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High Cycle Fatigue Properties and Fracture Behavior of Ti-5Al-5Mo-5V-1Cr-1Fe Titanium Alloy Ti-5Al-5Mo-5V-1Cr-1Fe钛合金高周疲劳性能及断裂行为
IF 0.7 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2018-12-01 DOI: 10.1016/S1875-5372(19)30015-3
Liu Yingying, Zhang Le, Shi Xiaonan, Xue Xihao

Under different stress concentration factors Kt and stress ratios R, the high cycle fatigue (HCF) properties and fracture morphologies of Ti-5Al-5Mo-5V-1Cr-1Fe (Ti-55511) forgings and bars in longitudinal orientation were studied at room temperature. The results show that both the fatigue strength of forgings and bars increases with the increasing stress ratio and decreases with the increasing stress concentration factor. The fatigue strength of forgings is 1.08∼1.57 times greater than that of bars. There are primary α phase particles in the forgings, with more uniform distribution and smaller size. However, there exist residual casting primary α phase particles with the shape of bulk or strip in bars.

在不同应力集中系数Kt和应力比R的条件下,研究了Ti-5Al-5Mo-5V-1Cr-1Fe (Ti-55511)锻件和棒材的纵向高周疲劳性能和断裂形貌。结果表明:锻件和棒体的疲劳强度均随应力比的增大而增大,随应力集中系数的增大而减小;锻件的疲劳强度是棒材的1.08 ~ 1.57倍。锻件中存在初生α相颗粒,分布更均匀,尺寸更小。但在棒材中存在块状或条状的残余铸造初生α相颗粒。
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引用次数: 2
Hydrogen-Related Properties of the Pd71.5Cu12Si16.5 Metallic Glass Pd71.5Cu12Si16.5金属玻璃的氢相关性质
IF 0.7 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2018-12-01 DOI: 10.1016/S1875-5372(19)30009-8
Du Xiaoqing, Ye Xiaoqiu, Zhang Guikai, Ren Qingbo

The Pd71.5Cu12Si16.5 metallic glass was synthesized as wide ribbons by arc melting and copper roller spinning. The structures were determined by X-ray diffraction patterns using the conventional X-ray diffractometer and short wavelength X-ray stress analyzer, and the fully glassy state of the ribbons is confirmed. Multiple hydrogen absorption and desorption cycles at room temperature under 100 kPa were carried out on the samples. No destruction after more than 10 cycles is observed, which demonstrates good hydrogen embrittlement resistance. The hydrogen permeation properties of the Pd71.5Cu12Si16.5 metallic glass and its crystallized counterpart were further tested using a direct permeation method. In the supercooled liquid region, the hydrogen permeation rate is obviously higher for the metallic glass form, which could be explained by the increasing free volumes introduced during isothermal stage in this range.

采用电弧熔炼和铜辊纺丝法制备了Pd71.5Cu12Si16.5宽带状金属玻璃。利用传统的x射线衍射仪和短波x射线应力分析仪对其结构进行了x射线衍射图分析,证实了带的全玻璃态。在100 kPa的室温条件下对样品进行多次吸氢和解吸循环。循环10次以上未见破坏现象,具有良好的抗氢脆性能。采用直接渗透法进一步测试了Pd71.5Cu12Si16.5金属玻璃及其晶化金属玻璃的氢渗透性能。在过冷液区,金属玻璃形式的氢渗透速率明显更高,这可以解释为等温阶段在该范围内引入的自由体积增加。
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引用次数: 1
Characteristics of Al2O3-Pt/YSZ-Pt Double Layer Composite Coatings Prepared by Cathode Plasma Electrolytic Deposition 阴极等离子体电解制备Al2O3-Pt/YSZ-Pt双层复合涂层的特性
IF 0.7 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2018-12-01 DOI: 10.1016/S1875-5372(19)30003-7
Deng Shunjie , Jiang Chi , Liu Tianwei , Shuai Maobing , Wang Peng

Al2O3-Pt/YSZ-Pt double layer composite coatings were prepared by cathode plasma electrolytic deposition (CPED) on the superalloy with a NiCoCrAlY bond-coat. The composite coatings consist of an Al2O3-Pt film and a YSZ-Pt top-coat and show a good adhesion to the metallic bond-coat. It is demonstrated, from the cyclic oxidation test and mechanical properties test, that such coatings possess good oxidation and spallation resistance. These beneficial results can be attributed to these effects: owing to the extremely low oxygen diffusion rate of Al2O3-Pt film, such composite coatings can inhibit further oxidation of the bond-coat; the mechanical properties of Al2O3-Pt/YSZ-Pt composite coating are improved by the toughening effect of Pt particles.

采用阴极等离子体电解沉积(CPED)技术在高温合金表面制备了Al2O3-Pt/YSZ-Pt双层复合涂层,并采用NiCoCrAlY结合涂层。复合涂层由一层Al2O3-Pt膜和一层YSZ-Pt面涂层组成,与金属粘结层具有良好的附着力。循环氧化试验和力学性能试验表明,该涂层具有良好的抗氧化性和抗剥落性。这些有益的结果可以归结为:由于Al2O3-Pt薄膜极低的氧扩散速率,这种复合涂层可以抑制键合层的进一步氧化;Pt颗粒的增韧作用提高了Al2O3-Pt/YSZ-Pt复合涂层的力学性能。
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引用次数: 1
Preparation and Microwave Absorption Properties of La-Ho-Fe Alloys La-Ho-Fe合金的制备及其微波吸收性能
IF 0.7 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2018-12-01 DOI: 10.1016/S1875-5372(19)30012-8
Luo Jialiang , Pan Shunkang , Qiao Ziqiang , Cheng Lichun , He Yu , Chang Junqing

The LaxHo2-xFe17 (x=0.0, 0.2, 0.4, 0.6, 0.8) powders were prepared by arc melting and high energy ball milling. The influence of the La substitution on phase structure, morphology, magnetic properties and electromagnetic parameters were investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM), vibrating-sample magnetometry (VSM) and vector network analyzer (VNA), respectively. The results show that the saturation magnetization increases and the average particle size increases with the increase of La content. The minimum absorption peak frequency shifts towards a lower frequency region with the increase of La content. The minimum reflection loss (RL) of La0.2Ho1.8Fe17 reaches –28.72 dB at 8.72 GHz, and the frequency bandwidth of RL<–10 dB reaches about 2.32 GHz with the best matching condition d=1.8 mm. The reflection loss with the thickness ranging of 1.2∼2.4 mm could reach –10 dB, which indicates that the particles are considered as the promising microwave absorbing materials with better absorption properties.

采用电弧熔炼和高能球磨法制备了LaxHo2-xFe17 (x=0.0, 0.2, 0.4, 0.6, 0.8)粉末。采用x射线衍射仪(XRD)、扫描电镜(SEM)、振动样品磁强计(VSM)和矢量网络分析仪(VNA)分别研究了La取代对材料相结构、形貌、磁性能和电磁参数的影响。结果表明:随着La含量的增加,饱和磁化强度增大,平均粒径增大;随着La含量的增加,最小吸收峰频率向低频区偏移。La0.2Ho1.8Fe17的最小反射损耗(RL)在8.72 GHz时达到-28.72 dB, RL< -10 dB的频宽达到2.32 GHz左右,最佳匹配条件d=1.8 mm。厚度为1.2 ~ 2.4 mm的粒子的反射损失可达-10 dB,表明该粒子具有较好的吸收性能,是一种很有前途的吸波材料。
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引用次数: 2
Effect of Benzotriazole on Corrosion Resistance of Al2O3/Cerium Oxide Composite Films on the Al Surface 苯并三唑对铝表面Al2O3/氧化铈复合膜耐蚀性的影响
IF 0.7 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2018-12-01 DOI: 10.1016/S1875-5372(19)30004-9
Wang Guixiang, Gao Gang, Han Xinchen, Ying Lixia, Ma Fuqiu

Al2O3/cerium oxide composite films were prepared on the surface of aluminum by an anodic oxidation and chemical conversion method. The aluminum was firstly anodized in sulfuric acid, and then the anodized aluminum was treated with the Ce(NO3)3 solution. The effect of different concentrations of 1H-Benzotriazole (BTA) on the corrosion resistance of Al2O3/cerium oxide composite films was investigated. X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscope (SEM) with energy dispersive spectrometer (EDS), and electrochemical workstation were used to characterize the properties of the composite films. The results show that the deposition effect of cerium ions is optimal in 0.5 g/L BTA. At the same time, the surface uniformity and smoothness of the composite films are both enhanced. And the corrosion resistance of the composite film is strengthened.

采用阳极氧化和化学转化的方法在铝表面制备了Al2O3/氧化铈复合膜。首先在硫酸中对铝进行阳极氧化,然后用Ce(NO3)3溶液对阳极氧化铝进行处理。研究了不同浓度的h -苯并三唑(BTA)对氧化铝/氧化铈复合膜耐腐蚀性能的影响。利用x射线衍射(XRD)、x射线光电子能谱(XPS)、扫描电子显微镜(SEM)和能谱仪(EDS)以及电化学工作站对复合膜的性能进行了表征。结果表明,在0.5 g/L BTA中,铈离子的沉积效果最佳。同时,复合膜的表面均匀性和光滑度都得到了提高。同时增强了复合膜的耐腐蚀性能。
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引用次数: 1
Friction Stir Incremental Forming of AA7075-O Sheets: Experimental Investigations on Performance Evaluation of Formed Parts AA7075-O板的搅拌摩擦增量成形:成形件性能评价的实验研究
IF 0.7 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2018-12-01 DOI: 10.1016/S1875-5372(19)30014-1
Zhang Qiaoxin , Li Guohao , Liu Zhaobing , Zhao Anguo , Xiong Xinhong , Lei Yongjie

A comprehensive performance of formed parts by AA7075-O sheets was studied in friction stir incremental forming (FSIF). Various tool rotation speeds were set to form two typical parts (truncated funnel and pyramid frustum). The formability, surface quality, tensile strength, micro-hardness and thickness distribution of the formed parts were investigated. Results show that the formability generally increases as tool rotation speeds increase. On the contact surface, variation trends of the surface roughness are different in horizontal direction (parallel to tool path) and vertical direction (perpendicular to tool path). However, the surface roughness on the non-contact surface is almost not affected by tool rotation speed. Furthermore, mechanical properties including tensile strength and surface micro-hardness in formed parts are obviously enhanced compared to those of the initial sheet, of which the hardness values begin to fall down gradually after rotation speed reaches 3000 r/min. As for thickness measurement, more uniform thickness distribution of formed parts can be obtained at relative high tool rotation speeds. In general, parts formed at high rotation speed have a better comprehensive performance except the mechanical property.

研究了AA7075-O板材在搅拌摩擦增量成形(FSIF)条件下成形件的综合性能。设置不同的刀具转速,形成两种典型零件(截形漏斗和金字塔锥)。对成形件的成形性能、表面质量、拉伸强度、显微硬度和厚度分布进行了研究。结果表明,随着刀具转速的增加,成形性普遍提高。在接触面上,表面粗糙度在水平方向(平行于刀路)和垂直方向(垂直于刀路)上的变化趋势不同。而非接触面的表面粗糙度几乎不受刀具转速的影响。成形件的抗拉强度和表面显微硬度等力学性能较初始板材有明显提高,当转速达到3000 r/min后,硬度值开始逐渐下降。在厚度测量方面,在较高的刀具转速下,成形件的厚度分布更为均匀。一般来说,高转速下成形的零件除力学性能外,综合性能较好。
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引用次数: 3
High Temperature Oxidation Behavior of Co-Cr-Y2O3 Modified Aluminide Coatings on Ni-based Superalloy by Pack Cementation Process Co-Cr-Y2O3改性铝化物涂层在ni基高温合金上的高温氧化行为
IF 0.7 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2018-12-01 DOI: 10.1016/S1875-5372(19)30007-4
Cao Jiangdong , Gong Shaojun , Zhong Chonggui , Yao Yanbin

The microstructure and high temperature oxidation behavior of Co-Cr-Y2O3 modified pack aluminide coatings on Ni-based superalloy GH586 were investigated. The results show that the specific Co-Cr-Y2O3 modified aluminide coating has a mass gain of only 0.36 mg/cm2 after oxidation at 1000 °C for 100 h, which is much less than that of the substrate at 1000 °C. From X-ray diffraction, the phase of the coatings is mainly AlNi, and after oxidation at 1000 °C for 100 h the denser oxidation scale is composed of Al2O3, Cr2O3, and CoCr2O4. Surface and cross sectional morphologies were characterized by scanning electron microscope (SEM). The coating exhibits a better resistance to high temperature oxidation, compared to the oxidation film of GH586 without coating. Moreover, the growing Cr (W) rich phase is gradually gathered at the grain boundaries during the oxidation, and it is beneficial to providing more Cr element for the dense oxidation film, which is mainly attributed to the excellent high temperature oxidation resistance.

研究了ni基高温合金GH586表面Co-Cr-Y2O3改性包铝化物涂层的显微组织和高温氧化行为。结果表明,在1000℃氧化100 h后,Co-Cr-Y2O3改性铝化物涂层的质量增益仅为0.36 mg/cm2,远低于基体在1000℃氧化后的质量增益。x射线衍射结果表明,涂层的相主要为AlNi,在1000℃氧化100 h后,较致密的氧化层由Al2O3、Cr2O3和CoCr2O4组成。采用扫描电镜(SEM)对其表面形貌和横截面形貌进行了表征。与未涂覆的GH586氧化膜相比,涂层具有更好的耐高温氧化性能。在氧化过程中,生长的富Cr (W)相在晶界处逐渐聚集,有利于为致密氧化膜提供更多的Cr元素,这主要归功于优异的耐高温氧化性。
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引用次数: 3
New Insights into Change Rate of Pore Volume – Taking Titanium Foam for Example 孔隙体积变化率的新认识——以泡沫钛为例
IF 0.7 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2018-11-01 DOI: 10.1016/S1875-5372(18)30234-0
Xiao Jian , Liu Jinping , Wang Zhixiang , Qiu Guibao

The space holder technique is widely used to fabricate metal foams, especially titanium foam. However, how to obtain the desired porosities is a big challenge for this technique, because they are not always equal to the expected ones. The results of the previous study (i.e., P = ax + b, where a = 1/(1 + δ), b = δ/(1 + δ)) give a very interesting conclusion that is the change rate of pore volume (δ) is an indefinite mathematical constant. Based on the research work, we obtains a new result by establishing a mathematical model, which can be expressed as equation δ = ϕ − 1. Here, ϕ is the length index product of the ratio between the actual length and the designed length of the sintered metal foam. It reveals that the length index product (ϕ) is also an indefinite mathematical constant and we can measure its value. Therefore, solving δ means both a and b are solved, so the porosity (P) of titanium foam can be predicted by the equation P = ax + b, depending on the spacer content (x). This indicates that in the absence of porosity measurements, the macroscopic dimensions of the sintered metal foam can be measured to obtain a controlling equation for porosity.

空间支架技术广泛应用于金属泡沫材料,尤其是钛泡沫材料的制备。然而,如何获得所需的孔隙率是该技术的一大挑战,因为它们并不总是等于预期的孔隙率。前人的研究结果(即P = ax + b,其中a = 1/(1 + δ), b = δ/(1 + δ))给出了一个非常有趣的结论,即孔隙体积变化率(δ)是一个不定的数学常数。在研究工作的基础上,我们建立了一个数学模型,得到了一个新的结果,该模型可以表示为公式δ = ϕ−1。其中φ为烧结金属泡沫的实际长度与设计长度之比的长度指标积。它揭示了长度指数积(φ)也是一个不定的数学常数,我们可以测量它的值。因此,解出δ意味着解出了a和b,因此泡沫钛的孔隙率(P)可以用方程P = ax + b来预测,这取决于间隔剂的含量(x)。这表明,在不进行孔隙率测量的情况下,可以测量烧结泡沫金属的宏观尺寸,从而得到孔隙率的控制方程。
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引用次数: 3
Preparation of Cladding Billet via Direct Chill Casting Process 直接冷铸工艺制备熔覆方坯
IF 0.7 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2018-11-01 DOI: 10.1016/S1875-5372(18)30239-X
Guo Jing , Han Xing , Teng Yingxue , Wang Hongbin , Zhang Haitao , Nong Deng

A mathematic model was built to describe the cladding casting process and the casting parametric influence on the cladding billet. The effect of casting speed, casting temperature and internal cooling water rate on the casting process performance was discussed. Based on the numerical simulation results, the cladding billet was prepared successfully. Moreover, the model was verified by the temperature measurements during the cladding casting process. The interfacial characteristics were investigated by metallographic examination, energy dispersive spectrometer and universal testing machine. The results show that there is a good agreement between the measured and calculated results. The comprehensively considered casting process is: casting speed 100 mm/min, internal cooling water rate 35 L/min, casting temperature 1020 K (AA4045) and 1000 K (AA3003). Based on the simulation results, the AA4045/AA3003 cladding billet with no defects and Φ140 mm/Φ110 mm in size is fabricated successfully. A diffusion layer with 15 μm in width is formed around the bonding interface. The interfacial bonding strength is 107.3 MPa, higher than that of AA3003, indicating that the two alloys have been bonded metallurgically.

建立了熔覆铸造过程的数学模型,描述了浇注参数对熔覆方坯的影响。讨论了浇注速度、浇注温度和内冷却水速率对浇注工艺性能的影响。根据数值模拟结果,成功制备了熔覆方坯。并通过熔覆铸造过程的温度测量对模型进行了验证。采用金相检验、能谱仪和万能试验机对界面特征进行了研究。结果表明,实测结果与计算结果吻合较好。综合考虑的铸造工艺为:铸造速度100mm /min,内冷却水流速35l /min,铸造温度1020k (AA4045), 1000k (AA3003)。在此基础上,成功制备了尺寸为Φ140 mm/Φ110 mm、无缺陷的AA4045/AA3003熔覆方坯。在键合界面周围形成了直径为15 μm的扩散层。界面结合强度为107.3 MPa,高于AA3003,表明两种合金已进行了冶金结合。
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引用次数: 0
Prediction of Flow Stresses for a Typical Nickel-Based Superalloy During Hot Deformation Based on Dynamic Recrystallization Kinetic Equation 基于动态再结晶动力学方程的典型镍基高温合金热变形流变应力预测
IF 0.7 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2018-11-01 DOI: 10.1016/S1875-5372(18)30240-6
Zhou Haiping , Zhang Hongbin , Liu Jie , Qin Shengxue , Lv Yuting

The hot deformation behavior of a typical nickel-based superalloy was investigated by isothermal compression tests in the temperature range of 1010∼1160 °C and strain rate range of 0.001∼1 s−1. The results indicate that the work hardening, dynamic recovery (DRV) and dynamic recrystallization (DRX) occurred in the alloy during hot deformation. Considering the coupled effects of deformation parameters on the flow behaviors of the alloy, the constitutive models were established to predict the flow stresses during the work hardening-DRV period and DRX periods. In the DRX period, the modified DRX kinetic equation was used to develop the constitutive models, and the strain for maximum softening rate was used in this equation. Additionally, the material constants in the constitutive models were expressed as the functions of Zener-Hollomon parameter by using a linear fitting method. Meanwhile, comparisons between the measured and the predicted flow stresses were carried out, while the correlation coefficient (R) and average absolute relative error (AARE) between the measured and predicted values were also calculated. The results confirm that the developed models could give an accurate estimation of the flow stresses.

通过等温压缩试验,研究了一种典型镍基高温合金在1010 ~ 1160℃温度范围和0.001 ~ 1 s−1应变速率范围内的热变形行为。结果表明:合金在热变形过程中发生了加工硬化、动态恢复和动态再结晶;考虑变形参数对合金流动行为的耦合影响,建立了预测加工硬化- drv和DRX过程流变应力的本构模型。在DRX阶段,采用修正的DRX动力学方程建立本构模型,采用最大软化速率应变。此外,采用线性拟合方法将本构模型中的材料常数表示为Zener-Hollomon参数的函数。同时,将实测值与预测值进行对比,计算实测值与预测值之间的相关系数R和平均绝对相对误差AARE。结果表明,所建立的模型能较准确地估计出流动应力。
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引用次数: 9
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稀有金属材料与工程
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