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Comparative assessment of air pollutant emissions from brick manufacturing 制砖过程中空气污染物排放的比较评估
Pub Date : 2020-10-14 DOI: 10.21698/rjeec.2020.222
V. Danciulescu, E. Bucur, M. Petrescu, M. Bratu, A. Cozea, G. Tanase
In this paper, a comparison is made of the level of air pollution between two brick production lines that apply different technologies, one old and one new, and more efficient. The main pollutants emitted in the air from the baking kilns are CO, SO2, NO2, HCl, HF, and dust. The monitoring of emissions was performed with a Testo 350 flue gas analyzer – the automatic method. A Paul Gothe isokinetic sampler was used to take dust, HCl, and HF sampling, and the analysis was performed in the laboratory using gravimetric and spectrophotometric analytical methods. The results of the tests performed showed a reduction in the level of pollution by applying the new and BAT technologies by up to 90% for all monitored pollutants, compared to the pollution produced by old and non-re-technologized line. At the same time, energy consumption is lower per unit of product, which results in a significant decrease in production costs.
本文对采用新老两种不同工艺的高效制砖生产线的空气污染水平进行了比较。焙烧窑向大气中排放的主要污染物是CO、SO2、NO2、HCl、HF和粉尘。使用Testo 350烟气分析仪进行排放监测,这是一种自动方法。采用Paul Gothe等速进样器对粉尘、HCl和HF进行取样,在实验室采用重量法和分光光度法进行分析。所进行的测试结果表明,与旧的和未重新技术化的生产线所产生的污染相比,采用新技术和BAT技术对所有监测污染物的污染水平降低了高达90%。同时,单位产品能耗更低,大大降低了生产成本。
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引用次数: 0
Determination of phosphorus in different types of waste using the ICP-MS technique 电感耦合等离子体质谱法测定不同类型废物中的磷
Pub Date : 2020-10-14 DOI: 10.21698/rjeec.2020.217
G. Catrina, Lidia Kim, A. Serbanescu, I. Cristea, M. Barbu, I. Nicolescu, G. Vasile
The research aimed to provide an optimized method for the determination of phosphorous concentration in different types of solid waste using inductive coupled plasma mass spectrometry (ICP-MS) technique. The analyzed waste matrices are: a) vegetable waste (P1), b) ash from the incineration of medical waste (P2) c) sewage sludge (P3) and d) sludge from the meat processing industry (P4). The results obtained by the ICP-MS method were compared with the UV-VIS spectrophotometric method for the determination of total phosphorus. In the case of using the colorimetric method by UV-VIS technique, lower results were obtained compared to the ICP-MS method due to the interferences given by the reagents used to determine the total phosphorus. The interferences given by other elements (metals) were also investigated and the performance parameters were determined such as detection limit, quantification limit, recovery and expandend incertainty using ICP-MS technique.
本研究旨在为电感耦合等离子体质谱(ICP-MS)技术测定不同类型固体废物中磷的浓度提供一种优化方法。所分析的废物基质为:a)蔬菜废物(P1), b)医疗废物焚烧产生的灰(P2) c)污水污泥(P3)和d)肉类加工业产生的污泥(P4)。将ICP-MS法与紫外-可见分光光度法测定总磷的结果进行了比较。在使用UV-VIS技术比色法的情况下,由于测定总磷所用试剂的干扰,所得结果低于ICP-MS法。研究了其他元素(金属)的干扰,确定了ICP-MS技术的检出限、定量限、回收率和扩展不确定度等性能参数。
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引用次数: 0
Comparative testing of Ag/Au/Pt graphene electromodified electrodes in electrochemical detection of tetracycline-emerging pollutant Ag/Au/Pt石墨烯修饰电极在四环素新兴污染物电化学检测中的对比测试
Pub Date : 2020-10-14 DOI: 10.21698/rjeec.2020.219
S. Negrea, L. A. Diaconu, V. Nicorescu, D. Neidoni, A. Baciu, Claudia Licurici, F. Manea
This study aimed to obtain new electrochemically modified electrodes with graphene and Au, Pt, Ag particles considering graphite (GP) and glassy carbon (GC) substrate by applying the chronoamperometry technique to develop the detection protocol of tetracycline (TC) considered as an emerging pollutant in water, using cyclic voltammetry (CV) technique. The graphite-based substrate used for Ag/ Au/ Pt electrodeposition led to the electrode compositions on which TC oxidation process was not diffusion-controlled and as consequence, TC detection failed. TC detection protocols were developed for all Ag/Au /Pt electrodeposited GC and GCGP electrodes. Better limits of TC detection was achieved for Ag electrodeposited on GC-GP at the cathodic potential of 0.460 V/SCE.
本研究以石墨(GP)和玻璃碳(GC)为衬底,采用时温法技术,制备了石墨烯和Au、Pt、Ag粒子的电化学修饰电极,并采用循环伏安法(CV)建立了水中新兴污染物四环素(TC)的检测方案。Ag/ Au/ Pt电沉积使用的石墨基衬底导致电极成分上的TC氧化过程不受扩散控制,从而导致TC检测失败。开发了所有Ag/Au /Pt电沉积GC和GCGP电极的TC检测方案。在阴极电位为0.460 V/SCE时,GC-GP上电沉积的银具有较好的TC检测限。
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引用次数: 0
Graphical and computational methods for determining the stability constants of mono- and polynuclear complexes with a common intersection point of the family of formation curves 确定具有形成曲线族共同交点的单核和多核配合物稳定性常数的图解和计算方法
Pub Date : 2020-10-14 DOI: 10.21698/rjeec.2020.210
I. Povar, O. Spînu, B. Pintilie
Aqueous polynuclear systems have been analyzed, for which the family of formation curves intersects at a common point. The analyzed graphical and computational method for determining the stability constants can be used as initial values within the iterative calculation process. In some cases, the stability constants are calculated using only the coordinates of the common intersection point. The obtained equations could be of special interest when the experimental data can be interpreted in several models. In these cases, given the large volume of experimental data, the calculation is simple and the model can certainly be chosen with high safety. The obtained equations may also be applied for critical evaluation of tabular data if the coordinates of the intersection point are known. A series of real polynuclear systems have been analyzed and useful conclusions have been made.
对地层曲线族相交于同一点的多核水系进行了分析。所分析的确定稳定常数的图解和计算方法可作为迭代计算过程中的初始值。在某些情况下,稳定性常数仅使用公共交点的坐标计算。当实验数据可以在几个模型中解释时,得到的方程可能特别有趣。在这些情况下,由于实验数据量大,计算简单,当然可以选择安全性高的模型。如果交点坐标已知,所得到的方程也可用于表格数据的临界计算。对一系列实际的多核系统进行了分析,得出了有益的结论。
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引用次数: 0
Cavitation action on the cocci bacteria 对球菌的空化作用
Pub Date : 2020-10-14 DOI: 10.21698/rjeec.2020.206
I. Koval, A. Hajiali
Features of growth of microorganisms on a nutrient medium and their microscopic researches were studied. Cavitation treatment (22 kHz, 91 W, 1.65 W/сm3) of water with the simultaneous action of bubbled inert gases (argon and helium) on the viability of microbial cells (Diplococcus and Sarcina) are presented. The highest water disinfection was obtained for water samples with Sarcina lutea cells for both used gases under cavitation conditions. Both investigated types of cocci bacteria were destroyed faster under Ar/US-action after comparison of the effectiveness of the gas nature action on the water disinfection.
对微生物在营养培养基上的生长特点及其显微研究进行了研究。提出了在气泡惰性气体(氩气和氦气)的同时对微生物细胞(双球菌和沙丁鱼)的活力进行空化处理(22 kHz, 91 W, 1.65 W/ m3)。在空化条件下,两种使用气体对含有黄斑肌细胞的水样的水消毒效果最好。通过对比气体自然作用对水的消毒效果,两种被调查的球菌细菌在Ar/ us作用下被更快地破坏。
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引用次数: 0
LDH-GO composites as catalysts for the oxidative removal of indigo carminedye from wastewater LDH-GO复合材料氧化脱除废水中靛蓝胭脂红的催化剂研究
Pub Date : 2020-10-14 DOI: 10.21698/rjeec.2020.201
Alexandra-Elisabeta Stamate, R. Zăvoianu, O. Pavel, A. Cruceanu, M. Corobea, M. Osiac, N. Cioateră
Herein, we present the results of our researches focused on obtaining composites with enhanced affinity for indigo carmine (IC) by combining two different 2D materials e.g. graphene oxide (GO) and a Cerium modified layered double hydroxide (LDH), which could act as catalysts for the oxidative removal of IC, both under ultrasonic irradiation and under conventional stirring, using H2O2 as oxidation agent. Three Mg3Al0.75Ce0.25 LDH-GO composites bearing different concentrations of GO in the range of 5-15 wt.% abbreviated as HT3Ce-xGO where x stands for the concentration of GO (x=5,10,15% wt. GO) have been prepared and characterized by XRD, SEM, Raman and DRIFT spectroscopy. The XRD patterns of HT3Ce-xGO solids have revealed the formation of nanocomposites with fine particles of CeO2 (Scherrer dimensions around 3 nm) embedded in the 2D layered structure of LDH-GO. CeO2 phase was favored by the increase in GO content for all investigated composites. The size decrease of the solid particles with the increase of GO content was proved both by SEM and DRIFT analyses. Raman spectra proved the incorporation of GO in all composites. The results of the catalytic tests showed, without any doubt the activation effect of the ultrasonic irradiation which allowed doubling the dye removal percentage (DR%) in the first 30 minutes of reaction time. For the most active catalyst, HT3Ce-15GO, the COD after 30 minutes reaction time under ultrasonic irradiation was 221 mgO2/L, while TOC was 93 mgC/L marking a decay of 61.6% for COD and 46.2% for TOC.
本文研究了氧化石墨烯(GO)和铈修饰层状双氢氧化物(LDH)这两种不同的二维材料,在超声波照射和常规搅拌条件下,以H2O2为氧化剂,获得了对靛蓝胭脂红(IC)具有增强亲和力的复合材料。制备了3种不同氧化石墨烯浓度的Mg3Al0.75Ce0.25 LDH-GO复合材料(5-15 wt.%),简称为HT3Ce-xGO,其中x代表氧化石墨烯浓度(x=5、10、15% wt. GO),并通过XRD、SEM、Raman和DRIFT光谱对其进行了表征。HT3Ce-xGO固体的XRD谱图显示,在LDH-GO的二维层状结构中嵌入了CeO2细颗粒(Scherrer尺寸约为3 nm)的纳米复合材料。在所有的复合材料中,氧化石墨烯含量的增加有利于CeO2相。SEM和DRIFT分析表明,随着氧化石墨烯含量的增加,固体颗粒的尺寸减小。拉曼光谱证实了氧化石墨烯在所有复合材料中的掺入。催化试验结果表明,毫无疑问,超声波辐照的活化作用,使染料去除率(DR%)在前30分钟的反应时间内翻了一番。催化活性最强的催化剂HT3Ce-15GO在超声照射下反应30 min后,COD为221 mgO2/L, TOC为93 mgC/L, COD衰减61.6%,TOC衰减46.2%。
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引用次数: 0
Municipal solid waste (MSW) - competitive raw materials for combustible materials obtaining 城市固体废物(MSW) -获得可燃材料的竞争性原料
Pub Date : 2020-10-14 DOI: 10.21698/rjeec.2020.221
A. Serbanescu, M. Barbu, I. Cristea, Lidia Kim, G. Catrina, Georgiana Cernica, I. Nicolescu
Waste-to-energy projects can be classified as a complementary technology for energy recovery from nonrecyclable municipal waste fractions and should therefore not compete with measures to reduce, reuse, and recycle materials. The article presents the characterization of some treated municipal solid wastes as competitive raw materials for combustible materials obtaining. Samples with lignocellulosic and polymeric composition were analyzed, namely 3 samples of SRFs (solid recovered fuels) used as secondary raw material in cement plants, SRF1, SRF2, SRF3; a sample of RDF, consisting of household waste; a sample of fluff (a homogeneous mixture of non-hazardous waste - selected, mechanically treated and dried) used as a secondary raw material in cement plants; 4 samples of municipal solid waste, fractions smaller than 100 mm, after a bio-drying process, with composition: paper and cardboard (70-80%), wood (6-15%), plastic (6-10%), glass and metal (3-14%), MBU1, MBU2, MBU3, MBU4. The waste samples were characterized in terms of technical and elementary characteristics and the ash (obtained by the sample incineration) behavior in the combustion process. The mineral matter was investigated by the X-ray fluorescence analytical technique using the Rigaku CG X-ray Spectrofluorimeter. The analysis of the indices used for the slagging and deposit formation risks evaluation shows that the analyzed samples present an obvious risk of melt formation and deposits, due to a high content of base oxides and silicon oxide.
废物发电项目可归类为从不可回收的城市废物部分中回收能源的补充技术,因此不应与减少、再利用和回收材料的措施竞争。本文介绍了一些处理过的城市生活垃圾作为获取可燃材料的竞争原料的特点。分析了具有木质纤维素和聚合物成分的样品,即作为水泥厂二次原料的SRFs(固体回收燃料)样品,SRF1, SRF2, SRF3;由家庭垃圾组成的RDF样本;在水泥厂中用作二次原料的绒毛样品(一种非危险废物的均匀混合物——经过选择、机械处理和干燥);4份小于100毫米的城市固体废物样品,经过生物干燥过程,成分:纸和纸板(70-80%),木材(6-15%),塑料(6-10%),玻璃和金属(3-14%),MBU1, MBU2, MBU3, MBU4。从技术和基本特征以及燃烧过程中的灰分(由样品焚烧获得)行为方面对废物样品进行了表征。采用Rigaku CG x射线荧光光谱仪对矿物进行了x射线荧光分析。通过对结渣和结渣风险评价指标的分析,发现所分析样品由于碱性氧化物和氧化硅含量高,存在明显的熔体形成和结渣风险。
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引用次数: 0
New ion-chromatography method for detection of chlorite, chlorate, and bromate in drinking water 离子色谱法检测饮用水中亚氯酸盐、氯酸盐和溴酸盐的新方法
Pub Date : 2020-10-14 DOI: 10.21698/rjeec.2020.207
I. Paun, V. Iancu, F. Chiriac, Nicoleta Vasilache, F. Pirvu, M. Niculescu, T. Galaon
A direct ion chromatographic method for the determination of chlorite, chlorate, and bromate in the presence of fluoride, chloride, nitrate, nitrite, and bromide in treated drinking waters was described. Separation of target analytes was achieved using an AS19-HC analytical column (250 mm x 4 mm), AG 19- HC guard column (50 mm x 4 mm), and KOH 25 mmol/L as mobile phase. Inorganic analytes were eluted using a flow rate of 1 mL/min. The column temperature was set up and maintained at 300C. The analyte ionswere quantified using a suppressed conductivity detector.
介绍了一种直接离子色谱法测定处理过的饮用水中存在氟化物、氯化物、硝酸盐、亚硝酸盐和溴化物的亚氯酸盐、氯酸盐和溴酸盐。采用AS19-HC分析柱(250 mm × 4 mm), AG 19-HC保护柱(50 mm × 4 mm), KOH 25 mmol/L为流动相进行分离。无机分析物以1ml /min的流速洗脱。设置柱温并保持在300℃。用抑制电导率检测器定量分析离子。
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引用次数: 0
Relationships between land use, predicted pollution loadings, and ecotoxicological assays in constructed wetlands 人工湿地中土地利用、预测污染负荷和生态毒理学分析之间的关系
Pub Date : 2020-10-14 DOI: 10.21698/rjeec.2020.215
S. G. Roy, T. Ehlinger
Environmental degradation related to uncontrolled development resulted in the passage of the United States Clean Water Act (CWA) in 1972, with the stated purpose “to restore and maintain the integrity of the nation’s waters”. Implementation of the CWA leads to increased research to develop multimetric indicators to better measure and understand the complex patterns of ecological responses to stress occurring across levels of biological, spatial, and temporal organization. One area of research is the use of integrated indices of chemical risk, ecotoxicological risk, and ecological risk to assess the impact of human activity across disturbance gradients of urbanization. Selecting relevant metrics for constructing a multimetric index requires identifying bioindicator organisms with capacities to detect signals from anthropogenic disturbances. This study explored the potential efficacy of a suite of higher plant ecotoxicological assays for use as bioindicators in ecological risk assessment along a gradient of urbanization in a wetland ecosystem. The study was conducted in the Pike River watershed (Racine, Wisconsin, USA) in six wetlands selected across a gradient of dominant land-use types (agricultural, commercial, residential, undeveloped, and industrial). MicroBioTest PhytotoxkitTM ecotoxicological assays, based on growth inhibition of three plants (Sinapis, Sorghum, and Lepidium) were used to assess sediment toxicity. The relationships between Phytotoxkit™ responses and predicted pollutant loadings calculated from surrounding land use provided clear signals of stress from watershed pollutants draining into the wetland sites. The potential for these ecotoxicological indicators to serve as biological response signatures is strong, and further research and calibration in field and microcosms studies will assist in calibrating responses for use in integrated monitoring efforts.
由于不受控制的开发而导致的环境退化导致1972年通过了《美国清洁水法》,其目的是“恢复和维持国家水域的完整性”。CWA的实施将导致更多的研究,以开发多度量指标,以更好地衡量和理解发生在生物、空间和时间组织水平上的应激生态反应的复杂模式。一个研究领域是利用化学风险、生态毒理学风险和生态风险的综合指数来评估人类活动对城市化扰动梯度的影响。选择相关指标来构建多指标指数需要识别具有检测人为干扰信号能力的生物指示生物。本研究探讨了一套高等植物生态毒理学分析作为生物指标在湿地生态系统城市化梯度生态风险评估中的潜在功效。该研究在派克河流域(美国威斯康辛州拉辛市)的六个湿地中进行,选择了主要土地利用类型(农业、商业、住宅、未开发和工业)的梯度。MicroBioTest PhytotoxkitTM生态毒理学试验,基于三种植物(Sinapis,高粱和Lepidium)的生长抑制,用于评估沉积物毒性。Phytotoxkit™响应与从周围土地利用计算的预测污染物负荷之间的关系提供了流域污染物排入湿地的压力的明确信号。这些生态毒理学指标作为生物反应标志的潜力很大,实地和微观研究的进一步研究和校准将有助于校准反应,以便用于综合监测工作。
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引用次数: 2
Assessment of the level of noise and chemical air pollution in two distinct urban areas 评估两个不同城市地区的噪音和化学空气污染水平
Pub Date : 2020-10-14 DOI: 10.21698/rjeec.2020.216
M. Bratu, E. Bucur, V. Danciulescu, M. Petrescu, G. Tanase, O. Vasile
In the paper are presented the results of tests on the evaluation of the level of noise and chemical air pollution in two distinct urban areas: an industrial area and an area characterized by heavy road traffic, with a focus on the novelty elements introduced by the regulations in force on the measurement and management of the level of ambient and industrial noise by periodically developing specific noise maps. The results of direct tests and noise maps developed in the case of the studied areas indicated higher values of the indicators measured near the road artery compared to the other measuring points, highlighting the influence of vegetation in urban areas to reduce noise levels and reduce air pollution.
本文介绍了在两个不同的城市地区(一个工业区和一个以道路交通繁忙为特征的地区)进行的噪声和化学空气污染水平评估试验的结果,重点介绍了通过定期制定具体的噪声地图来测量和管理环境和工业噪声水平的现行法规所引入的新奇因素。在研究地区进行的直接测试和绘制的噪音地图的结果表明,与其他测量点相比,在道路主干道附近测量到的指标值更高,突出显示了城市地区植被对降低噪音水平和减少空气污染的影响。
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引用次数: 0
期刊
Romanian Journal of Ecology & Environmental Chemistry
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