Pub Date : 2023-10-18DOI: 10.1080/15421406.2023.2262858
A. Tymoshyk, A. Martynes-Harsiia, N. Iukhymenko, A. Kolendo
AbstractIn this work for the creation of polymers of special purpose six new quinolin-6-yl-phenylmethacrylates were synthesized by acylation of 3- and 4-hydroxyphenylquinolines with methacrylic acid chloroanhydride. The structure of the synthesized compounds was proved by spectral methods. The effect of new monomers as dopands on the polystyrene destruction was investigated. It was found that the investigated additives at covalent introduction into polystyrene weakly inhibit the process of its destruction, and additives containing nitro group - even contribute to its accelerated destruction.Keywords: Methacrylic monomerspolystyrene destructionquinolin-containing monomers and polymers Disclosure statementNo potential conflict of interest was reported by the author(s).
{"title":"Synthesis of new methacrylates based on 6-phenylquinoline and their effect on the thermal degradation of polystyrene","authors":"A. Tymoshyk, A. Martynes-Harsiia, N. Iukhymenko, A. Kolendo","doi":"10.1080/15421406.2023.2262858","DOIUrl":"https://doi.org/10.1080/15421406.2023.2262858","url":null,"abstract":"AbstractIn this work for the creation of polymers of special purpose six new quinolin-6-yl-phenylmethacrylates were synthesized by acylation of 3- and 4-hydroxyphenylquinolines with methacrylic acid chloroanhydride. The structure of the synthesized compounds was proved by spectral methods. The effect of new monomers as dopands on the polystyrene destruction was investigated. It was found that the investigated additives at covalent introduction into polystyrene weakly inhibit the process of its destruction, and additives containing nitro group - even contribute to its accelerated destruction.Keywords: Methacrylic monomerspolystyrene destructionquinolin-containing monomers and polymers Disclosure statementNo potential conflict of interest was reported by the author(s).","PeriodicalId":18758,"journal":{"name":"Molecular Crystals and Liquid Crystals","volume":"153 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135885215","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-10-13DOI: 10.1080/15421406.2023.2267381
Kyoka Komaba, Takuya Yonehara, Mai Ichikawa, Hiromasa Goto
AbstractAn amphotropic liquid crystal polyacetylene derivative with pyrimidine–type two-ringed mesogenic core, exhibiting both thermotropic and lyotropic liquid crystallinity, was synthesized in this study. The polyacetylene derivative showed a lyotropic liquid crystal in d-limonene. The cis configuration of the main chain was confirmed via 1H NMR. Heat treatment induced cis–trans isomerization of the as-prepared polymer. Gas-phase iodine doping of the polymer initiated a chemical interaction between the polyene and iodine, acting as an electron acceptor, generating charge carriers (radical cations, solitons) detected with the electron spin resonance spectroscopy. Moreover, gas phase doping of the polymer induced cis–trans isomerization.Keywords: Amphotropic liquid crystald-limoneneelectrodopantelectron spin resonancemono-substituted polyacetylene AcknowledgmentsWe would like to thank the Open Facility, Research Facility Center for Science and Technology, University of Tsukuba for NMR and DSC measurements, as well as the Glass Workshop of the University of Tsukuba. P–009 as a mesogenic core material was kindly gifted by Midori Kagaku Co. (Midori Chemical Industry, Tokyo, Japan).Disclosure statementNo potential conflict of interest was reported by the author(s).Additional informationFundingThis work was supported by JST, the establishment of University fellowships toward the creation of science technology innovation (JPMJFS2106, K. Komaba); JST SPRING (JPMJSP2124, T. Yonehara); and Japan Society for the Promotion of Science (JSPS), Grants-in-Aid for Scientific Research (No. 20K05626, H. Goto).
摘要合成了一种具有热致性和溶致性的双相液晶聚乙炔衍生物，该衍生物具有嘧啶型双环介晶核。聚乙炔衍生物在d-柠檬烯中表现为溶致液晶。主链的顺式构型经1H NMR确证。热处理引起所制备的聚合物的顺反异构化。聚合物的气相碘掺杂引发了多烯和碘之间的化学相互作用，作为电子受体，产生电子自旋共振光谱检测到的载流子(自由基阳离子，孤子)。此外，聚合物的气相掺杂诱导了顺反异构化。关键词:两性液晶-柠檬烯-电掺杂-电子自旋共振-单取代聚乙炔致谢我们要感谢筑波大学开放设施，科学技术研究设施中心，筑波大学的核磁共振和DSC测量，以及筑波大学玻璃车间。P-009为介生核芯材料，由日本光理化学株式会社(日本东京光理化学工业)赠予。披露声明作者未报告潜在的利益冲突。本研究得到了JST的支持，建立了面向科技创新创造的大学奖学金(JPMJFS2106, K. Komaba);JST SPRING (JPMJSP2124, T. Yonehara);日本科学促进会(JSPS)科学研究资助项目(20K05626, H. Goto)。
{"title":"Amphotropic liquid crystal polyacetylene derivative bearing pyrimidine type mesogen","authors":"Kyoka Komaba, Takuya Yonehara, Mai Ichikawa, Hiromasa Goto","doi":"10.1080/15421406.2023.2267381","DOIUrl":"https://doi.org/10.1080/15421406.2023.2267381","url":null,"abstract":"AbstractAn amphotropic liquid crystal polyacetylene derivative with pyrimidine–type two-ringed mesogenic core, exhibiting both thermotropic and lyotropic liquid crystallinity, was synthesized in this study. The polyacetylene derivative showed a lyotropic liquid crystal in d-limonene. The cis configuration of the main chain was confirmed via 1H NMR. Heat treatment induced cis–trans isomerization of the as-prepared polymer. Gas-phase iodine doping of the polymer initiated a chemical interaction between the polyene and iodine, acting as an electron acceptor, generating charge carriers (radical cations, solitons) detected with the electron spin resonance spectroscopy. Moreover, gas phase doping of the polymer induced cis–trans isomerization.Keywords: Amphotropic liquid crystald-limoneneelectrodopantelectron spin resonancemono-substituted polyacetylene AcknowledgmentsWe would like to thank the Open Facility, Research Facility Center for Science and Technology, University of Tsukuba for NMR and DSC measurements, as well as the Glass Workshop of the University of Tsukuba. P–009 as a mesogenic core material was kindly gifted by Midori Kagaku Co. (Midori Chemical Industry, Tokyo, Japan).Disclosure statementNo potential conflict of interest was reported by the author(s).Additional informationFundingThis work was supported by JST, the establishment of University fellowships toward the creation of science technology innovation (JPMJFS2106, K. Komaba); JST SPRING (JPMJSP2124, T. Yonehara); and Japan Society for the Promotion of Science (JSPS), Grants-in-Aid for Scientific Research (No. 20K05626, H. Goto).","PeriodicalId":18758,"journal":{"name":"Molecular Crystals and Liquid Crystals","volume":"35 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135859123","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-10-13DOI: 10.1080/15421406.2023.2269749
Hong-Yao Shen, Xin-Ru Yang, Jia-Cheng Zhu, Rui-Peng Yang, Zheng-Fang Wang, Jun Li, Bo Zhang
AbstractIn recent years, organic-inorganic hybrid iodoargentates have suffered extensive research attention due to their rich structures and unique optical and semiconductor properties. In this article, using 4,4'-dbbpy (4,4'-dbbpy = 4,4'-dibromo-2,2-bipyridine) and 5,5'-dbbpy (5,5'-dbbpy = 5,5'-dibromo-2,2-bipyridine) ligands as structural modifiers, two new iodoargentate hybrids, namely [Ni(4,4'-dbbpy)3]AgI3 (1) and [Ni(5,5'-dbbpy)3]Ag2I4 (2) have been successfully constructed, which are then structurally, optically and theoretically studied. Compounds 1 and 2 have optical band gaps at 2.45 and 2.56 eV, displaying visible light responding photocurrent intensities of 0.26 and 0.47 μA·cm−2, respectively. Additionally, the Hirshfeld surface analyses and density of states have also been investigated.Keywords: Crystal structureiodoargentateoptical propertytheoretical calculation Disclosure statementNo potential conflict of interest was reported by the author(s).Additional informationFundingWe sincerely express our thanks for the financial support from Natural Science Foundation of Shandong Province [ZR2019BB074, ZR2018LB001].
{"title":"Two iodoargentate hybrids: syntheses, crystal structures, photocurrent responses and theoretical studies","authors":"Hong-Yao Shen, Xin-Ru Yang, Jia-Cheng Zhu, Rui-Peng Yang, Zheng-Fang Wang, Jun Li, Bo Zhang","doi":"10.1080/15421406.2023.2269749","DOIUrl":"https://doi.org/10.1080/15421406.2023.2269749","url":null,"abstract":"AbstractIn recent years, organic-inorganic hybrid iodoargentates have suffered extensive research attention due to their rich structures and unique optical and semiconductor properties. In this article, using 4,4'-dbbpy (4,4'-dbbpy = 4,4'-dibromo-2,2-bipyridine) and 5,5'-dbbpy (5,5'-dbbpy = 5,5'-dibromo-2,2-bipyridine) ligands as structural modifiers, two new iodoargentate hybrids, namely [Ni(4,4'-dbbpy)3]AgI3 (1) and [Ni(5,5'-dbbpy)3]Ag2I4 (2) have been successfully constructed, which are then structurally, optically and theoretically studied. Compounds 1 and 2 have optical band gaps at 2.45 and 2.56 eV, displaying visible light responding photocurrent intensities of 0.26 and 0.47 μA·cm−2, respectively. Additionally, the Hirshfeld surface analyses and density of states have also been investigated.Keywords: Crystal structureiodoargentateoptical propertytheoretical calculation Disclosure statementNo potential conflict of interest was reported by the author(s).Additional informationFundingWe sincerely express our thanks for the financial support from Natural Science Foundation of Shandong Province [ZR2019BB074, ZR2018LB001].","PeriodicalId":18758,"journal":{"name":"Molecular Crystals and Liquid Crystals","volume":"25 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135858066","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-10-12DOI: 10.1080/15421406.2023.2266636
Kyoka Komaba, Tomoaki Jo, Hiromasa Goto
AbstractIn this research, we report the synthesis of conjugated polymers with magnetism. Electrochemical polymerization in liquid crystal was conducted with 1-butyl-3-methylimidazolium tetrachloroferrate (BMITF), which is a paramagnetic character having a large magnetic susceptibility, as a supporting salt. The polymer films thus obtained had magnetism because BMITF remains in the films as a dopant. Poly(2,2′-bithiophene) and poly(bis-(3,4-ethylenedioxythiophene)) were prepared in nematic or cholesteric liquid crystal with BMITF by electrochemical polymerization. Transcription of the liquid crystal structure was succeeded with a small amount of BMITF. Blush or fingerprint structures were confirmed by polarizing optical microscopy observation. The addition of the excess amount of BMITF broke the structure of the liquid crystal. Poly(2,2′-bithiophene) transcribed the cholesteric liquid crystal structure showed a negative Cotton effect, indicating with left-handed helical structure. Poly(bis-(3,4-ethylenedioxythiophene)) transcribed the cholesteric liquid crystal structure showed a positive Cotton effect, indicating the polymer forms a right-handed helical structure. The X-ray photoelectron spectroscopy measurements, confirming the existence of Fe element in the polymers thus obtained. From the electron spin resonance measurements, the polymers thus obtained showed magnetic activity. This method affords facile synthesis of conjugated polymers with magnetism.Keywords: Conjugated polymerselectrochemical polymerizationferromagnetismionic liquidliquid crystalmagnetic dopant Disclosure statementNo potential conflict of interest was reported by the author(s).Additional informationFundingThis work was supported by JST, the establishment of university fellowships toward the creation of science technology innovation, Grant Number JPMJFS2106 and Japan Society for the Promotion of Science (JSPS), Grants-in-Aid for Scientific Research (No. 20K05626).
{"title":"Preparation of magneto-electro-optically active polymer using Fe ionic liquid as electro-magnetic dopant","authors":"Kyoka Komaba, Tomoaki Jo, Hiromasa Goto","doi":"10.1080/15421406.2023.2266636","DOIUrl":"https://doi.org/10.1080/15421406.2023.2266636","url":null,"abstract":"AbstractIn this research, we report the synthesis of conjugated polymers with magnetism. Electrochemical polymerization in liquid crystal was conducted with 1-butyl-3-methylimidazolium tetrachloroferrate (BMITF), which is a paramagnetic character having a large magnetic susceptibility, as a supporting salt. The polymer films thus obtained had magnetism because BMITF remains in the films as a dopant. Poly(2,2′-bithiophene) and poly(bis-(3,4-ethylenedioxythiophene)) were prepared in nematic or cholesteric liquid crystal with BMITF by electrochemical polymerization. Transcription of the liquid crystal structure was succeeded with a small amount of BMITF. Blush or fingerprint structures were confirmed by polarizing optical microscopy observation. The addition of the excess amount of BMITF broke the structure of the liquid crystal. Poly(2,2′-bithiophene) transcribed the cholesteric liquid crystal structure showed a negative Cotton effect, indicating with left-handed helical structure. Poly(bis-(3,4-ethylenedioxythiophene)) transcribed the cholesteric liquid crystal structure showed a positive Cotton effect, indicating the polymer forms a right-handed helical structure. The X-ray photoelectron spectroscopy measurements, confirming the existence of Fe element in the polymers thus obtained. From the electron spin resonance measurements, the polymers thus obtained showed magnetic activity. This method affords facile synthesis of conjugated polymers with magnetism.Keywords: Conjugated polymerselectrochemical polymerizationferromagnetismionic liquidliquid crystalmagnetic dopant Disclosure statementNo potential conflict of interest was reported by the author(s).Additional informationFundingThis work was supported by JST, the establishment of university fellowships toward the creation of science technology innovation, Grant Number JPMJFS2106 and Japan Society for the Promotion of Science (JSPS), Grants-in-Aid for Scientific Research (No. 20K05626).","PeriodicalId":18758,"journal":{"name":"Molecular Crystals and Liquid Crystals","volume":"171 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135969263","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-10-12DOI: 10.1080/15421406.2023.2262299
K. Pomorski, B. Stojewski
AbstractHybrid Schrödinger-Ginzburg-Landau approach is based on the fact of the mathematical similarity of Ginzburg-Landau (GL) and Schrödinger formalisms. Starting from Schrödinger approach by replacing the term V (x)−E with the term α(x)+β(x)|ψ(x)|2 we get the Ginzburg-Landau equation. In the proposed relaxation algorithm, we use one- and two-dimensional ground energy solutions of the Schrödinger equation and apply them as a starting trial solution for the GL relaxation method. The obtained numerical results and used methodology form the basis of the simulation platform for studying superconducting integrated structures and modeling various superconducting devices, including their time-dependent geometry.Keywords: Ginzburg-Landaurelaxation methodsuperconductivitysuperconducting integrated structures Disclosure statementNo potential conflict of interest was reported by the author(s).
{"title":"Hybrid Schrödinger-Ginzburg-Landau (Sch-GL) approach to study of superconducting integrated structures","authors":"K. Pomorski, B. Stojewski","doi":"10.1080/15421406.2023.2262299","DOIUrl":"https://doi.org/10.1080/15421406.2023.2262299","url":null,"abstract":"AbstractHybrid Schrödinger-Ginzburg-Landau approach is based on the fact of the mathematical similarity of Ginzburg-Landau (GL) and Schrödinger formalisms. Starting from Schrödinger approach by replacing the term V (x)−E with the term α(x)+β(x)|ψ(x)|2 we get the Ginzburg-Landau equation. In the proposed relaxation algorithm, we use one- and two-dimensional ground energy solutions of the Schrödinger equation and apply them as a starting trial solution for the GL relaxation method. The obtained numerical results and used methodology form the basis of the simulation platform for studying superconducting integrated structures and modeling various superconducting devices, including their time-dependent geometry.Keywords: Ginzburg-Landaurelaxation methodsuperconductivitysuperconducting integrated structures Disclosure statementNo potential conflict of interest was reported by the author(s).","PeriodicalId":18758,"journal":{"name":"Molecular Crystals and Liquid Crystals","volume":"90 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135969426","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-10-04DOI: 10.1080/15421406.2023.2262857
Cuiping Wang, Wenwen Sheng, Chen Sun, Jie Lei, Jinsong Hu
AbstractIn this paper, a new three-dimensional network coordination polymer {[Co(TPTC)(HBPDPE)2·2H2O]·3H2O}n [[[(1:1′:4′,1″-terphenyl)-3,3″,5,5″-tetracarboxylic cobalt (II)] dipyridine dihydrate] trihydrate] (Complex 1) was generated under solvothermal synthesis by rigid conjugated ligand H4TPTC ([1:1′:4′,1″-terphengl]-3,3″,5,5″-tetracarboxylic), V-shaped BPDPE (4,4′-bis (pyridyl) diphenyl ether) and Co(II) ion. In complex 1, the neighboring Co(II) ions are linked by deprotonated TPTC4- to achieve a 1D zigzag chain [Co(TPTC)(HBPDPE)2]n, then the adjacent [Co(TPTC)(HBPDPE)2]n chains linked each other by various H-bondings to extend the structure from 1D chain to 3D network. Complex 1 has excellent fluorescence sensing performance and exhibits high sensitivity and selectivity for detecting 2,4,6-trinitrophenol (TNP), the quenching constant Ksv is up to 2.08 × 105 M−1 along with the correlation coefficient R2 of 0.993. Furthermore, the quench mechanisms of this Co-MOF as a sensor to detect nitro- aromatic explosives were studied as well.A new three-dimensional coordination polymer {[Co(TPTC)(HBPDPE)2·2H2O]·3H2O}n (1), constructed by 1D zigzag chains and H-bondings interactions, was synthesized under solvothermal condition by a rigid conjugated ligand H4TPTC ([1:1′:4′,1″-terphengl]-3,3″,5,5″-tetracarboxylic), BPDPE (4,4′-bis (pyridyl) diphenyl) and Co(II) ion. Complex 1 has excellent fluorescence sensing performance for detecting Nitroaromatic explosive (NAE) 2,4,6-trinitrophenol (TNP), the quenching constant Ksv is up to 2.08 × 105 M−1, and the quenching mechanism was studied as well.Keywords: Coordination polymercrystal structureluminescent sensingnitroaromatic explosives Author contribution statementCuiping Wang: Collecting experimental data, Writing-original draft. WenWen Sheng: Writing-review & editing. Chen Sun: Collecting experimental data. Jie Lei: Collecting experimental data. JinSong Hu: Conceptualization, Writing-review & editing, Supervision.Data availabilityData will be made available on request.Disclosure statementNo potential conflict of interest was reported by the author(s).Additional informationFundingThis work thanks to the fund support of the Natural Science Foundation of China (No. 21671004) and the Key Project of Natural Science Research for Colleges and Universities of Anhui Province (KJ2020A0958), CCDC: 2165480
{"title":"A cobalt-coordination polymer as a highly selective and sensitive luminescent sensor for detecting 2,4,6-trinitrophenol","authors":"Cuiping Wang, Wenwen Sheng, Chen Sun, Jie Lei, Jinsong Hu","doi":"10.1080/15421406.2023.2262857","DOIUrl":"https://doi.org/10.1080/15421406.2023.2262857","url":null,"abstract":"AbstractIn this paper, a new three-dimensional network coordination polymer {[Co(TPTC)(HBPDPE)2·2H2O]·3H2O}n [[[(1:1′:4′,1″-terphenyl)-3,3″,5,5″-tetracarboxylic cobalt (II)] dipyridine dihydrate] trihydrate] (Complex 1) was generated under solvothermal synthesis by rigid conjugated ligand H4TPTC ([1:1′:4′,1″-terphengl]-3,3″,5,5″-tetracarboxylic), V-shaped BPDPE (4,4′-bis (pyridyl) diphenyl ether) and Co(II) ion. In complex 1, the neighboring Co(II) ions are linked by deprotonated TPTC4- to achieve a 1D zigzag chain [Co(TPTC)(HBPDPE)2]n, then the adjacent [Co(TPTC)(HBPDPE)2]n chains linked each other by various H-bondings to extend the structure from 1D chain to 3D network. Complex 1 has excellent fluorescence sensing performance and exhibits high sensitivity and selectivity for detecting 2,4,6-trinitrophenol (TNP), the quenching constant Ksv is up to 2.08 × 105 M−1 along with the correlation coefficient R2 of 0.993. Furthermore, the quench mechanisms of this Co-MOF as a sensor to detect nitro- aromatic explosives were studied as well.A new three-dimensional coordination polymer {[Co(TPTC)(HBPDPE)2·2H2O]·3H2O}n (1), constructed by 1D zigzag chains and H-bondings interactions, was synthesized under solvothermal condition by a rigid conjugated ligand H4TPTC ([1:1′:4′,1″-terphengl]-3,3″,5,5″-tetracarboxylic), BPDPE (4,4′-bis (pyridyl) diphenyl) and Co(II) ion. Complex 1 has excellent fluorescence sensing performance for detecting Nitroaromatic explosive (NAE) 2,4,6-trinitrophenol (TNP), the quenching constant Ksv is up to 2.08 × 105 M−1, and the quenching mechanism was studied as well.Keywords: Coordination polymercrystal structureluminescent sensingnitroaromatic explosives Author contribution statementCuiping Wang: Collecting experimental data, Writing-original draft. WenWen Sheng: Writing-review & editing. Chen Sun: Collecting experimental data. Jie Lei: Collecting experimental data. JinSong Hu: Conceptualization, Writing-review & editing, Supervision.Data availabilityData will be made available on request.Disclosure statementNo potential conflict of interest was reported by the author(s).Additional informationFundingThis work thanks to the fund support of the Natural Science Foundation of China (No. 21671004) and the Key Project of Natural Science Research for Colleges and Universities of Anhui Province (KJ2020A0958), CCDC: 2165480","PeriodicalId":18758,"journal":{"name":"Molecular Crystals and Liquid Crystals","volume":"38 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135591781","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
AbstractFe3O4-Au hybrid nanostructures combining magnetic and plasmonic properties based on nanomagnetite and Au nanocrystals have been synthesized and characterized. The SEIRA and SERS signal enhancement of Glycine adsorbed on these hybrid nanostructures was obtained. It is shown that different molecular groups of Glycine are enhanced in different ways, depending on the type of interaction and the orientation of the molecule relative to the surface. According to the results of the research, the obtained Fe3O4-Au nanohybrids have the properties of plasmonic metals, while retaining ferromagnetic properties and have great potential as substrates for surface-enhanced vibration spectroscopy in trace analysis.Keywords: Fe3O4-AuFTIR spectroscopyRAMAN spectroscopyGlyFe3O4-Au-Gly AcknowledgmentsAuthors thanks the National Academy of Sciences of Ukraine and the grant PH/23-2023 “Influence of size effects on the electrophysical properties of graphene ferroelectric nanostructures” of the Ministry of Education and Science of Ukraine for their support.Disclosure statementNo potential conflict of interest was reported by the author(s).
{"title":"Fe <sub>3</sub> O <sub>4</sub> -Au nanohybrids as novel SEIRA and SERS substrate for Glycine detection","authors":"Maxim Rallev, Olena Fesenko, Andrii Yaremkevych, Olena Lavrynenko","doi":"10.1080/15421406.2023.2260077","DOIUrl":"https://doi.org/10.1080/15421406.2023.2260077","url":null,"abstract":"AbstractFe3O4-Au hybrid nanostructures combining magnetic and plasmonic properties based on nanomagnetite and Au nanocrystals have been synthesized and characterized. The SEIRA and SERS signal enhancement of Glycine adsorbed on these hybrid nanostructures was obtained. It is shown that different molecular groups of Glycine are enhanced in different ways, depending on the type of interaction and the orientation of the molecule relative to the surface. According to the results of the research, the obtained Fe3O4-Au nanohybrids have the properties of plasmonic metals, while retaining ferromagnetic properties and have great potential as substrates for surface-enhanced vibration spectroscopy in trace analysis.Keywords: Fe3O4-AuFTIR spectroscopyRAMAN spectroscopyGlyFe3O4-Au-Gly AcknowledgmentsAuthors thanks the National Academy of Sciences of Ukraine and the grant PH/23-2023 “Influence of size effects on the electrophysical properties of graphene ferroelectric nanostructures” of the Ministry of Education and Science of Ukraine for their support.Disclosure statementNo potential conflict of interest was reported by the author(s).","PeriodicalId":18758,"journal":{"name":"Molecular Crystals and Liquid Crystals","volume":"62 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-09-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136060520","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
AbstractFirst series of fluorescein-based hexacatenar mesogens consisting of a central fluorescein unit and two 1,2,3-triazole dendritic wings were designed and synthesized by using the Williamson reaction and Cu-assisted alkyne-azide cycloaddition reaction. Polarized optical microscopy textures, differential scanning calorimetry curves, and X-ray diffraction (XRD) data demonstrated that all the compounds can self-assemble into hexagonal columnar mesophases. Organogel test demonstrated that these compounds could form organogel in some moderate polar solvents with irregularly winkled morphologies. Density functional theory calculation demonstrated that these mesogens adopted distorted conformation which might be the reason why narrow mesogenic temperature ranges and irregularly winkled morphologies in these compounds are observed.Keywords: Fluoresceinhexacatenarliquid crystalorganogel AcknowledgmentsWe thank beamline 1W2A at Beijing Synchrotron Radiation Facility (BSRF), China.Disclosure statementNo potential conflict of interest was reported by the authors.Additional informationFundingThis work was supported by China West Normal University Doctor Startup Fund (No. 412821), Major project funds of Chemical Synthesis and Pollution Control Key Laboratory of Sichuan Province (No. CSPC202101), The Science and Technology Department of Sichuan Province (No. 2022NSFSC1237), Natural Science Foundation of China (No. 22265030), and Funds for leading local scientific technological development by the central government (202307AB110010).
{"title":"Synthesis and self-assembly properties of the first fluorescein-based hexacatenar mesogens","authors":"Xiaoling Xie, Xiaoqin Yi, Yurun Liang, Jun Leng, Xiaotong Liu, Hongfei Gao, Yulong Xiao","doi":"10.1080/15421406.2023.2258695","DOIUrl":"https://doi.org/10.1080/15421406.2023.2258695","url":null,"abstract":"AbstractFirst series of fluorescein-based hexacatenar mesogens consisting of a central fluorescein unit and two 1,2,3-triazole dendritic wings were designed and synthesized by using the Williamson reaction and Cu-assisted alkyne-azide cycloaddition reaction. Polarized optical microscopy textures, differential scanning calorimetry curves, and X-ray diffraction (XRD) data demonstrated that all the compounds can self-assemble into hexagonal columnar mesophases. Organogel test demonstrated that these compounds could form organogel in some moderate polar solvents with irregularly winkled morphologies. Density functional theory calculation demonstrated that these mesogens adopted distorted conformation which might be the reason why narrow mesogenic temperature ranges and irregularly winkled morphologies in these compounds are observed.Keywords: Fluoresceinhexacatenarliquid crystalorganogel AcknowledgmentsWe thank beamline 1W2A at Beijing Synchrotron Radiation Facility (BSRF), China.Disclosure statementNo potential conflict of interest was reported by the authors.Additional informationFundingThis work was supported by China West Normal University Doctor Startup Fund (No. 412821), Major project funds of Chemical Synthesis and Pollution Control Key Laboratory of Sichuan Province (No. CSPC202101), The Science and Technology Department of Sichuan Province (No. 2022NSFSC1237), Natural Science Foundation of China (No. 22265030), and Funds for leading local scientific technological development by the central government (202307AB110010).","PeriodicalId":18758,"journal":{"name":"Molecular Crystals and Liquid Crystals","volume":"134 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135015023","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-09-16DOI: 10.1080/15421406.2023.2257515
A. M. Gaponov, O. L. Pavlenko, O. P. Dmytrenko, M. P. Kulish, A. S. Ryzhkova, A. I. Lesiuk, N. V. Obernikhina, B. Łuszczyńska, O. D. Kachkovsky
AbstractOptical absorption spectra were studied for films of tryptophan, thiochrome and their layer-by-layer composites. It was shown that the absorption spectra were rearranged in the composites. Quantum-chemical modeling of the electronic structure and optical transitions of the specified molecules, and their complexes, indicate that the reason for the rearrangement of the optical spectra is the heteroassociation between the molecules of thiochrome and tryptophan, which is accompanied by significant changes in the electronic states of the formed complexes.Keywords: Amino acid tryptophanquantum-chemical calculationsπ-π stakingsabsorption spectrumthiochrome dye Disclosure statementNo potential conflict of interest was reported by the author(s)
{"title":"Molecular heteroassociation in films of thiochrome and tryptophan","authors":"A. M. Gaponov, O. L. Pavlenko, O. P. Dmytrenko, M. P. Kulish, A. S. Ryzhkova, A. I. Lesiuk, N. V. Obernikhina, B. Łuszczyńska, O. D. Kachkovsky","doi":"10.1080/15421406.2023.2257515","DOIUrl":"https://doi.org/10.1080/15421406.2023.2257515","url":null,"abstract":"AbstractOptical absorption spectra were studied for films of tryptophan, thiochrome and their layer-by-layer composites. It was shown that the absorption spectra were rearranged in the composites. Quantum-chemical modeling of the electronic structure and optical transitions of the specified molecules, and their complexes, indicate that the reason for the rearrangement of the optical spectra is the heteroassociation between the molecules of thiochrome and tryptophan, which is accompanied by significant changes in the electronic states of the formed complexes.Keywords: Amino acid tryptophanquantum-chemical calculationsπ-π stakingsabsorption spectrumthiochrome dye Disclosure statementNo potential conflict of interest was reported by the author(s)","PeriodicalId":18758,"journal":{"name":"Molecular Crystals and Liquid Crystals","volume":"232 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-09-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135308463","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-09-16DOI: 10.1080/15421406.2023.2256577
Anju Bishnoi, Manoj Duhan, Satish Khasa
AbstractA glass series of Dy3+ ions doped zinc vanadium lithium borate with chemical composition xV2O5·(10-x)ZnO·30Li2O·60B2O3 (x = 0, 1, 5, 7, 9, 10) with 1.0 mol% of Dy2O3 has been synthesized by melt quench method. Efforts have been made to identify suitable optoelectronic material by studying the structural, electrical, photo-luminescence (PL), and optical characteristics of the dysprosium ions in the presence of VO2+ ions. PL emission spectra have been explored, depicting that when excited at 386 and 424 nm, the glass matrix is suitable for laser action and at 452 nm, it is apt for cool white light applications.Keywords: Dc conductivitydysprosiumoptical band gapphotoluminescence (PL)transition metal ions (TMI) AcknowledgmentsThe authors would like to thank the Central Instrumentation Laboratory (CIL), DCRUST, Murthal, for facilitating FTIR measurements.Disclosure statementNo potential conflict of interest was reported by the author(s).Additional informationFundingThe authors also want to acknowledge DST, Delhi, for providing Fluorescence facilities under FIST Research Grant (Sanction Order No. & Date: SR/FST/PS-1/2018/32).
{"title":"An insight into the transition metal dependent structural, optical, and electrical properties of dysprosium doped lithium zinc borate glasses","authors":"Anju Bishnoi, Manoj Duhan, Satish Khasa","doi":"10.1080/15421406.2023.2256577","DOIUrl":"https://doi.org/10.1080/15421406.2023.2256577","url":null,"abstract":"AbstractA glass series of Dy3+ ions doped zinc vanadium lithium borate with chemical composition xV2O5·(10-x)ZnO·30Li2O·60B2O3 (x = 0, 1, 5, 7, 9, 10) with 1.0 mol% of Dy2O3 has been synthesized by melt quench method. Efforts have been made to identify suitable optoelectronic material by studying the structural, electrical, photo-luminescence (PL), and optical characteristics of the dysprosium ions in the presence of VO2+ ions. PL emission spectra have been explored, depicting that when excited at 386 and 424 nm, the glass matrix is suitable for laser action and at 452 nm, it is apt for cool white light applications.Keywords: Dc conductivitydysprosiumoptical band gapphotoluminescence (PL)transition metal ions (TMI) AcknowledgmentsThe authors would like to thank the Central Instrumentation Laboratory (CIL), DCRUST, Murthal, for facilitating FTIR measurements.Disclosure statementNo potential conflict of interest was reported by the author(s).Additional informationFundingThe authors also want to acknowledge DST, Delhi, for providing Fluorescence facilities under FIST Research Grant (Sanction Order No. & Date: SR/FST/PS-1/2018/32).","PeriodicalId":18758,"journal":{"name":"Molecular Crystals and Liquid Crystals","volume":"159 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-09-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135307108","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
京公网安备 11010802042870号
京ICP备2023020795号-1
扫码关注我们
求助内容：
应助结果提醒方式：