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Monitoring Setting and Early Hydration of Cement Using Dielectric Spectroscopy 介电光谱法监测水泥凝结及早期水化
S. Ng, G. Shapiro, S. Mak
Dielectric permittivity is a promising technique for making non-destructive measurements of the setting and hydration behavior of cementitious systems. In this paper, preliminary work has been done to investigate the link between the dielectric permittivity behavior of a series of mortars of varying W/C and the setting and hydration behavior in the same mortars as observed using isothermal calorimetry and penetration resistance measurements. The dielectric permittivity of these mortars measured at a frequency of 2.45 GHz appears to be sensitive to the chemical changes experienced during setting. Regions in the dielectric behavior have been tentatively linked to the dormant period of cement hydration, the initial time of set and the peaks in isothermal calorimetry associated with C3S reaction and monosulphoaluminate formation. Dielectric permittivity also shows promise in determining the moisture content of portland cement-based systems.
介质介电常数是一种很有前途的无损测量胶凝体系凝结和水化行为的技术。本文利用等温量热法和穿透阻力测量法,初步研究了一系列不同W/C砂浆的介电常数行为与同一砂浆的凝结和水化行为之间的联系。在2.45 GHz频率下测量的这些砂浆的介电常数似乎对凝结过程中经历的化学变化很敏感。介电行为的区域已初步与水泥水化的休止期、凝固的初始时间以及与C3S反应和单硫铝酸盐形成相关的等温量热峰联系起来。介电常数在确定硅酸盐水泥基体系的水分含量方面也显示出前景。
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引用次数: 3
Rapid Microwave Curing of Precast Concrete Slab Elements 预制混凝土板构件的快速微波养护
S. Mak, D. Ritchie, G. Shapiro, R. W. Banks
The speed of curing is often a critical issue in the manufacture of precast concrete elements. For some products, the curing cycle consumes up to 70% of the total production cycle. To improve the speed of production, heat curing is often used to accelerate the hardening of precast concrete. Conventional heating techniques rely on thermal conduction. Microwave energy offers potential to increase the rate of bulk heating in precast concrete through its relatively deeper penetration, which allows quicker through-depth heating and maturing. Research on microwave curing of concrete has been ad hoc in the past and a wide range of issues remain unresolved. These encompass materials-microwave interactions, process design and control, hardware and logistics as well as the impact of microwave curing on concrete properties. In this paper, progress on research on microwave curing is described with reference to work carried out at CSIRO. In particular, results from pilot-scale heating of slab-type elements are discussed in relation to heating characteristics, process control, set acceleration, strength development and process efficiency. The authors' results show that for the same bulk heating rates, microwave heating produces significantly lower temperature gradients when compared to steam heating. Using rapid curing cycles of less than six hours, compressive strengths in excess of 25 MPa can be achieved in high quality precast concrete. Doubling the bulk heating rate using microwaves does not result in any deterioration in near-surface quality as was the case with conventional steam heating.
在预制混凝土构件的制造过程中,养护速度往往是一个关键问题。对于某些产品,固化周期消耗高达总生产周期的70%。为了提高生产速度,常采用热养护来加速预制混凝土的硬化。传统的加热技术依靠热传导。微波能量通过其相对较深的渗透,提供了增加预制混凝土中大块加热速率的潜力,这使得通过深度加热和成熟的速度更快。过去对混凝土微波养护的研究是临时性的,许多问题尚未得到解决。这些包括材料-微波相互作用,工艺设计和控制,硬件和物流以及微波固化对混凝土性能的影响。本文结合CSIRO的工作,介绍了微波固化的研究进展。特别讨论了板状构件中试加热的结果与加热特性、工艺控制、凝固加速度、强度发展和工艺效率的关系。作者的研究结果表明,在相同的体积加热速率下,微波加热产生的温度梯度明显低于蒸汽加热。使用少于6小时的快速养护周期,高质量预制混凝土的抗压强度可超过25兆帕。使用微波将体积加热速率提高一倍,不会像传统的蒸汽加热那样导致近表面质量的任何恶化。
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引用次数: 6
Chloride Diffusivity of Concrete Incorporating Rice Husk Ash 稻壳灰混凝土的氯离子扩散系数
N. Maeda, I. Wada, M. Kawakami, T. Ueda, G. Pushpalal
Effect of rice husk ash addition on the chloride diffusivity of concrete is investigated in the present paper. The concrete specimens, having water-cementitious materials ratio of 0.30, 0.36 and 0.53, with and without rice husk ash are subjected to accelerated chloride penetration using the following two methods: i) Immersion in saturated NaCl at 20 degrees C, ii) Exposure to alternate cycles of 3 days immersion in 3% NaCl solution at 20 degrees C and 4 days drying at 50% R.H. After the accelerated chloride penetration, the total chloride content of concrete specimens at various depths was determined. Consequently, using the chloride content distributions, the chloride diffusion coefficient of concrete is evaluated by applying Fick's second law. In addition, the pore size distribution of concrete is determined in order to assess the effect of concrete microstructure on chloride diffusivity. From the experimental results, the total chloride content of concrete incorporating rice husk ash was shown to be lower than that of the control concrete after accelerated chloride penetration. The concrete specimens incorporating rice husk ash had chloride diffusion coefficients 57% to 25% lower than the control concrete. The effect of rice husk ash on pore refinement in concrete was observed, especially in the pore radii larger than 50nm. The pore size distribution of concrete tended to shift towards the smaller pores with the addition of rice husk ash. The decrease of the chloride diffusion coefficient of concrete incorporating RHA may therefore be attributed to the pore-refinement effect.
研究了稻壳灰掺量对混凝土氯离子扩散系数的影响。混凝土标本,water-cementitious材料比率为0.30,0.36和0.53,有或没有稻壳灰受到加速氯离子渗透使用以下两种方法:1)浸泡在饱和氯化钠在20摄氏度,ii)接触交替周期3天浸泡在3%的氯化钠溶液在20摄氏度,4天干燥在50%相对湿度加速氯离子渗透后,混凝土的总氯含量的标本在不同深度决定。因此,利用氯化物含量分布,应用菲克第二定律计算混凝土的氯化物扩散系数。此外,还测定了混凝土的孔径分布,以评价混凝土微观结构对氯离子扩散系数的影响。从试验结果来看,掺入稻壳灰的混凝土经加速氯离子渗透后,总氯离子含量低于对照混凝土。掺稻壳灰混凝土的氯离子扩散系数比对照混凝土低57% ~ 25%。观察了稻壳灰对混凝土孔隙细化的影响,特别是对孔隙半径大于50nm的混凝土。稻壳灰掺入后,混凝土的孔径分布有向小孔方向移动的趋势。掺入RHA的混凝土氯离子扩散系数的降低可能是由于其孔隙细化效应。
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引用次数: 9
Use of Glass and Fly Ash in Manufacture of Controlled low Strength Materials 玻璃和粉煤灰在控制低强度材料制造中的应用
T. Naik, R. N. Kraus, Shiw S. Singh
This work was conducted to develop two types of controlled low strength materials (CLSM) or flowable slurry utilizing post-consumer glass (broken glass or glass cullet) aggregate and fly ash. Type A CLSM consisted of glass, fly ash, cement, and water; and Type B CLSM consisted of glass, sand, cement, and water. All mixtures were proportioned to achieve the 28-day compressive strength of 0.7 MPa (100 psi). The type A CLSM mixtures consisted of a control mixture (100% fly ash without glass) and five other mixtures with glass, as a replacement of fly ash in the range of 20% to 80%. The Type B CLSM mixtures were composed of a control mixture (without glass) and two other mixtures at 30% to 75% replacement of sand with glass. The flowable slurry developed in this project satisfied the ACI Committee 229 definition of CLSM. Decreasing the amount of fly ash and increasing the glass content led to increased bleeding and segregation at high replacement levels of 60% and 80%. Permeability of Type A CLSM remained essentially unchanged, except at high glass contents it was lower. For Type B CLSM, the permeability was about the same.
这项工作是为了开发两种控制低强度材料(CLSM)或流动浆料,利用消费后玻璃(碎玻璃或玻璃碎片)骨料和粉煤灰。A型CLSM由玻璃、粉煤灰、水泥和水组成;B型CLSM由玻璃、砂、水泥和水组成。所有混合物按比例配制,使其28天抗压强度达到0.7 MPa (100 psi)。A型CLSM混合物由一种对照混合物(100%不含玻璃的粉煤灰)和另外五种含玻璃的混合物组成,以替代20%至80%的粉煤灰。B型CLSM混合物由对照混合物(不含玻璃)和另外两种混合物组成,用玻璃代替30%至75%的砂。本项目开发的可流动浆料满足ACI委员会229对CLSM的定义。减少粉煤灰掺量和增加玻璃掺量,在60%和80%的高替代水平下,会导致出血性和离析加剧。A型CLSM的渗透率基本保持不变,但玻璃含量高时渗透率较低。B型CLSM的渗透率基本相同。
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引用次数: 10
Axial Compressive Behavior of Reinforced Concrete Short Columns Strengthened with Carbon Fiber Sheets 碳纤维板加固钢筋混凝土短柱轴压性能研究
J. Hwang, K. S. Lee, B. Bahn, S. Shin
This paper presents the test results on the study of reinforced concrete (R/C) columns strengthened with carbon fiber sheets (CFS). The purpose of this research was the evaluation of the CFS confinement characteristics of square reinforced concrete columns. The test specimens consisted of seventeen square columns (200x200mm cross-section and 400mm height). The test columns were fabricated with different lateral reinforcement ratios. The tests were performed with different CFS reinforcement ratios and reinforcing methods to investigate the effects on the strength and deformation characteristics of concrete columns. Test results were characterized according to failure patterns, maximum loads, and strain distribution along the column longitudinal axes.
本文介绍了碳纤维板加固钢筋混凝土(R/C)柱的试验研究结果。本研究的目的是评价方形钢筋混凝土柱的CFS约束特性。试件由17根方形柱组成,截面为200x200mm,柱高400mm。试验柱采用不同的配筋率制作。通过不同配筋率和配筋方式对混凝土柱强度和变形特性的影响进行了试验研究。试验结果根据破坏模式、最大载荷和沿柱纵向轴的应变分布进行表征。
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引用次数: 0
The U.S. Power Industry’s Activities to Expand Coal Ash Utilization in Face of lower Ash Quality 面对煤灰质量下降,美国电力工业扩大煤灰利用的活动
D. Golden
This paper describes a five-year Electric Power Research Institute (EPRI) program directed toward increasing ash utilization in the cement and concrete market within the United States, in the face of the impacts on ash quality due to more aggressive NOx controls. EPRI is undertaking this program to provide the technical basis for protecting the bulk sale of coal ash in high-volume applications in cement and concrete and other high volume civil engineering applications. In addition to higher carbon levels in ash from NOx control systems, problems associated with ammoniated ash have become a major concern for coal-fired facilities in recent years as a result of the increased use of ammonia-based environmental control technologies. Many coal-fired power producers have become concerned that post-combustion NOx controls could lead to fly ash containing high levels of ammonia. Therefore, EPRI conducted a research program designed to assist power producers to evaluate and mitigate the impacts of high carbon and ammoniated ash.
本文描述了一项为期五年的电力研究所(EPRI)计划,该计划旨在提高美国水泥和混凝土市场的灰分利用率,以应对由于更积极的氮氧化物控制对灰分质量的影响。EPRI正在开展该项目,为保护粉煤灰在水泥、混凝土和其他大量土木工程应用中的大量销售提供技术基础。除了氮氧化物控制系统产生的灰中碳含量较高外,近年来,由于氨基环境控制技术的使用增加,与氨化灰有关的问题已成为燃煤设施的主要关切。许多燃煤电厂已经开始担心,燃烧后的氮氧化物控制可能导致飞灰中含有高浓度的氨。因此,EPRI开展了一项研究计划,旨在帮助电力生产商评估和减轻高碳和氨化灰的影响。
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引用次数: 2
Durability of Reactive Powder Concrete When Subjected to a leaching Test 活性粉末混凝土经受浸出试验时的耐久性
Matte, M. Cheyrezy, M. Moranville, C. Richet, J. Torrenti
The Reactive Powder Concretes (RPC) are well known for their high strength, but they also present good performances regarding durability aspect due to their very dense microstructure. Studies were made to evaluate the durability of RPC to: freeze-thaw scaling, carbonation, chloride ions diffusion, abrasion coefficient and shrinkage. Their very good performance characteristics have led to a specific research program to evaluate the long-term durability of RPC for nuclear waste containment. Several kinds of potential degradation are studied, but here only the attack by de-ionized water, a very severe leaching test, will be presented. After pre-determined periods, the material was analyzed regarding its microstructure (altered depth, composition and mineralogical changes), porosity and ion transport properties. The results of SEM, X-ray diffraction, mercury intrusion porosimetry, BET pore-size and tritium diffusion coefficient analyses are presented.
活性粉末混凝土(RPC)以其高强度而闻名,但由于其非常致密的微观结构,它们在耐久性方面也表现出良好的性能。研究了RPC在冻融结垢、碳化、氯离子扩散、磨损系数和收缩率方面的耐久性。它们非常好的性能特性导致了一项具体的研究计划,以评估RPC用于核废料遏制的长期耐久性。研究了几种潜在的降解,但这里只介绍去离子水的攻击,这是一种非常严重的浸出试验。在预先确定的时间之后,对材料的微观结构(改变的深度、成分和矿物学变化)、孔隙度和离子传输特性进行分析。给出了扫描电镜(SEM)、x射线衍射(X-ray)、压汞法、BET孔径及氚扩散系数分析结果。
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引用次数: 2
Use of Recycled Concrete Powder in Self-Compacting Concrete 再生混凝土粉在自密实混凝土中的应用
H. Kasami, M. Hosino, T. Arasima, H. Tateyasiki
Although 37 million tons of concrete wastes have been generated annually in Japan, the use of recycled aggregate for concrete is limited because of low density and high absorption due to adhered cement paste and mortar. A new method to produce high quality recycled aggregate by heating and grinding concrete rubbles to separate cement portions adhering to aggregate was developed recently. In this process, by-product powder with the fineness of 400 m2/kg is generated. By-product recycled concrete powder consists of fine particles of hydrated cement and crushed aggregate. To utilize the recycled concrete powder as concrete additives two series of experiments were performed to make clear the effect of recycled powder. Self-compacting concrete with recycled concrete powder, ground blast-furnace slag and ground limestone were tested for slump-flow, compressive strength, modulus of elasticity and drying shrinkage. Reduction in superplasticizing effect of high-range water reducer was found for concrete with recycled concrete powder. Compressive strength of concrete with recycled concrete powder was the same as those with ground limestone, and lower than those with ground slag. Concrete with recycled concrete powder showed lower elastic modulus and higher drying shrinkage than those with ground slag and ground limestone. The recycled concrete powder is usable for self-compacting concrete without further processing, despite the possible increase in dosage of high-range water reducer for a given slump-flow and in drying shrinkage. The addition of ground blast-furnace slag together with recycled concrete powder to self-compacting concrete improved superplasticizing effect of high-range water reducer and properties of concrete.
虽然日本每年产生3700万吨混凝土废料,但由于水泥膏体和砂浆黏附,再生骨料密度低,吸收率高,因此使用再生骨料制作混凝土受到限制。近年来发展了一种通过对混凝土碎料进行加热和研磨,分离水泥粘附在骨料上的新方法,以生产高质量的再生骨料。在此过程中,产生细度为400 m2/kg的副产粉。副产品再生混凝土粉由水化水泥的细颗粒和破碎的骨料组成。为了利用再生混凝土粉作为混凝土添加剂,进行了两个系列的试验,以明确再生混凝土粉的效果。对再生混凝土粉、高炉矿渣粉和石灰石粉配制的自密实混凝土进行了坍落度、抗压强度、弹性模量和干燥收缩率试验。用再生混凝土粉配制的高效减水剂降低了混凝土的超塑效果。掺再生混凝土粉的混凝土抗压强度与掺石灰石的相同,但低于掺矿渣的混凝土。掺有再生混凝土粉的混凝土比掺有矿渣和石灰石的混凝土弹性模量更低,干收缩率更高。再生混凝土粉可用于自密实混凝土,无需进一步处理,尽管可能增加高范围减水剂的剂量,以给定坍落流和干燥收缩。在自密实混凝土中掺入磨碎的高炉矿渣和再生混凝土粉,改善了高范围减水剂的超塑效果,改善了混凝土的性能。
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引用次数: 13
Mechanical Properties of Concrete Containing Foundry Sand 含铸造砂混凝土的力学性能
J. Khatib, D. J. Ellis
The properties of concrete containing foundry sand as a partial replacement of fine aggregate were investigated. Three types of sand used in foundries were considered, the white fine sand without the addition of clay and coal, the foundry sand before casting (blended), and the foundry sand after casting (spent). The standard sand (Class M) was partially replaced by (0%, 25%, 50%, 75%, and 100%) these types of sand. Thirteen concrete mixtures were employed to conduct this study. Concrete strength up to 90 days and length change (drying shrinkage and expansion) up to 60 days were determined. As the replacement level of standard sand with sand used in foundries increased, the strength of concrete decreased. Concrete containing white sand showed somewhat similar strength to those containing spent sand at all replacement levels. The presence of high percentage of blended sand in the concrete mixture caused a reduction in strength as compared with concrete incorporating white sand or spent sand. The increase in strength was not observed at low replacement levels (less than 50%). The length change of concrete increased as the replacement level of standard sand with the three types of sand increased. Drying shrinkage values were higher in concrete containing spent sand and lower in concrete containing white sand. Expansion was generally lower in concrete containing white sand as compared with the other two types (blended and spent) at a low sand replacement level of 25%; and, a different trend was obtained at higher levels.
研究了部分替代细骨料的铸造砂混凝土的性能。考虑了铸造用砂的三种类型,即不添加粘土和煤的白细砂、铸造前的铸造砂(混合砂)和铸造后的铸造砂(废砂)。标准砂(M类)部分被这些类型的砂(0%、25%、50%、75%和100%)所取代。采用13种混凝土混合料进行本研究。测定了混凝土在90天内的强度和60天内的长度变化(干燥收缩和膨胀)。随着标准砂与铸造厂用砂替代水平的提高,混凝土强度下降。含有白砂的混凝土与含有废砂的混凝土在所有替换水平上表现出相似的强度。与掺入白砂或废砂的混凝土相比,混凝土混合物中掺砂比例高导致强度降低。在低置换水平(低于50%)时,强度未见增加。随着标准砂与三种砂替换水平的增加,混凝土长度变化量增大。掺废砂混凝土的干缩值较高,掺白砂混凝土的干缩值较低。含白砂混凝土的膨胀率一般低于其他两种类型的混凝土(混合和废砂),当砂替换量为25%时;在较高的水平上,得到了不同的趋势。
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引用次数: 88
Expansion of Powerhouse Structures Due to Alkali-Aggregate Reaction and the Use of low Calcium Fly Ash to Ameliorate the Reaction in Future Construction 碱-骨料反应引起厂房结构膨胀及在今后施工中使用低钙粉煤灰改善反应
W. Langley, E. Brown
Alkali-aggregate reactivity, a reaction between the alkalies in the concrete pore fluid and certain siliceous aggregates was identified as a cause of disruptive expansion in concrete in Nova Scotia in 1962. Powerhouse structures, constructed with concrete containing meta-sediments and biotite schists, which are commonly used as concrete aggregate in Nova Scotia, caused expansion which created problems with the operation of the plants within 10 years after construction. Extensive studies in the mid 1960's and late 1980's of operating quarries and deteriorated structures, indicated that the reactive aggregates were widespread. Studies in the 1980's on the use of low calcium fly ash as a replacement or addition for portland cement showed conclusively that the reaction could be ameliorated with 15 to 30 percent fly ash replacement of the cement. Low calcium fly ash is now used systematically to lessen the potential for alkali-aggregate reaction.
碱-骨料反应性,即混凝土孔隙流体中的碱与某些硅质骨料之间的反应,于1962年在新斯科舍省被确定为混凝土破坏性膨胀的原因。厂房结构是用含有元沉积物和黑云母片岩的混凝土建造的,这是新斯科舍省常用的混凝土骨料,造成了扩建,在建设后10年内给工厂的运行带来了问题。一九六〇年代中期及一九八〇年代末对营运的采石场及老化的结构进行的广泛研究显示,反应性骨料分布广泛。在20世纪80年代关于使用低钙粉煤灰替代或添加波特兰水泥的研究最终表明,用15%至30%的粉煤灰替代水泥可以改善反应。低钙粉煤灰现在被系统地用于减少碱-骨料反应的可能性。
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引用次数: 0
期刊
"SP-200: Fifth CANMET/ACI Conference on Recent Advances in Concrete Technology-Proceeding, Fifth International Conference"
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