Motivated by recent experimental refinements of stellar reaction rates, we establish a non-perturbative Green’s function formalism based on the exact solution of the Dyson equation for sub-barrier proton-nucleus resonant scattering. By utilizing bare Green’s functions to map the quantum tunneling problem onto a scattering formalism, we demonstrate that the summation of infinite quantum paths recovers the exact tunneling coefficients, enabling an analytical solution of the Dyson equation where the strong nuclear force is modeled as a surface delta-shell impurity embedded within the Coulomb field. Applying this framework to the astrophysically relevant , , and systems, we achieve precise agreement with experimental resonance energies while revealing a fundamental physical distinction in resonance formation. The heavier 23Na system is identified as a saturated state, residing on a geometric plateau where the resonance energy becomes insensitive to the interaction strength; our calculated value of 2.11 MeV aligns remarkably well with the experimental level of 2.08 MeV. In contrast, the lighter 7Li and 14N systems emerge as threshold states in a weak-coupling window, where the resonance energy is highly sensitive to the potential parameters and is sustained near the continuum edge. In this regime, our model yields energies of 0.489 MeV and 1.067 MeV, closely reproducing the experimental benchmarks of 0.441 MeV and 1.058 MeV, respectively. We demonstrate that these threshold states are characterized by a significant enhancement of the resonant cross-section, driven by the inverse relationship between the tunneling width and the spectral density peak. Finally, we establish the domain of validity for this method via a systematic lifetime scan across the periodic table (), identifying a sharp transition at (Argon). This finding confirms that while the method is bounded by the onset of classical stability in heavier nuclei, it provides a rigorous and parameter-free theoretical baseline for describing the sub-barrier resonant dynamics critical to light stellar nucleosynthesis cycles.
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