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Peculiarities of Hysteretic Properties and Magnetostriction of Nano-Structured Fe10Ni90 Films 纳米结构 Fe10Ni90 薄膜的磁滞特性和磁致伸缩的特殊性
IF 1.2 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-05-27 DOI: 10.1134/s0031918x23602901
K. G. Balymov, E. V. Kudyukov, M. A. Kalinin, V. N. Lepalovskij, E. A. Kravtsov, V. O. Vas’kovskiy

Abstract—The study is related to the investigation of hysteretic and magnetostrictive properties of single-layer Fe10Ni90 films and nano-structured [Fe10Ni90/Cu]p/Fe10Ni90 films, in which magnetostrictive layers are separated with a nonmagnetic interlayer. The magnetostriction effect is shown to depend on the total layer thickness; in this case, the magnetostriction of the [Fe10Ni90/Cu]p/Fe10Ni90 film structures was found to be higher than that of the single-layer Fe10Ni90 films. The observed peculiarity is associated with weakening the fixing effect of a substrate.

摘要--本研究涉及单层 Fe10Ni90 薄膜和纳米结构 [Fe10Ni90/Cu]p/Fe10Ni90 薄膜的滞后和磁致伸缩特性的研究,其中磁致伸缩层由非磁性夹层隔开。结果表明,磁致伸缩效应取决于层的总厚度;在这种情况下,[Fe10Ni90/Cu]p/Fe10Ni90 薄膜结构的磁致伸缩效应高于单层 Fe10Ni90 薄膜的磁致伸缩效应。观察到的这一特点与基底的固定效应减弱有关。
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引用次数: 0
Formation of Structural-Phase State and Elastic and Durometric Properties of Biocompatible Cold-Rolled Titanium Ti–Nb–Zr-Based Alloys during Aging 生物相容性冷轧钛 Ti-Nb-Zr 基合金在老化过程中形成的结构相态以及弹性和耐久性能
IF 1.2 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-05-27 DOI: 10.1134/s0031918x23603049
A. A. Korenev, A. G. Illarionov, M. S. Karabanalov

Abstract—The methods of scanning electron microscopy, X-ray diffraction analysis, and microindentation are used to study the effect of alloying with zirconium (within 3 to 6 at %) and complex Zr + Sn and Zr + Sn + Ta additions on the evolution of the structure, phase composition, and properties (effective modulus of elasticity, hardness, and wear-resistance parameters) of quenched biocompatible β-titanium (at %) Ti–26% Nb–3% Zr, Ti–26% Nb–5% Zr, Ti–26% Nb–6% Zr, Ti–26% Nb–3% Zr–1% Sn, and Ti–26% Nb–3% Zr–1% Sn–0.7Ta alloys during aging (at 400°C for 4, 16, and 64 h) after multipass cold rolling with a total degree of strain of 85%. As compared to the quenching, the cold rolling of the studied Ti–Nb–Zr alloys is shown to suppress the occurrence of the β → ω transformation in the course of aging and to favor the acceleration of the decomposition of β solid solution with the formation of nonequilibrium αl phase in the course of aging. The increase in the zirconium content from 3 to 6 at % in the cold-rolled ternary Ti–26% Nb – х% Zr alloys and introduction of complex Zr + Sn and Zr + Sn + Ta additions to the Ti–26% Nb alloy instead of only zirconium addition hinder the decomposition processes of the β phase during aging; this impacts the intensity of variations of the effective modulus of elasticity and microhardness. The aging of the cold-rolled alloys under study was found to allows us to obtain the higher values of the parameters H/Er and ({{{{H}^{3}}} mathord{left/ {vphantom {{{{H}^{3}}} {E_{{text{r}}}^{2}}}} right. kern-0em} {E_{{text{r}}}^{2}}}) (Н is the hardness and Er is the resolved modulus of elasticity) associated with the wear resistance as compared to those for the widely used medical Ti–6Al–4V alloy. The compositions of the alloys and conditions of their treatment are determined, which allow us to obtain the combination of the highest-level properties.

摘要 采用扫描电子显微镜、X 射线衍射分析和显微压痕等方法研究了锆合金(3% 至 6%)和 Zr + Sn 及 Zr + Sn + Ta 复合添加物对淬火生物相容性 β-钛(Ti-26% Nb-3% Ti-26%Nb-3%Zr)结构、相组成和性能(有效弹性模量、硬度和耐磨性参数)演变的影响、和性能(有效弹性模量、硬度和耐磨性参数)的变化。7Ta 合金在总应变度为 85% 的多道次冷轧后的老化过程(400°C,4、16 和 64 小时)中的变化。与淬火相比,所研究的 Ti-Nb-Zr 合金的冷轧可抑制时效过程中发生的 β → ω 转变,并有利于加速 β 固溶体的分解,在时效过程中形成非平衡的 αl 相。将冷轧三元 Ti-26% Nb - х% Zr 合金中的锆含量从 3% 提高到 6%,以及在 Ti-26% Nb 合金中引入复合 Zr + Sn 和 Zr + Sn + Ta 添加剂(而不是仅添加锆),都阻碍了β相在时效过程中的分解过程;这影响了有效弹性模量和显微硬度的变化强度。研究发现,冷轧合金的时效可以使我们获得更高的参数值 H/Er 和 ({{{{H}^{3}}} 。mathord{left/ {vphantom {{{{H}^{3}}}{E_{{text{r}}}^{2}}}}right.kern-0em}}{E_{{text{r}}^{2}}})(Н为硬度,Er为解析弹性模量)与广泛使用的医用 Ti-6Al-4V 合金的耐磨性相关。通过确定合金的成分及其处理条件,我们可以获得最高级别的性能组合。
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引用次数: 0
Hydrogen Traps in Tungsten: A Review 钨中的氢陷阱:综述
IF 1.2 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-05-27 DOI: 10.1134/s0031918x23602895
A. P. Persianova, A. V. Golubeva

Abstract

Tungsten is currently the most promising material for plasma-facing in FRs. The accumulation of radioactive tritium in tungsten is caused by presence of hydrogen traps in this metal. The paper analyzes the literature data on the parameters of hydrogen traps in tungsten. The review results can predict the accumulation of tritium in tungsten cladding of fusion reactors, ensuring their radiation safety.

摘要 钨是目前最有希望用于等离子体面阵的材料。放射性氚在钨中的积累是由于这种金属中存在氢阱。本文分析了有关钨中氢陷阱参数的文献数据。审查结果可以预测氚在聚变反应堆钨包壳中的积累,从而确保其辐射安全。
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引用次数: 0
Fatigue Resistance of the Sheets of Heat-Resistant Titanium Alloys 耐热钛合金薄板的抗疲劳性
IF 1.2 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-05-27 DOI: 10.1134/s0031918x23603141
M. S. Kalienko, A. A. Popov, A. V. Volkov, M. O. Leder, A. V. Zhelnina

Abstract

The results of a study of the resistance to fatigue fracture of the sheets made of the heat-resistant titanium alloys VT18U (Ti–6.5Al–4.3Zr–2.4Sn–0.8Nb–0.7Mo–0.1Si, wt %), VT8 (Ti–6.4Al–3.4Mo–0.3Si, wt %), and VT25U (Ti–6.51Al–3.76Zr–1.71Sn–3.94Mo–0.5W–0.13Si, wt %) have been presented. Fatigue curves have been obtained in the initial state and in the oxidized one after isothermal annealing at a temperature of 560°C for 1000 h in air. It has been established that after annealing, the fatigue resistance of all oxidized alloys in the low-cycle region decreases by an order of magnitude. The fatigue limit of the oxidized alloys VT18U and VT25U does not change and is of about 320 MPa. The high-cycle fatigue limit of the VT8 alloy decreases from 300 MPa in the initial state to 230 MPa in the oxidized state. It has been established that after annealing, the phase composition of an oxide of 250 nm in thickness on the surface of the alloys is different and contains the phases of anatase and rutile for the VT18U and VT25U alloys and contains predominantly rutile for the VT8 alloys, which is why the fatigue limit of the oxidized alloys differs.

摘要 对耐热钛合金 VT18U(Ti-6.5Al-4.3Zr-2.4Sn-0.8Nb-0.7Mo-0.1Si,重量百分比)、VT8(Ti-6.4Al-3.4Mo-0.3Si,重量百分比)和 VT25U(Ti-6.51Al-3.76Zr-1.71Sn-3.94Mo-0.5W-0.13Si,重量百分比)制成的板材。在空气中以 560°C 等温退火 1000 小时后,获得了初始状态和氧化状态下的疲劳曲线。结果表明,退火后,所有氧化合金在低循环区域的抗疲劳性都下降了一个数量级。氧化合金 VT18U 和 VT25U 的疲劳极限没有变化,约为 320 兆帕。VT8 合金的高循环疲劳极限从初始状态的 300 兆帕降至氧化状态的 230 兆帕。经证实,退火后,合金表面厚度为 250 nm 的氧化物的相组成不同,VT18U 和 VT25U 合金含有锐钛矿相和金红石相,而 VT8 合金主要含有金红石相,这就是氧化合金疲劳极限不同的原因。
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引用次数: 0
Influence of Low-Energy High-Current Electron Beam Exposure on the Phase Composition and Corrosion Resistance of the AM60 Magnesium Alloy 低能量大电流电子束暴露对 AM60 镁合金相组成和耐腐蚀性的影响
IF 1.2 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-05-27 DOI: 10.1134/s0031918x23603128
K. O. Akimov, K. V. Ivanov, M. G. Figurko

Abstract

The surface of an AM60 (Al—5.5, Zn—0.2, Cu—0.009, Fe—0.005, Si—0.1, Ni —0.002, Mn—0.3 wt %, Mg—the rest) magnesium alloy was exposed to a low-energy high-current electron beam. After the irradiation, the content of the β-phase (Mg17Al12) decreases and the aluminum content increases in the alloy surface layer. After the exposure to the electron beam, the corrosion resistance of the alloy in a 1-molar NaCl solution increases significantly compared to the initial state. The physical reason for an increase in the alloy corrosion resistance after exposure to the electron beam is the higher corrosion resistance of the oxide film formed on the alloy surface due to the increased aluminum content.

摘要 将 AM60(Al-5.5,Zn-0.2,Cu-0.009,Fe-0.005,Si-0.1,Ni-0.002,Mn-0.3 wt %,其余为 Mg)镁合金表面置于低能量大电流电子束中。辐照后,合金表层中的β相(Mg17Al12)含量减少,铝含量增加。经过电子束照射后,合金在 1 摩尔 NaCl 溶液中的耐腐蚀性与初始状态相比显著增加。暴露于电子束后合金耐腐蚀性增加的物理原因是铝含量增加导致合金表面形成的氧化膜具有更高的耐腐蚀性。
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引用次数: 0
Magnetization Processes of Exchange Coupled Nd2(Fe,Co)14B Alloys in Various Demagnetized States 各种退磁状态下交换耦合 Nd2(Fe,Co)14B 合金的磁化过程
IF 1.2 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-05-27 DOI: 10.1134/s0031918x23603013
I. V. Alekseev, S. V. Andreev, A. S. Volegov, N. V. Selezneva

Abstract

Processes of magnetization in exchange-coupled rapidly quenched nanocrystalline alloys Nd2(Fe1 – xCox)14B, where x = 0, 0.07, 0.2, 0.5, have been studied. Initial magnetization curves and interaction plots δM(H) for various demagnetized states were obtained. Based on comparison of measurement results, influence of the pinning type mechanism on magnetization process in the Nd2(Fe1 – xCox)14B melt-spun ribbons is shown. Using δM(H) plots, a change in intergrain exchange interaction depending on cobalt concentration in rapidly quenched Nd2(Fe1 – xCox)14B nanocrystalline alloys was investigated.

摘要 研究了交换耦合快速淬火纳米晶合金 Nd2(Fe1-xCox)14B(其中 x = 0、0.07、0.2、0.5)的磁化过程。获得了各种退磁状态下的初始磁化曲线和相互作用图 δM(H)。根据测量结果的比较,显示了针刺型机制对 Nd2(Fe1 - xCox)14B 熔纺带磁化过程的影响。利用 δM(H) 图,研究了快速淬火 Nd2(Fe1 - xCox)14B 纳米晶合金中晶粒间交换相互作用随钴浓度变化的情况。
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引用次数: 0
Critical Temperature and Order Parameter in Superconductor/Inhomogeneous Ferromagnet Heterostructures 超导体/同质铁磁体异质结构中的临界温度和有序参数
IF 1.2 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-05-27 DOI: 10.1134/s0031918x23602913
V. A. Tumanov, Yu. N. Proshin

Abstract

A method for solving a self-consistent boundary value problem for the linearized Usadel equation is proposed. The method makes it possible to find the sample-normalized distribution of the superconducting order parameter and the critical temperature as functions of the problem parameters and to solve relatively complex spatially inhomogeneous problems, e.g., superconducting heterostructures containing inhomogeneous magnetic layers. Within this approach, layered structures containing superconducting and domain-split ferromagnetic layers are considered. The theory is compared with experiment for the Fe 20 Å/V 340 Å/Fe 8 Å/Cr/Fe 8 Å system.

摘要 提出了一种求解线性化乌萨德尔方程自洽边界值问题的方法。该方法可以找到超导阶次参数和临界温度作为问题参数函数的样本归一化分布,并解决相对复杂的空间不均匀问题,例如包含不均匀磁层的超导异质结构。在这种方法中,考虑了包含超导层和畴裂铁磁层的层状结构。理论与实验对 Fe 20 Å/V 340 Å/Fe 8 Å/Cr/Fe 8 Å 系统进行了比较。
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引用次数: 0
Resonance Enhancement of the Faraday Effect in a Magnetoplasmonic Composite 磁悬浮复合材料中法拉第效应的共振增强
IF 1.2 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-05-27 DOI: 10.1134/s0031918x23603001
S. V. Tomilin, A. V. Karavaynikov, S. D. Lyashko, E. T. Milyukova, O. A. Tomilina, V. N. Berzhansky

Abstract

The paper presents the results of a theoretical and experimental study of the enhancement of the magneto-optical Faraday effect in a magnetoplasmonic nanocomposite, caused by localized plasmon resonance (LPR) in metal nanoparticles. The nanocomposite comprises a three-layer structure of self-assembled gold nanoparticles in a bismuth-substituted iron-garnet matrix. It is shown theoretically and experimentally that the enhancement of the magneto-optical Faraday effect is determined by the action of a magnetic field on the magnetoplasmonic composite as an effective medium as a whole. In this case, in the magnetoplasmonic nanocomposite, the Faraday effect is enhanced at the LPR wavelengths and is slightly weakened in the region of short wavelengths relative to the LPR. It is theoretically shown that the complex gyration index in the off-diagonal terms of the effective permittivity tensor for the magnetoplasmonic composite, in addition to rotation of the polarization plane, leads to the appearance of alternating ellipticity in the vicinity of the plasmon resonance, which is observed in the form of asymmetry of magneto-optical rotation.

摘要 本文介绍了对金属纳米粒子局域等离子体共振(LPR)引起的磁光电纳米复合材料磁光法拉第效应增强的理论和实验研究结果。这种纳米复合材料由自组装金纳米粒子在铋替代铁石榴石基体中的三层结构组成。理论和实验证明,磁光法拉第效应的增强取决于磁场对作为有效介质的磁光电复合材料整体的作用。在这种情况下,在磁性纳米复合材料中,法拉第效应在 LPR 波长处增强,而在相对于 LPR 的短波长区域则略有减弱。理论表明,除了极化平面的旋转之外,磁致共振复合材料有效介电常数张量对角线外项中的复回旋指数导致等离子体共振附近出现交替椭圆,这是以磁光旋转不对称的形式观察到的。
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引用次数: 0
Temperature Dependence of Magnetization and Exchange Interaction in Amorphous Fe–Ni–Si–B Alloys 非晶态 Fe-Ni-Si-B 合金中磁化和交换相互作用的温度依赖性
IF 1.2 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-05-27 DOI: 10.1134/s0031918x24600155
I. M. Sapovskii, N. V. Ilin, G. S. Kraynova, T. R. Rakhmatullaev, I. A. Tkachenko, V. V. Tkachev, V. S. Plotnikov, K. E. Pinchuk, A. M. Frolov

Abstract

The temperature dependence of the magnetization of rapidly quenched amorphous Fe–Ni–Si–B alloys was studied by the magnetometry method. The Curie temperatures were determined, and the exchange interaction parameters were calculated: the constants of spin-wave stiffness and exchange stiffness, the root mean-square range of the exchange interaction. The nearest neighboring distance between transition metal atoms was estimated based on the magnetic characteristics.

摘要 利用磁力测量法研究了快速淬火非晶态 Fe-Ni-Si-B 合金磁化的温度依赖性。确定了居里温度,并计算了交换相互作用参数:自旋波刚度和交换刚度常数、交换相互作用的均方根范围。根据磁性特征估算了过渡金属原子间的最近邻距。
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引用次数: 0
Anion Reorientations and Cation Diffusion in Nanostructured Closo-Borates: NMR and Quasielastic Neutron Scattering Studies 纳米结构氯硼酸盐中的阴离子定向和阳离子扩散:核磁共振和准弹性中子散射研究
IF 1.2 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-05-27 DOI: 10.1134/s0031918x23603050
A. V. Skripov, O. A. Babanova, R. V. Skoryunov, A. V. Soloninin

Abstract

The dynamical properties of sodium closo-borate NaCB11H12 embedded into SiO2-based nanoporous scaffolds have been studied by nuclear magnetic resonance (NMR) and quasielastic neutron scattering (QENS) over wide temperature ranges. It has been found that a confinement of the closo-borate in nanopores suppresses the order-disorder phase transition, retaining the orientationally disordered phase with high reorientational mobility of the anions and high diffusive mobility of the cations down to low temperatures. This paper is based on the presentation at the RNIKS-2023 conference.

摘要 通过核磁共振(NMR)和准弹性中子散射(QENS)研究了嵌入二氧化硅基纳米多孔支架中的氯硼酸钠 NaCB11H12 在宽温度范围内的动态特性。研究发现,封闭硼酸盐在纳米孔隙中的封闭作用抑制了有序-无序相变,在低温下保留了取向无序相,阴离子具有较高的再取向迁移率,阳离子具有较高的扩散迁移率。本文根据在 RNIKS-2023 会议上的发言整理而成。
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引用次数: 0
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Physics of Metals and Metallography
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