We report on a linear optical-feedback cavity ring-down spectrometer (LOF-CRDS) operating under ultra-high vacuum (UHV) conditions, designed for high-sensitivity detection of light hydrocarbons. The system employs an interband cascade laser (ICL) operating at 3 µm, in coincidence with the strong absorption features of the asymmetric C-H stretching vibrational mode. Taking advantage of the passive optical feedback from the high-finesse linear cavity, the ICL emission linewidth is drastically narrowed, thus facilitating light coupling into the cavity. An empty-cavity ring-down time of about 18 µs was measured, which translates into a cavity finesse of ∼37000 and a cavity-mode width of ∼9 kHz. As a result of an Allan-Werle analysis, performed at a fixed ICL frequency, we determined a minimum detectable absorption coefficient of ∼2.5×10-10 cm-1 for an integration time of approximately 100 s. The spectrometer was tested on the R(25) component of the acetylene ν3 vibrational band at 3352.2874 cm-1. In this regard, we report on spectroscopic measurements of the C2H2 partial pressure in the UHV chamber. For the selected line, the sensitivity leads to a limit of detection of 2.1×10-8 mbar.
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