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Pressure Acid Leaching of Printed Circuit Board Waste and Selective Metal Recovery from Extracted Solution 印制板废弃物的压力酸浸及萃取液中金属的选择性回收
Pub Date : 2013-02-01 DOI: 10.2473/JOURNALOFMMIJ.129.65
A. Hosoi, Y. Takasaki, A. Shibayama
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引用次数: 0
On the Interaction of Mineral Resources, Natural Energy, And Environment 论矿产资源、自然能源与环境的相互作用
Pub Date : 2013-01-01 DOI: 10.2473/JOURNALOFMMIJ.129.1
Y. Nishimatsu
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引用次数: 0
Separation of Lead Component from "K powder" Generated in Cement Kiln by Sulfidized Flotation:Part1. Determination of Flotation Conditions and Analysis of Reaction Mechanism 硫化浮选法分离水泥窑“K粉”中的铅组分(一)。浮选条件的确定及反应机理分析
Pub Date : 2011-11-25 DOI: 10.2473/JOURNALOFMMIJ.127.699
K. Ichitsubo, Masakazu Suzuki, Takaaki Ogami, Tsutomu Suzuki, Keiichi Miura, A. Shibayama, S. Owada
of NaHS addition. Then, we could separate lead components from “ K powder ” with the recovery of 60 % as a lead concentration of 10 ~ 30 Pb wt% under the same condition of sulfidized flotation for the “ K powders ” of various component.
NaHS的加入。在相同硫化浮选条件下,对不同组分的“K粉”,在铅浓度为10 ~ 30pb wt%的条件下,可从“K粉”中分离出铅组分,回收率可达60%。
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引用次数: 0
Rare Earth Resources and Related Industries in Japan 日本稀土资源及相关产业
Pub Date : 2011-08-25 DOI: 10.2473/JOURNALOFMMIJ.127.549
Tatsuo Ôta
The periodic table of the elements, shown in Table 1, highlights 17 elements comprising Scanndium, Yttrium and 15 elements known as “lanthanoids”1. The elements are lined up according to the atomic number displayed horizontally and the same type of electrons in the outermost shell vertically. The electron number and type of each element gives the physical and chemical properties2. It can be said that these elements called “rare earth elements” are similar to each other in some physical and chemical characters because the outermost electrons are the same1. Although there is no defined classification in rare earth, Table 2 shows common classifications of two methods. One is to classify into two categories and the other is into three categories. Solubility of potassium sulfate double salt into water is used in the case of three categories, e.g. not to solve; light rare earth, difficult to solve; middle rare earth, easy to solve; heavy rare earth3.
元素周期表如表1所示,突出显示了17种元素,包括钪、钇和15种被称为“类镧”的元素。元素按照原子序数水平排列,相同类型的电子在最外层垂直排列。每种元素的电子数和类型决定了它们的物理和化学性质。可以说,这些被称为“稀土元素”的元素在某些物理和化学性质上彼此相似,因为它们最外层的电子是相同的。虽然稀土没有明确的分类,但表2显示了两种方法的常见分类。一种是分为两类,另一种是分为三类。硫酸钾双盐溶解度用在遇水情况有三类,如不能溶解;轻稀土,难解;中稀土,易解;重稀土。
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引用次数: 2
Influence of Concrete Strength on the Bond Characteristics of Reinforcing Fibers 混凝土强度对增强纤维粘结特性的影响
Pub Date : 2011-05-25 DOI: 10.2473/JOURNALOFMMIJ.127.249
H. Dong, S. Okubo, K. Fukui
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引用次数: 0
Frost Damage to Bricks Observed in Kitami City, Hokkaido 北海道北上市观察到砖的霜冻损坏
Pub Date : 2011-03-25 DOI: 10.2473/JOURNALOFMMIJ.127.219
D. Nakamura, T. Goto, Yoji Ito, S. Yamashita, Teruyuki Suzuki, S. Yamasaki
At two different locations in Kitami City, Hokkaido, cracks have been found in bricks, seemingly due to frost damage. In this research, the mechanism of the occurrence of the cracks in the bricks has been looked into through field investigations and exposure experiment. The field investigations have revealed that some bricks located in sun-exposed areas have a higher frequency to crack and cracks occur in the protruded part of bricks. From the exposure experiment, cracks in the bricks have been found to occur in late winter from the end of February to the end of March. It has also been confirmed that the following unique temperature distribution exists when cracks occur in bricks; in late winter, bricks melt due to the daytime heat. If bricks do not melt completely during the daytime leaving some frozen parts and these remain overnight, the melted areas created during the daytime then refreeze surrounded by the frozen parts due to the low night temperatures. In this research, this frost damage caused by such temperature distribution has been defined as closed-type freeze-thaw phenomenon.From the above results, this article describes the mechanism of frost damage to bricks in Kitami City. The research results are considered useful when brick structures are built in cold regions like Hokkaido, ensuring the appropriate use of bricks.
在北海道北上市的两个不同地点,砖上发现了裂缝,似乎是由于霜冻造成的。本研究通过现场调查和暴露试验,探讨了砖体裂纹的发生机理。现场调查发现,部分位于日照区域的砖发生裂缝的频率较高,裂缝发生在砖的突出部分。从暴露试验中发现,在2月底至3月底的冬末,砖会出现裂缝。还证实了砖在发生裂纹时存在以下独特的温度分布:在冬末,由于白天的高温,砖块会融化。如果砖块在白天没有完全融化,留下一些冻结的部分,并且这些部分在晚上仍然存在,那么在白天产生的融化区域,然后由于夜间温度低,被冻结部分包围而重新冻结。本研究将这种温度分布引起的冻融损害定义为封闭型冻融现象。从上述结果出发,阐述了北北市砖的冻害机理。研究结果对于在北海道等寒冷地区建造砖结构,确保砖的合理使用,具有借鉴意义。
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引用次数: 1
Mechanical Behavior of Kimachi Sandstone under Ultralow Temperature 超低温条件下Kimachi砂岩力学行为研究
Pub Date : 2010-12-25 DOI: 10.2473/JOURNALOFMMIJ.127.8
N. Kamoshida, M. Okawara, Masayoshi Abe, M. Furuzumi
The practical application of the rock cavern storage of liquefied fuels (such as natural gas, liquid hydrogen or dimethyl ether) requires stability analysis of the cavern in question with regard to thermal stress, and an understanding of thermophysical properties and mechanical properties of rock mass is essential for such analysis.In our research, a linear expansion strain measurement test up to —170°C was first conducted using Kimachi sandstone (24.0% porosity) to study the relationship between the freezing of pore water and its expansion strain. Then a uniaxial compression test and indirect tensile test were conducted with wet sandstone cooled down below freezing point to ultralow temperatures to review the influence of the formation of pore ice on the strength of wet sandstone. The following findings were obtained.When Kimachi sandstone is cooled down, frost swelling occurs twice, and therefore the linear expansion coefficient fluctuates over range of temperatures between 0 to —70°C. This may be because pores of two different sizes exist in Kimachi sandstone and the freezing temperature of the pore water differs depending on the pore size. The compressive strength and indirect tensile strength of the wet sandstone increase with the decrease in the specimen temperature. Two causes of this phenomenon may be identified. One is that an increase in pore ice that shares the load is the main cause of the phenomenon in temperatures down to —50°C where freezing of the pore water is almost completed. The other is that an increase in strength by volumetric shrinkage of the rock forming minerals and pore ice is the main cause in temperatures below —50°C.
溶洞储存液化燃料(如天然气、液态氢或二甲醚)的实际应用需要对溶洞进行热应力稳定性分析,了解岩体的热物理性质和力学性质是进行此类分析的必要条件。本研究首先以孔隙度为24.0%的Kimachi砂岩为研究对象,进行了-170℃下的线性膨胀应变测量试验,研究孔隙水冻结与膨胀应变的关系。通过对湿砂岩在冰点以下冷却至超低温条件下的单轴压缩试验和间接拉伸试验,考察孔隙冰的形成对湿砂岩强度的影响。研究结果如下:当Kimachi砂岩冷却时,会发生两次霜胀,因此线性膨胀系数在0到-70°C的温度范围内波动。这可能是因为木町砂岩中存在两种不同大小的孔隙,孔隙水的冻结温度随孔隙大小的不同而不同。湿砂岩的抗压强度和间接抗拉强度随试样温度的降低而增大。造成这种现象的原因有两个。一种解释是,在温度降至-50°C时,孔隙水几乎完全冻结,分担荷载的孔隙冰的增加是造成这种现象的主要原因。另一种解释是,在低于-50℃的温度下,由造岩矿物和孔隙冰的体积收缩引起的强度增加是主要原因。
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引用次数: 2
A Numerical Model and Numerical Simulations in Consideration of Permeability Reduction by Coal-Matrix Swelling for CO_2-ECBMR CO_2-ECBMR煤基质溶胀降低渗透率的数值模型及数值模拟
Pub Date : 2009-12-25 DOI: 10.2473/JOURNALOFMMIJ.125.605
K. Sasaki, T. Yasunami, Y. Sugai
CO2 capture and storage (CCS) is one of expected methods to reduce CO2 emissions into the atmosphere. The Japan consortium to proceed the CO2 sequestration into coal seams carried out the project "Japan CO2 Geosequestration in Coal Seams Project (JCOP) " on CO2 injection and CH4 production during 2002 to 2007 at Yubari City, Hokkaido, which is hereinafter called as Yubari ECBMR pilot test. A targeted coal seam at the project was located about 890m below the surface. The project had a problem on CO2 injection with low injection rate of about 3ton/day. In the pilot-test data, it was observed as a common pattern that CO2 injection rate was decreasing during 3 to 10 days after starting CO2 injection, because of decreasing permeability around the injector. The maximum decreasing ratio of the permeability was evaluated as 1/50 of the initial one. The reason was assumed by swelling of the coal seam around the injector by injection liquid CO2. In this study, an analytical model has been presented in consideration of permeability reduction by swelling. Present predictions on CO2 injection rate with the model have been matched with monitoring data measured at the Yubari ECBMR pilot test. The ratio of permeability reduction of coal seams by the swelling (swelling factor) has been evaluated as 1/50 to 1/16.In this research, numerical simulations, which use double porosity model and Palmer & Mansoori model to express permeability reduction by shrinkage of micro-pores caused by CO2 adsorption, called as coal matrix swelling, has been carried out with the ECLIPS (CBM option) . A history matching study was conducted to estimate CH4 desorption time and production bottom-hole pressure (BHP). Other reservoir parameters such as pore compressibility and gas-water relative permeability curve, were set based on the report of Yubari pilot test and previous researches by Yamaguchi et al. (2007) and Pekot & Reeves (2002) . The numerical simulations for sensitivity studies on CO2 injectivity and CH4 productivity have been carried out by giving CO2 and CH4 adsorption capacities and viscocities of CO2 and water as a function of the coal seam temperature (30 to 60 °C) . Finally, the numerical simulation results with five spot model have been presented to evaluate CO2 injectivity and CH4 productivity by changing the well spacing. The results show that CO2 injection is roughly proportional to number of injectors, however the time at the maximum CH4 production rate is delayed with area including four production wells. From view of economical evaluation, drilling cost of wells and accumulated present value of revenue of CH4 production will be important to decide the optimum well spacing.
二氧化碳捕集与封存(CCS)是减少大气中二氧化碳排放的一种有望实现的方法。日本开展煤层二氧化碳封存项目的财团实施了“日本煤层二氧化碳地质封存项目”(JCOP)。2002 - 2007年在北海道夕张市进行的ECBMR中试,即“夕张ECBMR中试”。该项目的目标煤层位于地表以下约890m处。该项目存在CO2注入问题,注入速率较低,约为3吨/天。在中试数据中,由于注入器周围的渗透率下降,在开始注入CO2后的3 ~ 10天内,CO2注入速率普遍下降。渗透率最大降幅为初始降幅的1/50。其原因是由于注入液态CO2导致喷射器周围煤层膨胀。在本研究中,提出了一个考虑溶胀降低渗透率的分析模型。目前使用该模型预测的二氧化碳注入速率已与Yubari ECBMR中试测试的监测数据相匹配。煤层溶胀对渗透率的降低率(溶胀系数)为1/50 ~ 1/16。本研究使用ECLIPS (CBM选项)进行了数值模拟,采用双孔隙模型和Palmer & Mansoori模型来表达CO2吸附引起的微孔收缩导致的渗透率降低,称为煤基质膨胀。通过历史匹配研究估算CH4解吸时间和生产井底压力(BHP)。其他储层参数如孔隙压缩率、气水相对渗透率曲线等均是根据Yubari中试报告和Yamaguchi et al.(2007)、Pekot & Reeves(2002)的研究结果确定的。将CO2和CH4吸附量以及CO2和水的黏度随煤层温度(30 ~ 60℃)的变化规律进行了CO2注入率和CH4产能敏感性研究的数值模拟。最后,利用5点模型对不同井距下的CO2注入能力和CH4产能进行了数值模拟。结果表明:注CO2量与注注井数大致成正比,但最大CH4产速率时间随着含4口生产井的面积而延迟;从经济评价的角度出发,井的钻井成本和甲烷生产收益的累计现值是确定最佳井距的重要依据。
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引用次数: 1
Development of Grouting Material for Rehabilitations of Pipeline Using Flyash-Surfactant Cement Mixture Material 粉煤灰-表面活性剂水泥混合料修复管道注浆材料的研制
Pub Date : 2008-12-25 DOI: 10.2473/JOURNALOFMMIJ.124.794
Y. Yoshida, H. Shimada, T. Sasaoka, K. Matsui, M. Ichinose, S. Fujita, Masakazu Mineshita, T. Mizunuma
In recent years, many trenchless rehabilitations of pipeline that are considered of residents' living environment and mitigated the influence on traffic have been developed. Although the grouting material is required to make the established pipe and the lining material unify, it has high mobility etc. The grouting material using the material that was mixed the surface-active agent with the flyash was developed. Usage of flyash instead of cement leads to improving mobility, reducing construction cost and so on. In this paper, in order to examine the effect on ambient surroundings of the mixture material developed as grouting material, a fundamental investigation is performed and various these results are discussed.
近年来,在考虑居民生活环境和减轻对交通影响的基础上,开展了许多管道非开挖修复工程。虽然需要注浆材料使建立的管道与衬砌材料统一,但它具有高流动性等特点。研制了将表面活性剂与粉煤灰混合的灌浆材料。粉煤灰替代水泥具有提高流动性、降低施工成本等优点。为了考察作为注浆材料的混合材料对周围环境的影响,本文进行了基础研究,并对各种结果进行了讨论。
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引用次数: 0
Supporting Effects of Backfilling at the Hishikari Mine 石光矿回填支护效果研究
Pub Date : 2008-12-25 DOI: 10.2473/JOURNALOFMMIJ.124.765
Takahiko Kurakami, J. Yamatomi, R. Sato, Y. Sagawa, Shinsuke Murakami, Koji Tamada
The Hishikari Mine consists of epithermal vein type Au-Ag deposits. The veins are extracted mainly by drifting and bench stoping with backfill. Blasted waste rocks are generally used as backfilling materials and crushed waste rocks with cement are used for larger stopes. Although backfilling controls the displacement of excavation surface and increases the stope stability, practical evaluation for stope dimension in conjunction with backfilling effects is not established. In this study, supporting effects of stope ends were evaluated and available support lines were drawn by using a three-dimensional elastic finite element analysis. Based on available support lines, the properties of backfilling materials were evaluated. The behavior of rock mass in bench stoping was compared with a two-dimensional elasto-plastic finite element analysis. The results indicated more remarkable influence on the stope stability with the backfill stiffness. The Young's modulus of the backfilling materials containing cement at the Hishikari Mine changed from 10 MPa to 1 GPa by numerical analyses and field measurements.
石光矿为浅成热液脉状金银矿床。采出矿脉主要采用进路回采和台阶回采两种方法。爆破后的废石一般用作回填材料,较大的采场则采用水泥破碎后的废石。虽然回填控制了开挖面位移,提高了采场稳定性,但尚未建立结合回填效果的采场尺寸实用评价。采用三维弹性有限元分析方法,对采场端部的支护效果进行了评价,绘制了可行的支护线。在现有支护线的基础上,对回填材料的性能进行了评价。采用二维弹塑性有限元法对台阶回采过程中岩体的动态特性进行了比较。结果表明,充填体刚度对采场稳定性的影响更为显著。通过数值分析和现场实测,石光矿含水泥回填材料的杨氏模量从10 MPa变化到1 GPa。
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引用次数: 0
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Shigen-to-sozai
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