Pub Date : 2022-12-22DOI: 10.3390/agrochemicals2010001
R. Schmidt, B. Spangl, Edith Gruber, E. Takács, M. Mörtl, Szandra Klátyik, A. Székács, J. Zaller
Little is known about the non-target effects of glyphosate active ingredients (GLY) versus glyphosate-based herbicide (GBH) formulations on soil organisms, and whether effects are influenced by environmental conditions. We investigated the avoidance behavior, biomass growth, and reproduction of earthworms (Eisenia fetida, E. andrei) in response to two GLYs (glyphosate ammonium and potassium salt), the corresponding GBHs (Touchdown Quattro, Roundup PowerFlex) containing these GLYs, and the “inert” co-formulant alkylpolyglycoside (APG) at two temperature (15 °C vs. 20 °C) and soil organic matter levels (3.2% vs. 4.3%). Earthworm avoidance was lower at high soil organic matter content, but remained unaffected by substances and temperature. Earthworm biomass growth and reproduction (cocoons and juveniles) were significantly affected by substances and temperature; reproduction was also affected by a substance and temperature interaction. Biomass growth was almost zero at higher temperature; reproduction was generally higher at higher temperature. More cocoons were produced under Roundup PowerFlex than under the corresponding AI, due to the impact of the co-formulant APG. No other differences were observed between GBH and the corresponding AIs. We conclude that the non-target effects of pesticides can only be fully assessed if all ingredients in a formulation are known and environmental parameters are included in environmental risk assessments.
关于草甘膦活性成分(GLY)与草甘膦基除草剂(GBH)制剂对土壤生物的非靶标效应，以及这种效应是否受到环境条件的影响，人们知之甚少。研究了蚯蚓(Eisenia fetida, E. andrei)在不同温度(15°C vs. 20°C)和土壤有机质水平(3.2% vs. 4.3%)下对两种GLYs(草甘膦铵和钾盐)、相应的GBHs (Touchdown Quattro, Roundup PowerFlex)以及“惰性”共配方剂烷基聚糖苷(APG)的回避行为、生物量增长和繁殖的响应。土壤有机质含量高时，蚯蚓的避虫率较低，但不受物质和温度的影响。物质和温度对蚯蚓生物量(茧和幼虫)的生长和繁殖有显著影响;繁殖也受到物质和温度相互作用的影响。在较高温度下，生物量几乎为零;温度越高，繁殖能力越强。由于共配方APG的影响，使用农达PowerFlex的茧比使用相应AI的茧多。在GBH和相应的AIs之间没有观察到其他差异。我们的结论是，只有在配方中的所有成分都已知并且环境参数包括在环境风险评估中时，才能充分评估农药的非目标效应。
{"title":"Glyphosate Effects on Earthworms: Active Ingredients vs. Commercial Herbicides at Different Temperature and Soil Organic Matter Levels","authors":"R. Schmidt, B. Spangl, Edith Gruber, E. Takács, M. Mörtl, Szandra Klátyik, A. Székács, J. Zaller","doi":"10.3390/agrochemicals2010001","DOIUrl":"https://doi.org/10.3390/agrochemicals2010001","url":null,"abstract":"Little is known about the non-target effects of glyphosate active ingredients (GLY) versus glyphosate-based herbicide (GBH) formulations on soil organisms, and whether effects are influenced by environmental conditions. We investigated the avoidance behavior, biomass growth, and reproduction of earthworms (Eisenia fetida, E. andrei) in response to two GLYs (glyphosate ammonium and potassium salt), the corresponding GBHs (Touchdown Quattro, Roundup PowerFlex) containing these GLYs, and the “inert” co-formulant alkylpolyglycoside (APG) at two temperature (15 °C vs. 20 °C) and soil organic matter levels (3.2% vs. 4.3%). Earthworm avoidance was lower at high soil organic matter content, but remained unaffected by substances and temperature. Earthworm biomass growth and reproduction (cocoons and juveniles) were significantly affected by substances and temperature; reproduction was also affected by a substance and temperature interaction. Biomass growth was almost zero at higher temperature; reproduction was generally higher at higher temperature. More cocoons were produced under Roundup PowerFlex than under the corresponding AI, due to the impact of the co-formulant APG. No other differences were observed between GBH and the corresponding AIs. We conclude that the non-target effects of pesticides can only be fully assessed if all ingredients in a formulation are known and environmental parameters are included in environmental risk assessments.","PeriodicalId":18608,"journal":{"name":"Modern Agrochemicals","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-12-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84244365","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-12-16DOI: 10.3390/agrochemicals1010005
Á. Ambrus, J. Szenczi-Cseh, Vy Vy N. Doan, Zsuzsanna Domák, Tímea Gönczöl, Anna Lörincz, Gabriella Miklós, A. Nagy, Henriet Szemánné-Dobrik, A. Vásárhelyi
The development of quality requirements for the analyses of chemical contaminants is reviewed from the formation of the first association of analytical chemists in 1884. Without attempting to give complete coverage, it is shown that the elaboration of quality systems is commanded by the needs of the industry and international trade. Progress along the line of the initial inter-laboratory comparison, methods validated with collaborative tests, and development of internationally harmonized guidelines and protocols to perform complex studies aiming to improve the accuracy and reliability of the results facilitate international trade, and protect consumer health, as well as the environment. The international cooperation for limiting the replication of various (e.g., analytical, toxicological) tests is promoted by multilateral agreements that are also supported by legal obligations. Notwithstanding, the rapid development of requirements and guidance documents provides only the frame for obtaining accurate, defendable results. The production of such results is the duty of the laboratory management, analysts, and study personnel who play the decisive role and bear full responsibility for the samples analyzed.
{"title":"Development of Quality Requirements of Chemical Analytical Measurements","authors":"Á. Ambrus, J. Szenczi-Cseh, Vy Vy N. Doan, Zsuzsanna Domák, Tímea Gönczöl, Anna Lörincz, Gabriella Miklós, A. Nagy, Henriet Szemánné-Dobrik, A. Vásárhelyi","doi":"10.3390/agrochemicals1010005","DOIUrl":"https://doi.org/10.3390/agrochemicals1010005","url":null,"abstract":"The development of quality requirements for the analyses of chemical contaminants is reviewed from the formation of the first association of analytical chemists in 1884. Without attempting to give complete coverage, it is shown that the elaboration of quality systems is commanded by the needs of the industry and international trade. Progress along the line of the initial inter-laboratory comparison, methods validated with collaborative tests, and development of internationally harmonized guidelines and protocols to perform complex studies aiming to improve the accuracy and reliability of the results facilitate international trade, and protect consumer health, as well as the environment. The international cooperation for limiting the replication of various (e.g., analytical, toxicological) tests is promoted by multilateral agreements that are also supported by legal obligations. Notwithstanding, the rapid development of requirements and guidance documents provides only the frame for obtaining accurate, defendable results. The production of such results is the duty of the laboratory management, analysts, and study personnel who play the decisive role and bear full responsibility for the samples analyzed.","PeriodicalId":18608,"journal":{"name":"Modern Agrochemicals","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-12-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82342179","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-10-11DOI: 10.3390/agrochemicals1010004
C. Athanassiou, M. Sakka
Nitrogen treatment can be used as an alternative method to chemical control. Most of the research on nitrogen treatment mainly investigated the optimum concentration of oxygen level as well as duration as a means of insect control. Other parameters such as temperature and different insect species have been extensively studied and recent research focus on the modelling of nitrogen concentration and the efficacy on commodity. In this paper, we briefly review the major parameters (temperature, oxygen level, relative humidity, exposure time) using nitrogen treatment against stored product insects. Exposure to different oxygen levels or different exposure times can remarkably change pest control mortality. Moreover, different insect species and life stages have differing susceptibility to nitrogen treatment. Finally, these studies are reviewed in this paper to illustrate that nitrogen treatment can be used as a part of an IPM strategy.
{"title":"Using Nitrogen for the Control of Stored Product Insects: One Single Application for Multiple Purposes","authors":"C. Athanassiou, M. Sakka","doi":"10.3390/agrochemicals1010004","DOIUrl":"https://doi.org/10.3390/agrochemicals1010004","url":null,"abstract":"Nitrogen treatment can be used as an alternative method to chemical control. Most of the research on nitrogen treatment mainly investigated the optimum concentration of oxygen level as well as duration as a means of insect control. Other parameters such as temperature and different insect species have been extensively studied and recent research focus on the modelling of nitrogen concentration and the efficacy on commodity. In this paper, we briefly review the major parameters (temperature, oxygen level, relative humidity, exposure time) using nitrogen treatment against stored product insects. Exposure to different oxygen levels or different exposure times can remarkably change pest control mortality. Moreover, different insect species and life stages have differing susceptibility to nitrogen treatment. Finally, these studies are reviewed in this paper to illustrate that nitrogen treatment can be used as a part of an IPM strategy.","PeriodicalId":18608,"journal":{"name":"Modern Agrochemicals","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-10-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80301377","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-09-16DOI: 10.3390/agrochemicals1010002
Emma E. Leaseburg, Li-guo Lei, L. Fink
Mitigating climate change and enhancing fertility in agricultural systems require the adoption of more sustainable fertilizer management practices. Applications of recycled organic materials, such as animal and green wastes, can promote soil carbon stabilization via changing extracellular enzyme activities while providing the necessary nitrogen (N) for plant growth. The goals of this study were to quantify the effects of compost type (cow manure, green manures, mixtures of green and cow manure at various proportions, and inorganic fertilizers) on (1) enzyme activity (phenol oxidase, peroxidase, and urease), and (2) mineralized N under laboratory incubation at 30 °C over an eight-week period. The lowest oxidative enzyme activities (phenol oxidase and peroxidase) were found in the soil treated with a mixture of 50% cow manure and 50% green manure (2.45 μmol h−1 g−1) and a mixture of 30% cow manure and 70% green manure (3.21 μmol h−1 g−1) compared to all other fertilizer treatments. The highest phenol oxidase activity was found in soils amended with green manures (3.52 μmol h−1 g−1), while the highest peroxidase activity was found in soils amended with a mixture of 70% cow manure and 30% green manure (5.68 μmol h−1 g−1). No significant differences were found in total net mineralized N content among all organic fertilizer treatments, but these were significantly lower than total net mineralized N in soil treated with inorganic fertilizers. These results indicate similar effects of organic amendments and mixtures in providing plant-available N, but different effects on lignin-degrading enzyme activities, which may lead to differences in soil organic carbon cycling and long-term C storage depending on which organic amendment is utilized.
{"title":"Effects of Organic Amendments on Phenol Oxidase, Peroxidase, Urease, and Nitrogen Mineralization: A Laboratory Incubation Study","authors":"Emma E. Leaseburg, Li-guo Lei, L. Fink","doi":"10.3390/agrochemicals1010002","DOIUrl":"https://doi.org/10.3390/agrochemicals1010002","url":null,"abstract":"Mitigating climate change and enhancing fertility in agricultural systems require the adoption of more sustainable fertilizer management practices. Applications of recycled organic materials, such as animal and green wastes, can promote soil carbon stabilization via changing extracellular enzyme activities while providing the necessary nitrogen (N) for plant growth. The goals of this study were to quantify the effects of compost type (cow manure, green manures, mixtures of green and cow manure at various proportions, and inorganic fertilizers) on (1) enzyme activity (phenol oxidase, peroxidase, and urease), and (2) mineralized N under laboratory incubation at 30 °C over an eight-week period. The lowest oxidative enzyme activities (phenol oxidase and peroxidase) were found in the soil treated with a mixture of 50% cow manure and 50% green manure (2.45 μmol h−1 g−1) and a mixture of 30% cow manure and 70% green manure (3.21 μmol h−1 g−1) compared to all other fertilizer treatments. The highest phenol oxidase activity was found in soils amended with green manures (3.52 μmol h−1 g−1), while the highest peroxidase activity was found in soils amended with a mixture of 70% cow manure and 30% green manure (5.68 μmol h−1 g−1). No significant differences were found in total net mineralized N content among all organic fertilizer treatments, but these were significantly lower than total net mineralized N in soil treated with inorganic fertilizers. These results indicate similar effects of organic amendments and mixtures in providing plant-available N, but different effects on lignin-degrading enzyme activities, which may lead to differences in soil organic carbon cycling and long-term C storage depending on which organic amendment is utilized.","PeriodicalId":18608,"journal":{"name":"Modern Agrochemicals","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-09-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77029142","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-08-08DOI: 10.3390/agrochemicals1010001
C. Athanassiou
Agrochemicals in Contemporary Agriculture [...]
现代农业中的农用化学品[…]
{"title":"Agrochemicals—Shifting from the Past to the Future with a New Journal","authors":"C. Athanassiou","doi":"10.3390/agrochemicals1010001","DOIUrl":"https://doi.org/10.3390/agrochemicals1010001","url":null,"abstract":"Agrochemicals in Contemporary Agriculture [...]","PeriodicalId":18608,"journal":{"name":"Modern Agrochemicals","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-08-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84599268","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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