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Very high-T hydration in the lower gabbro section of Semail ophiolite, Hydrous components of the lower crust at fast-spreading ridge 塞迈尔蛇绿岩下部辉长岩段的超高沸点水合作用、快速扩张海脊的下地壳水合成分
IF 2.9 2区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-09-13 DOI: 10.1016/j.lithos.2024.107800
Françoise Boudier, David Mainprice, Adolphe Nicolas

Totally fresh black gabbros are observed locally at the very base of the gabbro section in southern Semail ophiolite. Devoid of medium to low-temperature diffuse alteration, the black gabbros are characterized by cloudy plagioclase marked by a high density of hydrothermal inclusions below the optical microscope resolution, evolving into diopside and pargasite crystals ∼10 μm sized. They record hydration at temperature over 900 °C as shown by their major elements composition. Focused Electron Backscattered Electron Diffraction (EBSD) study of the crystalline inclusions, suggests a phase transition from diopside to amphibole, and traces consistent crystallographic relationships of diopside inclusions with their host plagioclase. The detailed geometry of the microcrack system traces a complete fluid path from inter-grain cracking, to plagioclase intra-grain network, possibly thermally-induced. The evidence of solid-state deformation overprinting the magmatic textures suggests that twinning mechanism in plagioclase controls the intra-grain diffusion of hydrous fluids. Located at the interface of the Moho Transition Zone (MTZ) and semi-brittle lithosphere, the ‘black gabbros’ record a narrow domain where focused fluid flow induces rapid cooling below the gabbro solidus at the lowest limit of the magma chamber.

在塞迈尔蛇绿岩南部辉长岩剖面的底部,局部观察到完全新鲜的黑色辉长岩。这些黑色辉长岩没有中低温弥漫蚀变,其特征是混浊的斜长石,在光学显微镜分辨率以下有高密度的热液包裹体,并演化成大小为 10 μm 的透辉石和钠长石晶体。从其主要元素组成可以看出,它们在超过 900 °C 的温度下发生了水化反应。对晶体包裹体的聚焦电子反向散射电子衍射(EBSD)研究表明,透辉石向闪石发生了相变,并追踪到透辉石包裹体与其主斜长石之间一致的晶体学关系。微裂纹系统的详细几何形状描绘了从晶粒间裂纹到斜长石晶粒内网络的完整流体路径,可能是热引起的。在岩浆纹理上叠加的固态变形证据表明,斜长石中的孪晶机制控制着含水流体在晶粒内部的扩散。黑辉长岩 "位于莫霍过渡带(MTZ)和半脆性岩石圈的交界处,记录了一个狭窄的区域,在这个区域内,集中的流体流在岩浆室最低极限的辉长岩固结体下方引起了快速冷却。
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引用次数: 0
Dating syn-orogenic exhumation of subducted continental crust: The case of the Northern Apennines 俯冲大陆地壳同步成因掘起的年代测定:北亚平宁山脉案例
IF 2.9 2区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-09-11 DOI: 10.1016/j.lithos.2024.107801
Francesco Giuntoli , Giulio Viola , Igor M. Villa

Dating deformation is key to unravel the evolution of orogens. Unfortunately, this is commonly challenged by the occurrence in the rock record of multiple overprinting deformation stages that lead to repeated blastesis and form multiple fabrics during both prograde and retrograde evolutions. Additionally, recrystallization is not always complete, which causes a mixture of inherited and neoblastic mineral phases. Therefore, an approach integrating age dating with microstructural and petrographic analyses is necessary to extract structurally constrained ages from the rock record. We used this approach to contribute to the long-lasting debate about exhumation of continental metamorphic units subducted to high-pressure conditions. We studied continental metasedimentary sequences of the Tuscan Metamorphic Units of the Northern Apennines (Italy) from two localities: the Island of Giglio to the west and the Monticiano-Roccastrada Unit to the east. We obtained two analytically distinct 40Ar/39Ar age ranges: an older 21–16 Ma age cluster is related to syn-orogenic top-to-the E contractional deformation occurring at ca. 1 GPa and 350 °C. A younger 15–11 Ma age group is related, instead, to exhumation to shallower structural levels and retrogression of these units to greenschist facies conditions. The interpretation of the results is based on white mica chemical compositions and rock fabrics. By integrating our results with published literature, we conclude that the investigated high-pressure continental metasedimentary sequences experienced early syn-orogenic exhumation from blueschist to greenschist facies conditions predominantly by a combination of extrusion and out- and in-sequence thrusting, with only minor contributions by extensional shearing during regional crustal thinning. Therefore, this study highlights the role of contractional fabrics in accommodating significant exhumation amounts of deeply subducted continental rocks.

对变形进行定年是揭示造山运动演化过程的关键。遗憾的是,岩石记录中通常会出现多个叠压变形阶段,导致反复爆破,并在顺行和逆行演化过程中形成多种构造,这就给我们提出了挑战。此外,再结晶并不总是完全的,这就造成了继承矿物相和新生矿物相的混合。因此,有必要将年代测定与微结构和岩石学分析结合起来,以便从岩石记录中提取有结构约束的年代。我们利用这种方法,为有关大陆变质岩单元俯冲到高压条件下的掘起这一长期争论做出了贡献。我们研究了北亚平宁山脉托斯卡纳变质岩单元(意大利)的大陆变质岩序列,这些变质岩单元来自两个地方:西部的吉利奥岛和东部的蒙蒂西亚-罗卡斯特拉达单元。我们获得了两个在分析上截然不同的 40Ar/39Ar 年龄范围:较早的 21-16 Ma 年龄群与发生在约 1 GPa 和 350 °C的同步成因顶向东收缩变形有关。1 GPa 和 350 °C。而较年轻的 15-11 Ma 年龄组则与这些单元向较浅构造层位的掘起以及向绿岩面条件的逆退有关。对结果的解释基于白云母化学成分和岩石结构。通过将我们的研究结果与已发表的文献进行整合,我们得出结论:所调查的高压大陆变质岩序列经历了从蓝岩到绿岩面条件的早期同步成因蜕变,主要是通过挤压、向外和向内推力的组合作用,只有在区域地壳减薄过程中的延伸剪切作用起到了微小的作用。因此,这项研究强调了收缩构造在容纳深俯冲大陆岩石大量掘出方面的作用。
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引用次数: 0
Compositional diversity of late Mesozoic granites rooting from the subducted crust in the Qinling–Dabie orogenic belt 扎根于秦岭-大别造山带俯冲地壳的中生代晚期花岗岩的成分多样性
IF 2.9 2区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-09-11 DOI: 10.1016/j.lithos.2024.107785
Jun He , Zeqiu Qi , Aimin Hu , Zhiyi Wang , Jiansen Li , Fukun Chen

Continental subduction has been identified in many orogens, such as the Alps, the Himalayas, and the Dabie; however, better understanding of the mechanism and outcome of different subduction processes remains desirable. The Qinling–Dabie orogen in Central China shows an asymmetric distribution of Triassic ultrahigh-pressure metamorphic rocks and syn- and post-tectonic granitoid plutons, thereby providing an excellent means by which to probe the diverse processes of continental subduction. Many late Mesozoic granitoid plutons that formed in post-orogenic or even anorogenic settings are widely distributed in both the Qinling and Dabie tectonic units and can be useful for studying the composition of materials beneath the crust because of their conspicuous compositional diversity. In the present study, we report zircon ages and NdHf isotopic compositions for the Shangcheng and Heyu granite plutons, which represent late Mesozoic plutons in Dabie and Qinling. When compared with those of the Shangcheng pluton, the wide range of Nd isotopic values and the slightly depleted Hf isotopic compositions of the Heyu pluton indicate that there may be juvenile crust beneath the Qinling tectonic unit that is not present beneath the southern margin of North China. The currently undetectable juvenile material in this region may be an important candidate source of the late Mesozoic magmatism and metal mineralization in the southern margin of North China. The compositional diversity of these granites, as indicated by the NdHf isotopic compositions, is attributed to the nature of the deep crust within the orogenic belt, and the magmatic origins of this region are discussed in the present study.

在阿尔卑斯山、喜马拉雅山和大别山等许多造山带都发现了大陆俯冲现象,然而,人们仍然需要更好地了解不同俯冲过程的机制和结果。中国中部的秦岭-大别造山带显示出三叠纪超高压变质岩以及同步构造和后构造花岗岩柱的不对称分布,从而为探究大陆俯冲的各种过程提供了极好的手段。在秦岭构造单元和大别构造单元中,广泛分布着许多在后成因甚至无成因背景下形成的中生代晚期花岗岩质体,由于其明显的成分多样性,有助于研究地壳下的物质组成。本研究报告了代表大别和秦岭中生代晚期的商城花岗岩和河峪花岗岩的锆石年龄和钕铁硼同位素组成。与商城岩浆岩的同位素组成相比,河峪岩浆岩的钕同位素值范围较大,氦同位素组成略显贫化,这表明秦岭构造单元下可能存在华北南缘所没有的幼生地壳。该地区目前无法探测到的幼生物质可能是华北南缘中生代晚期岩浆活动和金属矿化的重要候选来源。从钕铁硼同位素组成来看,这些花岗岩的成分多样性与造山带深部地壳的性质有关,本研究对这一地区的岩浆起源进行了讨论。
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引用次数: 0
Corrigendum to “Magnetization related to late-Variscan extensional collapse in the Lugo Dome (NW Iberian Massiff): A metamorphic petrology approach” [Lithos Volumes 484–485 (2024) 107745] Corrigendum to "Magnetization related to late-Variscan extension collapse in the Lugo Dome (NW Iberian Massiff):变质岩石学方法" [Lithos Volumes 484-485 (2024) 107745] 更正
IF 2.9 2区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-09-10 DOI: 10.1016/j.lithos.2024.107781
Manuela Durán Oreja , Pavel Pitra , Alicia López-Carmona , José R. Martínez Catalán , Puy Ayarza
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引用次数: 0
Generation of isotopically enriched giant Lincang Batholith by disequilibrium melting of the heterogeneous lower crust 异质下地壳的非平衡熔融生成同位素富集的巨型临沧岩床
IF 2.9 2区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-09-10 DOI: 10.1016/j.lithos.2024.107803
Jin-Cheng Xie , Di-Cheng Zhu , Qing Wang , Peter A. Cawood , Zhi-Dan Zhao , Qiong-Yao Zhan , Jia-Hao Fan , Yao Wang

Deciphering the origin of granitoids with enriched isotopic compositions is essential to understanding the mechanism of continental growth and reworking. Establishing their origin is also an effective solution to the decoupled interpretations between geochemical and isotopic observations in competing petrogenetic models. This paper reports on the whole-rock major and trace elements, Sr-Nd-Pb-Hf isotopes, and zircon UPb age and Hf isotope data of samples from the Late Triassic Lincang Batholith in SW China. The hornblende-bearing granodiorites are weakly peraluminous, whereas the coeval biotite monzogranites are generally strongly peraluminous. These two types of granitoids show identical and extremely enriched isotopic compositions with (87Sr/86Sr)i ratios of 0.71991 to 0.74302, whole-rock εNd(t) values of −13.5 to −10.1, and εHf(t) values of −13.4 to −10.3, as well as a large variation of zircon εHf(t) values of −17.6 to +0.6. The inherited zircons from both suites of samples show similar age peaks (ca. 950 Ma and ca. 1150 Ma), trace element concentrations, and εHf(t) variations to those of the detrital zircons from the Lancang Group. These similarities indicate that these rocks are most likely derived from the anatexis of the Lancang Group that is mainly composed of quartz schist, sericite schist, greenschist, chlorite albite schist, and minor eclogite. On the other hand, the Lancang Group is characterized by more enriched isotopic compositions than the granitic batholith with whole-rock εNd(225 Ma) value of −13.3 and εHf(225 Ma) value of −19.1, but identical to those of the average εHf(225 Ma) values of inherited and detrital zircons (−18.1 and − 16.3). This isotopic fractionation between the granitoids and the Lancang Group may result from disequilibrium melting of the Lancang Group with different dissolution behavior of accessory minerals (i.e., zircon, monazite, apatite, titanite, etc.). The Lincang Batholith is on average more silicic and richer in incompatible elements than the upper continental crust, suggesting that the isotopically enriched giant granitic batholith is a mature magmatic response to continental reactivation and reworking.

破译富同位素组成的花岗岩的起源对于了解大陆生长和再加工机制至关重要。确定它们的起源也是解决在相互竞争的岩石成因模型中地球化学和同位素观测之间解释脱节问题的有效方法。本文报告了中国西南部晚三叠世临沧岩床样品的全岩主要元素和痕量元素、Sr-Nd-Pb-Hf同位素以及锆石UPb年龄和Hf同位素数据。含角闪石的花岗闪长岩为弱高铝质,而共生的生物橄榄石单斜花岗岩一般为强高铝质。这两类花岗岩的同位素组成完全相同且极为富集,(87Sr/86Sr)i比值为0.71991至0.74302,全岩εNd(t)值为-13.5至-10.1,εHf(t)值为-13.4至-10.3,锆石εHf(t)值变化较大,为-17.6至+0.6。两套样品中的继承锆石在年龄峰值(约950Ma和约1150Ma)、微量元素浓度和εHf(t)变化上与澜沧群的碎屑锆石相似。这些相似之处表明,这些岩石很可能来自澜沧群的安山岩,主要由石英片岩、绢云母片岩、绿泥石片岩、绿泥石白云母片岩和少量辉绿岩组成。另一方面,澜沧群的同位素组成比花岗岩浴成岩更为富集,全岩εNd(225 Ma)值为-13.3,εHf(225 Ma)值为-19.1,但与继承锆石和碎屑锆石的平均εHf(225 Ma)值(-18.1和-16.3)相同。花岗岩与澜沧群之间的这种同位素分馏可能是由于澜沧群的不平衡熔融与附属矿物(即锆石、独居石、磷灰石、榍石等)的不同溶解行为造成的。与上部大陆地壳相比,临沧浴成岩平均含硅量更高,不相容元素更丰富,这表明同位素丰富的巨型花岗岩浴成岩是对大陆再活化和再加工的成熟岩浆反应。
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引用次数: 0
Petrogenesis of magmatic charnockite-biotite granite suite from parts of the Chotanagpur Granite Gneissic Complex (CGGC), eastern Indian shield: Implication for the break down of the Columbia Supercontinent 印度东部盾构地区乔塔那格普尔花岗片麻岩群(CGGC)部分岩浆赤铁矿-黑云母花岗岩套件的岩石成因:对哥伦比亚超大陆解体的影响
IF 2.9 2区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-09-10 DOI: 10.1016/j.lithos.2024.107802
Somdipta Chatterjee , Subham Mukherjee , Sanjoy Sanyal , Pulak Sengupta

A rare porphyritic charnockite that is girdled by and mineralogically grades to biotite granite occurs as a part of the Chotanagpur Granite Gneissic Complex (CGGC) in and around Massanjore, Jharkhand, India. Preservation of certain textural features, including (a) euhedral to subhedral grains of orthopyroxene, (b) low dihedral angle subtended by orthopyroxene and plagioclase grains, and (c) relict intergranular and porphyritic textures, are consistent with the view that orthopyroxene in the studied rocks has a magmatic origin. Preserved magmatic features and other petrological attributes of these rocks do not support any significant mass change beyond a few tens of microns during the overprinting high-grade metamorphism. The geochemical variation of the felsic rock suite (porphyritic charnockite and biotite granite) indicates that they are cogenetic and are derived from a ferroan A-type granitoid magma by crystal fractionation. The observed geochemical trend of the studied felsic rock suites has been simulated by phase equilibria modelling in the open system using the system components Na2O-CaO-K2O-FeO-MgO-Al2O3-SiO2-H2O-TiO2-O2. The observed mineralogical and geochemical attributes and the results of the modelling study are consistent with a petrogenetic process in which high magma temperature (> 900 °C), low pressure, and low water activity in the parental melt favoured the separation of an orthopyroxene bearing cumulate assemblage (orthopyroxene + plagioclase + quartz + K-feldspar + ilmenite + magnetite) in the initial part of the magmatic differentiation. Removal of this anhydrous cumulitic assemblage raised the bulk H2O content in the residual melt. Orthopyroxene became unstable with respect to biotite in the evolved melt that eventually crystallised minerals that formed the biotite granite. An increase in magma fO2 also restricts the orthopyroxene stability in felsic magma. Taken together all the petrological and geochemical attributes, we demonstrate that fractionation of an orthopyroxene-bearing crystal cumulate from the melt is essential to form the charnockites, and that the biotite granite forms from the evolved melt after the fractionation. The charnockite-biotite granite association of the studied area was formed in an extensional tectonic setting, presumably during the breakdown of the Columbia Supercontinent.

在印度恰尔肯德邦马桑乔尔及其周围地区的乔塔纳布尔花岗片麻岩群(CGGC)中,有一种罕见的斑状赤铁矿,它被生物花岗岩所包围,在矿物学上属于生物花岗岩。所保留的某些纹理特征,包括(a)正辉石的优面体至亚面体晶粒,(b)正辉石和斜长石晶粒的低二面角,以及(c)残留的粒间纹理和斑状纹理,与所研究岩石中的正辉石起源于岩浆的观点一致。这些岩石所保留的岩浆特征和其他岩石学属性并不支持在叠加高品位变质过程中发生超过几十微米的重大质量变化。长英岩岩套(斑状黑云母和生物花岗岩)的地球化学变化表明,它们是同生岩,是由铁质 A 型花岗岩岩浆经晶体分馏而形成的。通过在开放系统中使用 Na2O-CaO-K2O-FeO-MgO-Al2O3-SiO2-H2O-TiO2-O2 系统成分的相平衡模型,对所研究的长英岩套件的地球化学趋势进行了模拟。观察到的矿物学和地球化学属性以及建模研究的结果都与岩石成因过程相一致,即在岩浆分异的初始阶段,母体熔体中的高岩浆温度(900 °C)、低压力和低水活性有利于分离出含正长石的累晶组合(正长石+斜长石+石英+钾长石+钛铁矿+磁铁矿)。除去这种无水的积岩集合体后,残余熔体中的大量 H2O 含量升高。在演化的熔体中,正长石相对于生物橄榄石变得不稳定,最终结晶出形成生物橄榄石花岗岩的矿物。岩浆 fO2 的增加也限制了长英质岩浆中正辉石的稳定性。综合所有岩石学和地球化学特征,我们证明从熔体中分馏出含正长石的晶体积聚物对形成霞石至关重要,而生物花岗岩则是在分馏后从演化熔体中形成的。所研究地区的黑云母-生物花岗岩组合是在延伸构造环境中形成的,可能是在哥伦比亚超大陆解体过程中形成的。
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引用次数: 0
Rheology modification in a subduction channel due to eclogite facies metasomatism (Rocky Beach Metamorphic Mélange, Port Macquarie, Australia) 斜长岩变质作用导致的俯冲通道流变学改变(澳大利亚麦夸里港岩石滩变质混合区)
IF 2.9 2区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-09-07 DOI: 10.1016/j.lithos.2024.107797
M.A. Finch , A. Olesch-Byrne , T. Chapman , M. Beilharz , A.G. Tomkins

The rheological properties of the interface between the down-going and overriding plates in subduction zones provides insight into how plate convergence is accommodated and the controls on seismic and aseismic slip. This interface is known as the subduction channel and exhumed examples provide the only direct information on deformation mechanisms and the impact of metamorphism on rheology. The Rocky Beach Metamorphic Mélange in eastern Australia is one such exhumed subduction channel, composed of eclogite, blueschist and greenschist facies blocks within a mélange matrix. Previous phase equilibria modelling indicates that high pressure blocks were subducted to ca. 100 km depth and then retrogressed during return flow and exhumation. We found that the rheology of blocks is modified by metasomatism, consistent with studies on other subduction channels. However, through comparison of blocks from different metamorphic grades we found that the effect of metasomatism on rheology varied depending on the pressure and temperature conditions of metasomatism. While unmetasomatised eclogites behaved as rigid objects in the mélange matrix, rocks with mineral assemblages that equilibrated during eclogite facies metasomatism accumulated significant strain, forming isoclinal folds and refolded folds. Deformation of these blocks began at eclogite facies and continued during return flow and retrogression to blueschist facies. At blueschist facies, metasomatised blocks developed mm-scale isoclinal folds with shearing parallel to fold limbs forming rootless isoclinal folds. At the transition between blueschist and greenschist facies, pressure solution became important, preferentially focusing along layers of lawsonite, dissolving it from the rock. At greenschist facies, dissolution-precipitation processes caused significant mass loss, producing mm-spacing between pressure solution seams and cuspate folds, analogous to dewatering structures in sediments. In the Rocky Beach Metamorphic Mélange eclogite facies metasomatism reduces the competence of rigid blocks, reducing overall subduction channel heterogeneity during return flow. We suggest that subduction channels that experience widespread eclogite facies metasomatism may be less likely to generate seismic slip during return flow, since the proportion of rigid blocks and block strength are both reduced.

俯冲带中下行板块和上行板块之间界面的流变特性,使人们能够深入了解板块聚合是如何进行的,以及对地震和非地震滑动的控制。这一界面被称为俯冲通道,挖掘出的实例提供了有关变形机制和变质作用对流变学影响的唯一直接信息。澳大利亚东部的岩石滩变质混合岩就是这样一个出露的俯冲通道,由混合岩基质中的埃克洛辉石、蓝辉石和绿辉石面块组成。之前的相平衡建模表明,高压块体被俯冲到约 100 千米的深度,然后在回流和吐出过程中发生逆冲。我们发现,块体的流变性受到变质作用的影响,这与对其他俯冲通道的研究结果一致。然而,通过比较不同变质等级的岩块,我们发现变质作用对流变学的影响因变质作用的压力和温度条件而异。在混杂基质中,未发生变质作用的斜长岩表现为刚性物体,而在斜长岩面变质作用期间,矿物组合平衡的岩石则积累了大量应变,形成了等轴褶皱和重褶褶皱。这些岩块的变形始于斜长岩面,并在回流和倒退至蓝斜岩面的过程中持续进行。在蓝斜岩面,变质块体形成了毫米级的等轴褶皱,与褶皱边缘平行的剪切力形成了无根等轴褶皱。在蓝斜岩面与绿斜岩面之间的过渡地带,压力溶蚀变得非常重要,主要集中在岩层沿线,将其从岩石中溶解出来。在绿岩层,溶解-沉淀过程造成了大量的质量损失,在压力溶解缝和尖状褶皱之间产生了毫米间距,类似于沉积物中的脱水结构。在岩石滩变质蜕变层蜕变岩面,变质作用降低了刚性块体的能力,从而减少了回流过程中俯冲通道的整体异质性。我们认为,由于刚性块体的比例和块体强度都会降低,因此经历过广泛的夕闪岩变质作用的俯冲通道在回流过程中产生地震滑移的可能性较小。
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引用次数: 0
Tectonic and magmatic evolution of the southernmost Mariana convergent margin: Constraints from geochronology and geochemistry of the Challenger Deep sediments 马里亚纳汇聚边最南端的构造和岩浆演化:挑战者深渊沉积物的地质年代和地球化学制约因素
IF 2.9 2区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-09-07 DOI: 10.1016/j.lithos.2024.107796
Ming Yang , Tao Wu , Wen Zhang , Liyan Tian , Jianggu Lu , Taoran Song , Hengrui Zhu , Yidi Hong , Jiawang Chen

The southernmost Mariana convergent margin (SMCM) is a distinct segment of the Izu-Bonin-Mariana (IBM) subduction system with unique east-west orientation, however, its nature and tectonic history remains enigmatic. Here, for the first time, we present the detailed geochemical data of detrital minerals and UPb ages of accessory minerals from two sediment samples recovered at the deepest part of Southern Marianna Trench including the Challenger Deep. Detrital magmatic zircon UPb ages can be divided into three groups. Group 1 zircons show a weighted mean age of 50.3 ± 1.2 Ma, contemporary to the published boninites from northern IBM. The εHf(t) of these zircons (11.1–16.4) are also similar to the boninites (12.6–16.8) and volcanic arc rocks (4.2–14.2), but lower than forearc basalts (17.8–22.1), suggesting that these zircons are from boninitic or arc magmatism. The apatite UPb dating obtained a similar age of 55.0 ± 5.5 Ma. Therefore, if they are all from boninites, then subduction initiation magmatism ended at SMCM was likely coeval with northern IBM. Group 2 and Group 3 zircons have εHf(t) values similar to Group 1 zircons, but recorded younger 206Pb/238U ages of 16.8 ± 1.8 Ma and 11.0 ± 0.2 Ma, respectively, which are most likely related to the arc volcanism at West Mariana Ridge (WMR). Additionally, a rutile age of 19.0 ± 0.6 Ma is identified, which is also likely related to WMR. The chemical composition and calculated P-T conditions of clinopyroxenes indicate that they are mainly from the Mariana forearc basalts and arc volcanic rocks. In situ Sr isotopic compositions of plagioclases also show strong affinity to the Mariana forearc basalts and arc volcanic rocks. Therefore, our study indicates that sediments at the deep trench can record the long-term tectonic and magmatic evolution of the convergent margin.

最南端的马里亚纳汇聚边(SMCM)是伊豆-波宁-马里亚纳(IBM)俯冲系统的一个独特区段,具有独特的东西走向,但其性质和构造历史仍是一个谜。在此,我们首次展示了在南马里安纳海沟(包括挑战者深渊)最深处采集的两个沉积物样本中分离矿物的详细地球化学数据和附属矿物的 UPb 年龄。岩屑锆石的 UPb 年龄可分为三组。第 1 组锆石的加权平均年龄为 50.3 ± 1.2 Ma,与已发表的 IBM 北部倭黑岩的年龄相当。这些锆石的εHf(t)(11.1-16.4)也与倭黑岩(12.6-16.8)和火山弧岩(4.2-14.2)相似,但低于前弧玄武岩(17.8-22.1),表明这些锆石来自倭黑岩或火山弧岩浆活动。磷灰石 UPb 测定得到了类似的 55.0 ± 5.5 Ma 的年龄。因此,如果这些锆石都来自倭黑岩,那么在SMCM结束的俯冲起始岩浆活动很可能与北部IBM同时发生。第2组和第3组锆石的εHf(t)值与第1组锆石相似,但记录到的206Pb/238U年龄分别为16.8 ± 1.8 Ma和11.0 ± 0.2 Ma,这很可能与西马里亚纳海脊(WMR)的弧形火山活动有关。此外,金红石的年代为 19.0 ± 0.6 Ma,也很可能与西马里亚纳海脊有关。霞石的化学成分和计算的 P-T 条件表明,它们主要来自马里亚纳前弧玄武岩和弧形火山岩。斜长石的原位锶同位素组成也表明它们与马里亚纳前弧玄武岩和弧火山岩有很强的亲缘关系。因此,我们的研究表明,深海沟的沉积物可以记录汇聚边缘的长期构造和岩浆演化。
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引用次数: 0
New insights from plumbing system below composite mafic volcanoes: Post-glacial volatile contents and magmatic fluids from Villarrica magmas 从复合岩浆火山下方的管道系统中获得新启示:来自比利亚里卡岩浆的冰川期后挥发性成分和岩浆流体
IF 2.9 2区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-09-04 DOI: 10.1016/j.lithos.2024.107786
Philippe Robidoux , Yves Moussallam , Estelle F. Rose-Koga , Andrea Luca Rizzo , Guillaume Georgeais , Joao Lages , Gilles Lévresse , Simona Ferrando , Alessandro Aiuppa
Villarrica volcano, in the southern Andes, is a composite mafic volcano whose persistent open-vent activity is punctuated by frequent Strombolian/Hawaiian eruptions and, more rarely, by more energetic (sub-Plinian) events. Here, we investigate the volatile composition of the parental melts that sustain this activity, and the conditions of pre-eruptive magma storage, by characterizing the composition of olivine-hosted melt and fluid inclusions. We concentrate on inclusions entrapped in minerals from pyroclastic materials erupted from both Villarrica summit and from its flank Minor Eruptive Centers (MECs) post the 14.5–13.5 kyr caldera collapse event that formed the Licán ignimbrite. Our micro-FTIR and SIMS measurements indicate that the Pucón eruption records the highest volatile contents, with 6.0 wt% H2O, >1500 ppm CO2, 1330 ppm S, 1556 ppm Cl, and 2055 ppm F. These volatile contents imply a volatile-saturated magma originating from a depth of 14.4 to 17 km below Villarrica. Results for other flank eruptions highlight a similarly deep (17–21 km depth) source for basaltic CO2-rich mafic magmas erupted at regional MECs (Los Nevados, Caburgua). Melt inclusion results also reveal that deep rising mafic magma batches, when temporarily stored at 1–5 km depth, produce the more differentiated and degassed magma batches that sustain the decadal-old persistent effusive-explosive eruptive activity at Villarrica. Helium isotope ratios (3He/4He; Rc/Ra when corrected for atmosphere) measured in bulk noble gases from olivines (Fo7588) indicate that the parental magmatic fluid signature (Rc/Ra = 6.7–7.6; CO2/3He = 4.7–7.5E+08) is only recorded during central paroxysmal sub-Plinian eruption, and that this primitive gas signal is diluted in lateral MECs (Rc/Ra < 6.5; CO2/3He = 1.4 × 10+9–3.1E+10).
比利亚里卡火山位于安第斯山脉南部,是一座复合岩浆火山,其持续的开放式喷口活动被频繁的斯特劳博勒式/夏威夷式喷发和更罕见的高能(亚普林式)喷发所打断。在这里,我们通过分析橄榄石托管熔体和流体包裹体的成分,研究了维持这种活动的母体熔体的挥发性成分,以及爆发前岩浆的储存条件。我们主要研究了在 14.5-13.5 千年火山口坍塌事件后,从比利亚里卡山顶及其侧翼小爆发中心(MECs)喷发出的火成碎屑物质中夹杂的矿物质,这些矿物质形成了利坎燃烧斑岩。我们的微傅立叶变换红外光谱(Micro-FTIR)和SIMS测量结果表明,Pucón喷发记录的挥发物含量最高,为6.0 wt% H2O、1500 ppm CO2、1330 ppm S、1556 ppm Cl和2055 ppm F。其他侧翼喷发的结果表明,在区域火山活动中心(Los Nevados、Caburgua)喷发的富含二氧化碳的玄武质岩浆也有类似的深度(17-21 千米)来源。熔融包裹体结果还显示,深层上升的岩浆群在 1-5 千米深处暂时储存时,产生了分化和脱气程度更高的岩浆群,这些岩浆群维持了比利亚里卡十年之久的持续喷发-爆炸性喷发活动。在橄榄石(Fo75-88)的大量惰性气体中测量到的氦同位素比率(3He/4He;按大气校正后的 Rc/Ra)表明,母岩浆流体特征(Rc/Ra = 6.7-7.6;CO2/3He = 4.7-7.5E+08),而且这种原始气体信号在横向岩浆流体中被稀释(Rc/Ra < 6.5;CO2/3He = 1.4 × 10+9-3.1E+10)。
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引用次数: 0
Geographic bias effects on interpretations of secular trends of Hf isotope times series in zircons 地理偏差对锆石中 Hf 同位素时间序列世俗趋势解释的影响
IF 2.9 2区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-09-04 DOI: 10.1016/j.lithos.2024.107787
Kent C. Condie , Stephen J. Puetz , Kurt E. Sundell , Sergei A. Pisarevsky , Christopher J. Spencer , Nick M.W. Roberts

The analysis of εHf(t) time series data from zircon reveals notable discrepancies based on sample type (igneous versus detrital), statistical weighting methodology, and geographic sampling bias. These differences warrant caution when interpreting data in the context of tectonic settings and the history of supercontinents. In terms of tectonic setting, accretionary orogens dominate in both sedimentary basins that host detrital zircons and in igneous zircon sources. Because of differences between the various time series, emphasis in this study is on peaks, valleys and secular trends and not on absolute εHf(t) values. Specifically, the igneous time series for εHf(t) in zircons shows more peaks and valleys than corresponding detrital time series for both weighted and unweighted data (weighting corrects for disproportionate geographic sampling). Also, sample-based (each sample considered separately) and site-based (samples grouped by geographic location and age) results align closely to the igneous time series, whereas the site-based detrital series displays more negative εHf(t) values. Regardless of the type of time series, the failure to compensate for disproportionate geographic sampling increases the prospects of producing an unrepresentative time-series. Nine zircon age peaks (both detrital and igneous) have corresponding εHf(t) peaks (3200, 2700, 2500, 2150, 1500, 1100, 750 Ma) and two have corresponding age valleys (1800–2000, 550 Ma). With exception of a geographically widespread 1500 Ma peak, most of the εHf(t) peaks and valleys are controlled by specific geographic regions and are likely not be global in extent.

Two distinct periods (200–0 and 1800–1600 Ma) display εHf(t) signatures that rise steadily for 100–200 Myr, coinciding with the final stages of supercontinent assembly and the transition to the retreat of exterior orogens. An εHf(t) peak at 750 Ma and a high at 1400–1100 Ma partly overlap with supercontinent breakup and valleys at 550 Ma and 900 Ma with supercontinent assembly. A large εHf(t) valley at 2000–1800 Ma corresponds with the onset of craton collisions that led to the final assembly of Columbia at 1800–1600 Ma. The steep rise in εHf(t) in the last 200 Myr in both igneous and detrital zircons is controlled by sites in Circum-Pacific orogens in North and South America and Southwest Asia, and it parallels the breakup of Pangea. The general increase in zircon εHf(t) in the last 500 Myr in both detrital and igneous data reflects an increase in the proportion of isotopically juvenile components in accretionary orogens.

对锆石εHf(t)时间序列数据的分析表明,基于样品类型(火成岩与碎屑岩)、统计加权方法和地理取样偏差的数据存在明显差异。在根据构造环境和超大陆历史解释数据时,这些差异值得警惕。就构造环境而言,沉积盆地和火成岩锆石源中的吸积造山运动都占主导地位。由于各种时间序列之间的差异,本研究的重点是峰值、谷值和世俗趋势,而不是εHf(t)的绝对值。具体来说,锆石中εHf(t)的火成岩时间序列在加权和非加权数据(加权可纠正不成比例的地理取样)上都比相应的碎屑岩时间序列显示出更多的峰值和谷值。此外,基于样本(每个样本单独考虑)和基于矿点(按地理位置和年龄分组的样本)的结果与火成岩时间序列非常接近,而基于矿点的碎屑岩序列则显示出更多的εHf(t)负值。无论是哪种类型的时间序列,如果不对不成比例的地理取样进行补偿,就会增加产生不具代表性的时间序列的可能性。九个锆石年龄峰(包括碎屑岩和火成岩)都有相应的εHf(t)峰(3200, 2700, 2500, 2150, 1500, 1100, 750 Ma),两个有相应的年龄谷(1800-2000, 550 Ma)。两个不同时期(200-0 Ma和1800-1600 Ma)的εHf(t)特征在100-200 Myr内持续上升,与超大陆组装的最后阶段和外部原点退缩的过渡阶段相吻合。εHf(t)在750Ma达到峰值,在1400-1100Ma达到高点,这与超大陆的解体部分重合,而在550Ma和900Ma的低谷则与超大陆的组装重合。2000-1800Ma处的εHf(t)大谷与1800-1600Ma处导致哥伦比亚最终组装的陨石撞击的开始相吻合。火成岩和碎屑锆石中的εHf(t)在过去 200 Myr 的急剧上升是由北美、南美和西南亚环太平洋造山带中的地点控制的,它与 Pangea 的解体相平行。锆石εHf(t)在过去500 Myr的碎屑岩和火成岩数据中的普遍上升反映了增生造山运动中同位素幼年成分比例的增加。
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