首页 > 最新文献

PROBLEMS OF ATOMIC SCIENCE AND TECHNOLOGY. SERIES: NUCLEAR AND REACTOR CONSTANTS最新文献

英文 中文
TRANSMUTATION OF MINOR ACTINIDES IN MOLTEN SALT BURNER REACTOR 熔盐燃烧器反应器中微量锕系元素的嬗变
Pub Date : 2021-12-26 DOI: 10.55176/2414-1038-2021-4-18-27
M. Belonogov, I. Volkov, D. Modestov, V. Simonenko, D. Khmelnitsky, V. Eliseev
Reduction in the amount of accumulated minor actinides (Np, Am, and Cm isotopes), as well as, the long-lived fission products, to the extent possible, is a top-priority task for the nuclear power engineering. Transmutation of this waste in a special-purpose molten-salt burner reactor has been currently proposed as a possible solution for this problem. The objective of the present paper is to investigate basic regularities of Np, Am, and Cm transmutation in the molten salt burner reactor and to determine optimal operational conditions of the reactor. In the optimal equilibrium mode just fluorides of these elements are added into the fuel composition but the fission products are extracted from it. This mode are reached by maintaining a specified actinide concentration. In order to provide the reactor criticality with a lower than optimum actinide concentration, it is required to add plutonium in the feed fuel instead of a certain amount of minor actinides, thus impairing the transmutation efficiency. To keep the critical state in the equilibrium mode, in situations where the actinide concentration is higher than the optimum one, it is essential to extract a portion of fuel with high content of 238Pu. It has been shown that the reactor configuration is the primary factor responsible for optimum actinide concentration value and that this value varies little with the feed fuel composition, the type of salt dissolving agent, and the fuel reprocessing mode. Optimal concentration for the molten-salt burner reactor with the core volume ranging from 2 to 30 m3 is within 17…10 mole %.
尽可能减少微量锕系元素(Np、Am和Cm同位素)的累积量,以及长寿命的裂变产物,是核电工程的首要任务。目前已提出在专用熔盐燃烧器反应堆中对这些废物进行嬗变,作为解决这一问题的可能方案。本文的目的是研究熔盐燃烧器反应器中Np、Am和Cm嬗变的基本规律,并确定反应器的最佳运行条件。在最佳平衡模式下,只将这些元素的氟化物添加到燃料成分中,而从中提取裂变产物。这种模式是通过维持特定的锕系元素浓度来实现的。为了使反应堆临界浓度低于最佳锕系元素浓度,需要在进料燃料中添加钚而不是一定量的微量锕系元素,从而降低嬗变效率。为了使临界状态保持在平衡模式,在锕系元素浓度高于最佳浓度的情况下,必须提取一部分高238Pu含量的燃料。结果表明,反应器结构是影响最佳锕系元素浓度值的主要因素,该浓度值随进料燃料组成、盐溶剂类型和燃料后处理方式变化不大。堆芯体积在2 ~ 30 m3的熔盐燃烧器反应器的最佳浓度在17 ~ 10摩尔%之间。
{"title":"TRANSMUTATION OF MINOR ACTINIDES IN MOLTEN SALT BURNER REACTOR","authors":"M. Belonogov, I. Volkov, D. Modestov, V. Simonenko, D. Khmelnitsky, V. Eliseev","doi":"10.55176/2414-1038-2021-4-18-27","DOIUrl":"https://doi.org/10.55176/2414-1038-2021-4-18-27","url":null,"abstract":"Reduction in the amount of accumulated minor actinides (Np, Am, and Cm isotopes), as well as, the long-lived fission products, to the extent possible, is a top-priority task for the nuclear power engineering. Transmutation of this waste in a special-purpose molten-salt burner reactor has been currently proposed as a possible solution for this problem. The objective of the present paper is to investigate basic regularities of Np, Am, and Cm transmutation in the molten salt burner reactor and to determine optimal operational conditions of the reactor. In the optimal equilibrium mode just fluorides of these elements are added into the fuel composition but the fission products are extracted from it. This mode are reached by maintaining a specified actinide concentration. In order to provide the reactor criticality with a lower than optimum actinide concentration, it is required to add plutonium in the feed fuel instead of a certain amount of minor actinides, thus impairing the transmutation efficiency. To keep the critical state in the equilibrium mode, in situations where the actinide concentration is higher than the optimum one, it is essential to extract a portion of fuel with high content of 238Pu. It has been shown that the reactor configuration is the primary factor responsible for optimum actinide concentration value and that this value varies little with the feed fuel composition, the type of salt dissolving agent, and the fuel reprocessing mode. Optimal concentration for the molten-salt burner reactor with the core volume ranging from 2 to 30 m3 is within 17…10 mole %.","PeriodicalId":20426,"journal":{"name":"PROBLEMS OF ATOMIC SCIENCE AND TECHNOLOGY. SERIES: NUCLEAR AND REACTOR CONSTANTS","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2021-12-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85071343","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
BEHAVIOR OF CHEMICALLY ACTIVE ORGANIC IMPURITIES IN SODIUM CIRCUITS 钠电路中化学活性有机杂质的行为
Pub Date : 2021-12-26 DOI: 10.55176/2414-1038-2021-4-154-161
Y. Zagorulko, N. Ganichev, M. Konovalov, V. Alekseev
Mineral oils and some other organic substances are employed as cooling-agents and lubricators of reactor equipment with movable parts. At normal operation condition these substances are able to penetrate into reactor protective gas plenum in vapor and aerosols forms. Due to their thermolysis and interaction with sodium there are produced hydrogen and different hydrocarbons species, that are detected usually in cover gas. Kinetic of the above processes is dependent on temperature conditions and with temperature increase from 350 to 500 °C the evolution of some hydrocarbons could rise up to 1-2 orders of magnitude. There were published notes on accidental ingress of oil in the primary circuit of fast reactor sodium coolant. Investigation results of such accidents simulation on the experimental sodium circuit are presented in the report. There are discussed results on kinetic of volatile hydrocarbons evolution from oil-pyrolysis products depositions on the circuit pipes walls and gas plenum surfaces. As well, different brands of oil are compared on their behavior in sodium environment.
矿物油和其他一些有机物质被用作具有活动部件的反应堆设备的冷却剂和润滑剂。在正常操作条件下,这些物质能够以蒸汽和气溶胶的形式渗透到反应堆保护气体中。由于它们的热分解和与钠的相互作用,产生了氢和不同种类的碳氢化合物,这些碳氢化合物通常在盖气中检测到。上述过程的动力学取决于温度条件,当温度从350°C升高到500°C时,一些碳氢化合物的演化可以上升到1-2个数量级。关于快堆钠冷却剂一次回路中意外入油的报道已发表。本文还介绍了在实验钠电路上对此类事故进行模拟的调查结果。讨论了油热解产物沉积在回路管壁和气体静压室表面的挥发性烃演化动力学结果。并比较了不同牌号的油脂在钠环境中的行为。
{"title":"BEHAVIOR OF CHEMICALLY ACTIVE ORGANIC IMPURITIES IN SODIUM CIRCUITS","authors":"Y. Zagorulko, N. Ganichev, M. Konovalov, V. Alekseev","doi":"10.55176/2414-1038-2021-4-154-161","DOIUrl":"https://doi.org/10.55176/2414-1038-2021-4-154-161","url":null,"abstract":"Mineral oils and some other organic substances are employed as cooling-agents and lubricators of reactor equipment with movable parts. At normal operation condition these substances are able to penetrate into reactor protective gas plenum in vapor and aerosols forms. Due to their thermolysis and interaction with sodium there are produced hydrogen and different hydrocarbons species, that are detected usually in cover gas. Kinetic of the above processes is dependent on temperature conditions and with temperature increase from 350 to 500 °C the evolution of some hydrocarbons could rise up to 1-2 orders of magnitude. There were published notes on accidental ingress of oil in the primary circuit of fast reactor sodium coolant. Investigation results of such accidents simulation on the experimental sodium circuit are presented in the report. There are discussed results on kinetic of volatile hydrocarbons evolution from oil-pyrolysis products depositions on the circuit pipes walls and gas plenum surfaces. As well, different brands of oil are compared on their behavior in sodium environment.","PeriodicalId":20426,"journal":{"name":"PROBLEMS OF ATOMIC SCIENCE AND TECHNOLOGY. SERIES: NUCLEAR AND REACTOR CONSTANTS","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2021-12-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83636232","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
CHARACTERISTICS OF AN ANNULAR FIN OF A RECTANGULAR PROFILE WITH ENERGY RELEASE 带能量释放的矩形型环形翅片的特性
Pub Date : 2021-12-26 DOI: 10.55176/2414-1038-2021-4-98-105
V. Levchenko, M. Kascheev, S. Dorokhovich, A. Zaytsev, A. Sorokin
The heat conduction equation for an annular fin with an arbitrary profile in the presence of energy release in the fin is obtained in the article. The resulting equation differs from the approximate equation given in the literature by the presence of energy release and a more accurate determination of the length of the arc element. As boundary conditions, the temperature of the base of the fin is set, and at the end of the fin, heat exchange occurs according to the Newton - Richmann law with the environment. The equation for the fin of a rectangular profile is an inhomogeneous modified Bessel equation. Its solution contains the Bessel functions of the imaginary argument of the first and second kind of zero order. The efficiency of the fin and the heat flow through the base of the fin are determined. The energy release in the fin increases its efficiency compared to the efficiency of the fin in the absence of energy release, and also reduces the heat flow. The restriction by the values of energy release in the fin is found as condition for the applicability of the finning. The fin efficiency must be less than one. If the efficiency exceeds one, the fin plays the opposite role: the flow is directed in the reverse side. In the article, an expression is obtained for the surface build-up coefficient kh. When calculating the heating (cooling) of a body with a finned surface, the heat transfer coefficient should be increased by kh times.
本文得到了任意型面环形翅片存在能量释放时的热传导方程。所得到的方程不同于文献中给出的近似方程,因为存在能量释放和更准确地确定弧元的长度。作为边界条件,设定翅片底部温度,在翅片末端根据牛顿-里奇曼定律与环境进行换热。矩形剖面翅片的方程是一个非齐次修正贝塞尔方程。它的解包含了第一类和第二类零阶虚参的贝塞尔函数。确定了翅片的效率和通过翅片底部的热流。与无能量释放时相比,翅片中的能量释放提高了其效率,同时也减少了热流。发现了鳍片能量释放值的限制是鳍片适用性的条件。翅片效率必须小于1。如果效率超过1,则翅片起相反的作用:气流被引导到相反的一侧。文中给出了表面堆积系数kh的表达式。在计算翅片表面物体的加热(冷却)时,传热系数应增加kh倍。
{"title":"CHARACTERISTICS OF AN ANNULAR FIN OF A RECTANGULAR PROFILE WITH ENERGY RELEASE","authors":"V. Levchenko, M. Kascheev, S. Dorokhovich, A. Zaytsev, A. Sorokin","doi":"10.55176/2414-1038-2021-4-98-105","DOIUrl":"https://doi.org/10.55176/2414-1038-2021-4-98-105","url":null,"abstract":"The heat conduction equation for an annular fin with an arbitrary profile in the presence of energy release in the fin is obtained in the article. The resulting equation differs from the approximate equation given in the literature by the presence of energy release and a more accurate determination of the length of the arc element. As boundary conditions, the temperature of the base of the fin is set, and at the end of the fin, heat exchange occurs according to the Newton - Richmann law with the environment. The equation for the fin of a rectangular profile is an inhomogeneous modified Bessel equation. Its solution contains the Bessel functions of the imaginary argument of the first and second kind of zero order. The efficiency of the fin and the heat flow through the base of the fin are determined. The energy release in the fin increases its efficiency compared to the efficiency of the fin in the absence of energy release, and also reduces the heat flow. The restriction by the values of energy release in the fin is found as condition for the applicability of the finning. The fin efficiency must be less than one. If the efficiency exceeds one, the fin plays the opposite role: the flow is directed in the reverse side. In the article, an expression is obtained for the surface build-up coefficient kh. When calculating the heating (cooling) of a body with a finned surface, the heat transfer coefficient should be increased by kh times.","PeriodicalId":20426,"journal":{"name":"PROBLEMS OF ATOMIC SCIENCE AND TECHNOLOGY. SERIES: NUCLEAR AND REACTOR CONSTANTS","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2021-12-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90900500","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
ALGORITHM FOR ESTIMATING THE EFFICIENCY OF NEURAL NETWORKS FOR n/γ-SEPARATION IN ORGANIC SCINTILLATORS 有机闪烁体中n/γ分离的神经网络效率估计算法
Pub Date : 2021-12-26 DOI: 10.55176/2414-1038-2021-4-5-17
T. Bobrovsky, P. Prusachenko, V. Khryachkov, P. D’yachenko
Machine learning is one of the leading directions in digital signal processing. For example, in neutron spectrometry, artificial neural networks are actively used to suppress gamma background when analyzing signals from scintillation detectors. This article describes a method for determining the quality of n/γ-separation by an artificial neural network. The efficiency of the method is demonstrated by analyzing the signals obtained by measuring the prompt neutron spectrum of 252Cf spontaneous fission using a scintillation detector based on a stilbene crystal. The essence of the method is to determine the proportion of falsely identified events for each of the analyzed signal classes using a known reference method. An exemplary gamma-ray source was used to determine the false count of recoil protons. This approach made it possible to estimate the fraction of events from electrons identified as recoil protons and the fraction of recoil protons perceived as electrons, depending on the light yield of the scintillation signal. This, in turn, made it possible to reconstruct the true energy spectra for different types of particles, including for the region of low signal amplitudes, where the separation quality is usually poor. The reconstructing error was less than 8 % for the light yield region of less than 120 keVee.
机器学习是数字信号处理的主要方向之一。例如,在中子能谱分析中,人工神经网络在分析闪烁探测器信号时被积极地用于抑制伽马背景。本文介绍了一种用人工神经网络测定n/γ分离质量的方法。利用二苯乙烯晶体的闪烁探测器对252Cf自发裂变的瞬发中子谱信号进行了分析,证明了该方法的有效性。该方法的本质是使用已知的参考方法确定每个被分析信号类的错误识别事件的比例。一个典型的伽玛射线源被用来确定反冲质子的假计数。根据闪烁信号的光产率,这种方法可以估计出被识别为反冲质子的电子和被感知为电子的反冲质子的比例。这反过来又使得重建不同类型粒子的真实能谱成为可能,包括分离质量通常较差的低信号幅值区域。在小于120keee的光屈服区,重建误差小于8%。
{"title":"ALGORITHM FOR ESTIMATING THE EFFICIENCY OF NEURAL NETWORKS FOR n/γ-SEPARATION IN ORGANIC SCINTILLATORS","authors":"T. Bobrovsky, P. Prusachenko, V. Khryachkov, P. D’yachenko","doi":"10.55176/2414-1038-2021-4-5-17","DOIUrl":"https://doi.org/10.55176/2414-1038-2021-4-5-17","url":null,"abstract":"Machine learning is one of the leading directions in digital signal processing. For example, in neutron spectrometry, artificial neural networks are actively used to suppress gamma background when analyzing signals from scintillation detectors. This article describes a method for determining the quality of n/γ-separation by an artificial neural network. The efficiency of the method is demonstrated by analyzing the signals obtained by measuring the prompt neutron spectrum of 252Cf spontaneous fission using a scintillation detector based on a stilbene crystal. The essence of the method is to determine the proportion of falsely identified events for each of the analyzed signal classes using a known reference method. An exemplary gamma-ray source was used to determine the false count of recoil protons. This approach made it possible to estimate the fraction of events from electrons identified as recoil protons and the fraction of recoil protons perceived as electrons, depending on the light yield of the scintillation signal. This, in turn, made it possible to reconstruct the true energy spectra for different types of particles, including for the region of low signal amplitudes, where the separation quality is usually poor. The reconstructing error was less than 8 % for the light yield region of less than 120 keVee.","PeriodicalId":20426,"journal":{"name":"PROBLEMS OF ATOMIC SCIENCE AND TECHNOLOGY. SERIES: NUCLEAR AND REACTOR CONSTANTS","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2021-12-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79788967","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
RESEARCH OF THE VORTEX FLOWS INFLUENCE ON THE NPP ELEMENTS 涡旋流动对NPP元件影响的研究
Pub Date : 2021-12-26 DOI: 10.55176/2414-1038-2021-4-72-81
O. Mitrofanova, A. Bayramukov, O. Ivlev, D. Urtenov, A. Fedorinov, A. Sorokin
The mechanisms of generation of stable large-scale eddies and flow swirling in complex channels of the 1st and 2nd circuits of transport nuclear power plants (NPP) are revealed. An analysis is given of the influence of vortex formation and flow swirling processes on failures in NPP systems. It is shown that with a complex geometry of the channels of the pipe systems of the thermohydraulic tract and the reactor plant (RP), the unauthorized swirl arising in certain dynamic modes can lead to the effect of blocking the flow caused by the swirl flow crisis. It has been established that the phenomenon of the crisis is accompanied by the generation of low-frequency acoustic vibrations and large pressure losses required to form a recirculation flow zone, which prevents the flow of fluids in complex channels of the nuclear power plant. In the presented work, the manifestation of a swirling flow crisis is considered by examples of modeling the processes of hydrodynamics and heat transfer in the channels of steam generators and the pressure compensation system of transport nuclear power plants. It is shown that the generation of stable vortex formations in the elements of the NPP equipment of the integral type can be directly related to the mechanism of excitation of hazardous vibroresonance effects. Methods for improving the design of pipe systems of steam generating plants are proposed to increase their thermal-hydraulic efficiency and vibration resistance.
揭示了运输核电站一回路和二回路复杂通道内稳定大尺度涡流和流旋的产生机理。分析了核动力核电厂系统中涡流的形成和旋流过程对失效的影响。研究结果表明,由于热工通道和反应堆装置管道系统的通道几何形状复杂,在某些动力模式下产生的非许可涡流会导致涡流流动危机造成的阻塞效应。已经确定,危机现象伴随着形成再循环流动区所需的低频声振动和大压力损失的产生,从而阻止了核电站复杂通道中流体的流动。在本工作中,通过对蒸汽发生器通道中的流体力学和传热过程以及运输核电站的压力补偿系统进行建模,考虑了漩涡流动危机的表现形式。结果表明,整体式核电站装置元件中稳定涡的产生与危险振共振效应的激发机制有直接关系。提出了改进蒸汽发电厂管道系统设计的方法,以提高其热水效率和抗振性。
{"title":"RESEARCH OF THE VORTEX FLOWS INFLUENCE ON THE NPP ELEMENTS","authors":"O. Mitrofanova, A. Bayramukov, O. Ivlev, D. Urtenov, A. Fedorinov, A. Sorokin","doi":"10.55176/2414-1038-2021-4-72-81","DOIUrl":"https://doi.org/10.55176/2414-1038-2021-4-72-81","url":null,"abstract":"The mechanisms of generation of stable large-scale eddies and flow swirling in complex channels of the 1st and 2nd circuits of transport nuclear power plants (NPP) are revealed. An analysis is given of the influence of vortex formation and flow swirling processes on failures in NPP systems. It is shown that with a complex geometry of the channels of the pipe systems of the thermohydraulic tract and the reactor plant (RP), the unauthorized swirl arising in certain dynamic modes can lead to the effect of blocking the flow caused by the swirl flow crisis. It has been established that the phenomenon of the crisis is accompanied by the generation of low-frequency acoustic vibrations and large pressure losses required to form a recirculation flow zone, which prevents the flow of fluids in complex channels of the nuclear power plant. In the presented work, the manifestation of a swirling flow crisis is considered by examples of modeling the processes of hydrodynamics and heat transfer in the channels of steam generators and the pressure compensation system of transport nuclear power plants. It is shown that the generation of stable vortex formations in the elements of the NPP equipment of the integral type can be directly related to the mechanism of excitation of hazardous vibroresonance effects. Methods for improving the design of pipe systems of steam generating plants are proposed to increase their thermal-hydraulic efficiency and vibration resistance.","PeriodicalId":20426,"journal":{"name":"PROBLEMS OF ATOMIC SCIENCE AND TECHNOLOGY. SERIES: NUCLEAR AND REACTOR CONSTANTS","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2021-12-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"91481854","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
SPECIFICS OF HEAT TRANSFER AND HYDRODYNAMICS DURING MOLTEN SALT IMITATOR FLOW IN A DUCT 熔盐模拟器在管道内流动时的传热和流体动力学特性
Pub Date : 2021-12-26 DOI: 10.55176/2414-1038-2021-4-82-97
E. Belavina, I. Belyaev, N. Pyatnitskaya, A. Sorokin
The possibility of using molten salts based on fluorides as a coolant in promising developments in nuclear power systems requires solving several key scientific and technical problems. These problems are associated with development of reliable structural materials and study of thermophysical characteristics of coolant. Solution to the latter problem was constrained by lack of reliable systematic data on physical and chemical properties, specificity of heat transfer processes, and operation technology of promising compositions of fluoride molten salt. In this regard, a comprehensive study, consisting of studying properties of promising fluoride salt melts, as well as creating an experimental base for verification of engineering calculations, is of particular interest for design of reactor facilities. In course of the work, specifics of interaction of electromagnetic forces and buoyancy forces during MHD heat transfer of molten salt, which can manifest itself in the formation of local overheating points or quasi-stationary flow regimes accompanied by low-frequency temperature fluctuations, were experimentally investigated. For first time, dependences of heat transfer coefficients in a stream under influence of a magnetic field in an extended range of operating parameters were experimentally obtained. The results are compared with known patterns and numerical modeling.
在核能系统的发展中,使用基于氟化物的熔盐作为冷却剂的可能性需要解决几个关键的科学和技术问题。这些问题与可靠结构材料的开发和冷却剂热物理特性的研究有关。由于缺乏关于氟熔盐的物理和化学性质、传热过程的特殊性以及有前途的组合物的操作技术的可靠的系统数据,限制了后一个问题的解决。在这方面,一项全面的研究,包括研究有前途的氟盐熔体的性质,以及建立一个验证工程计算的实验基地,对反应堆设施的设计特别有意义。实验研究了熔盐MHD换热过程中电磁力和浮力相互作用的具体情况,这些相互作用可以表现为局部过热点的形成或伴随低频温度波动的准稳态流动状态。本文首次通过实验获得了在一定范围的工作参数下,磁场影响下流体传热系数的依赖关系。结果与已知模式和数值模拟进行了比较。
{"title":"SPECIFICS OF HEAT TRANSFER AND HYDRODYNAMICS DURING MOLTEN SALT IMITATOR FLOW IN A DUCT","authors":"E. Belavina, I. Belyaev, N. Pyatnitskaya, A. Sorokin","doi":"10.55176/2414-1038-2021-4-82-97","DOIUrl":"https://doi.org/10.55176/2414-1038-2021-4-82-97","url":null,"abstract":"The possibility of using molten salts based on fluorides as a coolant in promising developments in nuclear power systems requires solving several key scientific and technical problems. These problems are associated with development of reliable structural materials and study of thermophysical characteristics of coolant. Solution to the latter problem was constrained by lack of reliable systematic data on physical and chemical properties, specificity of heat transfer processes, and operation technology of promising compositions of fluoride molten salt. In this regard, a comprehensive study, consisting of studying properties of promising fluoride salt melts, as well as creating an experimental base for verification of engineering calculations, is of particular interest for design of reactor facilities. In course of the work, specifics of interaction of electromagnetic forces and buoyancy forces during MHD heat transfer of molten salt, which can manifest itself in the formation of local overheating points or quasi-stationary flow regimes accompanied by low-frequency temperature fluctuations, were experimentally investigated. For first time, dependences of heat transfer coefficients in a stream under influence of a magnetic field in an extended range of operating parameters were experimentally obtained. The results are compared with known patterns and numerical modeling.","PeriodicalId":20426,"journal":{"name":"PROBLEMS OF ATOMIC SCIENCE AND TECHNOLOGY. SERIES: NUCLEAR AND REACTOR CONSTANTS","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2021-12-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78559402","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
SIMULATION OF THE THERMOMECHANICAL BEHAVIOR OF (U, Gd)O2 FUEL ELEMENTS IN THE RTOP-CA CODE 在RTOP-CA规范中模拟(U, Gd)O2燃料元件的热力学行为
Pub Date : 2021-12-26 DOI: 10.55176/2414-1038-2021-4-35-46
V. Likhanskii, A. Sorokin, V. Zborovskii, K. Ulibyshev, A. Strozhuk, I. Chernov
The paper presents a description of the RTOP-CA code models designed for simulating the behavior of (U, Gd)O2 fuel rods, presents the examples of program verification using experimental data obtained at the research reactor in Halden and in the post-irradiation examinations of WWER fuel. The experience of operating WWER fuel has shown that differences in the thermomechanical behavior of (U, Gd)O2 fuel elements and UO2 fuel rods during the first - second fuel cycles can be observed. In particular, an accelerated increase in the length of the (U, Gd)O2 fuel rod cladding as compared to UO2 fuel elements is possible. To simulate the behavior of (U, Gd)O2 fuel rods under irradiation in the RTOP-CA code, models that describe the features of uranium-gadolinium fuel were developed. To calculate the evolution of heat release in (U, Gd)O2 fuel rods in the RTOP-CA code, a model of burnup of gadolinium isotopes was implemented. The developed model makes it possible, without using of detailed neutron-physical calculations, to simulate the burnup of gadolinium and the evolution of heat generation along the radius of the pellets. The models take into account the effect of the gadolinium oxide content on the thermophysical and mechanical properties of the fuel. The calculations performed using the RTOP-CA code are in good agreement with the results obtained during the experiments in Halden on the dynamics of the central fuel temperature, gas pressure in the (U, Gd)O2 fuel rod, and the elongation of the fuel column and cladding. To simulate the accelerated elongation of (U, Gd)O2 fuel rods in comparison with standard WWER fuel elements at the initial stages of fuel operation at nuclear power plants in the RTOP-CA code, a model of mechanical interaction of pellets and cladding was developed taking into account the misaligned arrangement of pellets.
本文介绍了为模拟(U, Gd)O2燃料棒的性能而设计的RTOP-CA代码模型,并给出了在Halden研究堆和WWER燃料辐照后检验中获得的实验数据进行程序验证的实例。运行WWER燃料的经验表明,(U, Gd)O2燃料元件和UO2燃料棒在第一次和第二次燃料循环期间的热力学行为是不同的。特别是,与UO2燃料元件相比,(U, Gd)O2燃料棒包壳长度的加速增加是可能的。为了模拟(U, Gd)O2燃料棒在RTOP-CA规范下的辐照行为,建立了描述铀-钆燃料特性的模型。为了计算RTOP-CA规范中(U, Gd)O2燃料棒的放热演化,建立了钆同位素燃耗模型。开发的模型可以在不使用详细的中子物理计算的情况下,模拟钆的燃耗和沿球团半径产生热量的演变。该模型考虑了氧化钆含量对燃料热物理和机械性能的影响。用RTOP-CA程序计算的结果与在Halden试验中得到的中心燃料温度、(U, Gd)O2燃料棒内气体压力、燃料柱和包壳伸长率的动力学结果吻合较好。为了模拟核电厂燃料运行初期(U, Gd)O2燃料棒与标准WWER燃料元件相比的加速伸长,在RTOP-CA规范中,考虑球团排列不一致的情况,建立了球团与包壳的力学相互作用模型。
{"title":"SIMULATION OF THE THERMOMECHANICAL BEHAVIOR OF (U, Gd)O2 FUEL ELEMENTS IN THE RTOP-CA CODE","authors":"V. Likhanskii, A. Sorokin, V. Zborovskii, K. Ulibyshev, A. Strozhuk, I. Chernov","doi":"10.55176/2414-1038-2021-4-35-46","DOIUrl":"https://doi.org/10.55176/2414-1038-2021-4-35-46","url":null,"abstract":"The paper presents a description of the RTOP-CA code models designed for simulating the behavior of (U, Gd)O2 fuel rods, presents the examples of program verification using experimental data obtained at the research reactor in Halden and in the post-irradiation examinations of WWER fuel. The experience of operating WWER fuel has shown that differences in the thermomechanical behavior of (U, Gd)O2 fuel elements and UO2 fuel rods during the first - second fuel cycles can be observed. In particular, an accelerated increase in the length of the (U, Gd)O2 fuel rod cladding as compared to UO2 fuel elements is possible. To simulate the behavior of (U, Gd)O2 fuel rods under irradiation in the RTOP-CA code, models that describe the features of uranium-gadolinium fuel were developed. To calculate the evolution of heat release in (U, Gd)O2 fuel rods in the RTOP-CA code, a model of burnup of gadolinium isotopes was implemented. The developed model makes it possible, without using of detailed neutron-physical calculations, to simulate the burnup of gadolinium and the evolution of heat generation along the radius of the pellets. The models take into account the effect of the gadolinium oxide content on the thermophysical and mechanical properties of the fuel. The calculations performed using the RTOP-CA code are in good agreement with the results obtained during the experiments in Halden on the dynamics of the central fuel temperature, gas pressure in the (U, Gd)O2 fuel rod, and the elongation of the fuel column and cladding. To simulate the accelerated elongation of (U, Gd)O2 fuel rods in comparison with standard WWER fuel elements at the initial stages of fuel operation at nuclear power plants in the RTOP-CA code, a model of mechanical interaction of pellets and cladding was developed taking into account the misaligned arrangement of pellets.","PeriodicalId":20426,"journal":{"name":"PROBLEMS OF ATOMIC SCIENCE AND TECHNOLOGY. SERIES: NUCLEAR AND REACTOR CONSTANTS","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2021-12-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86983418","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
SOFTWARE MODULE FOR CALCULATING THERMOPHYSICAL PARAMETERS IN HYDRAULIC CHANNELS OF SUPERCRITICAL WATER REACTOR 超临界水反应堆水力通道热物性参数计算软件模块
Pub Date : 2021-12-26 DOI: 10.55176/2414-1038-2021-4-131-146
V. Zborovskii, O. Khoruzhii, V. Likhanskii, N. Elkin, M. Chernetskii, V. Mahin
The paper describes the software module FRC-SCP intended for thermohydraulic simulation of a coolant under supercritical pressure (SCP) and a cooled fuel rod. Several designs of supercritical water reactors utilize the transition of the coolant from the pseudoliquid state to pseudogas while it is heated in the reactor core. SCP coolant under pseudophase transition exhibits specific behavior as its density changes significantly. Furthermore, coolant thermophysical properties (density, heat capacity, viscosity, thermal conductivity) can also vary across the coolant channel affecting heat transfer from the fuel rod to the coolant and consequently the fuel temperature. Existing feedback dependencies on coolant density and fuel temperature are important for the nuclear safety analysis of the reactor. The paper considers the present version of the FRC-SCP module. It implements the steady-state thermohydraulic channel solver to calculate coolant parameters: temperatures of the flow core and a heater, as well as coolant pressures, densities etc. User-specified correlations define the heat transfer law under the normal conditions. The module solves the thermal problem for the fuel rod consistently with the channel thermohydraulic problem. It is also possible to couple the FRC-SCP module with the neutron physical codes. Thermohydraulic module is tested against experiments on the heat transfer to SCP water in heated tubes. We discuss the behavior of the fuel cladding under conditions imitating the deteriorated heat transfer modes and the effect of the nuclear fuel thermal conductivity.
本文介绍了用于超临界压力下冷却剂和冷却燃料棒热水力模拟的软件模块FRC-SCP。几种超临界水反应堆的设计利用了冷却剂在堆芯加热时从伪液体状态到伪气体状态的转变。伪相转变下的SCP冷却剂表现出特定的行为,其密度发生显著变化。此外,冷却剂的热物理性质(密度、热容量、粘度、导热系数)也会在冷却剂通道中变化,影响从燃料棒到冷却剂的传热,从而影响燃料温度。现有的对冷却剂密度和燃料温度的反馈依赖性对反应堆的核安全分析是重要的。本文考虑了当前版本的FRC-SCP模块。它实现了稳态热液通道求解器来计算冷却剂参数:流芯和加热器的温度,以及冷却剂的压力、密度等。用户指定的关联定义了正常条件下的传热规律。该模块既解决了燃料棒的热问题,又解决了通道热液压问题。也可以将FRC-SCP模块与中子物理代码耦合。通过热液模块在加热管中对SCP水的传热实验进行了测试。讨论了核燃料包壳在模拟变质传热模式条件下的行为以及核燃料导热系数的影响。
{"title":"SOFTWARE MODULE FOR CALCULATING THERMOPHYSICAL PARAMETERS IN HYDRAULIC CHANNELS OF SUPERCRITICAL WATER REACTOR","authors":"V. Zborovskii, O. Khoruzhii, V. Likhanskii, N. Elkin, M. Chernetskii, V. Mahin","doi":"10.55176/2414-1038-2021-4-131-146","DOIUrl":"https://doi.org/10.55176/2414-1038-2021-4-131-146","url":null,"abstract":"The paper describes the software module FRC-SCP intended for thermohydraulic simulation of a coolant under supercritical pressure (SCP) and a cooled fuel rod. Several designs of supercritical water reactors utilize the transition of the coolant from the pseudoliquid state to pseudogas while it is heated in the reactor core. SCP coolant under pseudophase transition exhibits specific behavior as its density changes significantly. Furthermore, coolant thermophysical properties (density, heat capacity, viscosity, thermal conductivity) can also vary across the coolant channel affecting heat transfer from the fuel rod to the coolant and consequently the fuel temperature. Existing feedback dependencies on coolant density and fuel temperature are important for the nuclear safety analysis of the reactor. The paper considers the present version of the FRC-SCP module. It implements the steady-state thermohydraulic channel solver to calculate coolant parameters: temperatures of the flow core and a heater, as well as coolant pressures, densities etc. User-specified correlations define the heat transfer law under the normal conditions. The module solves the thermal problem for the fuel rod consistently with the channel thermohydraulic problem. It is also possible to couple the FRC-SCP module with the neutron physical codes. Thermohydraulic module is tested against experiments on the heat transfer to SCP water in heated tubes. We discuss the behavior of the fuel cladding under conditions imitating the deteriorated heat transfer modes and the effect of the nuclear fuel thermal conductivity.","PeriodicalId":20426,"journal":{"name":"PROBLEMS OF ATOMIC SCIENCE AND TECHNOLOGY. SERIES: NUCLEAR AND REACTOR CONSTANTS","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2021-12-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89003855","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
EXPERIMENTAL MODELING OF HEAT EXCHANGE IN HEAT GENERATING ASSEMBLIES OF FAST REACTORS IN ACCIDENT REGIMES UNDER NATURAL CONVECTION CONDITIONS 自然对流条件下事故状态下快堆产热组件热交换的实验模拟
Pub Date : 2021-12-26 DOI: 10.55176/2414-1038-2021-4-106-120
Yu. A. Kuzina, A. Sorokin, N. Denisova, M. Kascheev
The results of experimental studies of heat transfer carried out at the State Research Center RF - IPPE on models of fuel assemblies in cores and screens of fast reactors BOR-60, BN-350, BN-600, BN-800 (the relative pitch of the fuel element simulators varied in the range 1.04≤s/d≤1.24) with natural and mixed convection of liquid metal coolants, which are the basis for the development of design codes. Model fuel assemblies of fast reactors contain 37 fuel elements (fuel rod simulators) located in a triangular lattice and enclosed in a hexagonal cover. The elements were heated with nichrome heaters, which ensure a constant heat flux on the inner surface of the elements and along the length of the heat generation. The central, lateral and corner elements are rotary. On their surface, 12 chromel-alumel thermocouples each in covers made of X18H9T steel (diameter of the cover 0.8-0.5 mm, diameter of thermoelectrodes 0.2 mm) are embedded, measuring the coolant temperature in the collectors of the models, as well as in each cell at the exit from the bundles. The spacing of the elements is carried out using wire coils; variants of smooth fuel rod simulators are also used. Experimental studies on model fuel assemblies revealed regularities in the formation of temperature fields in fuel elements and coolant. Natural convection manifests itself in the region of low velocities, promotes fluid mixing between channels, leveling the uneven heating of the coolant in the cross section of the fuel assembly, and reduces the azimuthal non-uniformity of the temperature of the wall fuel elements in the fuel assembly. The results of experimental studies show that the effect of natural convection manifests itself in the range of Pe<10 (Re<2000) numbers in gratings with relative steps (s/d<1.05) and in wide bundles (s/d<1.3 to a greater extent in bundles of smooth fuel rods in comparison with bundles of ribbed fuel rods. The introduction of displacers into the peripheral channels of a fuel assembly does not fundamentally change the nature of the temperature field in a fuel assembly as compared to the version of the geometry of a fuel assembly without displacers. An attempt was made to generalize the experimental data using the Gr*Pr criterion, where Gr* is the modified Grashof number calculated from the local heat flux on the heat exchange surface and the axial coordinate measured from the beginning of heat generation. In the dependences DTwmax = f(Gr*Pr2) at Pe<100 or ribbed side elements and Pe<10 for smooth side elements, two regions of DTwmax change in the Gr*Pr2 growth function are observed - first, DTwmax ncreases to a certain “limiting” value characteristic for fixed Pe, and then - a drop in DTwmax at large values of the parameter Gr*Pr2. As the Peclet number increases, the “limiting” value of DTwmax hifts to the region of larger values of Gr*Pr2; and at Pe=370 or ribbed elements and Pe=26.5; 100 or smooth elements, the limiting value of DTwmax is not achieved in
在RF - IPPE国家研究中心对BOR-60、BN-350、BN-600、BN-800快堆堆芯和堆筛内燃料组件模型(燃料元件模拟器的相对节距在1.04≤s/d≤1.24范围内变化)在液态金属冷却剂自然对流和混合对流条件下的传热进行了实验研究,为设计规范的制定提供了依据。快堆燃料组件模型包含37个燃料元件(燃料棒模拟器),这些燃料元件位于三角形晶格中,并被封闭在六边形盖内。这些元素用镍铬合金加热器加热,这确保了元素的内表面和沿热量产生的长度有恒定的热流。中央,侧面和角落的元素是旋转的。在它们的表面上,嵌入了12个铬铝热电偶,每个热电偶都由X18H9T钢制成(覆盖直径0.8-0.5 mm,热电极直径0.2 mm),测量模型集热器中的冷却剂温度,以及在束出口的每个电池中。元件的间距使用线圈进行;各种光滑燃料棒模拟器也被使用。模型燃料组件的实验研究揭示了燃料元件和冷却剂温度场形成的规律。自然对流在低速区域表现出来,促进了通道间的流体混合,平整了燃料组件横截面冷却剂的不均匀加热,降低了燃料组件壁面燃料元件温度的方位不均匀性。实验研究结果表明,相对步长光栅(s/d<1.05)和宽束(s/d<1.3)中,自然对流的影响在Pe<10 (Re<2000)数范围内表现得更明显,光滑燃料棒束比肋状燃料棒束表现得更明显。在燃料组件的外围通道中引入置换器,与没有置换器的燃料组件的几何形状相比,不会从根本上改变燃料组件温度场的性质。尝试用Gr*Pr准则对实验数据进行推广,其中Gr*为根据换热表面局部热流密度和从产热开始测量的轴向坐标计算得到的修正Grashof数。在p <100或肋边单元和p <10时的依赖关系DTwmax = f(Gr*Pr2)中,Gr*Pr2生长函数的DTwmax变化有两个区域:首先,当p固定时,DTwmax增加到一定的“极限”值特征;然后,当参数Gr*Pr2较大时,DTwmax下降。随着Peclet数的增加,DTwmax的“极限”值移向Gr*Pr2值较大的区域;和在Pe=370或肋构件,Pe=26.5;在Gr*Pr2参数变化的研究范围内,没有达到DTwmax的极限值。对于光滑侧元,不同Pe数的DTwmax极限值近似相同,均为DTwmax≈10。
{"title":"EXPERIMENTAL MODELING OF HEAT EXCHANGE IN HEAT GENERATING ASSEMBLIES OF FAST REACTORS IN ACCIDENT REGIMES UNDER NATURAL CONVECTION CONDITIONS","authors":"Yu. A. Kuzina, A. Sorokin, N. Denisova, M. Kascheev","doi":"10.55176/2414-1038-2021-4-106-120","DOIUrl":"https://doi.org/10.55176/2414-1038-2021-4-106-120","url":null,"abstract":"The results of experimental studies of heat transfer carried out at the State Research Center RF - IPPE on models of fuel assemblies in cores and screens of fast reactors BOR-60, BN-350, BN-600, BN-800 (the relative pitch of the fuel element simulators varied in the range 1.04≤s/d≤1.24) with natural and mixed convection of liquid metal coolants, which are the basis for the development of design codes. Model fuel assemblies of fast reactors contain 37 fuel elements (fuel rod simulators) located in a triangular lattice and enclosed in a hexagonal cover. The elements were heated with nichrome heaters, which ensure a constant heat flux on the inner surface of the elements and along the length of the heat generation. The central, lateral and corner elements are rotary. On their surface, 12 chromel-alumel thermocouples each in covers made of X18H9T steel (diameter of the cover 0.8-0.5 mm, diameter of thermoelectrodes 0.2 mm) are embedded, measuring the coolant temperature in the collectors of the models, as well as in each cell at the exit from the bundles. The spacing of the elements is carried out using wire coils; variants of smooth fuel rod simulators are also used. Experimental studies on model fuel assemblies revealed regularities in the formation of temperature fields in fuel elements and coolant. Natural convection manifests itself in the region of low velocities, promotes fluid mixing between channels, leveling the uneven heating of the coolant in the cross section of the fuel assembly, and reduces the azimuthal non-uniformity of the temperature of the wall fuel elements in the fuel assembly. The results of experimental studies show that the effect of natural convection manifests itself in the range of Pe<10 (Re<2000) numbers in gratings with relative steps (s/d<1.05) and in wide bundles (s/d<1.3 to a greater extent in bundles of smooth fuel rods in comparison with bundles of ribbed fuel rods. The introduction of displacers into the peripheral channels of a fuel assembly does not fundamentally change the nature of the temperature field in a fuel assembly as compared to the version of the geometry of a fuel assembly without displacers. An attempt was made to generalize the experimental data using the Gr*Pr criterion, where Gr* is the modified Grashof number calculated from the local heat flux on the heat exchange surface and the axial coordinate measured from the beginning of heat generation. In the dependences DTwmax = f(Gr*Pr2) at Pe<100 or ribbed side elements and Pe<10 for smooth side elements, two regions of DTwmax change in the Gr*Pr2 growth function are observed - first, DTwmax ncreases to a certain “limiting” value characteristic for fixed Pe, and then - a drop in DTwmax at large values of the parameter Gr*Pr2. As the Peclet number increases, the “limiting” value of DTwmax hifts to the region of larger values of Gr*Pr2; and at Pe=370 or ribbed elements and Pe=26.5; 100 or smooth elements, the limiting value of DTwmax is not achieved in ","PeriodicalId":20426,"journal":{"name":"PROBLEMS OF ATOMIC SCIENCE AND TECHNOLOGY. SERIES: NUCLEAR AND REACTOR CONSTANTS","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2021-12-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88882125","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
THE PHYSICAL MODEL OF MASS TRANSFER CORROSIVE HYDROGEN IN FAST REACTOR STEAM GENERATORS OF THE SODIUM-WATER TYPE 钠-水型快堆蒸汽发生器中腐蚀氢传质的物理模型
Pub Date : 2021-09-26 DOI: 10.55176/2414-1038-2021-3-206-212
V. Smykov, S. Kanukhina, K. Legkikh
For timely and prompt detection of the inter-circuit depressurization of the steam generator of the “sodium-water” type in the 2nd circuit, continuous monitoring of the content of hydrogen, as a product of the interaction of sodium with water, is carried out in all operating modes. However, in reality, the main source of hydrogen in the sodium of the 2nd circuit is the process of electrochemical corrosion of 10X2M steam generator steel in a steam-water medium, the speed of which is never zero and is controlled at the minimum achievable level by means of the water-chemical regime of the 3rd circuit. At the same time, during the operation of the steam generator, deposits of corrosion products accumulate on the surface of the structural steel from the side of the 3rd circuit. The removal of deposits is carried out with the help of operational chemical flushes (ECPs). However, during the ECP, the corrosion rate of steel inevitably increases significantly (by about three orders of magnitude), which leads to an increase in the concentration of hydrogen in water and in sodium. This phenomenon has previously caused concern to the operational services of nuclear power plants due to the likely through-corrosion during regular ECP (every year, one of the three steam generators is washed). However, it is unacceptable to operate a steam generator without ECP, and to reduce the corrosion rate of steel of steam generator pipes in a steam-water environment, after ECP, a chemical passivation stage is carried out with different formulations, the effectiveness of which is different. This article presents a physical model of the mass transfer of corrosive hydrogen in a steam generator during chemical washing, passivation and start-up of the steam generator. An operational criterion for evaluating the effectiveness of passivation by the rate of increase in the concentration of hydrogen in the sodium of the second circuit during the subsequent start-up of BN-600 steam generators is proposed: if the rate of increase in the concentration of hydrogen in the 2nd circuit is less than 0.05 ppm/h, then passivation is effective, if more than the passivation formula requires revision. For BN-800 steam generators, the technology of passivation after ECP has not yet been determined, the article proposes a calculated criterion for its efficiency of 0.015 ppm/h.
为了及时及时检测二回路“钠-水”型蒸汽发生器的回路间降压情况,在所有运行模式下对钠与水相互作用的产物氢的含量进行连续监测。然而,在现实中,第二回路钠中氢的主要来源是10X2M蒸汽发生器钢在蒸汽-水介质中的电化学腐蚀过程,该过程的速度永远不会为零,并通过第三回路的水-化学机制控制在可达到的最低水平。同时,蒸汽发生器在运行过程中,从第三回路侧面腐蚀产物沉积在结构钢表面。沉淀物的清除是在操作化学冲洗(ECPs)的帮助下进行的。然而,在ECP过程中,钢的腐蚀速度不可避免地显著增加(大约三个数量级),这导致水和钠中氢的浓度增加。这一现象以前曾引起核电站运行服务的关注,因为在常规ECP(每年清洗三个蒸汽发生器中的一个)期间可能发生穿透腐蚀。但是,蒸汽发生器不经ECP处理是不可接受的,为了降低蒸汽发生器管道钢在蒸汽-水环境中的腐蚀速率,在ECP处理后,采用不同配方进行化学钝化,其效果不同。本文建立了蒸汽发生器化学洗涤、钝化和启动过程中腐蚀性氢在蒸汽发生器内传质的物理模型。提出了BN-600蒸汽发生器后续启动过程中,通过第二回路钠中氢浓度的增幅来评价钝化效果的操作准则:如果第二回路中氢浓度的增幅小于0.05 ppm/h,则钝化是有效的,如果大于则需要修改钝化公式。对于BN-800型蒸汽发生器,ECP后钝化工艺尚未确定,本文提出了其效率为0.015 ppm/h的计算准则。
{"title":"THE PHYSICAL MODEL OF MASS TRANSFER CORROSIVE HYDROGEN IN FAST REACTOR STEAM GENERATORS OF THE SODIUM-WATER TYPE","authors":"V. Smykov, S. Kanukhina, K. Legkikh","doi":"10.55176/2414-1038-2021-3-206-212","DOIUrl":"https://doi.org/10.55176/2414-1038-2021-3-206-212","url":null,"abstract":"For timely and prompt detection of the inter-circuit depressurization of the steam generator of the “sodium-water” type in the 2nd circuit, continuous monitoring of the content of hydrogen, as a product of the interaction of sodium with water, is carried out in all operating modes. However, in reality, the main source of hydrogen in the sodium of the 2nd circuit is the process of electrochemical corrosion of 10X2M steam generator steel in a steam-water medium, the speed of which is never zero and is controlled at the minimum achievable level by means of the water-chemical regime of the 3rd circuit. At the same time, during the operation of the steam generator, deposits of corrosion products accumulate on the surface of the structural steel from the side of the 3rd circuit. The removal of deposits is carried out with the help of operational chemical flushes (ECPs). However, during the ECP, the corrosion rate of steel inevitably increases significantly (by about three orders of magnitude), which leads to an increase in the concentration of hydrogen in water and in sodium. This phenomenon has previously caused concern to the operational services of nuclear power plants due to the likely through-corrosion during regular ECP (every year, one of the three steam generators is washed). However, it is unacceptable to operate a steam generator without ECP, and to reduce the corrosion rate of steel of steam generator pipes in a steam-water environment, after ECP, a chemical passivation stage is carried out with different formulations, the effectiveness of which is different. This article presents a physical model of the mass transfer of corrosive hydrogen in a steam generator during chemical washing, passivation and start-up of the steam generator. An operational criterion for evaluating the effectiveness of passivation by the rate of increase in the concentration of hydrogen in the sodium of the second circuit during the subsequent start-up of BN-600 steam generators is proposed: if the rate of increase in the concentration of hydrogen in the 2nd circuit is less than 0.05 ppm/h, then passivation is effective, if more than the passivation formula requires revision. For BN-800 steam generators, the technology of passivation after ECP has not yet been determined, the article proposes a calculated criterion for its efficiency of 0.015 ppm/h.","PeriodicalId":20426,"journal":{"name":"PROBLEMS OF ATOMIC SCIENCE AND TECHNOLOGY. SERIES: NUCLEAR AND REACTOR CONSTANTS","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2021-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74590536","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
PROBLEMS OF ATOMIC SCIENCE AND TECHNOLOGY. SERIES: NUCLEAR AND REACTOR CONSTANTS
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1