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Comparative Study of Mechanical and Physical Properties of Rice Husk Filled Polyethylene Waste Composites 稻壳填充聚乙烯废弃物复合材料力学与物理性能的比较研究
Pub Date : 2023-09-21 DOI: 10.24191/srj.v20i2.23506
Siti Nor Din
Polyethylene (PE), a type of plastic, is utilized extensively in many different applications and has become a significant part of our daily life. However, numerous plastic product manufactures have a significant environmental impact. As a result, several approaches have been investigated in order to reduce waste disposal issues. Rice husk (RH), on the other hand, is a form of agricultural waste that contains lignocellulosic fiber that can be used as a filler in polymer composites. As a result, combining both PE waste and RH fiber could be a viable option for saving our world. The objective of this study was to ascertain the impact of different RH fiber loadings, including 5, 10, 15, 20, and 25 %, on the mechanical and physical characteristics of composites manufactured from used HDPE and LDPE materials. Due to inadequate bonding between the hydrophilic fiber and the hydrophobic polymer matrix, it was discovered that increasing the filler loading lowered the tensile strength, elongation at break, and impact strength of the composites. In comparison to RH/HDPE, the tensile strength of RH/LDPE composites showed a greater decline at 45 % at the highest loading of 25 % RH fiber. Both composites showed a 98–99 % decrease in elongation at break as a result of constrained chain elongation and mobility. Additionally, the impact strength value of RH/HDPE waste composites decreased by 43 % compared to 31 % for RH/LDPE waste composites. In contrast, the inclusion of fillers improved the modulus and density of the composites substantially. While the trends for RH/HDPE and RH/LDPE composites are similar, RH/HDPE waste composites demonstrated superior mechanical characteristics than RH/LDPE waste composites.
聚乙烯(PE)是一种塑料,广泛应用于许多不同的应用领域,已成为我们日常生活中重要的一部分。然而,许多塑料制品制造商对环境产生了重大影响。因此,研究了几种方法,以减少废物处理问题。另一方面,稻壳(RH)是一种农业废弃物,它含有木质纤维素纤维,可以用作聚合物复合材料的填料。因此,将PE废物和RH纤维结合起来可能是拯救我们世界的可行选择。本研究的目的是确定不同的相对湿度纤维负荷,包括5%、10%、15%、20%和25%,对用HDPE和LDPE材料制造的复合材料的机械和物理特性的影响。研究发现,由于亲水性纤维与疏水性聚合物基体之间的结合不足,填料用量的增加会降低复合材料的抗拉强度、断裂伸长率和冲击强度。与RH/HDPE相比,在25% RH纤维的最高负荷下,RH/LDPE复合材料的拉伸强度下降了45%。两种复合材料的断裂伸长率都下降了98 - 99%,这是由于链伸长率和迁移率受到了限制。此外,相对于RH/LDPE废料复合材料的31%,RH/HDPE废料复合材料的冲击强度值下降了43%。相反,填料的加入大大提高了复合材料的模量和密度。虽然RH/HDPE和RH/LDPE复合材料的发展趋势相似,但RH/HDPE废料复合材料的机械性能优于RH/LDPE废料复合材料。
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引用次数: 0
Evaluation of the Moisture Management, Air and Water Vapour Permeabilities of Knitted Fabrics for Garments 服装用针织织物的水分管理、空气和水蒸气渗透性的评价
Pub Date : 2023-09-21 DOI: 10.24191/srj.v20i2.21920
Mohd Rozi Ahmad
The market today offers a variety of fabrics that may be utilised to create any style of clothing. Fabrics are periodically altered as a result of technology’s continual growth, to the point that it became difficult for clothes makers to assess the fabric characteristics related to thermal comfort. This paper reports some investigations on the moisture management and permeability properties of several commercial knitted fabrics intended for garment application. The fabric’s ability to manage moisture as well as its air and water vapour permeability were assessed. A fabric rating index was used to combine the results from each test to determine the fabric’s thermal comfort characteristics. Among the five knitted fabrics, the fabric comprised of nylon & polyester with jersey structure gave the highest assessment rating which is 5. The study serves as a future reference for future textile and garment industry, that implement the laboratory method used in this paper i.e moisture management, water vapour and air permeability in choosing the better thermal comfort qualities for general wear.
今天的市场提供了各种各样的面料,可以用来制作任何风格的衣服。由于技术的不断发展,面料会周期性地改变,以至于服装制造商很难评估与热舒适相关的面料特性。本文报道了几种用于服装的商用针织物的湿性和透气性的研究。织物的管理水分的能力,以及它的空气和水蒸气的渗透性进行了评估。织物评级指数是用来综合从每个测试的结果,以确定织物的热舒适特性。在五种针织面料中,尼龙面料;涤纶丝织物的评价等级最高,为5分。本研究可为未来纺织服装行业应用实验室方法,即湿度管理、水蒸气和透气性来选择较好的热舒适性服装提供参考。
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引用次数: 0
Characterization and Properties of Durian Skin Fiber Filled Polylactic Acid/Polypropylene Compatibilized with Glut Palmitate Salt 棕榈酸盐增容聚乳酸/聚丙烯填充榴莲皮纤维的表征及性能研究
Pub Date : 2023-09-21 DOI: 10.24191/srj.v20i2.21016
Sarina Mohamad
PLA matrix provides good mechanical, physical and degradability properties, but somehow PLA alone is not good enough to produce a product as PLA has poor toughness resulting a brittle material. Natural fiber such as Durian skin fiber (DSF) can be incorporated into PLA/PP as a biopolymer to achieve the desired properties and better degradation which resulting a good bio-composite. Therefore, the study was carried out to produce bio-composite of DSF filled with PLA/PP and glut palmitate (GP) salt as compatibilizer. The bio-composites was successfully developed using different filler (DSF) loadings (0 php, 15 php, 30 php, 45 php and 60 php) with melt mixing blending. The FTIR analysis showed the new peak existed at 1595 cm-1 revealed a good interaction in the composite system which come from the bending of NH2 vibration from GP. The mechanical properties (tensile properties) and physical properties (water absorption ability and density) of prepared bio-composite were determined. Increasing of DSF filler loading to 60 php DSF in PLA/PP bio-composite with the addition of GP increased in tensile strength (5.06 ± 0.09 MPa) and elongation at break (3.74 ± 0.18%) due to enhanced interfacial bonding and strong adhesion between the polymer matrix and the filler due to the presence of compatibilizer. However, increased filler loading to 60 php DSF, showed a decreasing trend in the tensile modulus which represents high flexibility of the bio-composites. Furthermore, PLA/PP/DSF bio-composites absorption of water increases with the increasing filler loading until it reaches at saturation point. The study concludes that the DSF reinforced PLA/PP with the addition of GP was suitable to be used in the production of bioplastic by many industries which can promote a sustainable environment for society.
PLA基体提供了良好的机械、物理和可降解性能,但由于PLA韧性差,导致材料脆性,因此单独PLA不足以生产产品。将天然纤维如榴莲皮纤维(DSF)作为生物聚合物掺入PLA/PP中,可以获得理想的性能和更好的降解性,从而得到良好的生物复合材料。为此,研究了以聚乳酸/聚丙烯(PLA/PP)填充DSF,并以过量棕榈酸盐(GP)为相容剂制备DSF生物复合材料。采用不同的填料(DSF)掺量(0 php、15 php、30 php、45 php和60 php)与熔体混合共混制备了生物复合材料。FTIR分析表明,在1595 cm-1处有一个新的峰,表明复合体系中有良好的相互作用,这是由GP产生的NH2振动的弯曲引起的。测定了制备的生物复合材料的力学性能(拉伸性能)和物理性能(吸水能力和密度)。在PLA/PP生物复合材料中加入GP后,DSF的抗拉强度(5.06±0.09 MPa)和断裂伸长率(3.74±0.18%)均有所提高,这是由于增容剂的存在增强了聚合物基体与填料之间的界面结合和强附着力。然而,当填充量增加到60 php DSF时,拉伸模量呈下降趋势,表明生物复合材料具有较高的柔韧性。此外,PLA/PP/DSF生物复合材料的吸水率随着填料量的增加而增加,直到达到饱和点。研究结果表明,添加GP的DSF增强PLA/PP可广泛应用于生物塑料的生产,促进社会环境的可持续发展。
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引用次数: 0
Revival of Ferromagnetic-Metallic Phase and Emergence of Griffiths Phase via Ni and Cr Substitution in Charged-Ordered Pr0.75Na0.25MnO3 Manganite 带电有序Pr0.75Na0.25MnO3锰矿中Ni和Cr取代铁磁金属相的还原和Griffiths相的出现
Pub Date : 2023-09-21 DOI: 10.24191/srj.v20i2.22185
Rozilah Rajmi
Polycrystalline samples of Pr0.75Na0.25Mn1-xAxO3 (A = Ni, Cr; x = 0, 0.03) were prepared using conventional solid-state method and their structural and magnetic properties were investigated. Monovalent-doped Pr0.75Na0.25MnO3 exhibits insulating behavior which is related to the strong localization of charge carriers due to the presence of charge ordering (CO). The substitution of different types of magnetic ions, A, which are Ni2+ and Cr3+, at a concentration of x = 0.03 at the Mn site in the CO Pr0.75Na0.25Mn1-xAxO3 manganite, has been found to dramatically modify its structural and magnetic properties. X-ray diffraction patterns showed that all samples were present in single phase and crystallized in orthorhombic structure with Pnma space group. The Rietveld refinement analysis showed that the unit cell volume increased due to Ni2+ substitution, while it decreased due to Cr3+ substitution, which may be attributed to the different ionic radii of both ions. The suppression of the CO state and the induction of the ferromagnetic-metallic state in the Ni-substituted and Cr-substituted samples are suggested to be due to the induction of double-exchange interaction involving Ni2+–O–Mn4+ and Mn3+–O–Cr3+, respectively. The variation in magnetic properties between the Ni-substituted and Cr-substituted samples is suggested to be due to the existence of different strengths of ferromagnetic interaction between Ni2+–O–Mn4+ and Mn3+–O–Cr3+. In addition, the deviation of the temperature dependence of the inverse magnetic susceptibility curves from the Curie-Weiss law suggests the existence of Griffith’s phase-like behaviour for both substitution samples. The Ni-substituted sample induced a greater GP effect than the Cr-substituted sample due to the larger difference of TC and TG value (TC-TG).
Pr0.75Na0.25Mn1-xAxO3 (A = Ni, Cr)多晶样品X = 0, 0.03),并对其结构和磁性能进行了研究。单价掺杂的Pr0.75Na0.25MnO3表现出绝缘行为,这与电荷有序(CO)的存在导致载流子的强局域化有关。在CO Pr0.75Na0.25Mn1-xAxO3锰矿中,不同类型的磁性离子A (Ni2+和Cr3+)以x = 0.03的浓度取代Mn位,可以显著改变其结构和磁性能。x射线衍射图显示,所有样品均为单相,结晶为具有Pnma空间群的正交结构。Rietveld细化分析表明,Ni2+的取代使晶胞体积增大,而Cr3+的取代使晶胞体积减小,这可能是由于两种离子的离子半径不同所致。在ni -取代和cr -取代的样品中,CO态的抑制和铁磁金属态的诱导可能是由于分别诱导了Ni2+ -O-Mn4 +和Mn3+ -O-Cr3 +的双交换相互作用。ni取代和cr取代样品的磁性能变化可能是由于Ni2+ -O-Mn4 +和Mn3+ -O-Cr3 +之间存在不同强度的铁磁相互作用。此外,磁化率反曲线的温度依赖性与居里-魏斯定律的偏差表明,两种替代样品都存在Griffith类相行为。由于TC和TG值(TC-TG)的差异较大,ni取代的样品比cr取代的样品产生更大的GP效应。
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引用次数: 0
The Effect of Superplasticizer (SP) on the Workability and Skid Resistance of Geopolymer Concrete (GPC) Containing High Calcium Precursor (HCP) 高效减水剂(SP)对含高钙前驱体(HCP)地聚合物混凝土(GPC)和易性和抗滑性的影响
Pub Date : 2023-09-21 DOI: 10.24191/srj.v20i2.22141
Nazirah Mohd Apandi
A superplasticizer (SP) is one of the admixtures that may be used to improve the workability of concrete. However, its effects on geopolymer concrete (GPC) have yet to be well known or published, especially regarding its skid resistance and workability performance. This research aims to study the impact of the superplasticizer on the skid resistance and workability of geopolymer concrete containing high calcium precursor (HCP) in different proportions of SP, which are 0, 0.5, 1.0, 1.5 and 2.0 % by the weight of the HCP. Seven mix designs were produced: 1 conventional concrete mix, 5 geopolymers concrete mix, and 1 bituminous cold-mix asphalt mix. Slump flow and skid resistance tests were performed in this study. A skid resistance test is achieved using a British Pendulum Tester (BPT) on a 220 mm x 220 mm x 50 mm rectangle. This study found that the effect of SP on skid resistance is insignificant. However, the skid resistance of all GPC mix designs is higher than CC and asphalt mix. The workable flow of geopolymer concrete containing HCP and 0 - 2 % SP was 118-123 mm. However, less than 2 % of SP is given an insignificant difference. The optimum mix design of GPC is mix design GPC with an added 2 % SP (M6) that gives a high workability compared to other GPC mix designs and good skid resistance of 95 BPN. This study also found that workability correlates with skid resistance. The higher the spreading width value, the smaller the skid resistance value. In other words, the higher the flowability value, the less rough the sample surface. Hypothetically, the higher the percentage of SP, the higher the workability and the lower the skid resistance.
高效减水剂(SP)是一种可用于改善混凝土和易性的外加剂。然而,其对地聚合物混凝土(GPC)的影响尚未众所周知或发表,特别是关于其防滑性和和易性性能。本研究的目的是研究高钙原体(HCP)在不同SP(高钙原体质量比为0、0.5、1.0、1.5和2.0%)掺量下,高效减水剂对高钙原体(HCP)地聚合物混凝土的抗滑性和和易性的影响。共设计了7种配合比:1种常规混凝土配合比,5种地聚合物混凝土配合比,1种沥青冷拌沥青配合比。在本研究中进行了坍落性流动和防滑性试验。使用英国摆锤试验机(BPT)在220mm × 220mm × 50mm的矩形上进行防滑测试。本研究发现SP对防滑性能的影响不显著。然而,所有GPC混合料设计的抗滑性都高于CC和沥青混合料。含HCP和0 ~ 2% SP的地聚合物混凝土的工作流量为118 ~ 123 mm。然而,小于2%的SP是不显著的差异。GPC的最佳配合比设计是添加2% SP (M6)的GPC配合比设计,与其他GPC配合比设计相比,该配合比具有较高的可加工性,并且具有良好的抗滑性(95bpn)。该研究还发现,可加工性与防滑性相关。铺展宽度值越高,防滑性值越小。换句话说,流动性值越高,样品表面越不粗糙。假设SP含量越高,可加工性越高,防滑性越低。
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引用次数: 0
Extraction of Phytochemical from Murraya Koenigii (L.) Spreng Leaves using Maceration Method 锦葵中植物化学成分的提取用浸渍法洗嫩叶
Pub Date : 2023-09-21 DOI: 10.24191/srj.v20i2.23459
Saliza Asman
Curry leaves, scientifically known as Murraya koenigii (L.) Spreng is employed as a flavoring agent in a wide range of dishes and possesses the potential for treatment due to its content of flavonoid, steroid, and phenolic compounds. These compounds exhibit antioxidant and antibacterial properties. In this work, the extraction of phytochemicals from M. koenigii leaves was satisfactorily performed. The extraction process was conducted using a maceration technique with three different solvents: 95 % ethanol, 99 % acetone, and 96 % methanol individually. The qualitative and quantitative of existing phytochemicals compounds in the M. koenigii leaves were analyzed through phytochemical screening and gas chromatography-mass spectrometry (GCMS). The percentage yield shows 21.42 % of methanolic extracts, 6.50 % of acetone extracts, and 11.66 % of ethanolic extracts. The major compounds present from screening phytochemicals are terpenoid, phenolic, glycoside, and saponin. GC-MS result showed the major compounds present in M. koenigii leaves are terpene, terpenoid, carotenoid and alkaloid.
咖喱叶,科学上称为Murraya koenigii。春天被用作各种菜肴的调味剂,由于其类黄酮、类固醇和酚类化合物的含量,它具有治疗的潜力。这些化合物具有抗氧化和抗菌的特性。本研究对柯尼希叶中植物化学物质的提取进行了满意的研究。提取工艺采用浸提技术,浸提溶剂分别为95%乙醇、99%丙酮和96%甲醇。采用植物化学筛选和气相色谱-质谱联用技术对柯氏叶中存在的植物化学成分进行了定性和定量分析。甲醇提取物得率为21.42%,丙酮提取物得率为6.50%,乙醇提取物得率为11.66%。筛选的植物化学物质主要有萜类、酚类、糖苷类和皂苷类。气相色谱-质谱分析结果表明,山参叶中主要化合物为萜烯、萜类、类胡萝卜素和生物碱。
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引用次数: 0
Dual-axis Solar Energy Tracking and Monitoring System with Arduino as a Microcontroller 以Arduino为微控制器的双轴太阳能跟踪监测系统
Pub Date : 2023-09-21 DOI: 10.24191/srj.v20i2.22365
Mohd Sufian Ramli
As an inexhaustible and non-polluting energy source of the future, solar energy is improving to meet the world's ever-increasing energy demands. In this project, the solar panel is made movable to absorb energy in different directions based on the direction of the sun to maximize the amount of energy generated by solar photovoltaic system. Four Light Dependent Resistors (LDRs), a voltage sensor and a set of humidity and temperature sensor are acting as inputs. Meanwhile, two servo motor outputs are placed in the horizontal and vertical axes to maximize power absorption by orienting the PV panel towards the varying sun directions. The Arduino Mega2560 was used as the microcontroller that controls the inputs to make sure the outputs are operating as required. Apart from the servo motors, another important feature of the project includes the monitoring unit for the system which comprises of the LCD display and Microsoft Excel Data Streamer.
作为一种取之不尽、用之不竭、无污染的未来能源,太阳能正在不断发展,以满足世界日益增长的能源需求。在这个项目中,太阳能电池板是可移动的,可以根据太阳的方向吸收不同方向的能量,最大限度地利用太阳能光伏系统产生的能量。四个光相关电阻(ldr),一个电压传感器和一组湿度和温度传感器作为输入。同时,两个伺服电机输出分别放置在水平轴和垂直轴上,通过将光伏板朝向不同的太阳方向来最大限度地吸收能量。Arduino Mega2560被用作控制输入的微控制器,以确保输出按要求运行。除了伺服电机外,该项目的另一个重要特点包括系统的监控单元,该单元由LCD显示器和Microsoft Excel Data Streamer组成。
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引用次数: 0
Effect of High Calcium Precursor (HCP) Content on Bonding Strength of Geopolymer Concrete Exposed at Different Curing Temperatures 高钙原体(HCP)含量对不同养护温度下地聚合物混凝土粘结强度的影响
Pub Date : 2023-09-21 DOI: 10.24191/srj.v20i2.22142
Warid Wazien Ahmad Zailani
Geopolymer is a green cementitious binder that can be used to replace Portland cement binder and possesses exceptional physical, mechanical, and durability properties. Its mechanical properties such as bonding strength against the substrate were comparable to the Portland cement based repair products which can provide high durability and adhesive strength to the repaired structure. Geopolymer comprises two primary components which are the precursor and alkali activator. High Calcium Precursor (HCP) is the new repair material that was developed by Innovation Construction Materials (INCOM) Research Group to be used as a geopolymer’s precursor in Malaysia. In this research, the effect of HCP contents on the bonding strength of geopolymer concrete was assessed at different curing conditions. Based on the result, it was found that 100 g of HCP gave an optimum bonding strength of 21.3 MPa after 28 days of normal curing. In addition, in this research, the bonding strength also was measured after the geopolymer/substrate composite was exposed at different temperatures (60, 80, and 100 ⁰C). The bonding strength between HCP based geopolymer and the substrate does not significantly affected by the temperature’s exposure. Hence, HCP showed a high potential to be used as a precursor for geopolymer production.
地聚合物是一种绿色胶凝粘结剂,可替代硅酸盐水泥粘结剂,具有优异的物理、机械和耐久性。其机械性能,如与基材的结合强度与波特兰水泥基修复产品相当,可以为修复结构提供高耐久性和粘合强度。地聚合物包括两个主要组分:前驱体和碱活化剂。高钙前体(HCP)是由创新建筑材料(INCOM)研究小组开发的用于马来西亚地聚合物前体的新型修复材料。本研究考察了不同养护条件下HCP含量对地聚合物混凝土粘结强度的影响。结果表明,100g HCP在正常养护28天后的最佳粘结强度为21.3 MPa。此外,在本研究中,还测量了地聚合物/基质复合材料在不同温度(60摄氏度、80摄氏度和100摄氏度)下暴露后的结合强度。温度对HCP基地聚合物与基体的结合强度影响不显著。因此,HCP显示出作为地聚合物生产前驱体的巨大潜力。
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引用次数: 0
SONLU SAYDA NÖQTƏLƏRİNDƏN YANA DARTILARAQ YÜKLƏR ASILMIŞ BİRCİNS SİMİN MƏRKƏZLƏŞMİŞ QÜVVƏNİN TƏSİRİ ALTINDA YERDƏYİŞMƏSİ
Pub Date : 2023-07-01 DOI: 10.36719/2789-6919/23/28-38
Zəfər Abbasov
{"title":"SONLU SAYDA NÖQTƏLƏRİNDƏN YANA DARTILARAQ YÜKLƏR ASILMIŞ BİRCİNS SİMİN MƏRKƏZLƏŞMİŞ QÜVVƏNİN TƏSİRİ ALTINDA YERDƏYİŞMƏSİ","authors":"Zəfər Abbasov","doi":"10.36719/2789-6919/23/28-38","DOIUrl":"https://doi.org/10.36719/2789-6919/23/28-38","url":null,"abstract":"","PeriodicalId":21751,"journal":{"name":"Scientific Research Journal","volume":"3 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81282607","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
İRSİYYƏT, AİLƏ, ƏTRAF ALƏM, MƏKTƏB VƏ TƏHSİLİN VƏHDƏTİNDƏ FƏRDİN SOSİALLAŞMASI VƏ ŞƏXSİYYƏT PROBLEMİ
Pub Date : 2023-07-01 DOI: 10.36719/2789-6919/23/7-19
Kərim Novruzov
{"title":"İRSİYYƏT, AİLƏ, ƏTRAF ALƏM, MƏKTƏB VƏ TƏHSİLİN VƏHDƏTİNDƏ FƏRDİN SOSİALLAŞMASI VƏ ŞƏXSİYYƏT PROBLEMİ","authors":"Kərim Novruzov","doi":"10.36719/2789-6919/23/7-19","DOIUrl":"https://doi.org/10.36719/2789-6919/23/7-19","url":null,"abstract":"","PeriodicalId":21751,"journal":{"name":"Scientific Research Journal","volume":"19 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82373158","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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