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Exfoliated graphite as electrochemical double layer capacitor electrode: Electrochemical impedance study 剥落石墨作为电化学双层电容器电极:电化学阻抗研究
Pub Date : 2021-01-09 DOI: 10.4038/SLJP.V22I1.8077
D. S. K. Rajaguru, K. Vidanapathirana, K. Perera
Exfoliated graphite (EG) is one of the best alternatives for graphene in the electrochemical devices since graphene needed a cost-effective mass production to reach the commercialization. Liquid phase exfoliation has been identified as an inexpensive, ecofriendly method for high quality EG production. Sri Lankan natural graphite and commercially available graphite were used for exfoliation and the converted EG samples were used to fabricate electrochemical double layer capacitors (EDLCs). They were characterized using Electrochemical Impedance Spectroscopy (EIS). EG prepared by Sri Lankan natural graphite showed higher specific capacitance values compared with commercial graphite EG. Thereby, the value of Sri Lankan graphite over commercial graphite was emphasized.
由于石墨烯需要低成本的量产才能实现商业化,因此剥离石墨(EG)是石墨烯在电化学器件中的最佳替代品之一。液相剥脱法已被认为是一种廉价、环保的生产高质量EG的方法。采用斯里兰卡天然石墨和市售石墨进行剥离,转化后的EG样品用于制备电化学双层电容器(edlc)。用电化学阻抗谱(EIS)对其进行了表征。斯里兰卡天然石墨制备的导电石墨比电容值高于商用石墨导电石墨。因此,斯里兰卡石墨比商业石墨的价值被强调。
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引用次数: 1
Mechanical property evaluation of natural rubber/ vein graphite composites 天然橡胶/脉状石墨复合材料力学性能评价
Pub Date : 2021-01-09 DOI: 10.4038/SLJP.V22I1.8082
M. P. Viyanage, T. R. T. Manage, R.C.L. De Silva, L. Nayanajith, M. Milani, I. Kottegoda
Vein graphite filled natural rubber composites were prepared by keeping the total weight of composites constant in each using suitable dispersant, accelerators, and coagulants to use in high-end applications. All the composites were characterized by using X-ray diffraction (XRD), scanning electron microscopy (SEM), and Fourier transform infrared spectroscopy (FTIR). The tensile properties, Young’s modulus and hardness of the composites were evaluated. XRD and FTIR analysis verified the presence of rubber and graphite in the composites without any noticeable structural changes. The SEM image of composites showed a uniform homogeneous surface of the composites. High tensile strength was observed at 10% of graphite incorporation in natural rubber. Young’s moduli and hardness of composites were observed to be improved with the addition of the dispersed graphite. The hardness of the composites increases with increasing graphite in the composite and optimized at 60% of graphite. The properties of natural rubber/graphite investigated in the present study is useful for many applications including electronic devices, aerospace, automobiles, toys, heavy equipment industry, battery, consumer products, etc.
采用合适的分散剂、促进剂和混凝剂,在保持复合材料总重量不变的情况下,制备了脉状石墨填充天然橡胶复合材料,用于高端应用。采用x射线衍射(XRD)、扫描电镜(SEM)和傅里叶变换红外光谱(FTIR)对复合材料进行了表征。测试了复合材料的拉伸性能、杨氏模量和硬度。XRD和FTIR分析证实复合材料中存在橡胶和石墨,但没有明显的结构变化。复合材料的SEM图像显示复合材料表面均匀。天然橡胶中石墨掺入量为10%时,抗拉强度较高。分散石墨的加入提高了复合材料的杨氏模量和硬度。复合材料的硬度随复合材料中石墨含量的增加而增加,并在石墨含量为60%时达到最佳。本研究研究的天然橡胶/石墨的性能可用于电子器件、航空航天、汽车、玩具、重型设备工业、电池、消费品等领域。
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引用次数: 2
Solutions of Klein-Gordon equation for the modified central complex potential in the symmetries of noncommutative quantum mechanics 非对易量子力学对称性中修正中心复势的Klein-Gordon方程解
Pub Date : 2021-01-09 DOI: 10.4038/SLJP.V22I1.8079
A. Maireche
We explore the new analytical solutions for both bound and the new masses of mesons of the Klein–Gordon equation with the modified central complex potential, which describes the heavy light Ǭq, (Q = c, q = u/d, s) mesons and the quarkonium system ǭǭ, (q=c, b, s) via the standard Bopp’s shift method and standard perturbation theory.We have obtained the energy eigenvalues of the ground state E(0)nc(a, b, 0, j, l, m) the first excited state E(1)nc(a, b, 1, j, l, m) and pth  the excited state E(p)nc(a, b, p, j, l, m) in terms of the shift energy (ΔEcc(0, j, l, s, m), ΔEcc(1,j,l,s,m) and ΔEcc(p, j, l, s, m) and (E0l, E1l and Enl)) of ordinary relativistic quantum mechanics. In addition to the parabolic cylinder functions, the Gamma function, the discreet atomic quantum numbers (j, l, s, m) the potential parameters (a and b) and the noncommutativity parameters (θ and σ). In the second part of the research, we will apply the obtained results to calculate the new masses of the mentioned previously mesons in the symmetries of the relativistic three-dimensional noncommutative quantum mechanics. Moreover, some important special cases in the context of the symmetries of the relativistic three-dimensional noncommutative quantum mechanics are treated.
本文通过标准Bopp位移法和标准微扰理论,探讨了描述重轻介子Ǭq, (Q =c, Q = u/d, s)和夸克系统ǭǭ, (Q =c, b, s)的修正中心复势Klein-Gordon方程的束缚介子和新介子质量的新解析解。我们得到了基态E(0)nc(a, b, 0, j,l, m)的能量特征值,第一激发态E(1)nc(a, b, 1,j,l, m)和第五激发态E(p)nc(a, b, p, j,l, m)的位移能量(ΔEcc(0, j,l,s,m), ΔEcc(1,j,l,s,m)和ΔEcc(p, j,l,s,m)和(E0l, E1l和Enl))。除了抛物柱面函数外,还有伽马函数、离散原子量子数(j, l, s, m)、势参数(a和b)以及非交换性参数(θ和σ)。在第二部分的研究中,我们将利用所得结果计算上述介子在相对论性三维非交换量子力学对称性中的新质量。此外,在相对论性三维非交换量子力学的对称性背景下,处理了一些重要的特殊情况。
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引用次数: 22
A theoretical investigation of nonrelativistic bound state solution at finite temperature using the sum of modified Cornell plus inverse quadratic potential 有限温度下非相对论束缚态解的修正Cornell加逆二次势和的理论研究
Pub Date : 2020-05-29 DOI: 10.4038/sljp.v21i1.8069
A. Maireche
New modified nonrelativistic bound state energy eigenvalues have been obtained for the hydrogenic atoms with spin ½ under the sum of modified Cornell plus inverse quadratic potential (MCIQP), at finite temperature, in the symmetries of the noncommutative three-dimensional real space phase (NC: 3D-RSP). The ordinary sum of Cornell plus inverse quadratic potential is extended by including new central terms to become MCIQP. In addition, MCIQP is suggested as a quark–antiquark interaction potential for studying the masses of heavy and heavy–light mesons in (NC: 3D-RSP), in which the potential satisfies the features of quantum chromodynamics theory of strong interaction. For this purpose, the modified radial Schrodinger equation is analytically solved using the generalized Bopp’s shift method and standard perturbation theory. The energy eigenvalues and the corresponding new Hamiltonian operator are obtained in (NC: 3D-RSP). These results are applied to calculate the mass of mesons such as charmonium, bottomoniumand mesons with spin (0 or 1). In a thermal medium of a positive temperature, the new parameters of the studied potential MCIQP become temperature dependent because of color screening. It is found that the perturbative solutions of the discrete spectrum can be expressed on the Gamma function, the discreet atomic quantum numbers  and the potential parameters (), in addition to noncommutativity parameters (and). The influence of the induced magnetic field and the coupling parameter of the spin field on some quantum properties of the system have also been studied. The total complete degeneracy of modified energy levels under MCIQP is found to be equal to , which gives a very good indicator that our new treatments produce clear energy values when compared with similar energy levels obtained in ordinary relativistic quantum mechanics (RQM). New mass spectra for the quarkonium systems is found to be equal to the sum of ordinary values in RQM plus two perturbative terms proportional to the parameters (or) and (or) of noncommutativity space-phase. These results are in good agreement with the already existing results in nonrelativistic noncommutative quantum mechanics (NRNCQM) where the physical treatment was done using other potentials such as new modified potential containing Cornell, Gaussian and inverse square terms and modified quark-antiquark interaction potential.
在非对易三维实空间相对称(NC: 3D-RSP)的有限温度下,得到了自旋为1 / 2的氢原子在修正Cornell +逆二次势(MCIQP)和下新的修正非相对论束缚态能量特征值。通过引入新的中心项,扩展了Cornell和逆二次势的普通和,成为MCIQP。此外,MCIQP被认为是研究(NC: 3D-RSP)中重介子和重-轻介子质量的夸克-反夸克相互作用势,该势满足量子色动力学强相互作用理论的特征。为此,利用广义Bopp位移法和标准摄动理论对修正径向薛定谔方程进行了解析求解。在(NC: 3D-RSP)中得到了能量特征值和相应的新哈密顿算子。这些结果应用于计算介子的质量,如介子,底介子和自旋(0或1)的介子。在正温度的热介质中,由于颜色筛选,所研究的潜在MCIQP的新参数变得依赖于温度。发现离散谱的微扰解可以用Gamma函数、离散原子量子数和势参数()以及非交换性参数(和)来表示。研究了感应磁场和自旋场耦合参数对系统某些量子特性的影响。发现MCIQP下修正能级的总完全简并等于,这很好地表明,与普通相对论量子力学(RQM)中得到的类似能级相比,我们的新处理产生了清晰的能量值。发现夸克系的新质谱等于RQM中的普通值加上与非交换空间相的参数(或)和(或)成比例的两个微扰项的和。这些结果与非相对论性非交换量子力学(NRNCQM)中已经存在的结果很好地一致,其中使用其他势进行物理处理,例如包含康奈尔,高斯和逆平方项的新修正势以及修正的夸克-反夸克相互作用势。
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引用次数: 22
Appraisal of mechanical properties of different particle sizes of palm kernel shell, coconut shell and mixed palm kernel-coconut shells particles epoxy-filled composites 不同粒径棕榈仁壳、椰子壳及棕榈仁-椰子壳混合颗粒环氧复合材料力学性能评价
Pub Date : 2020-02-07 DOI: 10.4038/sljp.v21i1.8071
A. B. Alabi, M. A. Salawu, R. Jimoh, T. Akomolafe
This study presents the appraisal of indentation hardness and flexural modulus of composites prepared by mixing particles of palm kernel shell (PKS), coconut shell (CNS) and mixtures of palm kernel-coconut shell (MPKCNS) of different sizes (35.5 μm, 75 μm and 106 μm) with epoxy and hardener for various applications. The Rockwell hardness tester results showed that PKS particles epoxy filled composites of 35.5 μm had the highest hardness number of 77 while the MPKCNS particles epoxy filled composites of 106 μm had the least hardness number of 43. The CNS particles epoxy filled composites of 35.5 μm and 75 μm had relatively higher flex moduli of 428.66 MPa and 425.55 MPa respectively. The particle size of 106 μm had relatively higher flexure extension than 35.5 μm and 75 μm. The Scanning Electron Microscope (SEM) analysis revealed proper adhesion of the shell particles and epoxy resins with little or no pores in the composites. The PKS particles epoxy filled composites of 35.5 μm can be employed to enhance the mechanical properties of the composites for engineering applications.
研究了棕榈仁壳(PKS)、椰子壳(CNS)颗粒以及不同粒径(35.5 μm、75 μm和106 μm)棕榈仁-椰子壳(MPKCNS)颗粒与环氧树脂和硬化剂混合制备的复合材料的压痕硬度和弯曲模量。洛氏硬度测试结果表明,35.5 μm的PKS颗粒环氧树脂填充复合材料的硬度值最高,为77,而106 μm的MPKCNS颗粒环氧树脂填充复合材料的硬度值最低,为43。CNS颗粒填充35.5 μm和75 μm的复合材料的弯曲模量相对较高,分别为428.66 MPa和425.55 MPa。106 μm的颗粒比35.5 μm和75 μm的颗粒具有更高的挠曲延伸率。扫描电镜(SEM)分析表明,复合材料的壳颗粒与环氧树脂的粘附良好,孔隙很少或没有。采用35.5 μm的PKS颗粒填充环氧复合材料可以提高复合材料的力学性能,具有工程应用价值。
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引用次数: 2
Influence of Non -thermal Electron Parameter on Heavier Masses of Negative Ion Plasma 非热电子参数对重质量负离子等离子体的影响
Pub Date : 2019-03-28 DOI: 10.4038/SLJP.V20I0.8062
Sankar Chattopadhyay
In presence of non-thermal electrons, theoretical investigations on ion-acoustic solitary waves are made in a collisionless unmagnetized warm plasma consisting of positive and negative ions by the well known pseudopotential technique. The influence of non-thermal electron parameter on heavier masses (Q) of negative ion plasma for Sagdeev potential function, first and second order solitary wave solutions are mainly analysed and discussed here properly.
在非热电子存在的情况下,利用伪势技术对由正负离子组成的无碰撞非磁化热等离子体中的离子声孤波进行了理论研究。本文主要对Sagdeev势函数、一阶和二阶孤波解的非热电子参数对负离子等离子体重质量Q的影响进行了分析和讨论。
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引用次数: 1
Applicability of natural rubber based polymer electrolyte for electrochemical double layer capacitors 天然橡胶基聚合物电解质在电化学双层电容器中的适用性
Pub Date : 2019-03-28 DOI: 10.4038/SLJP.V20I0.8067
N. Sanjaya, K. Perera, K. Vidanapathirana
Natural rubber has received a great interest to be used for electrochemical applications recently. But, Sri Lankan natural rubber has not yet been considered for such activity other than exporting and using for some manufacturing processes. Main objective of the present study is investigating the candidacy of Sri Lankan natural rubber in electrochemical double layer capacitors. Methyl grafted natural rubber was dissolved in tetrahydrofuran and it was later mixed with a Li salt. Using the solvent casting method, it was possible to prepare a thin, bubble free film. It was sandwiched in between two identical Sri Lankan natural graphite electrodes. Performance evaluation was accomplished with cyclic voltammetry, electrochemical impedance spectroscopy and galvanostatic charge discharge test. Single electrode specific capacitance was depending on the potential window and the scan rate of cycling. Nyquist plots confirmed the capacitive behavior at low frequency region. The average specific discharge capacity was 0.31 Fg-1. Obtained results show that natural rubber electrolytes are suitable candidates for electrochemical double layer capacitors and they are also encouraging to proceed towards improving the performance further.
近年来,天然橡胶在电化学领域的应用受到了极大的关注。但是,除了出口和用于某些制造过程之外,斯里兰卡的天然橡胶尚未被考虑用于此类活动。本研究的主要目的是研究斯里兰卡天然橡胶在电化学双层电容器中的候选性。将甲基接枝天然橡胶溶解在四氢呋喃中,然后与Li盐混合。采用溶剂铸造法,可以制备一种薄的无气泡薄膜。它被夹在两个完全相同的斯里兰卡天然石墨电极之间。通过循环伏安法、电化学阻抗法和恒流充放电试验对其性能进行了评价。单电极比电容取决于电位窗口和循环扫描速率。Nyquist图证实了其在低频区的电容性。平均比放电容量为0.31 Fg-1。研究结果表明,天然橡胶电解质是电化学双层电容器的理想材料,具有进一步提高其性能的潜力。
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引用次数: 2
Approximate l-States Solutions to the Schrodinger Equation with Manning-Rosen plus Hellmann Potential via WKB Approximation Scheme 用WKB近似格式逼近具有Manning-Rosen加Hellmann势的薛定谔方程的l态解
Pub Date : 2018-08-08 DOI: 10.4038/SLJP.V19I1.8050
I. I. Benedict, H. Louis, Nzeata-Ibe Nelson, A. Ikeuba, Akakuru U. Ozioma, Magu O. Thomas, Amos I. Pigweh, M. O. Michael
The approximate analytical solutions of the radial Schrodinger equation have been obtained by the interaction of Manning-Rosen and Hellmann potentials which is a newly proposed potential. Using the Wentzel-Kramers-Brillouin WKB approach, we obtained the eigenstates solutions for any arbitrary angular momentum. Special cases of potential consideration have been discussed. Eigenenergy solutions to equations obtained play an important role in quantum mechanics because they contain a wealth of vital information regarding the system under consideration.
利用mann - rosen势和Hellmann势的相互作用,得到了径向薛定谔方程的近似解析解,这是一种新提出的势。利用Wentzel-Kramers-Brillouin WKB方法,我们得到了任意角动量的本征态解。讨论了可能考虑的特殊情况。所得到的方程的本征能解在量子力学中起着重要的作用,因为它们包含了关于所考虑的系统的大量重要信息。
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引用次数: 11
Dirac Equation with Unequal Scalar and Vector Potentials under Spin and Pseudospin Symmetry 自旋和伪自旋对称下标量势和矢量势不等的狄拉克方程
Pub Date : 2018-05-15 DOI: 10.4038/SLJP.V19I1.8043
Atachegbe Clement Onate, A. Ikot, M. Onyeaju, O. Ebomwonyi
An approximate solution of the Dirac equation in the D-dimensional space is obtained under spin and pseudospin symmetry limits for the scalar and vector inversely quadratic Yukawa potential within the framework of parametric Nikiforov-Uvarov method using a suitable approximation scheme to the spin-orbit centrifugal term. The two components spinor of the wave function and their energy equations are fully obtained. Some numerical results are obtained for the energy level with various dimensions (D), quantum number (n), vector potential V0 and scalar potential S0 . The results obtained under spin symmetry using either V0 or S0 are equal to the results obtained usingV S 0 0  . But under the pseudospin symmetry, the results obtained using V0 or S0 are not equal to the results obtained usingV S 0 0  .
在参数化Nikiforov-Uvarov方法的框架下,利用自旋-轨道离心项的适当逼近格式,得到了标量和矢量逆二次Yukawa势在自旋和伪自旋对称极限下的d维空间Dirac方程的近似解。得到了波函数的两分量旋量及其能量方程。得到了不同维能级(D)、量子数(n)、矢量势V0和标量势S0的一些数值结果。在自旋对称下使用V0或S0得到的结果等于使用vs0 0得到的结果。但在赝自旋对称下,使用V0或S0得到的结果不等于使用vs0 0 0 +得到的结果。
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引用次数: 2
Approximate Analytical Solutions of the Effective Mass Klein-Gordon Equation for Two Interacting Potentials 两个相互作用势的有效质量Klein-Gordon方程的近似解析解
Pub Date : 2018-02-15 DOI: 10.4038/SLJP.V19I1.8042
O. Ebomwonyi, Atachegbe Clement Onate, M. Onyeaju, J. O. Okoro, M. Oluwayemi
In this study, the approximate analytical solutions of the relativistic Klein-Gordon equation in the spatial dimensions with unequal Coulomb-inverse Trigonometry scarf scalar and vector potentials for an effective mass function is investigated in the framework of supersymmetric and shape invariance method by employing a suitable approximation scheme to the centrifugal term. The energy equation for some special cases such as the Coulomb potential and inverse Trigonometry scarf potential are obtained. Using a certain transformation, the non-relativistic energy equation is obtained which is identical to the energy equation of the Hellmann potential.
本文采用离心项的适当近似格式,在超对称和形状不变性方法的框架下,研究了具有不等库仑反三角标量势和矢量势的相对论Klein-Gordon方程在有效质量函数的空间维度上的近似解析解。得到了库仑势和反三角围巾势等特殊情况下的能量方程。通过一定的变换,得到了与赫尔曼势能量方程相同的非相对论性能量方程。
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引用次数: 0
期刊
Sri Lankan Journal of Physics
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