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Uncertainty aware unsupervised fault diagnosis of PWR nuclear power plant using KNN and SHAP method 基于KNN和SHAP方法的压水堆核电站不确定性无监督故障诊断
IF 3.2 3区 工程技术 Q1 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2025-12-13 DOI: 10.1016/j.pnucene.2025.106191
Fazle Haseeb , Minjun Peng , Furqan Arshad , Wasiq Ali
Machine learning based fault diagnosis methods in nuclear power plants (NPPs) often exhibit lack of labeled fault data in sufficient quantity, thus posing a significant challenge for the supervised fault diagnosis. This paper presents a novel, uncertainty-aware, and unsupervised fault diagnosis framework for pressurized water reactor (PWR) type NPP. For this purpose, it integrates the k-nearest neighbors (KNN) method with shapley additive explanations (SHAP) analysis, not only to enhance the model interpretability but also to ensure its reliability. The KNN model, trained on steady-state operational data, firstly detects anomalies, while SHAP analysis subsequently performs the fault classification in an unsupervised manner. For the purpose of fault classification, feature contributions are computed for each detected anomaly, thus providing an interpretable features pattern. This pattern information is further analyzed and transformed into an entropy-based metric, which is calculated from the normalized SHAP values. This metric enables a transparent classification between the sensor and process faults. Regarding the sensor faults, this methodology further provides the identification of the faulty sensor through the analysis of the highest contributing feature. In this way, explainable artificial intelligence (XAI) has been utilized not only for model interpretation but has also played its role in the fault diagnosis process. Additionally, a bootstrap resampling approach has been incorporated for the estimation of model uncertainty, thus providing the confidence measures that support safer and risk-informed decisions. Performance of the proposed methodology has been evaluated against various sensor and process faults, not only through clean data but also against noisy data. An inter-comparison among various anomaly detection methodologies within the proposed framework has also been presented. The testing results demonstrate that the proposed method achieves 99.56% ± 0.051% (mean ± standard deviation) classification accuracy across 100 bootstrap iterations, and also shows resilience under noisy conditions. This fully unsupervised, interpretable, and uncertainty-informed framework thus offers a significant advancement for reliable fault diagnosis in safety-critical nuclear power plant operations.
基于机器学习的核电厂故障诊断方法往往缺乏足够数量的标记故障数据,这对监督故障诊断提出了重大挑战。提出了一种新的、不确定性感知的、无监督的压水堆型核电站故障诊断框架。为此,将k近邻(KNN)方法与shapley加性解释(SHAP)分析相结合,既增强了模型的可解释性,又保证了模型的可靠性。KNN模型基于稳态运行数据进行训练,首先检测异常,而SHAP分析随后以无监督的方式进行故障分类。为了进行故障分类,计算每个检测到的异常的特征贡献,从而提供可解释的特征模式。进一步分析该模式信息并将其转换为基于熵的度量,该度量由规范化的SHAP值计算得出。该度量允许在传感器和流程故障之间进行透明的分类。对于传感器故障,该方法通过分析最大贡献特征进一步提供故障传感器的识别。通过这种方式,可解释人工智能(XAI)不仅用于模型解释,而且在故障诊断过程中也发挥了作用。此外,自举重采样方法已被纳入模型不确定性的估计,从而提供了支持更安全和风险知情决策的置信度措施。所提出的方法的性能已经针对各种传感器和过程故障进行了评估,不仅通过干净的数据,而且通过噪声数据。在此框架下,对各种异常检测方法进行了比较。测试结果表明,该方法在100次自举迭代中达到99.56%±0.051%(均值±标准差)的分类准确率,并且在噪声条件下具有良好的弹性。因此,这种完全无监督、可解释和不确定性信息的框架为安全关键型核电站运行中的可靠故障诊断提供了重大进展。
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引用次数: 0
Enhanced safety and emergency decision-making in NPPs: Multi-step parameter prediction for complex accident scenarios 核电厂安全与应急决策强化:复杂事故情景的多步参数预测
IF 3.2 3区 工程技术 Q1 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2025-12-12 DOI: 10.1016/j.pnucene.2025.106185
Siwei Li , Yichun Wu , Jiayan Fang , Wei Wang , Jiale Ling
Early fault detection and timely initiation of appropriate control or maintenance actions can significantly mitigate operational risks in nuclear power plants (NPPs) and enhance the reliability of operator decision-making during emergencies. Therefore, developing an efficient, multi-step Prognostics and Health Management (PHM) model is essential for the prediction of system health status to support accident mitigation and recovery efforts in NPP operations. In this paper, we propose a novel predictive approach that integrates a bidirectional long short-term memory (BiLSTM) neural network within a multiple input multiple output (MIMO) framework guided by an Expert Fuzzy Evaluation Method (EFEM). The model is trained and validated on simulation data from a CPR1000 pressurized water reactor under various accident scenarios, and it demonstrates a remarkable capability to accurately forecast key NPP parameters up to 128 steps into the future (with a 10-s interval per step, totaling 1280 s, thereby satisfying the temporal advance requirement for fault prognostics in NPPs, and provides valuable decision-support information for operators to control and recover from accidents. The proposed method also serves as an effective reference for other PHM applications such as anomaly detection and remaining useful life estimation.
及早发现故障并及时采取适当的控制或维护措施,可以显著降低核电站的运行风险,并提高运营商在紧急情况下决策的可靠性。因此,开发一个高效的、多步骤的预测和健康管理(PHM)模型对于预测系统健康状态至关重要,以支持核电厂运营中的事故缓解和恢复工作。在本文中,我们提出了一种新的预测方法,该方法将双向长短期记忆(BiLSTM)神经网络集成在多输入多输出(MIMO)框架中,并以专家模糊评价法(EFEM)为指导。基于CPR1000压水堆不同事故情景下的仿真数据对模型进行了训练和验证,结果表明,该模型能够准确预测未来128步(每步间隔10秒,总计1280秒)的核电厂关键参数,满足了核电厂故障预测的时间超前要求,为运营商控制和恢复事故提供了有价值的决策支持信息。该方法也为PHM异常检测和剩余使用寿命估计等其他应用提供了有效的参考。
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引用次数: 0
Nondestructive burnup evaluation and gamma spectroscopy analysis of spent fuel elements in the ITU TRIGA Mark II research reactor 国际电联TRIGA Mark II研究堆中乏燃料元件的无损燃耗评估和伽马能谱分析
IF 3.2 3区 工程技术 Q1 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2025-12-10 DOI: 10.1016/j.pnucene.2025.106186
A. Kaya , O. Erbay , Z. Boduroglu , I.A. Reyhancan , M.S. Kiziltas , T. Akyurek
This study presents a comprehensive burnup analysis of all fuel elements in the ITU TRIGA Mark II research reactor core using non-destructive assay (NDA) techniques based on gamma spectroscopy. Two distinct fuel inspection systems were employed to measure the gamma activity, with 137Cs used as the primary burnup indicator due to its strong correlation with fuel depletion. The results show a clear burnup pattern, with higher values in the inner core rings that gradually decreases toward the outer rings. This asymmetric burnup distribution underscores the need for reactor core reconfiguration, for which an optimized layout is proposed. Additionally, gamma spectroscopic analysis of fuel element F30 was conducted at cooling times of 10, 130, and 755 days. The results also suggest that 140La is a promising candidate for future burnup studies, which will be pursued in subsequent research.
本研究采用基于伽马能谱的无损分析(NDA)技术,对国际电联TRIGA Mark II研究堆堆芯中的所有燃料元件进行了全面的燃耗分析。两种不同的燃料检测系统被用来测量伽马活度,137Cs被用作主要燃耗指标,因为它与燃料消耗有很强的相关性。结果显示出一个清晰的燃耗模式,内核环的燃耗值较高,向外环逐渐降低。这种不对称燃耗分布强调了反应堆堆芯重构的必要性,为此提出了一种优化布局。此外,在冷却时间为10、130和755天时,对燃料元件F30进行了伽马光谱分析。结果还表明140La是未来燃耗研究的一个有希望的候选者,将在后续的研究中进行。
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引用次数: 0
Multi-physics simulation of the MSFR reactor for an explorative thermo-mechanical analysis of its confinement MSFR反应堆的多物理场模拟及其约束的探索性热力学分析
IF 3.2 3区 工程技术 Q1 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2025-12-10 DOI: 10.1016/j.pnucene.2025.106189
S. Deanesi , D. Pizzocri , F. Valsecchi , A. Cammi , S. Lorenzi
The Molten Salt Fast Reactor (MSFR) is the representative concept of the liquid-fuelled family within the Generation-IV International Forum. Given the harsh working conditions to which the MSFR is subjected, in terms of thermal load and fast neutron fluence, it is essential to investigate the reactor behaviour in nominal steady state operating conditions and during transient scenarios. This work is focused on assessing the behaviour of the confinement wall in a MSFR under the preliminary design conditions set by current studies. A step-by-step approach is proposed: first, multiphysics simulations coupling neutronics and thermal-hydraulics in OpenFOAM are performed on a 3D domain representative of the primary loop. The outcomes provide representative working conditions to be employed within an Abaqus thermo-mechanical model of a confinement shell simulated in a second step. Overall, the multiphysics and thermo-mechanical models and the material correlations form the foundation of a consistent approach to developing an explorative thermo-mechanical analysis of the component.
在第四代国际论坛上,熔盐快堆(MSFR)是液体燃料家族的代表性概念。考虑到MSFR所承受的恶劣工作条件,在热负荷和快中子通量方面,有必要研究反应堆在名义稳态运行条件和瞬态情况下的行为。这项工作的重点是在当前研究设定的初步设计条件下评估MSFR中约束墙的行为。提出了一种循序渐进的方法:首先,在具有主回路代表性的三维域上,在OpenFOAM中进行多物理场耦合中子和热工力学模拟。研究结果为第二步模拟的约束壳的Abaqus热力学模型提供了具有代表性的工作条件。总的来说,多物理场和热力学模型以及材料相关性构成了开发组件探索性热力学分析的一致方法的基础。
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引用次数: 0
Large language model-assisted digital twin for remote monitoring and control of advanced reactors 先进反应堆远程监测与控制的大型语言模型辅助数字孪生
IF 3.2 3区 工程技术 Q1 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2025-12-10 DOI: 10.1016/j.pnucene.2025.106172
Zavier Ndum Ndum , Doyeong Lim , John Ford , Simon Adu , Jian Tao , Yassin Hassan , Yang Liu
In this paper, we present a novel framework for real-time autonomous monitoring and control of advanced small-scale nuclear reactors by integrating a simulator-based digital twin (DT) with a domain-knowledge-enhanced large language model (LLM). The framework’s architecture, featuring robust bi-directional connectivity via the OPC-UA industrial protocol, was demonstrated on a lead-cooled fast reactor (LFR) case study. The LFR demonstration leverages a customized, MATLAB-Simulink-based simulator with natural circulation and burnup modeling capabilities, which has been validated against the System Analysis Module (SAM) code.
The system employs a hybrid supervisory methodology that incorporates both a traditional rate-limiting Reference Governor (rl-RG) and a novel, tool-centric LLM agent. The LLM agent’s primary capability involves processing incoming sensor data streams, invoking the simulator and related customized tools to obtain physics-based results, and interpreting this data to understand the current system status. Augmented with custom-built retrieval and diagnostic subroutines, the LLM agent then explains the reactor’s state and generates context-aware, quantitative recommendations for management actions, such as reactivity control and power maneuvers. We found that the control signals recommended by the LLM agent successfully matched those generated by the traditional rl-RG. Furthermore, the framework includes an intuitive, multi-tab graphical user interface that enhances human-machine interaction by enabling real-time transient visualization, interactive LLM queries, and detailed transient analysis. This research highlights the transformative potential of AI-enhanced, DT-based control frameworks for advanced reactors and demonstrates its utility as a robust educational and training tool.
在本文中,我们通过将基于模拟器的数字孪生(DT)与领域知识增强的大语言模型(LLM)相结合,提出了一种用于先进小型核反应堆实时自主监测和控制的新框架。该框架的架构通过OPC-UA工业协议实现了强大的双向连接,并在铅冷快堆(LFR)案例研究中进行了演示。LFR演示利用了一个定制的、基于matlab - simulink的模拟器,具有自然循环和燃耗建模功能,并已根据系统分析模块(SAM)代码进行了验证。该系统采用了一种混合监控方法,结合了传统的限速参考调速器(rl-RG)和一种新型的、以工具为中心的LLM代理。LLM代理的主要功能包括处理传入的传感器数据流,调用模拟器和相关定制工具以获得基于物理的结果,并解释这些数据以了解当前系统状态。通过定制的检索和诊断子程序,LLM代理可以解释反应堆的状态,并为管理行动(如反应性控制和功率机动)生成上下文感知的定量建议。我们发现LLM代理推荐的控制信号与传统的rl-RG生成的控制信号成功匹配。此外,该框架还包括一个直观的多选项卡图形用户界面,通过支持实时瞬态可视化、交互式LLM查询和详细的瞬态分析来增强人机交互。这项研究强调了人工智能增强的、基于dt的先进反应堆控制框架的变革潜力,并展示了其作为强大的教育和培训工具的实用性。
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引用次数: 0
Uncertainty estimation of bifurcated solutions in the Rayleigh–Bénard problem for advanced nuclear reactors applications 先进核反应堆rayleigh - bsamadard问题分岔解的不确定性估计
IF 3.2 3区 工程技术 Q1 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2025-12-10 DOI: 10.1016/j.pnucene.2025.106170
Fadel M. Nasr , Mauricio Tano , Yousry Azmy
Multiphysics models of nuclear reactors frequently comprise nonlinear systems of equations. The nonlinear nature of these models could lead to solution bifurcations, where a small change in a certain parameter, e.g., the thermophysical properties of the coolant, can lead to a sudden change in the system’s behavior. At the point in parameter space where this happens, called a critical point, the Jacobian matrix of the model’s nonlinear operator becomes singular potentially permitting multiple solutions to coexist. In this paper, we perform uncertainty estimation (UE) in a parameter range that includes bifurcated solutions within the context of Rayleigh–Bénard problem. We perform this analysis assuming uncertain temperature difference, and tilt angle for the iterative solution algorithm with a unit Prandtl number (Pr=1). Also, we perform this analysis under uncertain thermophysical properties for both FLiBe molten salt and liquid sodium as working fluid. We deploy two approaches to compute statistical moments for the resulting distributions of selected flow-field variables. The first approach is the blind computation of the mean and the standard deviation without any consideration of solution bifurcation, while the second approach utilizes k-means clustering to cluster each branch’s solutions together and compute separate statistical moments for each branch. The statistical distributions are obtained by perturbing the selected parameters about nominal values that correspond to a solution on one of the valid branches, and that solution is used as initial guess for the iterative solution algorithm. We found that perturbation of any parameter when its nominal value is close to its critical point always leads to branch jumping, i.e., the iterations converge to a solution on a branch different from the branch of the initial guess. This produces a statistical ensemble comprised of fundamentally different solutions leading to wrong mean values and uncertainty estimates, whereas clustering provides an efficient way to deal with this type of computation. This work is important for developing Gen IV nuclear systems because many of these systems rely on natural convection for cooling especially in accident conditions.
核反应堆的多物理场模型经常包含非线性方程组。这些模型的非线性特性可能导致解分叉,其中某个参数的微小变化,例如冷却剂的热物理性质,可能导致系统行为的突然变化。在参数空间中发生这种情况的点,称为临界点,模型的非线性算子的雅可比矩阵变为奇异,可能允许多个解共存。在本文中,我们在包含分岔解的参数范围内进行了不确定性估计(UE)。我们假设不确定的温差和倾角为单位普朗特数(Pr=1)的迭代解算法进行此分析。此外,我们还对FLiBe熔盐和液态钠作为工质进行了热物理性质不确定的分析。我们采用两种方法来计算所选流场变量的结果分布的统计矩。第一种方法是盲目计算均值和标准差,不考虑解的分叉,第二种方法是利用k-means聚类将每个分支的解聚在一起,并为每个分支计算单独的统计矩。通过扰动选定的标称值的参数,得到相应的统计分布,这些标称值对应于一个有效分支上的解,并将该解作为迭代解算法的初始猜测。我们发现,当任何参数的标称值接近其临界点时,扰动总是导致分支跳跃,即迭代收敛到与初始猜测分支不同的分支上的解。这产生了一个由根本不同的解决方案组成的统计集合,导致错误的平均值和不确定性估计,而聚类提供了一种有效的方法来处理这类计算。这项工作对于开发第四代核系统非常重要,因为许多这些系统依赖于自然对流进行冷却,特别是在事故条件下。
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引用次数: 0
Study on the neutronic effects of annular metallic fuel irradiation swelling in a fast reactor core 快堆堆芯环形金属燃料辐照膨胀的中子效应研究
IF 3.2 3区 工程技术 Q1 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2025-12-08 DOI: 10.1016/j.pnucene.2025.106181
Wenhua Yang , Liang Zhang , Shouhua Sun, Shuai Jin, Yixing Xu, Jin Lei, Yixiong Sun, Wenbin Zhao
The metallic fuel is a fast reactor fuel with good application prospects. Due to the anisotropic irradiation swelling of the metallic fuel slug, the spatial distribution of fissile materials in the core is changed, and the reactor neutronics performance is affected by the changes of neutron energy spectrum and neutron leakage rate of the core. In this paper, the Monte Carlo code RMC is used to establish the calculation model of a lead bismuth eutectic cooled fast reactor (LFR) with annular slug metallic fuel. The neutronics calculation of the core under different fuel swelling and different fuel burnup conditions is carried out. The quantitative calculation of the influence of three factors on keff, including radial swelling, axial swelling and fuel temperature rise, was performed. The influence of irradiation swelling on the neutronics parameters of the core and its change with fuel burnup are analyzed. The results show that the radial irradiation swelling of the core introduces positive reactivity, while the axial swelling and the rise of the fuel temperature caused by the fuel swelling introduce negative reactivity. There is a linear relationship between the axial elongation of the core and the introduced reactivity. For every 1 % axial elongation of the UZr and UPuZr fuel slug, the introduced reactivity is about −100 pcm. Considering the irradiation swelling of the fuel, the absolute values of the fuel axial expansion reactivity coefficient and fuel temperature reactivity coefficient increases by 35 % and 16 % respectively, and the core reactivity decreases by about 300 pcm ∼ 500 pcm. Combined with the irradiation swelling approximate model of annular metallic fuel, an approximate evaluation model of reactor reactivity caused by irradiation swelling under different burnup was obtained.
金属燃料是一种具有良好应用前景的快堆燃料。由于金属燃料段塞的各向异性辐照膨胀,改变了堆芯内可裂变物质的空间分布,堆芯中子能谱和中子泄漏率的变化影响了堆芯的中子性能。本文采用蒙特卡罗程序RMC建立了含环形段塞金属燃料的铅铋共晶冷却快堆的计算模型。对不同燃料膨胀和不同燃料燃耗条件下的堆芯进行了中子计算。定量计算了径向膨胀、轴向膨胀和燃油温升三种因素对燃油经济性的影响。分析了辐照膨胀对堆芯中子参数的影响及其随燃料燃耗的变化。结果表明,堆芯的径向辐照膨胀引起正反应性,而燃料膨胀引起的轴向膨胀和燃料温度升高引起负反应性。在芯的轴向伸长率和引入的反应性之间存在线性关系。UZr和UPuZr燃料段塞轴向伸长每1%,引入的反应性约为- 100 pcm。考虑到燃料的辐照膨胀,燃料轴向膨胀反应性系数和燃料温度反应性系数的绝对值分别提高了35%和16%,堆芯反应性降低了约300 ~ 500 pcm。结合环形金属燃料的辐照膨胀近似模型,得到了不同燃耗下辐照膨胀引起反应堆反应性的近似评价模型。
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引用次数: 0
A review of Monte Carlo-based multiphysics coupling in nuclear reactor analysis 核反应堆分析中基于蒙特卡罗的多物理场耦合研究进展
IF 3.2 3区 工程技术 Q1 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2025-12-06 DOI: 10.1016/j.pnucene.2025.106178
Shanfang Huang , Guodong Liu , Ying He , Xingyu Zhao , Zhigang Li , Yugao Ma , Meiming Qiu , Yongtang Wang , Haisheng Chen , Junren Hou , Kaiwen Li , Hao Luo , Chuan Lu , Kan Wang
The operation of nuclear reactors involves a complex interplay among multiple physical processes. Accurate reactor simulation requires the implementation of multiphysics coupling. Neutronics holds a particularly distinctive role in simulation, and can be solved via deterministic or Monte Carlo (MC) methods. Although research on deterministic-based coupling started earlier, MC-based coupling methods have been increasingly applied in recent years for both analyses of conventional reactors and designs of advanced reactors, due to their high fidelity. In view of this, this paper provides a comprehensive review of MC-based multiphysics coupling in nuclear reactors. Multiphysics coupling issues in representative reactors such as light water reactors, heat pipe-cooled reactors, and high-temperature gas-cooled reactors are systematically presented. Furthermore, multiphysics coupling technologies including cross-section treatments, coupling methods, iteration strategies, data mapping, data transfer, and convergence criteria are extensively discussed. Challenges and future exploration are also enumerated. This review indicates that while MC-based coupling demonstrates superior aptitude for simulation of advanced reactors, current research remains predominantly focused on methodological studies. Leveraging high-performance computing resources and artificial intelligence, the development of advanced algorithms such as tight, transient and full-loop coupling will accelerate the deployment. This comprehensive analysis thereby establishes the review as both a guide for newcomers and an up-to-date reference for researchers.
核反应堆的运行涉及多个物理过程的复杂相互作用。精确的反应堆模拟需要实现多物理场耦合。中子电子学在模拟中具有特别独特的作用,可以通过确定性或蒙特卡罗(MC)方法来解决。尽管基于确定性的耦合研究起步较早,但基于mc的耦合方法由于其高保真度,近年来越来越多地应用于传统反应器的分析和先进反应器的设计。鉴于此,本文对核反应堆中基于mc的多物理场耦合进行了综述。系统地介绍了轻水堆、热管冷却堆和高温气冷堆等典型反应堆的多物理场耦合问题。此外,还广泛讨论了多物理场耦合技术,包括截面处理、耦合方法、迭代策略、数据映射、数据传输和收敛准则。还列举了挑战和未来的探索。这篇综述表明,虽然基于mc的耦合在模拟先进反应堆方面表现出优越的能力,但目前的研究仍然主要集中在方法研究上。利用高性能计算资源和人工智能,紧耦合、瞬态耦合和全环耦合等先进算法的发展将加速部署。这种全面的分析,从而建立了审查既为新手指南和最新的参考研究人员。
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引用次数: 0
Influence of network modifiers on the physical, structural, elastic, thermal properties of lead boroaluminate glasses for advanced radioactive waste management 网络改性剂对先进放射性废物处理用硼铝酸铅玻璃物理、结构、弹性和热性能的影响
IF 3.2 3区 工程技术 Q1 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2025-12-06 DOI: 10.1016/j.pnucene.2025.106187
M. Vijayakumar , J. Inico Valanarasi , K. Ramachandran , M.S. Al-Buriahi , Nada Alfryyan , P. Devendran , K. Maheshvaran
In this study, a series of europium ions incorporated lead boroaluminate glasses containing a composition of 69B2O3+5Al2O3+10PbO+15MO+1Eu2O3 (where M = Li2O, Na2O, K2O, MgO, CaO, SrO in wt%) were synthesized and characterized to evaluate their potential for radiation shielding applications. The influence of various alkali and alkaline earth modifiers on physical, structural, thermal and elastic properties was systematically examined. Density showed a clear compositional dependence, increasing from 3.155 g/cm3 (K) to 3.897 g/cm3 (Sr), while the molar volume varied between 18.375 and 25.416 cm3/mol, reflecting the combined effects of cation size and field strength on network packing. The refractive index increased steadily from nd = 1.632 (Li) to nd = 1.881 (Sr), consistent with enhanced polarizability in heavier modifier-containing glasses. FTIR spectral analysis revealed significant structural changes, including the transformation of BO3 to BO4 units and a reduction in non-bridging oxygens, confirming enhanced polymerization. Mechanical studies showed that Sr2+- and Ca2+-rich glasses exhibited superior Young's, shear, and bulk moduli, reflecting better mechanical strength and rigidity. Thermal analysis through TG/DSC indicates the well-defined glass transition and crystallization events, with Tg and ΔT values strongly dependent influenced by the modifiers. Radiation shielding performance was evaluated using parameters such as mass attenuation coefficient (MAC), mean free path (MFP), half-value layer (HVL), electron density (Neff) and effective atomic number (Zeff). The radiation-shielding performance improved across the series, with MAC decreasing from 0.090 to 0.063 cm2/g, HVL reducing from 3.23 to 3.04 cm, and MFP shortening from 5.02 to 4.11 cm at 1 MeV while incorporating different modifiers from Li to Sr in the present compositions. Glasses containing Ca and Sr demonstrated enhanced photon interaction probabilities and reduced penetration depths compared to conventional shielding concretes. Moreover, buildup factor analysis and fast neutron removal cross-sections (FNRC) confirmed the dual-mode shielding capability of these glasses. The performance of the prepared glasses is benchmarked against commercial glass types such as RS 253, RS 360, RS 520, and RS G18/G19 and shielding concretes. The findings establish that careful selection of modifier oxides, especially Sr2+ and Ca2+, significantly enhances both structural and shielding efficiency, positioning these glasses as promising alternatives for compact and efficient radiation shielding materials in the advance nuclear waste management amenities.
本研究合成了一系列含铕离子的硼铝酸铅玻璃,其组成为69B2O3+5Al2O3+10PbO+15MO+1Eu2O3(其中M = Li2O, Na2O, K2O, MgO, CaO, SrO, wt%),并对其进行了表征,以评估其辐射屏蔽应用潜力。系统考察了各种碱和碱土改性剂对其物理、结构、热、弹性等性能的影响。密度表现出明显的组分依赖性,从3.155 g/cm3 (K)增加到3.897 g/cm3 (Sr),而摩尔体积在18.375 ~ 25.416 cm3/mol之间变化,反映了阳离子尺寸和场强对网络填充的综合影响。折射率从nd = 1.632 (Li)稳定增加到nd = 1.881 (Sr),这与较重的改性剂增强了玻璃的偏振性一致。FTIR光谱分析显示了显著的结构变化,包括BO3向BO4单元的转变和非桥接氧的减少,证实了聚合增强。力学研究表明,富含Sr2+和Ca2+的玻璃具有优越的杨氏模量、剪切模量和体积模量,反映出更好的机械强度和刚度。热分析通过TG/DSC表明明确的玻璃化转变和结晶事件,TG和ΔT值强烈依赖于改性剂的影响。采用质量衰减系数(MAC)、平均自由程(MFP)、半值层(HVL)、电子密度(Neff)和有效原子序数(Zeff)等参数评价辐射屏蔽性能。在加入Li和Sr等不同改性剂的情况下,该系列材料的辐射屏蔽性能得到了改善,在1 MeV下,MAC从0.090降低到0.063 cm2/g, HVL从3.23降低到3.04 cm, MFP从5.02缩短到4.11 cm。与传统的屏蔽混凝土相比,含有Ca和Sr的玻璃显示出增强的光子相互作用概率和降低的穿透深度。此外,累积因子分析和快中子去除截面(FNRC)证实了这些玻璃的双模屏蔽能力。所制备的玻璃的性能以商用玻璃为基准,如RS 253、RS 360、RS 520、RS G18/G19和屏蔽混凝土。研究结果表明,仔细选择改性氧化物,特别是Sr2+和Ca2+,显著提高了结构和屏蔽效率,使这些玻璃成为先进核废料管理设施中紧凑和高效辐射屏蔽材料的有前途的替代品。
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引用次数: 0
Experimental study on discharge behavior in automatic depressurization system: High pressure two phase discharge characteristics of pipeline 自动减压系统放电特性的实验研究:管道高压两相放电特性
IF 3.2 3区 工程技术 Q1 NUCLEAR SCIENCE & TECHNOLOGY Pub Date : 2025-12-06 DOI: 10.1016/j.pnucene.2025.106184
Zhengrun Shang , Dufeng Lv , Zhongning Sun , Zhaoming Meng , Pei Yu
To investigate the high pressure two phase discharge characteristics within the multi-stage pipelines of automatic depressurization system (ADS) under actual operating conditions, this study conducted experimental research on high pressure two phase discharge in multi-stage pipelines. The results shows that with an increase the number of depressurization stages, the pressure drop percentage of the discharge main pipeline increases, and the pressure drop percentage of ADS valve package decreases. Additionally, the position of the maximum pressure drop percentage in the valve package migrates upstream with the increase of depressurization stages. When the equilibrium quality is 90∼100 % and the pressure is 2–13.6 MPa, the equilibrium quality along the flow direction initially decreases and then increases, and as the inlet pressure increases, the inflection point gradually moves downstream. In the other conditions, the equilibrium quality shows an upward trend. When the equilibrium quality is 10–90 %, the pressure is 0–13.6 MPa and the equilibrium quality is 0–10 %, the pressure is 2–13.6 MPa, the equilibrium quality changes significantly along the pipeline. And other conditions is not obvious.
为研究实际工况下自动降压系统(ADS)多级管道内高压两相放电特性,本研究对多级管道内高压两相放电进行了实验研究。结果表明:随着降压级数的增加,排放主管道压降百分比增大,ADS阀组压降百分比减小;此外,随着降压级的增加,阀组中最大压降百分比的位置上游偏移。当平衡质量为90 ~ 100%,压力为2 ~ 13.6 MPa时,沿流动方向的平衡质量先减小后增大,随着进口压力的增大,拐点逐渐向下游移动。在其他条件下,平衡质量呈上升趋势。当平衡质量为10 ~ 90%,压力为0 ~ 13.6 MPa时,平衡质量为0 ~ 10%,压力为2 ~ 13.6 MPa时,平衡质量沿管道变化明显。而其他条件则不明显。
{"title":"Experimental study on discharge behavior in automatic depressurization system: High pressure two phase discharge characteristics of pipeline","authors":"Zhengrun Shang ,&nbsp;Dufeng Lv ,&nbsp;Zhongning Sun ,&nbsp;Zhaoming Meng ,&nbsp;Pei Yu","doi":"10.1016/j.pnucene.2025.106184","DOIUrl":"10.1016/j.pnucene.2025.106184","url":null,"abstract":"<div><div>To investigate the high pressure two phase discharge characteristics within the multi-stage pipelines of automatic depressurization system (ADS) under actual operating conditions, this study conducted experimental research on high pressure two phase discharge in multi-stage pipelines. The results shows that with an increase the number of depressurization stages, the pressure drop percentage of the discharge main pipeline increases, and the pressure drop percentage of ADS valve package decreases. Additionally, the position of the maximum pressure drop percentage in the valve package migrates upstream with the increase of depressurization stages. When the equilibrium quality is 90∼100 % and the pressure is 2–13.6 MPa, the equilibrium quality along the flow direction initially decreases and then increases, and as the inlet pressure increases, the inflection point gradually moves downstream. In the other conditions, the equilibrium quality shows an upward trend. When the equilibrium quality is 10–90 %, the pressure is 0–13.6 MPa and the equilibrium quality is 0–10 %, the pressure is 2–13.6 MPa, the equilibrium quality changes significantly along the pipeline. And other conditions is not obvious.</div></div>","PeriodicalId":20617,"journal":{"name":"Progress in Nuclear Energy","volume":"192 ","pages":"Article 106184"},"PeriodicalIF":3.2,"publicationDate":"2025-12-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145681056","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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Progress in Nuclear Energy
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