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Research news 研究新闻
IF 3.1 Q3 CRYSTALLOGRAPHY Pub Date : 2020-01-02 DOI: 10.1080/1358314X.2020.1771847
A. Draude
Active matter, in which local energy is converted into directed motion, is an area of strong interest in current soft matter research for potential applications in soft robotics. Living nematics are a category of active matter where nematic phases have active particles dispersed in them. In this paper, Turiv et al. study high and low concentrations of swimming bacteria in the nematic phase of the lyotropic chromonic liquid crystal DSCG via microscopy. Photo-alignment is used to create patterned director fields. Patterns including splay and bend are used to focus the trajectory of the bacteria and rectilinear jets undulate at high concentrations of bacteria. These jets are shown to be stabilised by the background director field and the experimental results are supported by simulations. In flows of either concentration of bacteria micro-spheres are shown to be transported along the pre-patterned flows.
活性物质,其中局部能量被转换为定向运动,是当前软物质研究中一个非常感兴趣的领域,在软机器人中有潜在的应用。活性向列相是一类活性物质,其中向列相中分散有活性颗粒。在本文中,Turiv等人通过显微镜研究了溶致变色液晶DSCG向列相中高浓度和低浓度的游动细菌。照片对齐用于创建图案化的指向矢场。包括张开和弯曲在内的模式用于聚焦细菌的轨迹,直线射流在高浓度细菌下波动。这些射流被证明是由背景指向矢场稳定的,实验结果得到了模拟的支持。在任一浓度的细菌流中,微球被显示为沿着预先图案化的流传输。
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引用次数: 0
The twist-bend phases: structure–property relationships, chirality and hydrogen-bonding 扭弯相:结构-性质关系、手性和氢键
IF 3.1 Q3 CRYSTALLOGRAPHY Pub Date : 2020-01-02 DOI: 10.1080/1358314X.2020.1771841
R. Walker
ABSTRACT This article will review some of our recent work concerning the relationships between molecular structure and the observation of the fascinating twist-bend nematic, NTB, phase. From a chemist’s perspective, understanding the molecular features influencing the formation and stabilisation of the NTB phase is of paramount importance, and allows for the design of new materials that have targeted properties. As such, recent work in Aberdeen has had the primary aim of enhancing our current understanding of these relationships in dimeric liquid crystals, through the synthesis and characterisation of a diverse range of materials, including a selection of supramolecular liquid crystals. A second aim has been to explore the intriguing question as to how the NTB phase, having spontaneous structural chirality, would respond at a microscopic level to the presence of intrinsic molecular chirality – the inclusion of chiral fragments in the dimers – and to obtain examples of the ‘chiral’ twist-bend nematic phase (N*TB) for comparative study alongside the conventional NTB phase. We also show that bent achiral molecules form heliconical smectic phases, as predicted by Dozov in his seminal 2001 work.
本文将回顾我们最近关于分子结构与观察到迷人的扭弯向列相(NTB)之间关系的一些工作。从化学家的角度来看,了解影响NTB相形成和稳定的分子特征是至关重要的,这有助于设计具有目标性能的新材料。因此,阿伯丁最近的工作主要目的是通过合成和表征各种材料,包括选择超分子液晶,增强我们目前对二聚体液晶中这些关系的理解。第二个目标是探索具有自发结构手性的NTB相如何在微观水平上对固有分子手性(二聚体中包含手性片段)的存在作出反应的有趣问题,并获得“手性”扭弯向列相(N*TB)的例子,以便与传统的NTB相进行比较研究。我们还表明,弯曲的非手性分子形成螺旋晶相,正如Dozov在他2001年开创性的工作中所预测的那样。
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引用次数: 8
A liquid crystal model for mitotic cell division - and the enigma of centriole involvement in mitosis in animals but not plants 有丝分裂细胞分裂的液晶模型——以及中心粒参与动物而非植物有丝分裂的谜团
IF 3.1 Q3 CRYSTALLOGRAPHY Pub Date : 2019-10-02 DOI: 10.1080/1358314X.2020.1726065
J. Lydon
ABSTRACT There is a strategic difference between the process of cell division by mitosis in animal cells and that in cells of higher plants. One particularly puzzling feature is the absence of centrioles in plant cells, when they appear to be of central importance in the control of the process in animal cells. It is argued that in both cases the dividing cell uses the versatility of the liquid crystalline state of the mitotic cytoplasm created by the wide-scale assembly of microtubules prior to mitosis. It is not the centrioles per se which are vital – it is the director field of the mesophase which is crucial – and alternative procedures have been developed by plants and animals to create this. In both cases, they can be related to known spontaneous alignment states of liquid crystalline systems.
动物细胞的有丝分裂过程与高等植物细胞的有丝分裂过程在策略上存在差异。一个特别令人困惑的特征是植物细胞中没有中心粒,而它们似乎在动物细胞的过程控制中起着至关重要的作用。有人认为,在这两种情况下,分裂细胞都利用了有丝分裂前微管大规模组装所产生的有丝分裂细胞质液晶状态的多功能性。中心粒本身并不是至关重要的,重要的是中间阶段的指导区,植物和动物已经发展出了替代程序来创造中间阶段。在这两种情况下,它们都可以与已知的液晶系统的自发排列状态有关。
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引用次数: 2
Editorial 编辑
IF 3.1 Q3 CRYSTALLOGRAPHY Pub Date : 2019-10-02 DOI: 10.1080/1358314x.2020.1726040
I. Dierking
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引用次数: 0
Research news 研究新闻
IF 3.1 Q3 CRYSTALLOGRAPHY Pub Date : 2019-10-02 DOI: 10.1080/1358314X.2020.1726068
A. Draude
Nematic liquid crystals have complex rheological properties compared to isotropic liquids, and achieving precise flows can be difficult experimentally. In this paper, Čopar et al. demonstrate transitions a discontinuous transition from homeotropic to planar director orientation in a microfluidic channel with homeotropic boundaries as the flow rate is increased. Furthermore, they demonstrate the existence of a topologically protected intermediate state, which is chiral despite the chosen system (5CB) being achiral. The authors go on to show that small amounts of chiral dopant can break the symmetry of the system and only one handedness is observed in the intermediate state. Laser tweezers which give rise to localised heating are also employed to manipulate the flow states. It is proposed that such phenomena could be exploited technology in optical shutters, in which the state is carefully tuned by the flow rate and/or laser heating.
与各向同性液体相比,向列型液晶具有复杂的流变特性,并且在实验上很难实现精确的流动。在本文中,Čopar等人展示了在具有同向同性边界的微流控通道中,随着流速的增加,从同向同性向平面定向的不连续转变。此外,他们还证明了拓扑保护中间态的存在,尽管所选择的体系(5CB)是非手性的,但该中间态是手性的。作者继续表明,少量的手性掺杂剂可以破坏系统的对称性,在中间状态下只观察到单手性。引起局部加热的激光镊子也被用来操纵流动状态。提出这种现象可以利用光学百叶窗的技术,其中的状态是精心调整流速和/或激光加热。
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引用次数: 0
Fluids, colloids and soft materials 流体、胶体和软质材料
IF 3.1 Q3 CRYSTALLOGRAPHY Pub Date : 2019-10-02 DOI: 10.1080/1358314X.2020.1726063
I. Dierking
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引用次数: 1
The topology of knots and links in nematics 向列矩阵中结点和链路的拓扑结构
IF 3.1 Q3 CRYSTALLOGRAPHY Pub Date : 2019-07-03 DOI: 10.1080/1358314X.2019.1681113
Thomas Machon
ABSTRACT We review some our results concerning the topology of knotted and linked defects in nematic liquid crystals. We discuss the global topological classification of nematic textures with defects, showing how knotted and linked defect lines have a finite number of ‘internal states’, counted by the Alexander polynomial of the knot or link. We then give interpretations of these states in terms of umbilic lines, which we also introduce, as well as planar textures. We show how Milnor polynomials can be used to give explicit constructions of these textures. Finally, we discuss some open problems raised by this work.
摘要:我们回顾了一些关于向列液晶中结状和连接缺陷拓扑结构的研究结果。我们讨论了具有缺陷的向列织构的全局拓扑分类,展示了结和连接的缺陷线如何具有有限数量的“内部状态”,由结或连接的亚历山大多项式计算。然后我们用脐带线来解释这些状态,我们也引入了脐带线,以及平面纹理。我们展示了如何使用米尔诺多项式来给出这些纹理的明确结构。最后,我们讨论了本研究提出的一些开放性问题。
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引用次数: 5
Editorial 编辑
IF 3.1 Q3 CRYSTALLOGRAPHY Pub Date : 2019-07-03 DOI: 10.1080/1358314x.2019.1693102
I. Dierking
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引用次数: 0
Research news 研究新闻
IF 3.1 Q3 CRYSTALLOGRAPHY Pub Date : 2019-07-03 DOI: 10.1080/1358314X.2019.1693104
M. Nagaraj
Pattern formation in out-of-equilibrium systems is diverse. Examining the nature of hydrodynamic patterns in active nematics has been a topic of interest for the past couple of years. Sokolov et al. investigate the dynamics of circularly aligned swimming bacteria. They show that in an active matter system the interplay of activity, elasticity and geometry leads to a wellcontrolled pattern formation and finer control of dynamic structures and transport phenomena. They report the emergence of bend stripes, an activityinduced undulations of the liquid crystal director field, in areas of high local curvature. Parameters such as velocity, relaxation rate and vorticity are compared for two experimental geometries; a pendant drop attached to a glass slide and in a thin free-standing film suspended between filaments. Hydrodynamic simulations are used to explain the origin of bend stripes. The effect of adding an extensile active stress on the hydrodynamic flows and its implications on the time evolution of the director field and the local curvature are compared. The instability patterns are seen to introduce a strong anisotropy to the angular distribution of emerging topological defects.
非平衡系统的模式形成是多种多样的。在过去的几年里,研究主动向列式中流体动力模式的性质一直是人们感兴趣的一个话题。Sokolov等人研究了环状排列游动细菌的动力学。研究表明,在活性物质体系中,活动性、弹性和几何结构的相互作用导致了良好的模式形成和对动力结构和输运现象的精细控制。他们报告了弯曲条纹的出现,这是一种活动引起的液晶引导场波动,在高局部曲率区域。比较了两种实验几何形状的速度、弛豫率和涡度等参数;挂珠附在玻璃载玻片上的垂坠水滴,并悬挂在细丝之间的独立薄膜中流体力学模拟用于解释弯曲条纹的起源。比较了加张应力对流体动力流动的影响及其对导向场和局部曲率时间演化的影响。不稳定模式被视为引入了一个强的各向异性的角度分布的新出现的拓扑缺陷。
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引用次数: 0
Conference report FLC 2019: frontiers of chirality and polarity in soft matter 2019年FLC会议报告:软物质手性和极性的前沿
IF 3.1 Q3 CRYSTALLOGRAPHY Pub Date : 2019-07-03 DOI: 10.1080/1358314x.2019.1693097
A. Mertelj
Conference report FLC 2019: frontiers of chirality and polarity in soft matter The 17 International Conference on Ferroelectric Liquid Crystal, after 28 years, again took place in picturesque Boulder from August 4–7, 2019. It was held under the auspices of the Soft Materials Research Center, the NSF Materials Research Science and Engineering Center at the University of Colorado Boulder. The local organisers Noel Clark (Honorary Chair), Dave Walba (Conference Chair), Matt Glaser, Eva Korblova, Joe Maclennan, Christine Morrow, and Dakota Nanton provided a pleasant and inspiring ambient for the 83 attendees from 13 countries (Figure 1). The FLC 2019 focused on frontiers of polarity and chirality in soft matter. In six plenary lectures, 12 invited talks and 19 oral presentations, as well as 21 posters the main themes: (i) design and synthesis of novel ferroelectric/polar liquid crystal materials; (ii) the twist-bend phases; (iii) spontaneous achiral symmetry breaking (chiral self-assembly of achiral molecules); (iv) fluid ferroelectrics and ferromagnetics; (v) blue phases; (vi) liquid crystals and biology; (vii) simulation, modelling and theory; (viii) advances in resonant X-ray scattering; and (ix) industrial applications, were covered. In his plenary lecture, Corrie Imrie presented a range of new liquid crystal dimers and other types of materials which exhibit the twist-bend nematic and, the recently observed twist-bend smectic phases and discussed structure–property relationships. Oleg Lavrentovich demonstrated electrically driven three-dimensional particle-like dissipative solitons representing self-trapped waves of oscillating director, called director bullets, which propagate with a very high speed perpendicularly to the electric field. Ewa Gorecka showed that a molecular system built of achiral mesogenic dimeric molecules exhibits a complexity with four levels of structural chirality, which were studied using resonant X-ray scattering. Alenka Mertelj presented a new modulated nematic phase, called the splay nematic phase, which results from polar ordering of the molecules and consequent instability towards splay deformation. Frank Giesselmann reviewed some new aspects of chirality in lyotropics, among them chiral structures that appear due to anomalously small twist elastic constants in chromonic and standard micellar lyotropic nematics confined to, e.g. cylindrical capillaries. Carsten Tschierske discussed the development of polarity and chirality in systems made of molecules with a shape at the cross-over from linear to bent which provides a series of interesting phenomena related to layer coupling, emergent polar order and concerning chirality issues. In the concluding session, chaired by Joe Maclennan, the prizes were awarded and future prospects for ferroelectric liquid crystals and chiral/ polar soft matter were discussed. The Luckhurst-Samulski prize, which is handed out for the best paper published each year in Liquid Crystals, was awa
2019年FLC会议报告:软物质手性和极性的前沿时隔28年的第17届铁电液晶国际会议于2019年8月4日至7日在风景如画的博尔德再次举行。它是在科罗拉多大学博尔德分校的美国国家科学基金会材料研究科学与工程中心软材料研究中心的赞助下举行的。当地组织者Noel Clark(名誉主席)、Dave Walba(会议主席)、Matt Glaser、Eva Korblova、Joe Maclennan、Christine Morrow和Dakota Nanton为来自13个国家的83名与会者提供了一个愉快而鼓舞人心的环境(图1)。FLC 2019聚焦于软物质的极性和手性前沿。在6次全体讲座中,12次受邀演讲和19次口头演讲,以及21张海报,主题是:(i)新型铁电/极性液晶材料的设计和合成;(ii)扭转-弯曲阶段;(iii)自发的非手性对称性破坏(非手性分子的手性自组装);(iv)流体铁电体和铁磁性;(v) 蓝相;(vi)液晶与生物学;(vii)模拟、建模和理论;(viii)共振X射线散射的进展;以及(ix)工业应用。在他的全体演讲中,Corrie Imrie介绍了一系列新的液晶二聚体和其他类型的材料,这些材料表现出扭曲弯曲向列相和最近观察到的扭曲弯曲近晶相,并讨论了结构-性能关系。Oleg Lavrentovich展示了电驱动的三维类粒子耗散孤子,它们代表振荡指向矢的自陷波,称为指向矢子弹,以非常高的速度垂直于电场传播。Ewa Gorecka表明,由非手性介晶二聚体分子构建的分子系统表现出四个层次的结构手性的复杂性,这是使用共振X射线散射进行研究的。Alenka-Mertelj提出了一种新的调制向列相,称为“散向列相”,这是由分子的极性有序和由此产生的散向变形的不稳定性引起的。Frank Giesselmann综述了溶致性手性的一些新方面,其中手性结构是由于限制在例如圆柱形毛细管内的发色和标准胶束溶致性向列相中异常小的扭曲弹性常数而出现的。Carsten Tschierske讨论了由具有从线性到弯曲的交叉形状的分子组成的系统中极性和手性的发展,这提供了一系列有趣的现象,这些现象与层耦合、出射极性秩序和手性问题有关。在由Joe Maclennan主持的闭幕式上,颁奖并讨论了铁电液晶和手性/极性软物质的未来前景。Luckhurst-Samulski奖是为每年在《液晶》杂志上发表的最佳论文而颁发的,该奖授予了Carsten Tschierske,以表彰其论文《液体和液晶中的镜像对称破坏》(图2)。由Forth Dimensions Displays赞助的最佳学生海报奖授予了科罗拉多大学博尔德分校的Nathan Cobasko,以表彰他对铁磁向列细丝中Fréedericksz跃迁的贡献,以及科罗拉多大学博尔特分校的Greg Smith,以表彰其对4碱基纳米DNA序列的复杂行为:凝聚态和RNA世界的交叉。人们普遍认为,FLC会议的重点已经从传统的显示技术转移到了软物质研究的前沿,包括决定软物质行为和性质的分子组装机制,从简单的液晶相到复杂的生物系统。除了科学计划外,还举办了两个同样令人愉快的社交活动。会议开始时举行了欢迎招待会,为整个会议期间的讨论营造了气氛,最后一天晚上在千年丰收之家举行了会议宴会。今日液晶2019,第28卷,第3期,74–75https://doi.org/10.1080/1358314X.2019.1693097
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