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Release of oregano essential oil from PHBV films in simulated food conditionsa PHBV薄膜中牛至精油在模拟食物条件下的释放
IF 1.3 4区 化学 Q4 POLYMER SCIENCE Pub Date : 2022-01-01 DOI: 10.1590/0104-1428.20220060
R. C. D. Costa, Ana Paula Ineichen, C. S. Teixeira, I. C. Bellettini, L. N. Carli
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引用次数: 0
Incorporation of Aloe vera extract in bacterial nanocellulose membranes 芦荟提取物在细菌纳米纤维素膜中的掺入
IF 1.3 4区 化学 Q4 POLYMER SCIENCE Pub Date : 2022-01-01 DOI: 10.1590/0104-1428.210062
L. Piaia, C. Q. P. Pittella, Samara Silva de Souza, F. Berti, L. Porto
Florianópolis, SC, Brasil *piaialyapi@gmail.com Obstract Nanocellulose (BNC) is a natural polymer produced by bacteria. Its structure has only glucose monomer, it has various properties such as high water holding capacity, unique nanostructure, high crystallinity and high mechanical strength. Pure BNC or in combination with different components can be used for a wide range of applications. Aloe vera is a medicinal plant with polysaccharides in its composition that has a potential for tissue regeneration and repair. The aim of this study was to evaluate the effect of incorporating Aloe vera ( A. vera ) into BNC membranes produced with three fractions of A. vera extract (BNC-Aloe) on the behavior of epithelial cells. Human fibroblasts and keratinocytes were shown to have increased metabolic activity and proliferation when cultured on BNC-Aloe membranes compared to control. Quantification of collagen biosynthesis was significantly higher in BNC-Aloe membranes. In conclusion, BNC-Aloe membranes are suggested as a material for the
纳米纤维素(Nanocellulose, BNC)是一种由细菌产生的天然聚合物。它的结构只有葡萄糖单体,具有高持水能力、独特的纳米结构、高结晶度和高机械强度等多种性能。纯BNC或与不同组件的组合可用于广泛的应用。芦荟是一种药用植物,其成分中含有多糖,具有组织再生和修复的潜力。本研究的目的是评价芦荟提取物(BNC-Aloe)三组分制备的BNC膜中掺入芦荟对上皮细胞行为的影响。与对照相比,在bnc -芦荟膜上培养的人成纤维细胞和角化细胞具有更高的代谢活性和增殖能力。bnc -芦荟膜中胶原生物合成的定量明显增加。综上所述,bnc -芦荟膜被认为是一种新型的膜材料
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引用次数: 1
Classification of natural rubber foam grades by optimising the azodicarbonamide content 通过优化偶氮二甲酰胺含量对天然橡胶泡沫等级进行分类
IF 1.3 4区 化学 Q4 POLYMER SCIENCE Pub Date : 2022-01-01 DOI: 10.1590/0104-1428.20210111
Fateehah Baru, S. Saiwari, N. Hayeemasae
This study aimed to focus on classifying rubber foam grades according to ASTM D1056. The natural rubber foams were prepared by varying the Azodicarbonamide (ADC) content from 2 - 10 phr. The results were evaluated on their physical and mechanical properties. The relative foam density of the foams decreased, and the expansion ratio increased with the addition of ADC. This was due to the increase in the gas phase raised by ADC. In addition, adding ADC also decreased hardness and compression-deflection of the foams, whereby the values obtained were higher after oven aging due to the radical recombination caused by chain breaking. According to ASTM D1056, the compression-deflection values of the foams were 2A2 and 2A3 grades, where the ADC content at 6 – 10 phr met the basic properties required by the same standard. Furthermore, the ADC content at 6 phr is strongly suggested when considering the foam morphology.
本研究旨在根据ASTM D1056对泡沫橡胶等级进行分类。通过偶氮二甲酰胺(ADC)含量在2 ~ 10phr范围内的变化,制备了天然泡沫橡胶。对其物理力学性能进行了评价。随着ADC的加入,泡沫体的相对泡沫密度降低,膨胀比增大。这是由于ADC增加了气相。此外,添加ADC还降低了泡沫的硬度和压缩挠度,其中由于链断裂引起的自由基复合,烘箱时效后得到的数值更高。根据ASTM D1056,泡沫的压缩挠度值为2A2和2A3级,其中ADC含量在6 - 10 phr时满足相同标准的基本性能要求。此外,在考虑泡沫形态时,强烈建议采用6 phr时的ADC含量。
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引用次数: 1
Surface and micromechanical analysis of polyurethane plates with hydroxyapatite for bone structure 羟基磷灰石聚氨酯骨结构板的表面和微观力学分析
IF 1.3 4区 化学 Q4 POLYMER SCIENCE Pub Date : 2022-01-01 DOI: 10.1590/0104-1428.20220058
Wenderson da Silva do Amaral, Milton Thélio de Albuquerque Mendes, J. Câmara, J. Pierote, F. Reis, J. Matos, AnaCristina Vasconcelos Fialho, W. Moura
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引用次数: 0
Development of an SO2 indicator label applied to shrimp 虾用二氧化硫指示剂标签的研制
IF 1.3 4区 化学 Q4 POLYMER SCIENCE Pub Date : 2022-01-01 DOI: 10.1590/0104-1428.20220033
Gleyca de Jesus Costa Fernandes, Karoline Ferreira Silva, C. Marques, L. Z. Benedito, Beatriz Ribeiro Cabral, P. Campelo, S. V. Borges, J. Marconcini, Z. Magriotis, P. Claro, M. V. Dias
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引用次数: 1
Selection of materials with entropy-topsis by considering technological properties of impregnated wood 考虑浸渍木材工艺性能的熵顶性材料选择
IF 1.3 4区 化学 Q4 POLYMER SCIENCE Pub Date : 2022-01-01 DOI: 10.1590/0104-1428.20220067
Nadir Ersen, Hüseyin Peker, I. Akyüz
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引用次数: 3
A review on research, application, processing, and recycling of PPS based materials PPS基材料的研究、应用、加工及回收利用综述
IF 1.3 4区 化学 Q4 POLYMER SCIENCE Pub Date : 2022-01-01 DOI: 10.1590/0104-1428.20210108
L. Montagna, M. Kondo, E. S. Callisaya, Celson Mello, Bárbara Righetti de Souza, A. P. Lemes, E. C. Botelho, M. L. Costa, M. Alves, M. V. Ribeiro, M. C. Rezende
Among the engineering thermoplastics, poly(phenylene sulfide) (PPS) stands out for its excellent properties and mainly for processing at lower temperatures. The requirements requested by industries can be made by improving mechanical strength, weight reduction, and durable components by reinforcing the PPS matrix with fiberglass (FG) and carbon fiber (CF). This review intends to present the most current research related to the physical, mechanical, and thermal properties of PPS and the PPS/FG and PPS/CF composites most currently used by the aerospace, automotive, and energy industries. In addition to presenting the feasibility of mechanical and thermal recycling processes for PPS-based waste to reinsert a high market value thermoplastic into the industrial production cycle, thus contributing to the minimization of waste destined for landfills and incinerated or even improperly disposed of in the environment.
在工程热塑性塑料中,聚苯硫醚(PPS)以其优异的性能脱颖而出,主要用于低温加工。通过用玻璃纤维(FG)和碳纤维(CF)增强PPS基体,可以提高机械强度、减轻重量和耐用部件,从而满足工业要求。本文综述了PPS和PPS/FG和PPS/CF复合材料的物理、机械和热性能的最新研究进展,这些复合材料目前在航空航天、汽车和能源工业中应用最为广泛。除了提出机械和热回收工艺对基于pps的废物的可行性外,还可以将高市场价值的热塑性塑料重新插入工业生产周期,从而有助于最大限度地减少运往垃圾填埋场和焚烧甚至在环境中不当处置的废物。
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引用次数: 4
A hybrid green composite for automotive industry 用于汽车工业的混合绿色复合材料
IF 1.3 4区 化学 Q4 POLYMER SCIENCE Pub Date : 2022-01-01 DOI: 10.1590/0104-1428.20220027
Gabriella Neto Chagas, M. M. Barros, A. Leão, N. O. Tapanes, R. C. Ribeiro, D. C. Bastos
Hybrid composites were prepared using recycled polypropylene (rPP), dimension stone waste (Bege Bahia, BB) and coconut fiber (CF). Post-consumer the formulations of rPP/BB/CF and virgin PP, were processed in a Haake mixer. The films were characterized according to chemical, physical and mechanical properties. Multiple linear regression tests were used to develop mathematical models, which allow simulating the behavior of the composition of composite on mechanical properties. Density variations were associated with differences in particle packing and particle wall roughness. The impact resistance of rPP/BB/CF was slightly higher in the 70/10/20 wt% composite. SEM micrographs of the ternary (70/20/10 wt%) showed stronger traces of decohesion, allowing higher water absorption and reducing impact resistance. The response surface methodology suggest that the increase in the variable “coconut fiber content” is responsible for improving the mechanical properties of the composite. The ternary composite (70/10/20 wt%) was best for replacement of virgin PP.
以再生聚丙烯(rPP)、维石废料(Bege Bahia, BB)和椰子纤维(CF)为原料制备杂化复合材料。消费后的配方rPP/BB/CF和原PP,在Haake混合器中进行加工。根据化学、物理和机械性能对膜进行了表征。采用多元线性回归测试建立数学模型,模拟复合材料组成对力学性能的影响。密度变化与颗粒堆积和颗粒壁粗糙度的差异有关。在wt%为70/10/20的复合材料中,rPP/BB/CF的抗冲击性略高。三元化合物(70/20/10 wt%)的SEM显微照片显示出更强的脱粘痕迹,允许更高的吸水性和降低抗冲击性。响应面方法表明,增加变量“椰子纤维含量”是负责改善复合材料的力学性能。三元复合材料(70/10/20 wt%)替代原生PP效果最好。
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引用次数: 2
Effect of non-thermal argon plasma on the shear strength of adhesive systems 非热氩等离子体对胶粘剂抗剪强度的影响
IF 1.3 4区 化学 Q4 POLYMER SCIENCE Pub Date : 2022-01-01 DOI: 10.1590/0104-1428.20220019
Isabella de Almeida Guimarães Passos, J. N. Marques, J. Câmara, R. Simão, M. Prado, G. Pereira
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引用次数: 1
Influence of carbon black trimodal mixture on LDPE films properties: Part2 – SME 炭黑三模态混合物对LDPE薄膜性能的影响:第二部分- SME
IF 1.3 4区 化学 Q4 POLYMER SCIENCE Pub Date : 2022-01-01 DOI: 10.1590/0104-1428.20220053
J. Barbosa, C. G. Beatrice, L. Pessan
In this work, the influence of Specific Mechanical Energy (SME) to disperse a trimodal distribution of carbon black (CB) by extrusion was studied to evaluating the effect on LDPE films properties (colorimetric and rheological). Three types of CB were previously evaluated (PART1) and determined that the best formulation was the combination between small (S) and medium (M) particles (F18 and F13), obtaining greater tinting strength with lower viscosity. In this work (PART2), these formulations were processed with different SME levels by varying the extrusion parameters, like screw rotation speed (N) and feed rate (Q), modulate the SME. The result of each process was evaluated by Tinting Strength, MFI, Total Transmittance and it was determined that the process with 600 rpm and 10 kg/h feed rate, generating a SME of 0.29 kWh/kg for F18-P03, developed the best results, mainly in the Tinting Strength, from 126.7% to 133.2% related to F18 (PART1)
在这项工作中,研究了比机械能(SME)对挤压分散炭黑(CB)三峰分布的影响,以评估对LDPE薄膜性能(比色和流变学)的影响。先前对三种类型的CB进行了评估(PART1),确定最佳配方是小(S)和中(M)颗粒(F18和F13)的组合,以较低的粘度获得更高的着色强度。在本工作(PART2)中,通过改变螺杆转速(N)和进料速度(Q)等挤出参数来调节SME,对这些配方进行了不同SME水平的加工。通过对各工艺的着色强度、MFI、总透光率进行评价,结果表明,在转速为600 rpm、进料速度为10 kg/h、SME为0.29 kWh/kg的情况下,F18- p03的着色强度达到了最佳,主要表现在着色强度方面,与F18相比,着色强度提高了126.7% ~ 133.2% (PART1)。
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Polimeros-ciencia E Tecnologia
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