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Electrospun PHBV nanofiber containing Tea Tree Oil: physicochemical and antimicrobial activity 含茶树油的电纺丝PHBV纳米纤维:理化及抗菌活性
IF 1.3 4区 化学 Q4 POLYMER SCIENCE Pub Date : 2023-04-14 DOI: 10.1590/0104-1428.20220088
V. R. Santos, Samara Domingues Vera, G. L. Cena, A. P. Silva, A. P. Lemes, Katia Conceição, D. Tada, Alexandre Luiz Souto Borges, E. S. Trichês
Aiming to produce an antimicrobial dressing for wound healing applications, in this work Tea Tree oil (TTO) was incorporated into PHBV nanofibers by absorption. It was observed increase in the nanofiber diameter due to 5% TTO absorption efficiency, which also led to a 54% decrease in the contact angle. The releasing assay indicates a 6.8% oil release in the first 24 h – being probably the oil deposited at the polymer surface – followed by a minimal release at 48 h. The set of antimicrobial assays performed suggests the incorporation of TTO optimized the antimicrobial activity of the polymer for E. coli and C. albicans , while against S. aureus no significant difference was observed. The MTT assay showed no cytotoxicity of PHBV, but the incubation of L929 fibroblast cells with PHBV-TTO reduced cell viability. Overall, the PHBV nanofibers containing TTO present great potential as an antimicrobial dressing.
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引用次数: 0
Effects of replacing Carbon Black with Wood Fibers in wood-rubber composites 木纤维替代炭黑在木胶复合材料中的应用效果
IF 1.3 4区 化学 Q4 POLYMER SCIENCE Pub Date : 2023-04-14 DOI: 10.1590/0104-1428.20220051
Renan Zunta Raia, S. Iwakiri, R. Trianoski, A. S. D. Andrade, Edemir Luiz Kowalski, A. Job, F. Paiva
The objective of this research was to develop a more sustainable composite and still keep its characteristics. Fibers treated with NaOH at 5% w/w for 2 hours were incorporated into natural rubber in different proportions (0 phr, 24 phr, 36 phr, 48 phr and 60 phr). The mechanical properties of the composites suffered changes, increasing the hardness, young’s modulus and decreasing its tensile strength. All the physical properties were not statistically different. The coloration became less dark in the WF60/CB0 treatment, and the electrical properties presented better resistivity with the increase in the concentration of fibers in the composite. This presents a possibility of using WF for the production of wood-rubber composites for the production of rubber artifacts which do not require high rolling resistance. Based on the results from this research, we recommended the WF24/CB36 mix to produce antistatic floors.
{"title":"Effects of replacing Carbon Black with Wood Fibers in wood-rubber composites","authors":"Renan Zunta Raia, S. Iwakiri, R. Trianoski, A. S. D. Andrade, Edemir Luiz Kowalski, A. Job, F. Paiva","doi":"10.1590/0104-1428.20220051","DOIUrl":"https://doi.org/10.1590/0104-1428.20220051","url":null,"abstract":"The objective of this research was to develop a more sustainable composite and still keep its characteristics. Fibers treated with NaOH at 5% w/w for 2 hours were incorporated into natural rubber in different proportions (0 phr, 24 phr, 36 phr, 48 phr and 60 phr). The mechanical properties of the composites suffered changes, increasing the hardness, young’s modulus and decreasing its tensile strength. All the physical properties were not statistically different. The coloration became less dark in the WF60/CB0 treatment, and the electrical properties presented better resistivity with the increase in the concentration of fibers in the composite. This presents a possibility of using WF for the production of wood-rubber composites for the production of rubber artifacts which do not require high rolling resistance. Based on the results from this research, we recommended the WF24/CB36 mix to produce antistatic floors.","PeriodicalId":20282,"journal":{"name":"Polimeros-ciencia E Tecnologia","volume":"1 1","pages":""},"PeriodicalIF":1.3,"publicationDate":"2023-04-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"67122158","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Poly(methyl methacrylate) modified Starch: their preparations, properties and applications 聚甲基丙烯酸甲酯变性淀粉的制备、性能及应用
IF 1.3 4区 化学 Q4 POLYMER SCIENCE Pub Date : 2023-04-14 DOI: 10.1590/0104-1428.20220068
Anjana Dhar, J. Barman, H. Talukdar, D. Haloi
Plastic wastes are generally not easily degradable under the action of environmental components. They are very much resistant to microbial attack too. These non-biodegradable plastics accumulate over a longer period of time on earth leading to environmental pollution. However, this may be avoided by using biodegradable polymers. Thus the demand for the preparation of biodegradable polymers has grown up. In recent years, researchers have developed a few biodegradable polymers from renewable sources; those find a large application in the field of packaging, agriculture, and biomedical fields. Starch is one such biopolymer, modification of which may lead to a semi-synthetic polymer with good properties with an edge of biodegradability. Poly(methyl methacrylate) is a good modifying agent for such modification as revealed by the literature search. This review report summarizes the preparation of such poly(methyl methacrylate) grafted starch polymers via different physical and chemical methods, their properties, and their applications.
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引用次数: 0
Separation of plastic mixtures by sink-float combined with froth flotation 沉浮—泡沫浮选联合分离塑料混合物
4区 化学 Q4 POLYMER SCIENCE Pub Date : 2023-01-01 DOI: 10.1590/0104-1428.20220094
Fernando Pita
The aim of this research was to separate a mixture of six post-consumer plastics (PS, PMMA, PVC-D, PVC-M, PET-D and PET-S) by combination of sink-float separation and froth flotation.. In sink-float method two mediums of separation were used: sodium chloride water solution and ammonium nitrate water solution. Sink-float method allowed complete separation of the less dense plastic (PS) from intermediate density plastics (PMMA and PVC-D) and from high density plastics (PET-S, PET-D and PVC-M); also allowed good separation of intermediate density plastics (PMMA and PVC-D) from high density plastics (PVC-M, PET-D and PET-S) with an efficiency close to 100%. Separation of PVC-M from PET-D and PET-S by sink-float method led to fair results allowing a separation efficiency of about 60%. Since PMMA and PVC-D have similar density, their separation was achieved by froth flotation, using sodium lignosulfonate as selective wetting agent of PVC-D, with a separation efficiency of 85%.
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引用次数: 0
Sustainable composites of eco-friendly polyethylene reinforced with eggshells and bio-calcium carbonate 可持续复合材料的环保聚乙烯增强与蛋壳和生物碳酸钙
4区 化学 Q4 POLYMER SCIENCE Pub Date : 2023-01-01 DOI: 10.1590/0104-1428.20220108
Kássia Peçanha Vieira, Alexandra Augusta Reichert, Gabriel Monteiro Cholant, Dielen Marin, Cesar Augusto Gonçalves Beatrice, Amanda Dantas de Oliveira
This work aimed to obtain and analyze composite materials made from green polyethylene and calcium carbonate extracted from chicken eggshells. The shells were collected and prepared for later extraction of calcium carbonate. With the X-ray diffraction analysis it was possible to confirm that both the in natura reinforcement and the calcined one, have the same polymorph mineral (calcite). With regard to thermal behavior, compounds with in natura reinforcement showed greater mass loss due to the moisture contained in them. The results showed a significant increase in Young’s moduli of the composites compared to the pure polymer. The scanning electron microscopy showed good dispersion and adhesion between the reinforcement materials and matrix. In view of the results, eggshells have the potential to be used as fillers, where greater rigidity is required. Since these materials come from a waste material, with low cost, their use becomes even more viable.
这项工作旨在获得并分析由绿色聚乙烯和从鸡蛋壳中提取的碳酸钙制成的复合材料。收集贝壳,为提取碳酸钙做准备。通过x射线衍射分析,可以证实天然增强和煅烧增强具有相同的多晶矿物(方解石)。在热性能方面,含有非天然增强剂的化合物由于其中含有水分而表现出更大的质量损失。结果表明,与纯聚合物相比,复合材料的杨氏模量显著增加。扫描电镜显示增强材料与基体之间具有良好的分散和粘附性。鉴于这些结果,蛋壳有可能被用作需要更大刚度的填料。由于这些材料来自废料,成本低,它们的使用变得更加可行。
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引用次数: 0
Development and characterization of chitosan-collagen films loaded with honey 载蜜壳聚糖-胶原膜的研制与表征
4区 化学 Q4 POLYMER SCIENCE Pub Date : 2023-01-01 DOI: 10.1590/0104-1428.20230031
David Servín de la Mora-López, Tomás Jesús Madera-Santana, Jaime López-Cervantes, Dalia Isabel Sánchez-Machado, Jesús Fernando Ayala-Zavala, Herlinda Soto-Valdez
Biomaterials developed with biopolymers contribute to the healing process of healthy or diabetic patients. The objective of the present study was to evaluate the effect of honey incorporation (0.3, 0.6, and 1.2 g/100 mL) in chitosan/collagen/glycerol composite films. The Ch/Coll/1.2H films revealed the greatest percentage of elongation (27.10%) and Young´s modulus (65.58 MPa). The barrier properties (WVTR and WVP) exhibited a significant increase when the honey was incorporated into the films. The absorption capacity, solubility, and enzymatic biodegradability were lower in films containing honey. The chemical interactions between the functional groups of the films were verified by FTIR. The morphology studied by SEM confirmed the mixture’s homogeneity. Finally, all formulations exhibited antibacterial properties against Staphylococcus aureus, Pseudomonas aeruginosa, Listeria monocytogenes, and Salmonella Typhimurium. The aforementioned properties of formulated dressings are suitable for their potential application in chronic wounds.
用生物聚合物开发的生物材料有助于健康或糖尿病患者的愈合过程。本研究的目的是评价蜂蜜掺入(0.3、0.6和1.2 g/100 mL)在壳聚糖/胶原/甘油复合膜中的效果。Ch/Coll/1.2H薄膜的伸长率为27.10%,杨氏模量为65.58 MPa。当蜂蜜掺入膜中时,膜的阻隔性能(WVTR和WVP)显著增加。在含蜂蜜的薄膜中,吸收能力、溶解度和酶的生物降解性较低。用红外光谱(FTIR)验证了膜官能团之间的化学相互作用。SEM形貌分析证实了混合物的均匀性。最后,所有配方均表现出对金黄色葡萄球菌、铜绿假单胞菌、单核增生李斯特菌和鼠伤寒沙门氏菌的抗菌性能。配方敷料的上述特性适合其在慢性伤口中的潜在应用。
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引用次数: 0
Development and characterization of green polyethylene/clay/antimicrobial additive nanocomposites 绿色聚乙烯/粘土/抗菌添加剂纳米复合材料的研制与表征
IF 1.3 4区 化学 Q4 POLYMER SCIENCE Pub Date : 2022-01-01 DOI: 10.1590/0104-1428.20210097
Priscylla Jordânia Pereira de Mesquita, T. S. Alves, R. Barbosa
In this work, nanocomposites were developed and evaluated using high-density bio polyethylene (BPEAD)/Cloisite 20A (3 and 6%)/commercial antimicrobial additive (0,5 and 1%) containing 1% of zinc pyrithione dispersed in vinyl acetate (EVA). The samples were prepared in a single screw extruder using the melt intercalation technique and then by flat extrusion to obtain the films. X-ray diffraction (XRD) showed an increase in basal spacing and exfoliation of the structure of some films. The Fourier Transform Infrared Spectroscopy (FTIR) analysis illustrated the main functional groups for BHDPE and EVA. Thermal analysis indicated that BHDPE degradation did not change with organoclay addition, but crystallinity increased. The mechanical properties showed an increase in the elastic modulus and a decrease in maximum tensile strength. This work contributes to the development and improvement of the natural properties of BHDPE in order to enlarge its applications.
采用高密度生物聚乙烯(BPEAD)/Cloisite 20A(3%和6%)/商用抗菌添加剂(0%、5%和1%)制备纳米复合材料,并对其进行了评价。采用熔体嵌入技术在单螺杆挤出机中制备样品,然后采用平挤压法制备薄膜。x射线衍射(XRD)结果表明,部分薄膜的基底间距增大,结构脱落。傅里叶变换红外光谱(FTIR)分析表明了BHDPE和EVA的主要官能团。热分析表明,有机粘土的加入对BHDPE的降解没有影响,但结晶度增加。力学性能表现为弹性模量增加,最大抗拉强度降低。这项工作有助于BHDPE的天然性能的开发和改善,以扩大其应用范围。
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引用次数: 0
Influence of carbon black trimodal mixture on LDPE films properties: Part1 - DOE 炭黑三模态混合物对LDPE薄膜性能的影响:第一部分- DOE
IF 1.3 4区 化学 Q4 POLYMER SCIENCE Pub Date : 2022-01-01 DOI: 10.1590/0104-1428.20220039
J. Barbosa, C. G. Beatrice, L. Pessan
In this study, the influence of carbon black (CB) trimodal mixture, with different medium particle sizes, on the colorimetric and rheological properties of polyethylene was evaluated. Three different types of CB were selected, with particle sizes of 15nm (S), 38nm (M), and 75nm (L) and combined, generating a Design of Experiments (DOE) with 19 formulations to be dispersed at 30% in low density polyethylene (LDPE) in twin screw extruder. Such formulations were evaluated in performance and process properties, such as Tint Strength, Melt Flow Index (MFI), and Total Transmittance (TT). It was observed that the mixtures between small (S) and medium (M) particles developed greater tinting strength and lower viscosity, demonstrating the synergy of the mixture, which was superior in the performance of the mixture containing only a particular of 15nm (S) that would have greater potential for results.
本研究考察了不同中等粒径的炭黑(CB)三模态混合物对聚乙烯比色和流变性能的影响。选择粒径为15nm (S)、38nm (M)和75nm (L)的三种不同类型的CB,并将其组合在一起,形成了19种配方在双螺杆挤出机中以30%的比例分散在低密度聚乙烯(LDPE)中的实验设计(DOE)。这些配方在性能和工艺性能方面进行了评估,如着色强度、熔体流动指数(MFI)和总透光率(TT)。观察到,小(S)和中(M)颗粒之间的混合物具有更大的着色强度和更低的粘度,证明了混合物的协同作用,其中仅含有15nm (S)特定颗粒的混合物的性能更优越,具有更大的结果潜力。
{"title":"Influence of carbon black trimodal mixture on LDPE films properties: Part1 - DOE","authors":"J. Barbosa, C. G. Beatrice, L. Pessan","doi":"10.1590/0104-1428.20220039","DOIUrl":"https://doi.org/10.1590/0104-1428.20220039","url":null,"abstract":"In this study, the influence of carbon black (CB) trimodal mixture, with different medium particle sizes, on the colorimetric and rheological properties of polyethylene was evaluated. Three different types of CB were selected, with particle sizes of 15nm (S), 38nm (M), and 75nm (L) and combined, generating a Design of Experiments (DOE) with 19 formulations to be dispersed at 30% in low density polyethylene (LDPE) in twin screw extruder. Such formulations were evaluated in performance and process properties, such as Tint Strength, Melt Flow Index (MFI), and Total Transmittance (TT). It was observed that the mixtures between small (S) and medium (M) particles developed greater tinting strength and lower viscosity, demonstrating the synergy of the mixture, which was superior in the performance of the mixture containing only a particular of 15nm (S) that would have greater potential for results.","PeriodicalId":20282,"journal":{"name":"Polimeros-ciencia E Tecnologia","volume":"1 1","pages":""},"PeriodicalIF":1.3,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"67122040","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Potential antioxidant migration from polyethylene packaging to food: a systematic review 从聚乙烯包装到食品的潜在抗氧化剂迁移:系统综述
IF 1.3 4区 化学 Q4 POLYMER SCIENCE Pub Date : 2022-01-01 DOI: 10.1590/0104-1428.20220081
Mayara de Simas Mesquita, S. Abrantes
{"title":"Potential antioxidant migration from polyethylene packaging to food: a systematic review","authors":"Mayara de Simas Mesquita, S. Abrantes","doi":"10.1590/0104-1428.20220081","DOIUrl":"https://doi.org/10.1590/0104-1428.20220081","url":null,"abstract":"","PeriodicalId":20282,"journal":{"name":"Polimeros-ciencia E Tecnologia","volume":"1 1","pages":""},"PeriodicalIF":1.3,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"67122203","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Obtaining and characterization of bioplastics based on potato starch, aloe, and graphene 基于马铃薯淀粉、芦荟和石墨烯的生物塑料的制备和表征
IF 1.3 4区 化学 Q4 POLYMER SCIENCE Pub Date : 2022-01-01 DOI: 10.1590/0104-1428.20220084
Mercedes Puca Pacheco, Oscar Rafael Tinoco Gómez, G. C. Escamilla, Santiago Duarte Aranda, M. Velázquez
{"title":"Obtaining and characterization of bioplastics based on potato starch, aloe, and graphene","authors":"Mercedes Puca Pacheco, Oscar Rafael Tinoco Gómez, G. C. Escamilla, Santiago Duarte Aranda, M. Velázquez","doi":"10.1590/0104-1428.20220084","DOIUrl":"https://doi.org/10.1590/0104-1428.20220084","url":null,"abstract":"","PeriodicalId":20282,"journal":{"name":"Polimeros-ciencia E Tecnologia","volume":"1 1","pages":""},"PeriodicalIF":1.3,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"67122272","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Polimeros-ciencia E Tecnologia
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