熔化的源岩时,熔体体积中含有不同数量的固相,这些固相通常比熔体中的钙-铁-镁-钛-富集,比硅-萘-钾-贫化。因此,这些相的夹杂将产生所述的成分趋势。在本手稿中,我将根据个人对偏硅酸源部分熔化的热力学建模经验以及其他作者发表的结论,对这一过程进行回顾。特别是,我回顾了什么是休止符、控制矿物夹带的因素、所提出的休止符夹带类型、支持(或反对)这一过程的证据以及其他相关方面。
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引用次数: 0
Givetian-Frasnian rift-related volcanism of the Shipunikha Depression, NW Rudny Altai, Central Asia: Tectono-magmatic significance and new constraints on whole-rock geochemistry, Nd-isotopic data and UPb ages 中亚鲁德尼阿尔泰西北部希普尼克哈洼地与纪元-新生代断裂有关的火山活动:构造-岩浆学意义以及对全岩石地球化学、钕同位素数据和 UPb 年龄的新约束
IF 2.9 2区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-11-04 DOI: 10.1016/j.lithos.2024.107849
M.L. Kuibida , N.N. Kruk , I.V. Vikentiev , O.V. Murzin , N.M. Murzina , V.A. Yakovlev , Ya Yu Shelepov , A.V. Chugaev , M.A. Mizernaya , R.A. Shelepaev , P.D. Kotler , E.I. Mikheev , I.V. Nikolaeva , S.V. Palesskiy , D.V. Semenova , N.G. Soloshenko , A.P. Pyatkova , G.F. Karmanov
<div><div>The paper presents new original data on the Devonian rift-related volcanism from the Rudny Altai, a marginal terrane of the Siberian continent (Altai-Sayan Fold Belt, western Central Asian Orogenic Belt). The extensional regime in relation to tectono-magmatic reactivation of the continental margin was accompanied by an intense flare up of bimodal-type shallow-marine volcanism and injection of subvolcanic intrusions. On the first stage basic magmatism evolved from (i) injection of “More LREE- and HFSE-enriched” dolerite (<em>ε</em><sub>Nd</sub>(t) = +5.1) to (ii) eruption of their effusive analogues (<em>ε</em><sub>Nd</sub>(t) = +1.4), and following “Less LREE- and HFSE-enriched” basalt (<em>ε</em><sub>Nd</sub>(t) = +6.1). This stage reflects initial opening of the rift. On the second stage, volcanism evolved from (iii) “LREE- and HFSE-depleted” (<em>ε</em><sub>Nd</sub>(t) = +5.4) to (iv) “LREE-enriched and HFSE-depleted” (<em>ε</em><sub>Nd</sub>(t) = +4.1 to +4.7) types. This stage correspond to the prolonged opening of the pull-apart basin, as there is no geological evidence for island-arc uplift during this period. Variations in indicator HFSE ratios (Th/Yb, Nb/Yb and Zr/Y), enrichment of Nb relative to La and Th in combination with moderate Nd isotopic values resemble those for basalts from the behind-arc region with close spatial-temporal relation to rifting. The trace element variation indicates a change in the partial melting degree of the mantle source, from lower to higher, consistent with progressive rifting. The petrogenesis of magmas has been interpreted as shallow melting of a lithospheric mantle, metosomatised by a previous subduction event, and inherited geochemical signatures of relict mantle. The voluminous felsic magmatism was formed by crustal melting during lithospheric extension when basic magmas reached high crustal levels. The dacites yield zircon U<img>Pb ages of ca. 375 Ma, reflecting the peak of volcanic activity. The tectonic record bear evidence of strike-slip deformation, which could been induced by translation of arc and back-arc lithospheric plates.</div></div><div><h3>Summary</h3><div>The Devonian evolution of the Altai Convergent Margin (NW Rudny Altai) of the Siberian continent was accompanied by the generation of basalt-dacite volcanism (∼380-375 Ma). Based on the sequence of volcanic phases and their geochemical variations in the time range, two stages corresponding to the initial and long-term opening of the pull-apart basin are distinguished. The petrogenesis of the magmas is interpreted as shallow melting of lithospheric mantle metasomatised by a previous subduction event and inheriting geochemical signatures of the relict mantle. The initial and subsequent magmatic phases can be reproduced by varying the degree of partial melting of the magma source from lower to higher, consistent with the evolution of the pull-apart basin. Rift-related magmatism is caused by arc and back-arc plate translation, wi
本文提供了关于鲁德阿尔泰泥盆纪断裂相关火山活动的新原始数据,鲁德阿尔泰是西伯利亚大陆(阿尔泰-萨彦褶皱带,中亚造山带西部)的一个边缘陆相。与大陆边缘构造-岩浆再活化有关的延伸机制伴随着双峰型浅海火山活动的强烈爆发和亚火山侵入体的注入。在第一阶段,基本岩浆活动从(i)注入 "富含更多 LREE 和 HFSE "的辉绿岩(εNd(t) = +5.1)发展到(ii)喷出其类似物(εNd(t) =+1.4),然后是 "富含更少 LREE 和 HFSE "的玄武岩(εNd(t) = +6.1)。这一阶段反映了裂谷的初步打开。在第二阶段,火山活动从(iii) "LREE-和HFSE-贫化 "型(εNd(t) = +5.4)演变为(iv) "LREE-富集和HFSE-贫化 "型(εNd(t) = +4.1至+4.7)。这一阶段与拉开海盆的长期开放相对应,因为在此期间没有地质证据表明岛弧隆升。指标高频扫描比(Th/Yb、Nb/Yb 和 Zr/Y)的变化、Nb 相对于 La 和 Th 的富集以及适度的 Nd 同位素值与弧后地区的玄武岩相似,与断裂的时空关系密切。痕量元素的变化表明地幔源的部分熔融程度发生了变化,从较低到较高,这与渐进式断裂是一致的。岩浆的岩石成因被解释为岩石圈地幔的浅层熔融,由先前的俯冲事件和继承的残余地幔的地球化学特征代谢而成。大量长粒岩浆是岩石圈延伸过程中地壳熔融形成的,当时碱性岩浆达到地壳高位。白云母的锆石 UPb 年龄约为 375 Ma,反映了火山活动的高峰期。摘要西伯利亚大陆阿尔泰汇聚边缘(鲁德尼阿尔泰西北部)泥盆纪的演化伴随着玄武岩-英安岩火山活动的产生(∼380-375 Ma)。根据火山相的序列及其在时间范围内的地球化学变化,可将拉开盆地的开辟分为初始和长期两个阶段。岩浆的岩石成因被解释为岩石圈地幔在之前的俯冲事件中变质后的浅层熔融,并继承了残余地幔的地球化学特征。通过改变岩浆源的部分熔化程度,从较低到较高,可以再现最初和随后的岩浆阶段,这与拉开盆地的演化相一致。与裂谷有关的岩浆活动是由弧和弧后板块平移引起的,俯冲因素作用较小。
{"title":"Givetian-Frasnian rift-related volcanism of the Shipunikha Depression, NW Rudny Altai, Central Asia: Tectono-magmatic significance and new constraints on whole-rock geochemistry, Nd-isotopic data and UPb ages","authors":"M.L. Kuibida ,&nbsp;N.N. Kruk ,&nbsp;I.V. Vikentiev ,&nbsp;O.V. Murzin ,&nbsp;N.M. Murzina ,&nbsp;V.A. Yakovlev ,&nbsp;Ya Yu Shelepov ,&nbsp;A.V. Chugaev ,&nbsp;M.A. Mizernaya ,&nbsp;R.A. Shelepaev ,&nbsp;P.D. Kotler ,&nbsp;E.I. Mikheev ,&nbsp;I.V. Nikolaeva ,&nbsp;S.V. Palesskiy ,&nbsp;D.V. Semenova ,&nbsp;N.G. Soloshenko ,&nbsp;A.P. Pyatkova ,&nbsp;G.F. Karmanov","doi":"10.1016/j.lithos.2024.107849","DOIUrl":"10.1016/j.lithos.2024.107849","url":null,"abstract":"&lt;div&gt;&lt;div&gt;The paper presents new original data on the Devonian rift-related volcanism from the Rudny Altai, a marginal terrane of the Siberian continent (Altai-Sayan Fold Belt, western Central Asian Orogenic Belt). The extensional regime in relation to tectono-magmatic reactivation of the continental margin was accompanied by an intense flare up of bimodal-type shallow-marine volcanism and injection of subvolcanic intrusions. On the first stage basic magmatism evolved from (i) injection of “More LREE- and HFSE-enriched” dolerite (&lt;em&gt;ε&lt;/em&gt;&lt;sub&gt;Nd&lt;/sub&gt;(t) = +5.1) to (ii) eruption of their effusive analogues (&lt;em&gt;ε&lt;/em&gt;&lt;sub&gt;Nd&lt;/sub&gt;(t) = +1.4), and following “Less LREE- and HFSE-enriched” basalt (&lt;em&gt;ε&lt;/em&gt;&lt;sub&gt;Nd&lt;/sub&gt;(t) = +6.1). This stage reflects initial opening of the rift. On the second stage, volcanism evolved from (iii) “LREE- and HFSE-depleted” (&lt;em&gt;ε&lt;/em&gt;&lt;sub&gt;Nd&lt;/sub&gt;(t) = +5.4) to (iv) “LREE-enriched and HFSE-depleted” (&lt;em&gt;ε&lt;/em&gt;&lt;sub&gt;Nd&lt;/sub&gt;(t) = +4.1 to +4.7) types. This stage correspond to the prolonged opening of the pull-apart basin, as there is no geological evidence for island-arc uplift during this period. Variations in indicator HFSE ratios (Th/Yb, Nb/Yb and Zr/Y), enrichment of Nb relative to La and Th in combination with moderate Nd isotopic values resemble those for basalts from the behind-arc region with close spatial-temporal relation to rifting. The trace element variation indicates a change in the partial melting degree of the mantle source, from lower to higher, consistent with progressive rifting. The petrogenesis of magmas has been interpreted as shallow melting of a lithospheric mantle, metosomatised by a previous subduction event, and inherited geochemical signatures of relict mantle. The voluminous felsic magmatism was formed by crustal melting during lithospheric extension when basic magmas reached high crustal levels. The dacites yield zircon U&lt;img&gt;Pb ages of ca. 375 Ma, reflecting the peak of volcanic activity. The tectonic record bear evidence of strike-slip deformation, which could been induced by translation of arc and back-arc lithospheric plates.&lt;/div&gt;&lt;/div&gt;&lt;div&gt;&lt;h3&gt;Summary&lt;/h3&gt;&lt;div&gt;The Devonian evolution of the Altai Convergent Margin (NW Rudny Altai) of the Siberian continent was accompanied by the generation of basalt-dacite volcanism (∼380-375 Ma). Based on the sequence of volcanic phases and their geochemical variations in the time range, two stages corresponding to the initial and long-term opening of the pull-apart basin are distinguished. The petrogenesis of the magmas is interpreted as shallow melting of lithospheric mantle metasomatised by a previous subduction event and inheriting geochemical signatures of the relict mantle. The initial and subsequent magmatic phases can be reproduced by varying the degree of partial melting of the magma source from lower to higher, consistent with the evolution of the pull-apart basin. Rift-related magmatism is caused by arc and back-arc plate translation, wi","PeriodicalId":18070,"journal":{"name":"Lithos","volume":"490 ","pages":"Article 107849"},"PeriodicalIF":2.9,"publicationDate":"2024-11-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142658365","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
First-principles calculations of equilibrium inter-mineral nickel isotope fractionation in the mantle 地幔中矿物质间镍同位素平衡分馏的第一原理计算
IF 2.9 2区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-11-02 DOI: 10.1016/j.lithos.2024.107848
Zhuang Ma , Wenzhong Wang , Shui-Jiong Wang
The nickel (Ni) isotopic systematics has been increasingly utilized to understand the processes governing planetary differentiation. However, there is a lack of fundamental knowledge regarding equilibrium Ni isotope fractionation among mantle minerals, which hampered further applications of Ni isotopes in this domain. In this study, we conducted first-principles calculations to determine the reduced partition function ratios of 60Ni/58Ni (103lnβ6058) in major Ni-doped mantle minerals, including olivine, orthopyroxene, clinopyroxene, pyrope and spinel. Our calculations reveal that the 103lnβ6058 is insensitive to the Ni concentration within the mineral Ni concentration ranges investigated here, and the 103lnβ6058 increases in the order of pyrope < clinopyroxene < orthopyroxene < olivine < spinel. Moreover, the 103lnβ6058 demonstrates a predominantly linear relationship with the average force constant (< F >) of Ni that is mainly influenced by the average NiO bond length. By comparing the measured inter-mineral Ni isotopic differences in mantle rocks with our predicted results, we find that olivine, spinel and orthopyroxene in most peridotitic samples have attained Ni isotopic equilibrium. Conversely, clinopyroxene appears to fall out of equilibrium with other mineral phases, likely attributed to its metasomatic origin. Furthermore, in conjunction with the melt-olivine Ni isotope fractionation factor obtained from theoretical calculation and laboratory experiment, we demonstrate that mantle silicate melting produces melts with a heavier Ni isotopic signature compared to the source. Consequently, the systematically lighter Ni isotopic compositions observed in global basalts cannot be purely attributed to silicate melting-induced Ni isotope fractionation. An additional process, perhaps sulfide dissolution, must be invoked.
人们越来越多地利用镍(Ni)同位素系统学来了解行星的分化过程。然而,由于缺乏地幔矿物间镍同位素平衡分馏的基础知识,阻碍了镍同位素在这一领域的进一步应用。在这项研究中,我们进行了第一原理计算,以确定主要掺镍地幔矿物(包括橄榄石、正长石、挛辉石、辉石和尖晶石)中 60Ni/58Ni (103lnβ60-58)的还原分区函数比。我们的计算显示,在本文研究的矿物掺镍浓度范围内,103lnβ60-58对镍浓度不敏感,103lnβ60-58依次为辉石、挛辉石、正长石、橄榄石和尖晶石。此外,103lnβ60-58 与镍的平均作用力常数(< F >)主要呈线性关系,这种关系主要受 NiO 键平均长度的影响。通过比较地幔岩石中测得的矿物间 Ni 同位素差异与我们的预测结果,我们发现橄榄石、尖晶石和正辉石在大多数橄榄岩样品中达到了 Ni 同位素平衡。相反,霞石似乎与其他矿物相失去了平衡,这很可能是由于霞石的成因。此外,结合理论计算和实验室实验得出的熔体-岩浆 Ni 同位素分馏系数,我们证明地幔硅酸盐熔融产生的熔体与来源相比具有更重的 Ni 同位素特征。因此,在全球玄武岩中观察到的系统性较轻的镍同位素组成不能纯粹归因于硅酸盐熔融引起的镍同位素分馏。还必须考虑到另外一个过程,也许是硫化物溶解。
{"title":"First-principles calculations of equilibrium inter-mineral nickel isotope fractionation in the mantle","authors":"Zhuang Ma ,&nbsp;Wenzhong Wang ,&nbsp;Shui-Jiong Wang","doi":"10.1016/j.lithos.2024.107848","DOIUrl":"10.1016/j.lithos.2024.107848","url":null,"abstract":"<div><div>The nickel (Ni) isotopic systematics has been increasingly utilized to understand the processes governing planetary differentiation. However, there is a lack of fundamental knowledge regarding equilibrium Ni isotope fractionation among mantle minerals, which hampered further applications of Ni isotopes in this domain. In this study, we conducted first-principles calculations to determine the reduced partition function ratios of <sup>60</sup>Ni/<sup>58</sup>Ni (10<sup>3</sup>lnβ<sub>60</sub><sub>–</sub><sub>58</sub>) in major Ni-doped mantle minerals, including olivine, orthopyroxene, clinopyroxene, pyrope and spinel. Our calculations reveal that the 10<sup>3</sup>lnβ<sub>60</sub><sub>–</sub><sub>58</sub> is insensitive to the Ni concentration within the mineral Ni concentration ranges investigated here, and the 10<sup>3</sup>lnβ<sub>60</sub><sub>–</sub><sub>58</sub> increases in the order of pyrope &lt; clinopyroxene &lt; orthopyroxene &lt; olivine &lt; spinel. Moreover, the 10<sup>3</sup>lnβ<sub>60</sub><sub>–</sub><sub>58</sub> demonstrates a predominantly linear relationship with the average force constant (&lt; F &gt;) of Ni that is mainly influenced by the average Ni<img>O bond length. By comparing the measured inter-mineral Ni isotopic differences in mantle rocks with our predicted results, we find that olivine, spinel and orthopyroxene in most peridotitic samples have attained Ni isotopic equilibrium. Conversely, clinopyroxene appears to fall out of equilibrium with other mineral phases, likely attributed to its metasomatic origin. Furthermore, in conjunction with the melt-olivine Ni isotope fractionation factor obtained from theoretical calculation and laboratory experiment, we demonstrate that mantle silicate melting produces melts with a heavier Ni isotopic signature compared to the source. Consequently, the systematically lighter Ni isotopic compositions observed in global basalts cannot be purely attributed to silicate melting-induced Ni isotope fractionation. An additional process, perhaps sulfide dissolution, must be invoked.</div></div>","PeriodicalId":18070,"journal":{"name":"Lithos","volume":"490 ","pages":"Article 107848"},"PeriodicalIF":2.9,"publicationDate":"2024-11-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142586047","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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