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Effect of Sea Water on Frost Damage to Mortar and Cement Paste 海水对砂浆和水泥浆冻损的影响
X. Wang, K. Ayuta
Serious deterioration of concrete usually occurs under the influence of both sea water and frost action in cold regions. In order to clarify the connection between pore structure and frost behavior of concrete surface as affected by sea water and freezing-thawing action, three series were carried out using small mortar and cement paste specimens. The first one was to investigate the effects of sea water on pore structure by means of mercury-intrusion porosity meter; the second one was to investigate the effects of sea water on products by means of X-ray diffraction; and the last one was to investigate the effects of sea water on freezable water by means of differential scanning calorimetry. Results obtained show that specimens immersed in sea water have many pores ranging in size of several hundred nm to thousand nm, and contain much more freezable water than those immersed in fresh water. When concrete is affected by both sea water and freezing and thawing action, the number of medium-size pores (100 nm to 1000 nm) and the amount of freezable water increase. There is good correlation between the total pore volume and the amount of freezable water. Accordingly, it is considered that marine concrete in cold regions deteriorates because the pore structure near the exposure surface becomes more porous and the amount of freezable water increases.
在寒冷地区,混凝土在海水和霜冻共同作用下往往会发生严重的劣化。为了弄清海水和冻融作用下混凝土表面孔隙结构与结霜行为之间的关系,采用小型砂浆和水泥浆试件进行了三个系列的试验研究。首先利用汞侵入孔隙度仪研究海水对孔隙结构的影响;二是用x射线衍射法研究海水对产品的影响;最后用差示扫描量热法研究了海水对可冻水的影响。结果表明,浸泡在海水中的试样具有许多几百~几千nm大小的孔隙,并且含有比浸泡在淡水中的试样多得多的可冻水。在海水和冻融作用共同作用下,混凝土中孔径(100 ~ 1000 nm)和可冻水量增加。总孔隙体积与可冻水量之间存在较好的相关性。因此,可以认为寒冷地区海工混凝土的劣化是由于暴露面附近的孔隙结构变得更多孔,可冻水量增加。
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引用次数: 1
Effect of Incorporating Metakaolin on Fresh and Hardened Properties of Concrete 掺加偏高岭土对混凝土新鲜性能和硬化性能的影响
H. A. Razak, H. Wong
High strength concrete mixtures containing 10% metakaolin replacement and 10% metakaolin addition, water/cementitious material ratio of 0.3 and 1% superplasticizer were studied. Similar mixtures incorporating silica fume were also prepared. The effect of mineral admixtures on the fresh and hardened properties of concrete was investigated. Mixtures with mineral admixture exhibited lower workability, less bleeding, and slightly lower air content. Metakaolin resulted in a higher loss of workability compared with silica fume. Mixtures incorporating mineral admixture developed greater compressive strength and elastic modulus at all ages. The enhancement was more pronounced at early ages and in the addition mixtures. The study concludes that the performance of metakaolin is equivalent to silica fume in terms of contribution to the enhancement of strength and elastic modulus. The metakaolin addition mixture attained 70% and 50% strength improvement while the metakaolin replacement mixture achieved 67% and 39% strength increment at the respective ages of 3 and 28 days.
研究了掺10%偏高岭土、掺10%偏高岭土、水胶比为0.3、高效减水剂为1%的高强混凝土配合比。还制备了含有硅灰的类似混合物。研究了矿物外加剂对混凝土新鲜性能和硬化性能的影响。含有矿物外加剂的混合物具有较低的和易性、较少的出血和稍低的空气含量。偏高岭土与硅灰相比,工作性损失更大。含矿物外加剂的混合物在各个年龄阶段都具有更高的抗压强度和弹性模量。这种增强在幼龄和添加混合物中更为明显。研究结果表明,偏高岭土在提高强度和弹性模量方面的贡献与硅灰相当。在3日龄和28日龄时,偏高岭土添加混合物的强度提高了70%和50%,偏高岭土替代混合物的强度提高了67%和39%。
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引用次数: 5
Shear Capacity of Reinforced Concrete Beams Made with Recycled-Aggregate 再生骨料钢筋混凝土梁抗剪承载力研究
B. Han, H. Yun, S. Chung
The use of recycled-aggregate concrete is increasing faster than the development of appropriate design recommendations. This paper reports limited experimental data on the shear capacity of reinforced concrete beams recycled-aggregate. Twelve beams were tested to determine their diagonal cracking and ultimate shear capacities. The variables in the test program were shear-span/depth ratio a/d = 1.5, 2.0, 3.0 and 4.0; aggregate types; and shear reinforcement ratio = 0, 0.089, 0.244, 0.507, and 0.823 percent. Six of the test beams had no web reinforcement and the other six had web reinforcement along the entire length of the beam. Test results indicate that the ACI Building Code predictions of Eq. (11-3) and (11-5) for recycled aggregate concretes are unconservative for beams with a tensile steel ratio of 1.11% and a/d ratios greater than 3.0.
再生骨料混凝土的使用增长速度超过了适当设计建议的发展速度。本文报道了钢筋混凝土再生骨料梁抗剪承载力的有限试验数据。12根梁进行了测试,以确定其对角开裂和极限抗剪能力。试验程序变量为剪跨/深度比a/d = 1.5、2.0、3.0、4.0;聚合类型;抗剪配筋率分别为0、0.089、0.244、0.507、0.823%。6个试验梁没有腹板加固,另外6个沿梁的整个长度有腹板加固。试验结果表明,式(11-3)和式(11-5)对再生骨料混凝土的ACI建筑规范预测对于拉伸钢比为1.11%、a/d比大于3.0的梁是非保守性的。
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引用次数: 59
Recycling of Demolished Concrete 拆卸混凝土的循环再造
S. Nagataki, K. lida
In Japan, it has been predicted that enormous quantities of demolished concrete will be produced in the future. Therefore, a great deal of research is being conducted to find ways to recycle this demolished concrete as concrete aggregate. However, because the characteristics of the original concrete are not well known in many cases, the results are also not clear. Moreover, the recycling of the cement in concrete is also necessary from the standpoint of resolving global environmental problems and achieving sustainable development. This paper describes the properties of the concrete made with recycled aggregates from the original concrete of known quality and the recycling of the cement in concrete as the approach that should be taken in the 21st Century.
在日本,据预测,未来将产生大量的拆除混凝土。因此,人们正在进行大量的研究,寻找回收这些拆除的混凝土作为混凝土骨料的方法。然而,由于在很多情况下对原混凝土的特性不太了解,结果也不清楚。此外,从解决全球环境问题和实现可持续发展的角度来看,混凝土中水泥的回收利用也是必要的。本文介绍了用已知质量的原混凝土再生骨料制成混凝土的性能,以及21世纪混凝土中水泥的再生利用应采取的方法。
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引用次数: 37
Influence of Setting Accelerators on Chemical Shrinkage of Portland Cement 凝结促进剂对硅酸盐水泥化学收缩的影响
F. Clemmens, P. Depuydt, H. Justnes, D. Gemert, E. J. Sellevold
The influence of a number of calcium salts on the total chemical shrinkage (used as a measure of cement hydration) of different portland cement pastes was followed during the first 48 hours. All calcium salts (acetate, chloride, formate, nitrate and nitrite) were added in an equimolar dosage of Ca2+ corresponding to 1.5% calcium nitrate by cement weight. An automatic Vicat-apparatus was used to monitor the setting time of the cement pastes. Experiments conducted at 5 degrees C, 13 degrees C and 23 degrees C revealed that calcium nitrate was the most effective set accelerator at lower temperatures and even more effective than calcium chloride at the lowest temperature. The anions of the different calcium salts were also found to influence the setting and the efficiency of each accelerator strongly depended on the cement types.
研究了不同钙盐对不同硅酸盐水泥膏体前48小时总化学收缩率(作为水泥水化指标)的影响。钙盐(醋酸盐、氯化物盐、甲酸盐、硝酸盐盐和亚硝酸盐盐)的加入量为等摩尔钙,相当于水泥质量中硝酸钙的1.5%。采用全自动维卡仪对水泥浆体的凝结时间进行了监测。在5℃、13℃和23℃下进行的实验表明,硝酸钙在较低温度下是最有效的凝固促进剂,在最低温度下甚至比氯化钙更有效。不同钙盐的阴离子也会影响固相,并且每种促进剂的效率强烈依赖于水泥类型。
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引用次数: 1
Evaluation of Procedures for In Situ Tensile Bond Testing of Concrete Repairs 混凝土修补现场拉伸粘结试验方法评价
J. E. McDonald, A. Vaysburd
To achieve durable repairs, it is usually necessary to ensure adequate bond between the repair and the existing concrete substrate. Tensile bond tests are being increasingly used for quality control/quality assurance testing. However, there has been little standardization of test methods. Consequently, a total of 266 partial-depth cores in 77 experimental repairs were tested to evaluate the effect of material properties and environmental conditions on the bond between nine repair materials and a common concrete substrate. Three pull-off testing devices were used to determine bond strengths for each of the experimental repairs. In addition, the testing devices themselves were evaluated by analyzing the magnitude and relative precision of the pull-off strengths, modes of failure, and ease of use in an effort to identify a reliable and practical device for determining in situ tensile bond. The optimum depth of core drilling into the existing substrate was determined by comparing theoretical finite element analyses of failure stress and location with measured test results.
为了实现持久的修复,通常需要确保修复与现有混凝土基材之间有足够的粘合。拉伸粘结试验越来越多地用于质量控制/质量保证测试。然而,测试方法几乎没有标准化。因此,我们对77个试验修复中的266个部分深度岩心进行了测试,以评估材料性能和环境条件对9种修复材料与普通混凝土基材之间结合的影响。三个拉脱测试装置用于确定每个实验修复的粘结强度。此外,通过分析拉拔强度、失效模式和易用性的大小和相对精度,对测试设备本身进行了评估,以确定一种可靠实用的设备来确定原位拉伸键合。通过对破坏应力和位置的理论有限元分析与实测试验结果进行比较,确定了岩心钻入现有基板的最佳深度。
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引用次数: 0
Counteracting Retardation of Cement Setting By Other Admixtures with Calcium Nitrate 其他硝酸钙外加剂对水泥凝结缓凝的抵消作用
H. Justnes, B. G. Petersen
High dosages of lignosulphonates or super-plasticizing are prohibited by the simultaneous setting retardation. However, the set retardation of lignosulphonates can be counteracted by calcium nitrate without destroying the rheology. Thus, such combinations can be cost-effective alternatives to super-plasticizers. The effect of different calcium nitrate dosages on 5 different lignosulphonates is documented by Fann viscosity, flow resistance and setting time on two different cement pastes. It has also been shown that calcium nitrate is capable of counteracting the effect of strong setting retarders like citric acid, etc. Another application can thus be over-retardation of concrete for long transport from the concrete ready mix plant, followed by activation by adding calcium nitrate to the revolving drum of the concrete truck when arriving at, or being close to, the construction site.
高剂量的木质素磺酸盐或超塑化剂被同时凝结阻滞禁止。然而,木质素磺酸盐的凝结缓凝可以用硝酸钙抵消,而不破坏流变性。因此,这种组合可以是高效增塑剂的成本效益替代品。研究了不同硝酸钙用量对5种不同木质素磺酸盐的影响,通过对两种不同水泥体的范恩粘度、流动阻力和凝结时间进行了表征。研究还表明,硝酸钙能够抵消柠檬酸等强凝结缓凝剂的作用。因此,另一种应用可以是从混凝土搅拌站长途运输的混凝土的过度缓凝,然后在到达或接近施工现场时,通过向混凝土车的旋转滚筒中添加硝酸钙进行活化。
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引用次数: 3
Effects of Ground and Classified Fly Ash on Properties of High-Performance Concrete 磨粒粉煤灰和分级粉煤灰对高性能混凝土性能的影响
M. K. H. Patoary, P. Nimityongskul
The investigation presented in this study shows an example of the improvements of fly ash fineness achieved by a physical process, air-classification and a mechanical process, grinding. To make high-performance concrete, three different types of fly ash namely, original, air-classified, and ground fly ash, with different finenesses was used as cement replacement. The percentage replacement of cement by each type of fly ash was used as 0, 10, 15 and 20% by weight of cementing materials. Finally, the results were compared with silica fume concrete. The results showed that substitution of part of the cement with original or classified fly ash produces concrete mixtures with greater workability than the control as measured by slump and slump-flow. On the contrary, it was found that the ground fly ash, having more or less the same degree of fineness as classified fly ash resulted in a lower workability due to the loss of its spherical shape and lubricant effect. The inclusion of original fly ash reduced the early strength and this reduction was more significant with the increase of percentage replacements. Classified and ground fly ash improved the early strength. The long-term strength development of classified and ground fly ash concrete was found to be considerably higher than that of control concrete for all the percentage replacements.
本研究中提出的调查显示了通过物理过程-空气分级和机械过程-磨矿来改善粉煤灰细度的一个例子。为了制备高性能混凝土,采用不同细度的三种不同类型的粉煤灰,即原始粉煤灰、空气分级粉煤灰和地面粉煤灰作为水泥替代品。每种粉煤灰替代水泥的百分比分别为胶结材料重量的0%、10%、15%和20%。最后,将试验结果与硅灰混凝土进行了比较。结果表明,用原粉煤灰或分级粉煤灰替代部分水泥后,混凝土的和易性比用坍落度和坍落度流动测量的对照混凝土要好。而细度与分级粉煤灰大致相同的地面粉煤灰,由于失去了其球形和润滑作用,其和易性较低。原粉煤灰掺入降低了材料的早期强度,且随着掺入比例的增加,这种降低更为显著。分级和碾磨粉煤灰提高了早期强度。分级粉煤灰混凝土和地面粉煤灰混凝土的长期强度发展在所有替换百分比下都明显高于对照混凝土。
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引用次数: 0
Chloride Diffusion in Reinforced Concrete Beam Under Sustained loading 钢筋混凝土梁在持续荷载作用下的氯离子扩散
A. Castel, O. Francy, R. François, G. Arliguie
The purpose of this paper is to determine the effect of mechanical loading on the transport properties of concrete. The test specimen (B1CL) used for chloride measurement, was a three-meter long reinforced beam kept in a loading state, in a confined salt fog (35 g/l of NaCl) for fourteen years. Because of corrosion of reinforcement, the characterization of mechanical loading was made on another old beam (B1T) cast at the same time but stored in a non-aggressive environment. The measurement of tensile concrete strains using strain gauges showed two parts in the bottom of the beam: the first one is characterized by an elastic behavior and the second one by non-elastic one which is still controlled by the steel reinforcement. Total chloride profiles in relation to the depth were measured in different locations of the tensile zone of reinforced beam B1CL. Until 15 mm depth, the chloride content is constant and corresponds to the maximum chloride content available, taking into account both concrete porosity (where free chloride content corresponds to 35 g/l of NaCl) and concrete binding capacity. Beyond 15 mm depth, total chloride profiles appear to be pure diffusion profiles allowing to calculate the effective diffusion coefficient by using a saturated model of chloride motion taking into account the non-linear binding capacity of concrete. The evolution of effective diffusion coefficient in the beam field (B1CL) is strongly correlated with the field of non-elastic strains in concrete (B1T) and can increase up to 40% in the part of the beam where the non-elastic damage is the more important.
本文的目的是确定机械载荷对混凝土运输性能的影响。用于氯离子测量的试样(B1CL)是一根3米长的钢筋梁,在35 g/l NaCl的密闭盐雾中保持加载状态14年。由于钢筋的腐蚀,机械载荷的表征是在另一个旧梁(B1T)上进行的,同时铸造,但存储在非侵蚀环境中。用应变计测量的混凝土受拉应变显示了梁底部的两部分:第一部分具有弹性行为,第二部分为非弹性行为,仍受钢筋控制。测定了B1CL钢筋梁受拉区不同位置的总氯离子分布与深度的关系。考虑到混凝土孔隙率(其中游离氯含量对应35g /l NaCl)和混凝土的结合体能力,在15mm深度之前,氯含量保持不变,对应于可获得的最大氯含量。超过15mm深度,总氯化物剖面似乎是纯粹的扩散剖面,允许使用氯化物运动的饱和模型计算有效扩散系数,同时考虑到混凝土的非线性结合能力。梁场中有效扩散系数(B1CL)的演化与混凝土中的非弹性应变场(B1T)密切相关,在梁的非弹性损伤较重的部分,有效扩散系数可增加40%。
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引用次数: 11
Old and New Coatings Against Chloride Ingress in Concrete 防止混凝土中氯化物侵入的新旧涂料
J. Beslać, K. Mavar
The results of laboratory and in situ tests of a number of different types of coatings commercially available in Croatia (polymer-cement, epoxy, acrylic, epoxy-acrylic and epoxy-polyurethane), used for reinforced concrete protection of the KRK bridge, are presented. The tests have been carried out throughout the last ten years. Some coatings like epoxy and polymer-cement were found completely unacceptable for technical reasons. However, epoxy-polyurethane coatings applied on the concrete finished with a thin layer of epoxy-cement mortar are estimated rather effective. They had high adhesion strength (above 2.0 MPa), very low gas permeability, low capillary absorption, satisfactory water vapor diffusion and satisfactory aging resistance.
介绍了克罗地亚市售的用于KRK大桥钢筋混凝土保护的若干不同类型涂料(聚合物水泥、环氧树脂、丙烯酸、环氧树脂-丙烯酸和环氧树脂-聚氨酯)的实验室和现场试验结果。这些试验在过去十年中一直在进行。由于技术原因,一些涂料如环氧树脂和聚合物水泥被发现完全不能接受。然而,环氧聚氨酯涂料应用于混凝土完成与环氧水泥砂浆薄层估计相当有效。具有较高的粘接强度(2.0 MPa以上)、极低的透气性、较低的毛细吸收率、良好的水蒸气扩散性能和良好的耐老化性能。
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引用次数: 0
期刊
"SP-200: Fifth CANMET/ACI Conference on Recent Advances in Concrete Technology-Proceeding, Fifth International Conference"
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