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Typomorphic features of garnet xenocrysts from the crater and diatreme parts of the high diamondiferous V. Grib kimberlite pipe (Arkhangelsk diamondiferous province): application in prospecting and exploration for diamonds in the north of the East European platform 高含金刚石V. Grib金伯利岩管(阿尔汉格尔斯克含金刚石省)火山口和双孔部分石榴石异晶的标型特征:在东欧地台北部找矿勘探中的应用
Pub Date : 2023-09-07 DOI: 10.24930/1681-9004-2023-23-4-622-636
E. O. Barabash, E. Agasheva
Research subject. Morphology of garnet xenocryst grains from the crater and diatreme parts of the highly diamondiferous V. Grib kimberlite pipe of the Arkhangelsk diamondiferous province. Aim. To reconstruct the main stages of endogenous and exogenous morphogenesis of garnet xenocrysts from the crater and diatreme parts of the kimberlite pipe based on a detailed study of their morphological features. To demonstrate the applicability of the data obtained in the interpretation of the morphology of grains of kimberlite indicator minerals from modern alluvial sediments during prospecting and exploration for diamonds in the north of the East European Platform. Materials and methods. A detailed study of the morphology of 655 garnet grains was carried using the methods of optical and electron-scanning microscopy. Garnet grains were selected from the heavy mineral concentrate of crushed rocks, representing the crater (sandstones) and diatreme (kimberlite) parts of the V. Grib pipe. All visually diagnosed garnet grains were handpicked selected from the rocks of the crater part, extracted from the core of one borehole and representing an interval from 70 to 174 m from the surface. For comparison, out of 1100 grains of garnet xenocrysts, selected by random sampling from the concentrate of minerals of the heavy fraction of kimberlite of the diatreme part, 180 garnet grains were selected, representing four-color groups: purple, red, red-orange and orange. Results. The majority of garnets from the crater (96%) and diatreme (89%) parts of the V. Grib kimberlite pipe were shown to exhibit the “primary” magmatic morphology. Nevertheless, the garnet grains with well-developed pyramidal shingle-like (3% in the crater and 11% in the diatreme) and drop-shaped (1% in the crater) reliefs have been identified. These types of garnets were formed under the influence of postmagmatic processes. For the first time, in the deep diatreme part of the pipe (more than 200 m from the surface), composed of dense kimberlite, garnets with a well-developed pyramidal shingle-like relief were found, which had been previously interpreted for the East European Platform only as components of the secondary deposits or the upper horizons of the crater parts of the pipes. Conclusions. Garnets with a well-developed pyramidal shingle-like relief, found in modern alluvial sediments, can be interpreted as from a secondary deposit only if they show signs of mechanical abrasion; the absence of traces of mechanical abrasion on such grains does not allow us to exclude the proximity of the primary source. The presence of drop-shaped relief garnets in the crater of the V. Grib pipe (150-168 m from the surface) also calls into question the unambiguous interpretation of such grains as a sign of secondary deposits: only the maximum degree of chemical abrasion of garnets with the formation of cuboids grains can indicate their redeposited nature. The results confirm the need to improve the method of prospec
研究课题。阿尔汉格尔斯克含金刚石省高含金刚石V. Grib金伯利岩管的火山口和双辉岩部分石榴石异晶颗粒的形态。的目标。在详细研究金伯利岩管中火山口和双孔部分石榴石异种结晶形态特征的基础上,重建其内源和外源形态发生的主要阶段。为了证明在东欧地台北部钻石勘探和勘探过程中,对现代冲积沉积物中金伯利岩指示矿物颗粒形态的解释所获得的数据的适用性。材料和方法。用光学显微镜和电子扫描显微镜对655颗石榴石晶粒的形貌进行了详细的研究。石榴石颗粒是从破碎岩石的重矿物精矿中挑选出来的,代表了V. Grib管道的陨石坑(砂岩)和硅藻土(金伯利岩)部分。所有视觉诊断的石榴石颗粒都是从火山口部分的岩石中精心挑选出来的,从一个钻孔的岩心中提取出来,距离地表70到174米。为了进行对比,从金伯利岩重段矿物精矿中随机抽取1100粒石榴石杂晶,从中选出180粒石榴石,分别代表紫色、红色、红橙色和橙色四种颜色组。结果。在V. Grib金伯利岩管中,陨石坑(96%)和透气孔(89%)部分的石榴石显示出“原生”岩浆形态。然而,已确定的石榴石颗粒具有发育良好的金字塔状瓦状(陨石坑中占3%,陨石坑中占11%)和水滴状(陨石坑中占1%)浮雕。这些类型的石榴石是在岩浆后作用的影响下形成的。首次在由致密金伯利岩组成的管道深部(距地表超过200米)发现了具有发育良好的金字塔状瓦状浮雕的石榴石,这些石榴石以前被解释为东欧地台的次生矿床或管道火山口部分的上部地层的组成部分。结论。在现代冲积沉积物中发现的具有发育良好的金字塔状瓦状浮雕的石榴石,只有当它们显示出机械磨损的迹象时,才能解释为来自次生矿床;这种颗粒上没有机械磨损的痕迹,这不能使我们排除原始来源的接近。V. Grib管陨石坑(距地表150-168米)中水滴状浮雕石榴石的存在,也对这种颗粒作为二次沉积标志的明确解释提出了质疑:只有形成长方颗粒的石榴石的最大化学磨损程度才能表明它们的再沉积性质。结果表明,根据从东欧地台北部取样的现代沉积物中回收的金伯利岩指示矿物的标型特征,需要改进金刚石矿床的找矿方法。
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引用次数: 0
U-Pb (LA-ICP-MS) age of detrital zircons from sandstones of the crater part of the V. Grib kimberlite pipe and KL-01 magmatic object, Arkhangelsk diamondiferous province (north of the East European Platform) 东欧地台北部阿尔汉格尔斯克钻石省V. Grib金伯利岩管火山口部分和KL-01岩浆体碎屑锆石U-Pb (LA-ICP-MS)年龄
Pub Date : 2023-09-06 DOI: 10.24930/1681-9004-2023-23-4-603-621
E. Agasheva
Research subject. Detrital zircons from sandstones that contain no admixtures of magmatic material, sampled from the crater parts of the highly diamondiferous V. Grib kimberlite pipe and KL-01 magmatic object. Both objects are located in the north of the East European Platform, within the Arkhangelsk diamondiferous province, at a distance of ≈100 km from each other. Aim. To obtain the first data on the composition of the U-Pb isotope system of detrital zircons from sandstones of magmatic objects of the Arkhangelsk diamondiferous province in order to evaluate the ages of their sources and reveal correlations with known tectono-thermal events in the continental crust of the region. Materials and methods. Using the LA-ICP-MS method, data were obtained on the composition of the U-Pb isotopic system of 52 zircon grains from the sandstones of the V. Grib pipe and 143 zircon grains from the KL-01 sandstones. Results. Sources of various ages from Archean to Neoproterozoic were established for the studied zircons. However, the majority zircons have Mesoproterozoic age, namely 63 and 65% of grains from the V. Grib pipe and KL-01 object, respectively. The sandstones of the V. Grib pipe contain a larger amount of Meso- and Neo-Archean zircons (≈15%) and a smaller amount of Paleoproterozoic grains (≈14%) compared to those from the KL-01 object ≈7 and 20%, respectively. The population of zircons with the U-Pb ages of 900-700 Ma is absent in the two objects. The minimum age of zircons from sandstones of the crater of the V. Grib pipe (557 ± ± 9 Ma) and KL-01 object (609 ± 9 Ma) is consistent with that of formation of the Vendian sandstones in the area of the pipes of the Arkhangelsk diamondiferous province. Conclusions. The obtained U-Pb age for the studied detrital zircons generally correlate with the previously identified stages of tectono-thermal events in the continental crust of the northern territories of the East European Platform, with the exception of the Mesoproterozoic period 1.7-1.4 and 1.3-1.0 Ga ago, which corresponds to the predominant part U-Pb age values of the studied zircons.
研究课题。从高钻石含量的V. Grib金伯利岩管和KL-01岩浆物体的火山口部分取样的砂岩中不含岩浆物质混合物的碎屑锆石。这两个目标都位于东欧平台的北部,在阿尔汉格尔斯克钻石省内,彼此之间的距离约为100公里。的目标。首次获得了阿尔汉格尔斯克钻石省岩浆岩中碎屑锆石U-Pb同位素系统的组成数据,以评价其来源的年龄,并揭示该地区已知大陆地壳构造-热事件的相关性。材料和方法。采用LA-ICP-MS方法对V. Grib管道砂岩中的52颗锆石和KL-01砂岩中的143颗锆石进行了U-Pb同位素体系组成分析。结果。研究的锆石具有太古宙至新元古代不同年龄的物源。而V. Grib管和KL-01对象的锆石年龄大多为中元古代,分别为63%和65%。V. Grib管砂岩中中太古代和新太古代锆石的含量约为15%,而古元古代颗粒的含量约为14%,分别高于KL-01的约为7%和20%。2个样品中均未发现U-Pb年龄在900 ~ 700 Ma之间的锆石。V. Grib管陨石坑砂岩锆石年龄(557±±9 Ma)和KL-01对象砂岩锆石年龄(609±9 Ma)与阿尔汉格尔斯克钻石省管区文迪安砂岩形成年龄一致。结论。研究碎屑锆石的U-Pb年龄与先前确定的东欧地台北部大陆地壳构造-热事件阶段基本一致,但中元古代1.7 ~ 1.4 Ga和1.3 ~ 1.0 Ga除外,这与研究锆石的大部分U-Pb年龄值相对应。
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引用次数: 1
Diamond potential of the marginal parts of ancient platforms and associated folded areas 古台地边缘及相关褶皱区的钻石潜力
Pub Date : 2023-09-06 DOI: 10.24930/1681-9004-2023-23-4-471-475
D. A. Zedgenizov
In recent years, more and more information has become available on the subsidence of the oceanic lithosphere into the horizons of the transition zone and the lower mantle of the Earth. Highly metamorphosed rocks are often found in ophiolite complexes of folded areas, which, according to some researchers, can also have significant diamond content. A comprehensive study of all possible sources of information about the formation conditions and evolution of contrasting crustal protoliths opens up new prospects for determining such complex geological processes. These studies are also important in the context of identification of new mineralogical and geochemical markers of diamond-forming processes and, on their basis, determination of the possibility of their practical use in improving methods for predicting, prospecting and evaluating diamond deposits. The current issue of our Journal is devoted to these relevant problems.
近年来,关于海洋岩石圈沉降到地球过渡带和下地幔的水平面的信息越来越多。高度变质的岩石通常在褶皱区的蛇绿岩复合体中发现,根据一些研究人员的说法,这些岩石也可能含有大量的钻石。对形成条件和对比地壳原岩演化的所有可能信息来源进行全面研究,为确定这种复杂的地质过程开辟了新的前景。这些研究在鉴定金刚石形成过程的新的矿物学和地球化学标志方面也很重要,并在此基础上确定它们在改进预测、勘探和评价金刚石矿床方法方面实际应用的可能性。本期《华尔街日报》专门讨论这些相关问题。
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引用次数: 0
Formation conditions of andesites of Sulawesi Island (Indonesia) 印度尼西亚苏拉威西岛安山岩形成条件
Pub Date : 2023-07-10 DOI: 10.24930/1681-9004-2023-23-3-386-409
N. Dmitrieva, I. Safonova, V. Simonov, A. Kotlyarov, N. Karmanov, I. Nizametdinov
Research subject. Andesitic complexes of the Tondono caldera and Lokon-Empung volcano locate din the northeastern part of the Sulawesi Island (Indonesia).Aim. To determine the petrogenesis conditions of andesites in the northeast Sulawesi Island based on detailed studies of volcanic rocks of the Tondono caldera and Lokon-Empung volcano.Materials and methods. We studied volcanic rock samples collected by I.Yu. Safonova. To determine the petrogenesis conditions of andesites, conventional petrochemical, geochemical and mineralogical methods were used. Melt inclusions were also studied using a MIRA 3 LMU scanning microscope equipped with Aztec Energy XMax 80 system of microanalysis, and a Horiba LabRam HR800 Raman spectroscope. The PT-parameters of crystallization were estimated from the data on the composition of melt inclusions using approaches reported by K.D. Putirka, F. Yavuz and D.K. Yıldırım.Results. The Sulawesi andesites represent tholeiitic and calc-alkaline island-arc magmas. Pyroxenes phenocrysts crystallized from melts that evolved with accumulation of alkalis and silica. Plagioclase phenocrysts crystallized from the felsic magmas, which are characterized by a decreasing role of alkalis. The composition of volcanic glass of the mesostasis suggests participation of felsic melts with a very high content of alkalis. The compositions of minerals and glasses in inclusions and in the mesostasis allowed us to estimate PT-parameters of the petrogenesis of the andesites. The phenocrysts of pyroxene crystallized in two intermediate magma chambers at depths of 27.6–14.6 and 11.3–7.2 km and temperatures ranging from 1150 to 970ºС. The phenocrysts of plagioclase crystallized at 930–910 and 900–890ºС. The microcrystals (laths) of plagioclase in the mesostasis crystallized at lower temperatures of 875–865 and 840–810ºС.Conclusions. The andesites of the Sulawesi Island were derived from tholeiitic to calc-alkaline melts compositionally similar boninites. The compositions of the glasses in melt inclusions and mesostasis showed three types of compositionally different parental magmas, which produced the Sulawesi andesites. The phenocrysts of pyroxenes crystallized from these melts in two magma chambers at depths of 27.6 to 7.2 km and at temperatures of 1150 to 970ºС. The phenocrysts and laths of plagioclase crystallized at lower temperatures of 930 to 810ºС.
研究课题。Tondono火山口和Lokon-Empung火山的安山岩复合体位于苏拉威西岛(印度尼西亚)的东北部。通过对Tondono火山口和Lokon-Empung火山火山岩的详细研究,确定苏拉威西岛东北部安山岩的成岩条件。材料和方法。我们研究了I.Yu收集的火山岩样本。Safonova表示。为了确定安山岩的成岩条件,采用了常规的石油化学、地球化学和矿物学方法。采用配有Aztec Energy XMax 80微量分析系统的MIRA 3 LMU扫描显微镜和Horiba LabRam HR800拉曼光谱仪对熔体夹杂物进行了研究。结晶的pt参数是根据Putirka, F. Yavuz和D.K. Yıldırım.Results所报道的方法从熔体包裹体的组成数据中估计出来的。苏拉威西安山岩代表拉斑岩和钙碱性岛弧岩浆。辉石斑晶是随着碱和硅的积累而形成的熔体结晶。斜长石斑晶在长英质岩浆中结晶,其特征是碱的作用减弱。中间平衡火山玻璃的组成表明,长英熔体的参与,碱含量很高。包裹体和中间平衡体中矿物和玻璃的组成使我们能够估计安山岩岩石成因的pt参数。辉石斑晶在深度27.6 ~ 14.6 km和11.3 ~ 7.2 km、温度1150 ~ 970ºС的两个中间岩浆房中结晶。斜长石的斑晶在930 ~ 910℃和900 ~ 890℃С下结晶。中稳态斜长石微晶(板条)在875 ~ 865℃和840 ~ 810℃С.Conclusions低温下结晶。苏拉威西岛的安山岩是由拉斑岩到钙碱性熔体组成的,它们的成分相似。熔融包裹体和中间平衡玻璃的组成显示出三种成分不同的母岩浆,形成了苏拉威西安山岩。辉石的斑晶在两个岩浆房中从这些熔体中结晶,深度27.6至7.2 km,温度为1150至970ºС。斜长石的斑晶和板条在930 ~ 810ºС低温下结晶。
{"title":"Formation conditions of andesites of Sulawesi Island (Indonesia)","authors":"N. Dmitrieva, I. Safonova, V. Simonov, A. Kotlyarov, N. Karmanov, I. Nizametdinov","doi":"10.24930/1681-9004-2023-23-3-386-409","DOIUrl":"https://doi.org/10.24930/1681-9004-2023-23-3-386-409","url":null,"abstract":"Research subject. Andesitic complexes of the Tondono caldera and Lokon-Empung volcano locate din the northeastern part of the Sulawesi Island (Indonesia).Aim. To determine the petrogenesis conditions of andesites in the northeast Sulawesi Island based on detailed studies of volcanic rocks of the Tondono caldera and Lokon-Empung volcano.Materials and methods. We studied volcanic rock samples collected by I.Yu. Safonova. To determine the petrogenesis conditions of andesites, conventional petrochemical, geochemical and mineralogical methods were used. Melt inclusions were also studied using a MIRA 3 LMU scanning microscope equipped with Aztec Energy XMax 80 system of microanalysis, and a Horiba LabRam HR800 Raman spectroscope. The PT-parameters of crystallization were estimated from the data on the composition of melt inclusions using approaches reported by K.D. Putirka, F. Yavuz and D.K. Yıldırım.Results. The Sulawesi andesites represent tholeiitic and calc-alkaline island-arc magmas. Pyroxenes phenocrysts crystallized from melts that evolved with accumulation of alkalis and silica. Plagioclase phenocrysts crystallized from the felsic magmas, which are characterized by a decreasing role of alkalis. The composition of volcanic glass of the mesostasis suggests participation of felsic melts with a very high content of alkalis. The compositions of minerals and glasses in inclusions and in the mesostasis allowed us to estimate PT-parameters of the petrogenesis of the andesites. The phenocrysts of pyroxene crystallized in two intermediate magma chambers at depths of 27.6–14.6 and 11.3–7.2 km and temperatures ranging from 1150 to 970ºС. The phenocrysts of plagioclase crystallized at 930–910 and 900–890ºС. The microcrystals (laths) of plagioclase in the mesostasis crystallized at lower temperatures of 875–865 and 840–810ºС.Conclusions. The andesites of the Sulawesi Island were derived from tholeiitic to calc-alkaline melts compositionally similar boninites. The compositions of the glasses in melt inclusions and mesostasis showed three types of compositionally different parental magmas, which produced the Sulawesi andesites. The phenocrysts of pyroxenes crystallized from these melts in two magma chambers at depths of 27.6 to 7.2 km and at temperatures of 1150 to 970ºС. The phenocrysts and laths of plagioclase crystallized at lower temperatures of 930 to 810ºС.","PeriodicalId":18202,"journal":{"name":"LITHOSPHERE (Russia)","volume":"20 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-07-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88141623","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mineralogy and Р-T conditions for the formation of metasomatic rocks of the Voznesenskoye gold deposit (Southern Urals) 南乌拉尔Voznesenskoye金矿床交代岩形成的矿物学及Р-T条件
Pub Date : 2023-07-10 DOI: 10.24930/1681-9004-2023-23-3-430-446
S. E. Znamensky
Research subject. Mineral associations, their chemical composition, and formation conditions of metasomatic rocks of the Voznesenskoye gold deposit located in the area of the Main Ural Fault in the Southern Urals.Methods. The chemical composition of minerals was studied using a Tescan Vega Compact scanning electron microscope equipped with an Oxford Instruments Xplorer 15 energy-dispersive analyzer. The formation P-T parameters were estimated using a chlorite geothermometer and a dolomite-calcite geothermobarometer.Results and conclusions. Two types of metasomatic rocks were identified: 1) propylites, which make up the outer zones of the metasomatic aureole, and 2) beresite-listvenites, common in its inner parts and hosting gold mineralization. The main propylite minerals were amphibole, orthoclase, albite, and ripidolite. Amphibole is represented by two generations, with the early generation comprising magnesian and actinolite hornblende and the late generation comprising actinolite. The crystallization temperature of ripidolite (307–313°С) corresponds to the temperature range of formation of propylites of the albite-actinolite facies. Beresite-listvenites (association: quartz, albite, chlorite, white mica, and carbonate) were formed at a temperature of 255–338°C and a pressure of 0.48–0.72 kbar. Gold ore mineralization was concentrated in the highest temperature zones of the halo of beresite-listvenite alterations. Such temperature conditions existed in dikes and their exocontact zones disturbed by ruptures. Light mica in beresite-listvenites is represented by sericite and phengite, and carbonate is a paragenesis of calcite and dolomite-ankerite. According to the composition and formation period, chlorite is differentiated into early ferruginous ripidolite and late pycnochlorite, depleted in Fe and enriched in Si, which is probably associated with a decrease in temperature during mineral formation and an increase in the activity of sulfide sulfur in the fluid. Along with an increase in the distance from the ore bodies, pycnochlorite exhibits greater contents of Si and lower contents of AlIV. The observed changes in the pycnochlorite composition are related to a decrease in temperature. The research results indicate the formation of the Voznesenskoye deposit under mesothermal conditions.
研究课题。乌拉尔南部乌拉尔主断裂带Voznesenskoye金矿床交代岩的矿物组合、化学组成及形成条件。使用Tescan Vega Compact扫描电子显微镜和Oxford Instruments Xplorer 15能量色散分析仪研究矿物的化学成分。利用绿泥石地温计和白云石-方解石地温计估算地层P-T参数。结果和结论。鉴定出两种类型的交代岩:1)丙岩,构成交代光晕的外围带;2)辉绿岩-辉绿岩,在交代光晕的内部常见,并赋存金矿。主要的丙岩矿物为角闪石、正长石、钠长石和透沸石。闪孔分为两代,早期为镁质角闪石和放光石角闪石,晚期为放光石角闪石。沸石的结晶温度(307 ~ 313°С)对应于钠长岩-放光石相丙岩的形成温度范围。石英、钠长石、绿泥石、白云母和碳酸盐组合形成于温度为255 ~ 338℃,压力为0.48 ~ 0.72 kbar。金矿成矿主要集中在辉绿岩-辉绿岩蚀变晕的最高温度带。这种温度条件存在于岩脉及其受破裂干扰的外接触区。辉绿岩中的轻云母以绢云母和云母为代表,碳酸盐为方解石和白云石的共生体。根据绿泥石的组成和形成时期,绿泥石可分为早期含铁的沸石和晚期的绿泥石,贫铁富硅,这可能与矿物形成过程中温度的降低和流体中硫化物硫活性的增强有关。随着与矿体距离的增加,辉绿石的Si含量增加,AlIV含量降低。所观察到的辉绿石组成的变化与温度的降低有关。研究结果表明,Voznesenskoye矿床是在中温条件下形成的。
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引用次数: 0
High-alumina rocks from the Panimba and Mayakon areas (Yenisei Ridge): Composition and industrial perspectives Panimba和Mayakon地区(叶尼塞岭)的高铝岩:成分和工业前景
Pub Date : 2023-07-10 DOI: 10.24930/1681-9004-2023-23-3-447-465
A. V. Nekipelova, E. Sokol, S. Kokh, I. Likhanov, P. Khvorov
Research subject. Аndalusite- and kyanite-bearing (13–19 wt % Al2SiO5) rocks of the Teya metamorphic complex (Mayakon and Panimba areas), Yenisei Ridge.Aim. To study the composition and mineral content of high-alumina rocks from the Panimba and Mayakon areas.Materials and methods. Laboratory mineral processing was employed to estimate the mineral content of metamorphic rocks of the Teya complex using a magnetic and gravity separation at the Institute of Geology and Mineralogy, Siberian Branch of the Russian Academy of Sciences (Novosibirsk). The concentrates were obtained from typical samples of andalusite, kyanite, and andalusite-kyanite metapilites. After crushing and grinding, the rock samples were separated into size fractions <0.06, 0.06 ≤ x < 0.1 and 0.1 ≤ x < 0.25 mm. The concentrates were recovered from size fractions ≥0.06 mm. Phase, bulk rock, and trace element composition of the rock samples, mineral concentrates, and other fractions were analyzed using XRD, XRF, ICP-MS, and SEM.Results. The magnetic product obtained at the first stage of mineral processing using magnetic separation accumalated staurolite, biotite, chlorite, ilmenite, pyrrhotite, and pyrite. At the second stage, light products containing quartz, feldspars, and muscovite were separated from non-magnetic products with CHBr3 using a centrifugal concentrator. At the last stage, using a double-knife separator, the heavy product from the previous beneficiation stage was separated into a “magnetic” raw concentrate (52–92 wt % Al2SiO5) and a “non-magnetic” final (70–97 wt % Al2SiO5) concentrate. The andalusite-kyanite concentrates (up to 97 wt % Al2SiO5) were obtained by the combination of cheapest and simplest methods of magnetic and gravity separation. The concentrates containing andalusite and kyanite with low recovery (0.7–6%) are comparable to the grade of kyanite-bearing ores of Karelia, the Kola Peninsula, and Gansu Province, China.Conclusions. The study shows that high-quality andalusite and/or kyanite concentrates can be recovered from high-alumina metapelites of the Teya metamorphic complex.
研究课题。Yenisei山脊Teya变质杂岩(Mayakon和Panimba地区)中含蓝晶石(13-19 wt % Al2SiO5)的Аndalusite岩石。研究了Panimba和Mayakon地区高铝岩的组成和矿物含量。材料和方法。在俄罗斯科学院西伯利亚分院地质与矿物学研究所(Novosibirsk),利用磁选和重力分离法,利用实验室矿物加工技术估计了Teya杂岩变质岩的矿物含量。从红柱石、蓝晶石和红柱石-蓝晶石的典型样品中获得精矿。破碎磨矿后,将岩样分离成小于0.06、0.06≤x < 0.1和0.1≤x < 0.25 mm的粒径段。精矿的回收粒度≥0.06 mm。采用XRD、XRF、ICP-MS、sem等分析了岩石样品、矿物精矿和其他组分的物相、整体岩石和微量元素组成。磁选选矿第一阶段获得的磁性产物主要为橄榄石、黑云母、绿泥石、钛铁矿、磁黄铁矿和黄铁矿。在第二阶段,含石英、长石和白云母的轻产物用CHBr3从非磁性产物中分离出来。在最后阶段,使用双刀分离机,将前一选矿阶段的重产品分离成“磁性”原精矿(52-92 wt % Al2SiO5)和“非磁性”终精矿(70-97 wt % Al2SiO5)。采用最便宜、最简单的磁选和重选相结合的方法,获得了红柱石-蓝晶石精矿(Al2SiO5质量分数高达97%)。含红柱石和蓝晶石的精矿回收率较低(0.7-6%),与中国甘肃省卡累利阿、科拉半岛和甘肃含蓝晶石矿石的品位相当。研究表明,从特雅变质杂岩的高铝变质岩中可回收出高质量的红柱石和蓝晶石精矿。
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引用次数: 0
Geochemical record of Lake Sabakty: Electrical conductivity and reconstruction of the Lateglacial and Holocene environments in the Southern Urals (Russia) steppe 俄罗斯南乌拉尔草原Sabakty湖的地球化学记录:电导率及其冰川和全新世环境的重建
Pub Date : 2023-07-10 DOI: 10.24930/1681-9004-2023-23-3-410-429
A. Maslennikova, D. A. Artemiev, E. Zazovskaia, V. Deryagin, V. O. Gulakov, N. Udachin, P. Aminov, V. Udachin
Research subject. The Lake Sabakty sediments core, as a source of data on the Holocene and Lateglacial environments in the Southern Urals.Aim. To obtain a multiple regression model for quantitative reconstructions of the electrical conductivity of water based on the geochemistry of lake sediments and to reconstruct the Late Glacial and Holocene environments based on the study of the Lake Sabakty geochemical record.Materials and methods. After determination of correlations between the content of chemical elements in lake sediments and hydrochemical parameters of 107 Ural lakes, multiple regression models were obtained. Reconstructions were performed based on the results obtained by accelerator mass spectrometry (AMS 14C), 210Pb activity determination, and an analysis of chemical elements and organic matter contents in the sediment core.Results. Three multiple regression models using the concentrations of Na, Ca, Li, and Sr were obtained for electrical conductivity of water reconstruction. In the cold and dry Lateglacial (>12.0 ka cal BP), Lake Sabakty was a slightly brackish reservoir. During the transition from the Lateglacial to the Holocene (12–11.6 ka cal BP), the Lake Sabakty became more productive. In the Early (11.6–8.2 ka cal BP) and Middle (8.2–4.2 ka cal BP) Holocene, the electrical conductivity of water varied under the action of fluctuations in effective moisture. In the Late Holocene (4.2 ka cal BP – present), the Lake Sabakty became less saline due to an increase in effective moisture.Conclusions. The proposed multiple regression models enable rapid quantitative reconstructions of the electrical conductivity of water, which are particularly relevant for Lateglacial–Early Holocene sediments with a low number of microfossils. The Lake Sabakty geochemical record reflects global and regional climatic fluctuations, being more informative compared to the geochemical records of forest lakes in the Southern Urals. The decrease in the electrical conductivity of water of Lake Sabakty of approximately 7.9 and 4.2 ka cal BP coincides with similar data for several other lakes in the Urals.
研究课题。Sabakty湖沉积物岩心作为乌拉尔南部全新世和冰河环境资料的来源。基于湖泊沉积物的地球化学特征,建立定量重建水体电导率的多元回归模型,并基于Sabakty湖地球化学记录重建晚冰期和全新世环境。材料和方法。通过对107个乌拉尔湖泊沉积物中化学元素含量与水化学参数的相关性分析,建立了多元回归模型。根据加速器质谱法(AMS 14C)、210Pb活度测定以及沉积物岩心中化学元素和有机质含量的分析结果进行了重建。利用Na、Ca、Li和Sr的浓度建立了水的电导率重建的三个多元回归模型。在寒冷干燥的冰川期(>12.0 ka cal BP), Sabakty湖为微微咸型水库。在冰川期到全新世(12-11.6 ka cal BP)的过渡时期,萨巴克提湖的生产力有所提高。在全新世早期(11.6 ~ 8.2 ka cal BP)和中期(8.2 ~ 4.2 ka cal BP),水的电导率在有效水分波动的作用下发生了变化。在晚全新世(4.2 ka cal BP - present),由于有效水分的增加,Sabakty湖的含盐量减少。所提出的多元回归模型能够快速定量重建水的电导率,这对于具有少量微化石的冰川-早全新世沉积物尤为重要。Sabakty湖的地球化学记录反映了全球和区域气候波动,与乌拉尔南部森林湖泊的地球化学记录相比,提供了更多的信息。Sabakty湖水的电导率下降了约7.9和4.2 ka cal BP,与乌拉尔其他几个湖泊的类似数据相吻合。
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引用次数: 0
Gabbroids of the Bazhenov gabbro-hyperbasite massif (Middle Urals): Material composition and age 中乌拉尔巴日诺夫辉长-超基岩地块的辉长岩:物质组成和年龄
Pub Date : 2023-07-10 DOI: 10.24930/1681-9004-2023-23-3-367-385
Yu. V. Erokhin, K. Ivanov, V. Smirnov, A. V. Zakharov, A. E. Chugaev
Research subject. Saussurite-amphibole rocks (metagabbroids) of the Bazhenov gabbro-hyperbasite massif (eastern sector of the Middle Urals).Materials and methods. The material composition of metagabbroids and their mineralogy were studied in the analytical laboratories of the Institute of Geological Geology, Ural Branch, Russian Academy of Sciences (Ekaterinburg), Urals State Mining University (Ekaterinburg), Institute of Mineralogy, Ural Branch, Russian Academy of Sciences (Miass), Institute of Geology of Ore Deposits, Petrography, Mineralogy and Geochemistry, Russian Academy of Sciences (Moscow), and Moscow State University (Moscow). Isotope analyzes of zircon were performed on a SHRIMP-II ion microanalyzer at the Center for Isotope Research of VSEGEI (St.Petersburg).Results. The metagabbroids under study feature the following mineral composition: clinozoisite (zoisite, epidote), magnesian hornblende (pargasite, tremolite), albite, clinochlore, and dolomite. According to petro-geochemistry data, saussurite-amphibole rocks were formed after gabbronorites and olivine gabbro-norites, belonging to the alpine-type formation of gabbro-hyperbasite complexes. U-Pb dating showed the ancient age of zircons from metagabbroids, most of the analyzes are grouped below the concordia line, forming a discordia line, the upper intersection of which with the concordia corresponds to the age of 1992 Ma. Two points on the diagram located below the concordia line, although not falling on the continuation of the discordia line, apparently reflect the influence of intermediate stages of metamorphism, and two points with concordant ages of 256 and 251 Ma record the time of the last tectono-thermal episode.Conclusions. The formation of saussurite-amphibole rocks took place under the conditions of greenschist facies. In local areas of the massif, metamorphism reached the zeolite facies with signs of hydrothermal reworking. The primary gabbroids of the Bazhenov massif were most likely formed under the conditions of a suprasubduction basin. The age of zircons of about 2 Ga obtained by the U-Pb method indicates that the crystallization of the studied zircons occurred in the mantle rocks. It is not yet possible to unambiguously explain the presence of grains of these zircons in the metagabbroids of the Bazhenov massif; several possible explanations have been proposed. Zircons with the youngest age (256 and 251 Ma) were most likely formed as a result of metamorphic transformations under thermal influence from the nearby Aduy granite-leucogranite complex.
研究课题。中乌拉尔东段巴治诺夫辉长岩-超基岩地块的索氏闪孔岩(变辉长岩)。材料和方法。在俄罗斯科学院(叶卡捷琳堡)乌拉尔分院地质地质研究所、乌拉尔国立矿业大学(叶卡捷琳堡)、俄罗斯科学院(米斯)乌拉尔分院矿物学研究所、俄罗斯科学院(莫斯科)矿床地质、岩石学、矿物学和地球化学研究所和莫斯科国立大学(莫斯科)的分析实验室中,研究了metagabbroids的物质组成及其矿物学。锆石的同位素分析是在圣彼得堡VSEGEI同位素研究中心的SHRIMP-II离子微量分析仪上进行的。所研究的偏辉长岩的矿物组成包括:斜黝帘石(黝帘石、绿帘石)、镁角闪石(寄生石、透闪石)、钠长石、斜辉石和白云石。岩石地球化学资料显示,辉长岩-角闪岩是在辉长岩和橄榄辉长-辉长岩之后形成的,属于辉长岩-超玄武岩杂岩的高岭山型构造。U-Pb测年结果显示,这些锆石的年龄大多集中在康考迪亚线以下,形成一条不康考迪亚线,其上部与康考迪亚线的交点对应的年龄为1992 Ma。图中位于concordia线下方的两个点虽然没有落在discordia线的延长线上,但明显反映了变质作用的中间阶段的影响,256 Ma和251 Ma的两个一致年龄点记录了最后一次构造-热事件的时间。闪石-角闪岩是在绿片岩相条件下形成的。局部变质作用达到沸石相,有热液改造的迹象。巴治诺夫地块的原生辉长岩极有可能形成于上俯冲盆地条件下。U-Pb法测定的锆石年龄约为2 Ga,表明锆石结晶发生在地幔岩中。目前尚不能明确地解释这些锆石颗粒在巴治诺夫地块的变质斑岩中的存在;人们提出了几种可能的解释。年龄最小的锆石(256和251 Ma)很可能是在附近Aduy花岗岩-浅花岗岩杂岩的热作用下变质而形成的。
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引用次数: 0
Junction zone structure of the Sarmatia, Volga-Uralia, and Fennoscandia microcontinents as part of the East European Platform basement 萨尔马提亚、伏尔加-乌拉利亚和芬诺斯坎迪亚微大陆的接合带结构,作为东欧地台基底的一部分
Pub Date : 2023-07-09 DOI: 10.24930/1681-9004-2023-23-3-309-324
T. N. Kheraskova, Y. Volozh, M. Antipov, V. A. Bykadorov, I. S. Patina, R. B. Saposhnikov
Research subject. The structure of the pre-Paleozoic deposits and different-age Precambrian basement of the East European platform based on geological and geophysical data.Aim. To trace the evolution of the area under study and to study the geodynamics of processes in order to reconstruct the paleostructure of the Baltica continent.Materials and methods. The current state of the consolidated crust was studied using a geological interpretation of seismic profiling data (transects: “EB-1”, “Tatseys”, “Magnit”) and materials of gravity and geomagnetic surveys. The material composition of the basement rock complexes was studied based on drilling data.Results. The Baltica continent forms the basement of the modern East European Platform. After the Sveconorwegian folding about 1000 Ma, Baltica had become part of the Rodinia supercontinent and merged with the North American platform. A passive continental margin with the Riphean-Vendian sedimentary cover was formed on the eastern Baltica edge. The Petrozavodsk-Khopersky orogen, which arose in the place of the Karelian (Early Proterozoic) Petrozavodsk-Khopersky paleoocean, was reconstructed. The submeridional suture was a result of this paleoocean closure. The orogen structure, as well as that of the paleocontinent Baltica, was disturbed and partially destroyed by subsequent tectonic processes, which continue at the present time with modern rifting.Conclusions. The closure of the Petrozavodsko-Khopersky paleoocean led to the formation of the Baltica continent, which included three microcontinents – Sarmatia, Fennoscandia and Volga- Uralia. Baltica became part of the Rodinia supercontinent during the Sveconorwegian orogeny. Volga-Uralia was located on the border with the PaleoPacific and had a Late Riphean sedimentary cover of the Rodinia supercontinent. This margin underwent destruction during a collision with the Timanides. The scale and extent of the reconstructed Petrozavodsk-Khopersky orogen is comparable to Paleozoic orogenic belts, such as Cadomides, Caledonides, Variscides, or Timanides.
研究课题。基于地质和地球物理资料的东欧地台前古生代沉积构造和不同时代的前寒武纪基底。追踪研究区域的演化,研究过程的地球动力学,以重建波罗的海大陆的古构造。材料和方法。利用地震剖面数据(“EB-1”、“Tatseys”、“Magnit”断面)的地质解释以及重力和地磁调查资料,研究了固结地壳的现状。根据钻井资料,对基岩杂岩的物质组成进行了研究。波罗的海大陆形成了现代东欧地台的基底。在大约1000年前的挪威褶皱之后,波罗的海成为罗丁尼亚超大陆的一部分,并与北美地台合并。波罗的海东部边缘形成了一个被动大陆边缘,具有里芬—文德沉积盖层。重建了原Karelian(早元古代)Petrozavodsk-Khopersky古海洋位置上发育的Petrozavodsk-Khopersky造山带。水下缝合是古大洋闭合的结果。造山带构造以及古波罗的海大陆的造山带构造受到后来的构造作用的干扰和部分破坏,这些构造作用以现代裂陷作用延续至今。Petrozavodsko-Khopersky古海洋的闭合导致了波罗的海大陆的形成,其中包括三个微大陆——萨尔马提亚、芬诺斯坎迪亚和伏尔加-乌拉利亚。波罗的海在挪威造山运动期间成为罗丁尼亚超大陆的一部分。伏尔加-乌拉利亚位于古太平洋的边界,有罗丁尼亚超大陆的晚里芬沉积盖层。这个边缘在与提马尼德号的碰撞中遭到破坏。重建的Petrozavodsk-Khopersky造山带的规模和范围可与古生代的Cadomides、Caledonides、Variscides、Timanides等造山带相媲美。
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引用次数: 1
Ostracod zonation of the Givetian-Frasnian boundary interval in the Timan-North Urals Region 提曼—北乌拉尔地区吉田—弗拉斯界段介形类的分带
Pub Date : 2023-07-09 DOI: 10.24930/1681-9004-2023-23-3-348-366
D. B. Sobolev, M. A. Soboleva, I. Evdokimova
Research subject. Ostracods and Givetian-Frasnian boundary deposits of the Timan-North Urals Region.Materials and methods. The work was based on the results of studying ostracods from the stratotype sections of the Southern Timan, which are considered referential for regional and global correlations. The analysis of the distribution intervals of the most significant taxa was based on the results of previous studies, both published and archival materials on the Timan-Urals Region. Ostracods were considered in association with conodonts, which is an important criterion for applying a reasonable biostratigraphic subdivision. The use of different-scale regional cyclicity of sedimentation and individual “marking” levels of manifestation of global events were shown.Results. The ostracod distribution in the Givetian-Frasnian boundary interval of the Timan-Northern Urals region was analyzed. The following most significant taxa were identified: Cavellina devoniana, Cavellina uchtensis, Cavellina batalinae, Cavellina chvorostanensis, Nodella faceta, Nodella ex gr. hamata. The correlation of established assemblages with ostracods from the Franco-Belgian basin was shown. The difference consists in the absence of a polyzygid assemblage with Polyzygia beckmanni beckmanni, which was established at the base of the Nismes Formation of Belgium near the historical boundary between the Givetian and Frasnian stages. The determined relationship of biostratigraphic data in combination with the transgressive-regressive sequence of sedimentation shows a more reasonable solution to the problem of the position of the lower boundary of the Frasnian stage of the Upper Devonian in the Timan-Northern Urals Region.Conclusions. An updated version of the scheme of zonal subdivision of the Givetian-Franian boundary interval in the Timan- Northern Urals region has been developed, taking into account the ostracod distribution of the Cavellinidae and Nodellidae families, as well as the discrepancies in the levels of the first appearance of index species and the boundaries of zones in the regional stratigraphic scheme. The correlation of ostracod zones relative to the conodont scale is shown.
研究课题。梯曼—北乌拉尔地区介形类与吉田—弗拉斯系界线沉积。材料和方法。这项工作是基于对南提曼层型剖面介形类的研究结果,这些结果被认为是区域和全球相关性的参考。最重要的分类群分布区间的分析是基于先前对Timan-Urals地区的研究结果,包括已发表的和档案资料。介形虫被认为与牙形刺相关联,这是应用合理的生物地层细分的重要标准。利用不同尺度的区域沉积旋回和全球事件的个别“标记”水平进行了论证。分析了提曼—北乌拉尔地区吉田—弗拉斯界段介形类的分布。鉴定出最重要的分类群为:泥盆鱼(cavelina devoniana)、乌氏鱼(cavelina uchtensis)、蝙蝠鱼(cavelina batalinae)、chvorostanensis、面Nodella faceta、hamata noella ex grg . hamata。已建立的组合与来自法比盆地的介形类进行了对比。不同之处在于,在比利时尼斯姆组的底部,在吉夫梯和弗拉斯梯的历史边界附近,没有一个多接合体组合,而多接合体是在吉夫梯和弗拉斯梯之间建立的。结合沉积的海侵-退序,确定了生物地层资料的关系,较合理地解决了天—北乌拉尔地区上泥盆统弗拉斯期下界的位置问题。考虑到甲壳纲科和甲壳纲科介形类的分布,以及指数种首次出现的水平和区域地层格局中带界的差异,提出了提曼-北乌拉尔地区吉田-弗朗尼亚边界区间分区划分方案的更新版本。给出了介形虫带与牙形石尺度的相关性。
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